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By Wright S, Rogers L. J, Precious T. H

Brown coal and its char were investigated as substitutes for petroleum coke in the manufacture of anodes for Hall-Heroult cells. The char, which had been densified by several techniques, was made into compacts with various binders and the anodic consumption determined during electrolysis. The results were an improvement on previous work, but the anodes still fell short of acceptability for use in aluminium smelters because of intractable microporosity. Some options for future development have been discounted.

Jan 1, 1986

Supercritical fluids are gases compressed to near liquid densities and, as such, have unique properties compared to liquids: low viscosity; zero latent heat; high diffusivity and pressure-dependent, solvation characteristics. These properties are being utilised in new processes and current research is delineating areas where such processes may be applicable to extractive metallurgy. The processes and areas of interest are as follows: Supercritical Fluid Extraction in which substrates are dissolved at high pressure and fractionated at successively lower pressures. Areas of interest include extraction of organic materials for regeneration of activated carbon for the CIP process and for upgrading alumina industry products and, separation of transition metal chlorides. ò Supercritical Water Oxidation in which high pressure gaseous water acts as a medium in which substrates are oxidised while suspended or dissolved. This process may be of use for oxidation of organics in Bayer liquor and oxidation of mine waters etc. ò Supercritical Fluid Reactions where reactions occur in a supercritical fluid medium, particularly when the medium itself is a reactant. This may be of use in treating refractory or carbon-aqueous auriferous ores and in lower-temperature chlorination of transition metal oxides. Research is described which is aimed at chlorination and separation of transition metal oxides by two supercritical operations.

Jan 1, 1991

By Ariti J

The mineralogy and extractive metallurgy of platinum and palladium in ores and residues is examined and the relative reactivity of Pt, Pd, PtS and PdS in cyanide and chloride media at 20¦C is discussed. Electrochemical measurements establish that Pd is readily leached in chloride media but more slowly in cyanide media due to a passivating PdO film. The passivating oxide film on Pt prevents leaching in either system at ambient temperatures. The results of leaching Au, Pd and Pt from an iron oxide residue obtained from the Sherritt Gordon Process using CN/air and Cl-/H202 are compared. It appears that passivation is overcome either by roasting at ?600¦ or by leaching at >_100¦C.

Jan 1, 1991

Present knowledge of the Pacific floor in- dicates: Postulated subduction zones and/or moving basements overlain by undisturbed sediments. Contiguous mantle convections of conflict ing directions and variable rates. Disharmony between transform faults and mantle convections. =hese features are shown to be difficult to reconcile with conventional hypotheses of sea f 1mr spreading and cast the model into serious doubt.

Jan 1, 1987

Process variables in flotation circuits are outlined with a view to producing mathematical models of circuits. The nature of the kinetics of flotation are discussed and the effect of process variables on the kinetics considered. An approach for a possible model is briefly outlined.

Jan 1, 1971

A shift in the present day oil exploration scenario from West Coast can be foreseen keeping in mind peak of exploration in Cambay Basin and fast pace of development in Bombay High and its associated fields by the end of this century. Shifts in exploration from structural traps to stratigraphic traps, techno- logical development to drill in deep waters, improving economic situation for oil ventures and proven oil and gas potential of East Coast basins suggest that Indian oil explorat- ion scene will be at its peak along east coast during early 21st century. Hydrocarbon shows in Poonch and Jawalamukhi in Punjab Basin, improvements in drilling to greater depths, better seismic data aquisition, good source rock potential of Subathus and its equivalents and large geologi- cally mapped structures will reopen new avenues for explorationists. Not much exploration effort has been put up so far in Ganga Basin. Keeping in mind size of the basin, sedimentary thickness involved, presence of algal matter deposited in shallow marine environment & higher hydrocarbon indications warrant active exploration. Gondwanas in India having such a large sedimentary area can not be ignored keeping in view generation and production from the non marine sediments of Kenya, Chad, Sudan, Gadon and China. Gondwanas become all the more important in view of gas production from their equivalents-Karoos in Ethiopia and South Africa. In all, above mentioned changes can be predicted in Indian oil exploration scenario during 21st century.

Jan 1, 1986

By Till M, McGee WA

The Hermit Islands are situated at 145¦ E 1 30'S in the Bismarck Sea approximately 200km WNW of Manus Island. They are dominated by basalt flows, one of which yielded a K/Ar isotopic date of 3.4 + 0.05Ma. All basalts examined were olivine-bearing, but one sample also contained hornblende. Although many outcrops were weathered, no evidence of pervasive hydrothermal alteration was observed on any islands and non-weathered rocks are petrographically fresh and many retain glass.

Jan 1, 1990

By Y Bissiri

The ever increasing demand for metals and minerals is putting significant pressure on current mining companies to find more ore. As these companies explore and mine, the future appears to be to go deeper and deeper underground. With depth, however, comes ever increasing costs as infrastructure such as hoisting, ventilation, the movement of workers and materials increase in size and scope. Further, the actual rock mass becomes prone to destruction through rock bursts and the heat generated becomes a major issue resulting in extreme expenditures in cooling plants and some of the biggest air movers in the world. All these issues result in dramatic changes in both capital and operating costs, subsequently making cut-off grades rise. As this trend continues there is an economic limit to how deep one can go, resulting therefore in a severe shortage of accessible ore deposits to mine. This paper discusses the need for larger marine robotics technology and presents the state-of-the-art in current research in underwater tele-autonomy, specifically the development of high bandwidth optical communication networks critical to any future activities (mining, construction, etc) underwater. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Bukovinsky SB

The smelting, refining and hydrometallurgical operations practised in the winning of non-ferrous metals are associated with severe aqueous and high temperature corrosion problems.With the increasing costs of maintenenace and the utilization of computerization to control the processes, the trend in recent years has been to spend more capital on improved and proprietory grades of engineering materials, which offer greater reliability and more cost effective plant performance.The problems which have plagued stainless steel users for many years are the alloys' poor performance in chloride or other halide media where pitting, crevice or chloride induced stress corrosion cracking may occur, have been essentially solved by the new proprietory grades. The controlled additions of minor alloying elements including rare earth metals have led to the development of stainless steels with high mechanical strengths, improved corrosion resistance, and high temperature corrosion resistance and structural stability.

Jan 1, 1985

The continued exploration of the major brown coal deposits of the Latrobe Valley has resulted not only in the discovery of huge additional reserves, but also in new concepts of the stratigraphy and structure of the coal seams in that area. The author sets out his interpretation of the new information which has become available over the last six years.A section of the paper is devoted to the quality of the coal. As the chemical composition of these brown coals has been discussed in some detail by previous authors, only the major constituents and the heat value of the coal are dealt with in this paper. Some of the variations in quality are related to the geological structure.The occurrence of underground water and its relation to open cuts is dealt with briefly.INTRODUCTIONThe Latrobe Valley Tertiary Basin is almost entirely covered by a layer of Post Tertiary sediments which mask the underlying rocks and their structures. As a result, the geological understanding of this area has had to await the comprehensive drilling campaign in search of brown coal, initiated by the Victorian Mines Department in 1917, and subsequently carried on by the State Electricity Commission of Victoria. The first detailed geology was published by Herman (1922), and this was followed some 25 years later by papers by Edwards, and later Thomas and Baragwanath, to which reference will be made later in this paper. Herman included a section on the geology of the Latrobe Valley in his book Brown Coal, which was published in 1952.Since that time a considerable amount of new information has become available from the continued drilling carried out by the Commission. In addition, geophysical work carried out by the Commonwealth Bureau of Mineral Resources has assisted in the defining of geological structures in the area.

Jan 1, 1960

This monograph presents a unified theory of adsorption and desorption of aurocyanide on activated carbon. This theory has proved useful for CIP/CIL carbon adsorption and Zadra and AARL elution process and equipment design; in accounting for the effects of various water qualities and process temperatures; and in the development of reagents to improve these processes. The theory presented is based on rigorous fundamentals : Classical Eyring theory links initial first order kinetics with Langmuir isotherm equilibria, and this isotherm is demonstrated for the first time to be a consequence of the activated complex postulate of Eyring theory. Simple extension to Freundlich conditions at high solution tenors is possible, but not presented. Supporting entropy data determined by the author includes practically all the pioneering CIP plants built in South Africa and Australia in the early 1980s.

Jan 1, 1991

By Zamel G. I, Zenari L. P

Technological developments in modem Tunnel Boring Machines (TBMs) and associated back-up equipment are offering significant alternatives for mining operators to consider, in the selection of equipment for coal mine development drifts, roadways, longwall gate roads as well as metalliferous mining declines and development drives.Greater flexibility in handling variable ground conditions, muck disposal and radius of turn as well as advance rates, are just some of the areas where modem TBMs can accomplish the flexibility that mine operators require to achieve cost-effective developments.Compact TBMs are achieving this acceptance because of the fundamental design of a shielded machine containing electrics and hydraulics within the forward shell, ability to achieve tight radius of curvature and grades, and ability to provide highly flexible support systems to meet all possible ground conditions.However, a single TBM design will not suit all mine developments, as each development method - while having common goals with all mine developments - will also require certain unique criteria to be fulfilled.

Jan 1, 1993

By Beamish B. B

In this study, a systematic examination of the scale and variety of micro-structures in coal using Scanning Electron Microscopy (SEM) has been carried out, using coal samples of differing stages of coalification from the Bowen Basin and New Zealand. SEM provides detail of various micro-structural features and shows that a variety of micron-sized fractures and cavities are present in coals. These are differentiated into three pore types: fracture porosity, phyteral porosity and matrix porosity. Fracture porosity is generally associated with bright coals (although it has been shown that micro-fractures are present in maceral fragments from the dull coal layers). Characteristically the macro- and micro- fractures form a continuous structural fabric through the bright coal layers and thus make a significant contribution to overall permeability. The macro- and micro-fractures appear to have been formed during the process of coalification rather than being formed due to shrinkage during methane extraction, as most of them are infilled with secondary minerals. In contrast, phyteral and matrix porosity is associated with the dull coal layers that are composed of plant fragments or a heterogeneous mixture of macerals. Like the macro- and micro-fractures, the continuity of the observed cavities suggest that these too are a significant contribution to overall permeability, and therefore play a major role in the transmissibility of methane at a level between diffusion at the micropore level and laminar flow at the macro-fracture level. Due to different spacing, orientation and persistence of individual fractures and cavities, the rate of methane transmissibility through a coalseam will vary according to coal rank, coal type and the organic precursors from which the coal was derived. This is important as a knowledge of the micro-structure system and its relationship to coal type and coal rank, plays an important consideration in: a) gas drainage modelling, b) enhancing permeability by inducing fractures and c) predicting the occurrence of outbursts.

Jan 1, 1991

Tectonic subsidence plots have been calculated for well, extrapolated-well and significant off-well (seismically-based) locations in the Vulcan Sub-basin and adjacent highs (western Timor Sea). The subsidence curves have been normalized to a common datum, the distinctive "near top Permian" marker, and corrected for sediment compaction, palaeobathymetry, eustatic sea-level change and loading effects.Four principal phases of post-Permian basin development are recognised and quantitatively described by integrating the results of the sub-sidence analysis into the regional (e.g. recent Ocean Drilling Program-derived) framework of the tectonic evolution of the North West Shelf. They are1. the Triassic-mid Jurassic Westralian Superbasin intracratonic phase,2. the late Jurassic-early Cretaceous North West Shelf rift phase,3. the mid Cretaceous-Palaeogene North West Shelf subsidence phase, and4. the Neogene-present Timor collision phase. Rapid Triassic tectonic subsidence occurred in an intracratonic setting, possibly subsequent to aborted late Palaeozoic rifting. Intracratonic sub-sidence mechanisms such as deep crustal metamorphism and/or intrustion and regional tectonic compression are invoked in addition to any post-rift thermal subsidence which may have occurred.

Jan 1, 1990

The gossan developed from the Whim Creek Cu-Zn-Pb-Ag sulphide deposit, in the Pilbara region of Western Australia, occurs near the top of a ridge in a dissected plateau 01 moderate relief. The gossan is characterized by the abundance of secondary ore minerals which indicates that it is relatively immature, due to climatic conditions and erosional stripping.The abundant presence of secondary carbonates indicates that the low pH generally resulting from sulphide oxidation has been neutralized, probably by the buffering effect of carbonatcs and silicates. Fe, Cu, Pb, 'Ag and Sn have been enriched in the gossan relative to the primary ore, and Mn, Ti, Co and Ni have been strongly depleted; other elements have remained substantially unchanged. The gossan has a strong gcochemical signature characterized by high Cu, Zn, Pb, As, Sb, Sn, Ag and Mo coutents. Boxwork textures are poorly developed, bu't the gossan has other diagnostic mineralogical features including sulphide inclusions in quartz and the presence of residual cassiterite.

Jan 1, 1982

By G W. Wilson, P Ritchie, N A. Currey

The design and rehabilitation of potentially acid forming (PAF) waste rock dumps is site specific, being a function, among other factors, of the rock types, the dumping and storage method employed, and the climatic setting. The æstore and releaseÆ cover system developed to manage acid rock drainage (ARD) from mineralised waste rock dumps at Kidston Gold MinesÆ open pit operations in the semi-arid climate of North Queensland, Australia, has been monitored for seven years. The paper describes the philosophy behind the design of the PAF dump and æstore and releaseÆ cover system and the adaptation of the cover system over time to suit KidstonÆs conditions. The results of monitoring over the seven years since the first cover was constructed are presented, and the approach being taken at Kidston to ensure that the risk of impacts from any residual ARD is accommodated and to facilitate lease surrender are described. The Kidston story is a valuable case study of a successful approach to remediating an identified source of ARD in a semi-arid climate, which has actively engaged all Stakeholders.

Jan 1, 2003

By Wang S

Fragmentation is the basic concern in rock blasting and serves as the main measure of blasting effectiveness. A good estimation of fragment size distribution before blasting is very useful and helpful for selecting the proper equipment for loading, transporting, and crushing rocks. A fragmentation model is presented that is based on a hole by hole analysis and correlates the rock properties, burden, spacing, and explosive column with the blasted volume and fragmentation obtained. The drill bench is divided into three separate areas corresponding to different breakage mechanisms. They are: 1) a main breakage or casting area, 2) a secondary breaking area, and 3) an overbreak area. The boundary of the main breakage area is found from the magnitudes of strains in the stress waves and the tensile strength of the rock. The secondary breaking area is determined by stress wave reflections at discontinuities and interactions between colliding stress waves from adjacent boreholes. The overbreak area is that beyond the main breakage area "where the reflected tensile waves no longer break the rock. This analysis is applied on a hole by hole basis to locate the breaking points. Then connecting the breaking points on each side of a borehole forms the triangle of the main breakage area. This is repeated for the next hole and the remaining area is the secondary breakage area. After the angle and area for each hole are found the Kuz-Ram model is used to predict the fragmentation size distribution for each hole. Then summing up the size distribution for each hole gives the total fragmentation distribution. This analysis has been successfully applied to field tests performed in a limestone bench where the entire spoil pile was screened to determine the fragment size distribution. Knowing the explosive and rock properties the breaking area was found for each hole, the strain and stress values, the breaking point, and angle of breakage (104 degrees). The fragmentation size distribution was then calculated and compared to the field data with excellent agreement.

Jan 1, 1990

By K Hortin

Kidd Creek mine in north western Ontario is developing phase 1 of the deep mine project for mining between 2100 m and 3100 m below surface. Heat problems were experienced during the 2003 summer in working places about 2300 m below surface. At the time the mine had a æcold stopeÆ for cooling the air supplied to the mine below 1500 m from surface. The æcold stopeÆ is where during winter, ice is created in both the open pit and its connecting airways to the mine and used to cool air in summer. The operation and limitations of the existing cold stope were evaluated and led to the requirement for additional mechanical cooling to be available for the summer of 2004. The first stage of a surface refrigeration plant providing 7.5 MWR of cooling was approved, the compressor set was ordered in early January 2004 and the plant commissioned six months later in early July 2004. Based on the current modifications to the mining plan, further plant expansions are required in 2006 and 2009 leading to a total of 19 MWR of mechanical refrigeration and 8.5 MWR equivalent from the extended cold stope. The refrigeration system is described with emphasis on the specific adaptations necessary to suit Canadian conditions. Additional investigations were; using the refrigeration compressors in winter for heating and, extending the performance of either cold stopes or alternative ice storage systems. The winter use of refrigeration involve removing heat from the mine exhaust air to provide a cooling load and to use the hot water in the condensing circuit to heat the intake air and reduce reliance on mine air heating with natural gas. This paper follows on from an earlier one presented at the Seventh International Mine Ventilation Congress where the background and planning of the mine ventilation and cooling requirements were described for extending the mine at depth to 3100 m.

Jan 1, 2005

By D S. Nicholson, T Marshall

Reserves of high-grade quartz gravel, lignite and timber suitable for the production of silicon metal and ferrosilicon on large scale occur within 40 miles of Bluff Harbour. Undeveloped hydroelectric power resources on the Clutha River are located within 50 miles of the most promising quartz gravel deposits while opencastable lignite, potentially suitable for electric power production, occurs in the same locality as the quartz gravels. A preliminary study of production economics indicates that the commercial feasibility of silicon/ferro-silicon production would depend mainly on the cost of electric power, total capital cost of plant, and the market value of the products. The proximity of Bluff Harbour is advantageous for the export of products.

Jan 1, 1971

This paper will describe the exploration project which led to the discovery of the La Escondida porphyry copper deposit in northern Chile and will serve as companion paper to the description of the geology of Escondida being presented by J M Ojeda. The author would like to express his appreciation to Robert Hickman, Chairman of Minera Escondida, for permission to present this paper.In July 1978, a proposal was made by J D Lowell to Robert Wheaton, then Exploration Manager of Utah International, that Utah fund a "grass roots" program exploring for porphyry copper deposits in northern Chile. Wheaton expressed interest, and it was agreed that Getty Oil Co also be invited to participate. A joint venture agreement for the Atacama Exploration Project was signed January 1, 1979, between Utah, Getty and Lowell. The project was managed by Lowell who reported to a management committee which through most of the project consisted of Lowell, Francisco Ortiz, Robert Wheaton, Maurice Young, Sigfried Muessig and Louis Rove. Oliver Warin and Jim Bratt participated in the committee in the last phase of the contract. Special thanks are due Louis Rove of Getty and Maurice Young of Utah who made contributions throughout the course of the project. Francisco Ortiz was resident manager through most of the project.

Jan 1, 1990