Search Documents

By Philip D. Wilson

WHEN the United Nations win the war and the decision has been made to control future armament in the Axis countries, plans for the extent and operation of such control must have been prepared, to be ready to put into immediate execution. Such control to be effective must be premised upon complete military occupation of the two countries for a substantial period, with an arrangement at the end of such occupation for continued supervision of these industries into an indefinite future.

Jan 1, 1944

By Reichmuth, Donald R.

Most brittle solids are relatively weak in tension and this weakness can be very significant in determining their performance in structures and excavations. Consequently, accurate knowledge of the tensile strength of brittle materials has long been recognized as important. In the past, measurements of the tensile strength of materials such as concrete, ceramics, and particularly rock have been hindered by problems encountered in fabricating test specimens and in accurately loading them. These difficulties have resulted in a scarcity of published tensile strength data. This can be readily seen in tabulations such as Wuerker's "Annotated Tables of Strength and Elastic Properties of Rocks.

Jan 1, 1968

By V. F. Swanson

A petrographic study was made of the type and sources of mineral contamination occurring in Florida phosphate rock products. Emphasis was placed on contaminants in the screened rock (+1 mm), since this portion of the product undergoes no physical beneficiation except for scrubbing to remove slimes. Since iron and aluminum contents of the finished product affect the salability, special emphasis was placed on identifying types and sources of these contaminants and relating chemical composition to visual characteristics. Wavellite derived from the overburden was the major aluminum contaminant with some aluminum being included as secondary clay balls. Iron occurred as phosphates in the overburden and as colloidal oxides included in the phosphate pebbles. Chert and limestone contamination derived from the Hawthorne formation underlying the phosphate matrix.

Jan 1, 1972

By L. J. W. JONES, B. H. Bennetts

THE removal and disposition of large quantities of slag from blast-furnaces is a question of great importance in the design of works, and various methods have been devised, from time to time, in order to take the best advantage of local conditions. In blast-furnaces treating copper-ores or lead-ores, it is necessary to use a fore-hearth, or matte-settler, in order to collect, if possible, every particle of valuable matte which, otherwise, would be carried away with the out-flowing slag. In all of these cases, the slag overflowing from the fore-hearth is caught in pots and then conveyed to the dump. If the slag is of no value and the necessary water-supply, grade and dumping-space be available, the disposal of the slag by granulation is by far the cheapest and best method. It involves a minimum of labor, both at the furnace and at the dump; and it permits a continuous outflow of slag from the furnace- or settling-pot, thereby avoiding frequent tapping and plugging. When the conditions of water-supply, grade and dump-area will not permit slag-granulation, there are three other methods in common use. Large steel or cast-iron pots, or ladles, supported by trunnions on heavy cars which are moved by steam-, air-, or electric locomotives; some type of mechanical conveyor; and small pots or buggies moved by hand. The pots on the slag-cars are generally circular or oval in shape, and each one contains from 15 to 40 or more en. ft. of molten material. The mechanism for tipping them is more or less elaborate; and, as a general rule, the slag is dumped alongside, and quite close to, the track. They are more or less costly to construct and to keep in repair, and, in order to use them to best advantage, it is necessary to have a good elevation of track above the dumping-ground; furthermore, the rails must be of heavy weight, and well-supported on heavy ties. Other disadvantages of the slag-pots are-1, that the slag cannot be removed continuously

Mar 1, 1905

By C. L. Dake

AN insistent and steadily growing demand is evident for the broadening of undergraduate curricula in engineering. Among suggested additions are training in public speaking, report writing, business law and contracts, accounting, finance, money and banking, scientific management, economics, social and labor problems, psychology, and ethics. The demand for these subjects comes from the older engineers and from the industries that employ our graduates. Of course, many of the men who suggest such changes are influenced largely by their personal needs and contacts, but the demand is sufficiently widespread to merit serious study by educators. In fact, many educators themselves concur in the proposals for broader training. These matters were examined intensively a few years ago in an exhaustive study of engineering education. Opinion at that time was rather strongly against any profound change. Since then, however, the whole economic system has undergone violent disruption. Even if recommendations made a few years ago were appropriate to the conditions then- obtaining, the enormously changed conditions of the present make advisable a further careful study of this problem. In recent years, mergers, to reduce costs, have sharply limited the number of engineers employed and have thereby intensified the struggle to secure positions. In this stiffer competition, engineers with the most adequate training undoubtedly fare the best.

Jan 1, 1934

By John F. Knudsen

Following the flowsheet from the primary crushing plant of Ray mines division through the final products sample mill, there are eight exhaust systems ranging in size from 12,000 to 30,000 cfm. Where possible, hood face velocities are kept around 500 ft per min, permitting branch velocities of 2500 ft per min. Tight-fitting enclosures are provided over all ore drops, crushing operations, and vibrating screens. All enclosures are exhausted either primarily or secondarily, except those around conveyor head-pulleys where the ejector effect of the falling ore creates sufficient indraft to abate dust dissemination. IN 1947 an Industrial Hygiene Department was organized to represent and assist the four western mining divisions in industrial hygiene problems. Department headquarters are located at the Utah Copper Division, Magna Plant, Magna, Utah, with a branch office at the Chino Mines Division, Hurley, N. M. The headquarters staff includes a director, a department secretary, an industrial hygienist, a supervising ventilation engineer, and two ventilation designers. To be in closer association with work at the Southwest properties, a field engineer at the branch office conducts field studies which include ventilation problems at the New Mexico and Arizona properties;i.e., the Chino and Ray mines divisions. Functions of the department are to discover and evaluate existing hazards and to develop protective measures, either by personal protective devices or by proper ventilation, depending on the nature of the contaminant. Other than dust counting, all air samples collected at the four properties are processed at the home office. If through plant surveys or by suggestion of management some type of ventilation or air conditioning is required, the problem is usually handled by the ventilation section of the headquarters department, where general arrangement or line drawings are prepared, showing hoods, ducting, and equipment. Some hood and special parts detailing is done at headquarters; otherwise, required detailing is done by the respective plant engineering departments. Prior to the design of industrial ventilation, either new projects or the revamping of old ones, a thorough survey is made of existing conditions. In so far as possible weighted average exposures are determined and adequate ventilation provided on the basis of maximum allowable concentrations of the contaminant in question, as well as medical case histories, if these are available.

Jan 1, 1954

By Howard Talbot

THE history of the development of the strip in- dustry, mentioned in this paper, was covered in considerable detail by Stephen Badlam in his paper presented. before the American Iron and Steel Institute at its meeting in New York last October. The description of progress in rolling strip there out-lined will be found good reading by anyone interested in the subject. Quoting from Mr. Badlam's paper, "For practically thirty years, we find no record of the use of the backing-roll principle, until in 1916 the Lukens Steel Co., Coatesville, Pa., put in a 206-in. plate mill of the four-high type. This was a reversing mill with two 32-in. working rolls and two 50-in. backing rolls and is today making the widest and heaviest plate made anywhere in the world." The functioning of this mill, though rolling hot plate, is, on account of the extreme width and thinness of plate rolled, quite comparable to the rolling of wide strip either hot or cold and was a considerable factor in demonstrating the marked advantages available with the four-high or backing-roll mill for thin accurate rolling. As the writer has brought out, a demand for a product, the rolling of which required the character-istics of the backing-roll mill, was broached by the In-ternational Nickel Co. This resulted in an inquiry of March, 1924, for the building of a mill capable of cold-rolling wide nickel and monel metal sheets or strip, as mentioned. It may be of some interest to note, that whereas the .six-roll cluster mill with plain bearings was built for this installation, the mill designed by the United En-gineering and Foundry Co. for this inquiry was of the four-high type with roller bearings on the backing-roll necks, being essentially the same design as the four-high roller-bearing mill built in 1925 for the Rome Brass & Copper Co. This Rome mill, to quote again from Mr. Badlam's paper, "fulfilled every requirement, and was the model on which succeeding mills of this type were built."

Jan 5, 1928

HAVING already shown you the methods of making the moulds for casting and how they are to be prepared so that they may receive the melted metals well, it is now necessary, in order to complete the casting with perfection, that I show you not only the operations and instruments by which metals are softened, but also how metals can be made as liquid and fluid as water so they may easily enter into all the hollows of the moulds that you have made. Of these, besides the fire which is the prime agent, there is a very powerful furnace, which is called a reverberator.* I believe this is chosen not only for convenience but also because it is necessary in large casts. This is made of baked bricks, or of crude ones if desired or of suitable fire-resistant stones. Although all masters have the same objective, each one proceeds to make this kind of furnace according to his own ideas so that it can be said that there are almost as many different shapes of such furnaces as there are masters. This can be seen in the place that contains the metal, which is of such a shape that the force of the fire may operate better. Thus some masters are called good who, seeing no farther than what has been shown them, make them circular like a bread oven. Some others make them oval across the fire en- trance, while others extend them lengthwise. Also, there are some who make a single outlet for the flames, some two, and some three. Some make the entrance for the fire high and narrow and others, wide and low. The same is true of the place where the flames are generated, which is called the firebox. Some put the wood in from the side, some lengthwise in the same direction as the entrance for the flames, and some from above by means of a little hole. Also, one makes the vault low, and another makes it high. And while one puts an entrance for air underneath so that the

Jan 1, 1942

By W. J. Tait, A. E. Craig, E. P. McCurdy

C. M. Marquard—The problem of the automatic control of a grinding-classification circuit is not nearly as simple as has been indicated and it cannot be universally solved through the application of this device. The sound emanating from a ball mill such as the metallic clink of the balls against the liners can at times be misleading. The fact that the sound level due to the balls hitting the liners may be at a minimum does not necessarily mean that the mill is properly loaded. I have in mind an ore we treat that has a soft talcy gangue. The soft fluffy nature of this material makes the sound from the ball mill a most misleading parameter that is worthless as a means for controlling the amount of ore fed to the mill. In every milling plant there are transportation lags due to the time it takes the ore to travel from the mill bins to the ball mill. In many plants there may be several different transportation lags due to varying distances of bins from ball mill. These transportation lags can most seriously affect the operation of a controller. It has been found that under many circumstances the transportation lags can be so bad as to cause the controller to hunt seriously. Hunting can and in many cases does become so serious as to render automatic control impossible because of the surges it causes. While it is possible to compensate for this type of lag, this apparatus does not lend itself readily to accomplish the required compensation. Further, if there are groups of bins at various distances from the ball mill, compensation for one may not be sufficient or may be too great for another. Each milling plant presents a separate problem. The apparatus as presently described does not appear sufficiently flexible to accomplish this. It should be noted that the load on the classifier rakes is determined by measuring the current input to the rake drive motor. Variations in line voltage will

Jan 1, 1951

By E. P. McCurdy, W. J. Tait, A. E. Craig

C. M. Marquard—The problem of the automatic control of a grinding-classification circuit is not nearly as simple as has been indicated and it cannot be universally solved through the application of this device. The sound emanating from a ball mill such as the metallic clink of the balls against the liners can at times be misleading. The fact that the sound level due to the balls hitting the liners may be at a minimum does not necessarily mean that the mill is properly loaded. I have in mind an ore we treat that has a soft talcy gangue. The soft fluffy nature of this material makes the sound from the ball mill a most misleading parameter that is worthless as a means for controlling the amount of ore fed to the mill. In every milling plant there are transportation lags due to the time it takes the ore to travel from the mill bins to the ball mill. In many plants there may be several different transportation lags due to varying distances of bins from ball mill. These transportation lags can most seriously affect the operation of a controller. It has been found that under many circumstances the transportation lags can be so bad as to cause the controller to hunt seriously. Hunting can and in many cases does become so serious as to render automatic control impossible because of the surges it causes. While it is possible to compensate for this type of lag, this apparatus does not lend itself readily to accomplish the required compensation. Further, if there are groups of bins at various distances from the ball mill, compensation for one may not be sufficient or may be too great for another. Each milling plant presents a separate problem. The apparatus as presently described does not appear sufficiently flexible to accomplish this. It should be noted that the load on the classifier rakes is determined by measuring the current input to the rake drive motor. Variations in line voltage will

Jan 1, 1951

By A. Mitchell

An approximate phase diagram has been developed for the CaF2-CaC2 system, indicating a eutectic point at 1240°C, Ncac2 = 0.13, and no detectable solid solution in either phase. The liquidus line is shown to correspond to a simple c22- ion in solution. A thermo-chemical study of&apos; the reaction between carbon-saturated Ni-Ca alloys and CaC2-CaF2 liquids indicates that lhe Raoullian activity coefficient of CaC2 in dilute solution in Cap2 al 1500°C lies between 8 and 10. Some effects of the stabilily of Cap2-CaC2 solutions at high temperatures on electroslag remelting praclice are outlined. THE alkaline earth acetylides. MIIC2, have a reasonably high thermochemical stability at high temperature in the solid state,&apos; with the exception of magnesium, which forms an unstable acetylide at low temperatures (-500°C) and a carbide, Mg2C3, in the range 700&apos; to 1000°C. The acetylides of calcium and barium have been shown to have limited solubility in their respective chlorides,&apos; and further these solutions contain the acetylide as a C: ion.&apos; The equivalent magnesium solutions have not been studied. Although calcium "carbide" is used as a desulfuriz-ing reagent in steelmaking. and is possibly present as an acetylide-oxide phase in very basic electric arc practice slags, the acetylide ion appears to be substantially unstable in a silicate slag.* As a conse- *This instability arises from equilibria in the reaction: CaC2 + CO = (Ca0) + 3C where the low intrinsic solubility of CaC2 in silicate lattice, and the low activity of CaO in a silicate solution where CaO/Si02 < 1, combine to give a very small equilibrium concentration of CaC2 in solution in such silicate slags at temperatures in the region of I 500°c, even under carbon-saturated conditions. Under highly basic conditions, a liquid CaO-CaC2 phase may separate from the silicate system quence of this, the possibility that reactions involving CaC2 in silicate solutions are of importance to general steelmaking practice is remote. However, in operations involving a slag primarily based on a halide, or alkaline earth oxide, we must take into account the possibility that CaC2 will appear in quantities sufficient to significantly affect both the chemical and physical properties of the slag. The work outlined below presents a study of the CaF2-CaC2 system intended to provide sufficient data to allow an estimate of the importance of this system to electroslag remelting and welding practice. However, we should indicate at this point that there will be other processes, e.g., heat treatment, flux cleaning of castings, fused salt electrolysis, and so forth, where alkaline-earth halide fluxes are in contact with carbon, graphite, or carbides, and where halide-acetylide solutions must be taken into account. EXPERIMENTAL 1) Structural Studies. In view of the difficulty ex-perienced in handling CaC2 prepared from calcium turnings and propane gas at 700°C, it was decided to use solutions prepared directly in the equilibration apparatus, Fig. 1. The starting materials were: a) Ni-Ca-C alloy, prepared by adding calcium to liquid nickel held under calcium fluoride in an induction-heated graphite crucible; b) calcium fluoride, prepared by fusing calcium fluoride powder (British Drug House "EXTRA PURE") calcium fluoride in an induction-heated graphite crucible, in air, followed by electrolysis between graphite electrodes at 1 amp cm-2 density, for 10&apos; coulombs per g CaF2. This procedure decomposes the CaO produced by hydrolysis during the fusion step, replacing it by CaC2; Ca2+ + 2e-Ca*(l) Ca*(l) + 2C(gr)-(CaC2)caF2 O2- -2e-O*(g) O*(g) +C(gr)-CO(g) This results in a composition of between 2 and 5 wt pct CaC2 in CaF2. Fifty grams (in lumps) of this material were placed in a graphite crucible, together with Ni-Ca-C alloy (averaging 20 wt pct Ca), and the equilibration apparatus assembled. The alloy reacted with the crucible at high temperature to give CaC2, which dissolved in the calcium fluoride solution to give the desired composition. Cooling curves were plotted manually for these liquids, with rapid stirring and CaF2 seeding to minimize supercooling, and using a Pt/Pt 13 Rh thermocouple calibrated on the freezing points of nickel and copper. This gave a reproducibility of ±0.l°C. and an absolute accuracy of the thermocouple of ±l°C. An example curve is shown in Fig. 2, with the CaF2 end of the binary system in Fig. 3. The CaF2-CaC2 ingots were crushed, under dry nitrogen, and sampled for chemical analysis and X-ray examination. Analytical details are given in the Appendix. Powder diffraction data indicated that the only phases present in all samples examined were calcium fluoride and tetragonal (Types I and 111) calcium acetylide,4 with no evidence of solid solutions or compound formation. 2) Thermochemical Studies. The apparatus used to obtain activity data on CaC2 in these systems is shown in Fig. 4. It consists of an arrangement whereby the graphite crucible and its contents (CaF2-CaC2. Ni-Ca-C) can be rapidly cooled without exposure to air. Trial experiments to determine an equilibration time by ap-

Jan 1, 1969

By G. R. Gray, T. S. Chapman, J. L. Foster

THE wall-building properties of salt-water drilling muds can be improved markedly by the addition of: (I) natural gums, such as tragacanth, karaya, and ghatti; (2) seaweeds, such as Irish moss; or (3) gelatinized starch. Results of laboratory tests have been confirmed by field trials. For drilling operations in which the mud becomes contaminated by salt, either through penetrating salt-bearing rocks or by addition of sea water to the mud, the added cost resulting from the use of one of the substances listed above is more than offset by freedom from stuck drill pipe and ease in running casing. INTRODUCTION It has been recognized for many years that oil production might be seriously hampered by infiltration of water from the drilling mud.1-4 As knowledge of the mechanism of the wall-building process advanced, methods were developed for evaluating the filtration characteristics of muds.5-11 The wall-building properties of fresh-water muds are commonly regulated by the addition of bentonitic clays, or of agents to promote the dispersion of the natural mud solids. When strata bearing soluble salts are encountered in the course of drilling, the salts are incorporated in the mud; the clay solids are flocculated and water loss is increased tremendously. Methods generally used in controlling filtration of fresh-water muds are no longer applicable. The problem of reducing water loss from salt-water muds is not confined to any particular area, but is acute in parts of West Texas. Salt beds several hundred feet thick must be penetrated before the oil-bearing formation is reached. Since the formation drilled does not provide mud-making material, it is necessary to use large quantities of commercial clays, and even the best commercial clay does not afford relief from the problem of high filtration. A laboratory study has been made of methods of improving the filtration characteristics of salt-water muds, and some of the methods have been used in field practice. LABORATORY INVESTIGATIONS Procedure Inasmuch as the immediate object of the investigation was the development of means of improving the wall-building properties of muds used in West Texas, an attempt was made to employ muds in the laboratory study comparable to those in field use. Samples of muds used in drilling the producing formations in six wells were secured. The properties of these samples are summarized in Table I, which lists the densities, viscosities, filtrations, and analyses of the filtrates for calcium, chloride, and sulphate. Viscosity was measured in the Stormer viscosimeter at 600 r.p.m. Water loss was determined at 80°F. with the Baroid low-pressure wall-building tester&apos; at a pressure of 10o lb. per sq. in. Filtration rates are considerably higher than those of usual fresh-water muds, which amount to about 20 c.c. in 30 min. Water loss was so rapid in samples 4, 5 and 6 that filtration was complete in less than 10 min. and the values for 30 min. were extrapolated from the rates at shorter

Jan 1, 1941

By A. M. Hall

SULPHUR, even in small amounts, may often be harmful to nickel and high-nickel alloys, causing impairment of mechanical strength and destruction of malleability and ductility, as shown by Merica and Waltenberg.1,2 It may act. either in the form of nonmetallic inclusions produced in the liquid state during furnacing or as reaction products resulting from its diffusion into the solid metal. In recognizing the action of this element, ability to identify its various forms by means of the microscope is often of considerable importance, especially when direct quantitative methods are inapplicable. [ ] Of the sulphur compounds associated with nickel and high-nickel alloys, the sulphides that may be found in malleable nickel, Monel? and Inconel? are an important group. These sulphides were investigated by metallographic methods in order to provide descriptive data by which to identify them. The nominal compositions of malleable nickel, Monet and Inconel are given in Table I. The term "sulphide" is employed here in a very general sense, to designate a substance in which sulphur and one or more metallic elements are combined. The term includes any combinations of compounds and solid solutions. METHOD OF INVESTIGATION Three groups of small laboratory melts were made, one group to represent each of the three types of alloy under investigation. Within each group, a number of ingots with a sufficient variety of chemical analyses were prepared so that the effect of each of the elements entering the complete commercial alloy could be isolated and observed. In most cases, to facilitate metallographic study by exaggerating the number and size of the resulting sulphides, somewhat greater amounts of the minor elements were added than are present in the commercial alloys. Likewise, considerably more sulphur was added than is normal, but not enough to complicate the system. Transverse sections were cut at a point one third of the distance from the butt to the head of each ingot, polished and examined with an inverted stage metallograph equipped with a combination polarizing-analyzing vertical illuminator. The light source was a tungsten-mercury vapor arc lamp.

Jan 1, 1943

By N. K. Chen, R. Maddin

Single crystals of molybdenum were extended at temperatures from 1300° to 2500°C. It was found that with increasing temperatures, the yield becomes more pronounced and the number of slip bands for equal amounts of elongation decreases. Slip at high temperatures fragments the structure. OTHER than the investigations on sodium and potassium by Andrade and Tsien,&apos; the researches of Steijn and Brick&apos; on a iron single crystals at low temperatures are about the only studies of the influence of temperature on glide of body-centered cubic single crystals. The effect of test temperature on glide has been rather widely investigated with hexagonal crystals" and less widely with face-centered cubic crystals. ~~ a result of these studies it can be said that, in general, the onset of plastic flow as measured by the initial rate of strain hardening becomes more abrupt with increasing temperature, and the value of the yield decreases with increasing temperature. Strain hardening, however, is markedly affected by changes in temperature except at very low and very high temperatures where the strain hardening rate becames constant. In the present investigation it is shown that temperature affects the glide of molybdenum single crystals in much the same manner as crystals of other classes, it., for comparable strains the number of slip bands decreases with increasing temperature; shear along the slip bands increases with increasing temperature; the yield becomes more pronounced with increasing temperature of test; and the strain hardening approaches a constant at very high temperatures. In addition, it is shown that, in agreement with the work of Tsien and Chow, Qlip occurs on (110) planes in <Ill> directions. It is further shown that slip at high temperatures fragments the structure into either irregular sized cells or bent atomic planes which are roughly aligned in crystallographic directions. Experimental Procedure Single crystals 3 mm in diameter by about 25 mm long were prepared using the technique previously described.&apos; The furnace in which the crystals were grown served as the extension apparatus for the tension tests. It consisted of a 4 in. water-cooled brass tube 20 in. long which was continuously evacuated at the bottom. Two water-cooled copper electrodes held the specimen by means of spherical collets secured in place in the electrodes by set screws. These electrodes served also to transmit power and stress to the specimen. The lower electrode was clamped to a stand, while the upper electrode was fastened to one side of a lever arm flexibly supported at the top through a slightly offset pinion. A metal bellows operating elastically was attached to the upper electrode to affect a vacuum seal and allow freedom of motion. The level of the arm was adjusted by rotating a graduated nut. Rotation of the electrode was prevented by a key fitted into a groove. After the specimen was mounted and the vacuum secured, the lever arm was adjusted so that the bellows was at its relaxed position. This insured that the total weight of the specimen, the upper electrode, and the downpull of the vacuum were balanced by the horizontal beam. Since the specimen was heated by its own resistance, expansion of the specimen proceeded freely by this arrangement. During the time of heating the specimen, the beam was maintained in a horizontal position by turning the nut at the top. By graduating the lever arm and using a known dead weight on the lever arm to supply a tensile stress, the graduated nut could be read to 0.0001 in. extension. Since

Jan 1, 1955

By G. R. Speich

A cellular precipitation reaction in which cells consisting of an Ni3Ti (DO24) phase and austenite are formed has been studied in an austenitic Fe-30 Ni-6 Ti alloy. The variation of the growth rate and interlamellar spacing of the Ni3Ti cells with temperature has been determined m the range 400" to 975°C; the interlamellar spacing is proportional to the degree of undercooling; the growth rate can be expressed by an equation of the form G = K?T)2 exp(-Q/RT). The habit of the Ni3Ti lamellae is (001)Ni3Ti (111)y;[010]Ni3T2 [010]y. An almost perfectly coherent interface is formed between Ni3Ti lamellae with this orientation rela -tionship and the intervening austenite. This first Ni3Ti cellular product is subsequently consumed by a second cellular reaction of much coarser spacing. CELLULAR precipitation reactions have been studied in copper-base,1,2 Au-Ni,3 pb-sn,4 and iron-base ferritic5,6 solid solutions, and this mode of precipitation has been treated theoretically by smith," Turnbull,8,9 cahn,10 and more recently by bohm.11 In the case of substitutional austenitic iron-base alloys little or no data are available, Cellular precipitation reactions are well known in austenitic nickel-base alloys12,13 but usually these reactions do not proceed to completion because of general precipitation occurring in the matrix, and they have not been studied in detail. Precipitation from an austenitic Fe-30 Ni-6 Ti alloy was studied as part of a larger investigation of the mechanisms of precipitation from substitutional iron-base alloys. This alloy, austenitic at high temperatures, decomposes at lower temperatures by a double cellular precipitation reaction. The first decomposition product consists of alternate lamellae of an Ni3Ti(DO24) phase and austenite. The reaction proceeds to completion, consuming all of the original austenite. This first cellular product is subsequently consumed by a second cellular reaction of much coarser spacing. The first cellular reaction was studied in detail by light and electron microscopy, hardness measurements, and by X-ray and electron diffraction. Interlamellar spacings and growth rates were measured during isothermal aging in the range 400" to 975°C. The orientation relationship between the Ni3Ti and austenite lamellae was determined and indicates that an almost perfectly coherent interface exists between the two phases. This first Ni3Ti cellular reaction is of particular interest because it occurs over such a wide temperature interval. This allows cellular growth rates and interlamellar spacing data to be obtained for much larger degrees of undercooling than reported hitherto. MATERIALS AND EXPERIMENTAL PROCEDURE The Fe-30 Ni-6 Ti alloy was prepared from electrolytic iron, Mond nickel shot, and sponge-purity titanium* by vacuum melting in a zirconia crucible

Jan 1, 1963

By E. O. Kirkendall

THE investigation reported herein was undertaken to obtain data to supplement those presented in an earlier paper,&apos; particularly for longer times at a higher temperature. This information may further develop our knowledge of the mechanism of diffusion in substitutional solid solutions. Diffusion of solute atoms interstitially dissolved is not difficult to visualize; it can take place without much disturbance of the solvent atoms. The mechanism of diffusion of solute atoms substitutionally dissolved is not so easily understood. Many theories have been advanced. Rosenhain,2.3 Frenkel,4 Smekal,5 Langmuir,3,6 Steigman, Shockley and Nix,7 and Johnson8 all proposed theories to explain diffusion. Langmuir&apos;s proposed mechanism consisted of a simple cyclic interchange of atoms involving an interchange in lattice positions of four or more atoms. This mechanism, accepted by the author at the time of his previous publication,&apos; and apparently quite generally accepted, required a net exchange in positions of both solute and solvent atoms in equal numbers. In other words, the rate of diffusion of the solvent and solute atoms would be the same. That this cyclic interchange in lattice positions of solute and solvent atoms in equal numbers is the only true mechanism of diffusion is denied by the evidence presented in this paper. EXPERIMENTAL PROCEDURE This modification of similar procedure1 will be outlined briefly. The method consisted of the following steps: I. A pure Muntz metal (60.6 per cent Cu, 0.1 per cent total impurities) that was almost all beta brass at 780°C. was chosen. 2. The brass was turned between centers in a lathe to a diameter of 0.5965 inches. 3. After the brass was cleaned, it was electroplated with pure copper to a diameter of about one inch. 4. The sample was heated slowly to 400°C. under reduced pressure and held at that temperature for 4 hr. to remove occluded gases. It was then cooled to room temperature. 5. The sample was heated to 780°C. ±3°C. and held at that temperature for different lengths of time; then quenched. Samples were cut off each time after quenching. Metallographic samples 34 in. thick were removed at I hr., 6 hr., 24 hr., 96 hr. and 701 hr. After 96 and 701 hr. samples of about I in. were removed for X-ray analysis. 6. The metallographic samples were polished on the cross section and photo-micrographs were taken. 7. The I-in. samples were polished and etched on both ends. With the aid of a microscope each was carefully mounted in a four-jaw chuck in a lathe, so that they could be accurately bored for an arbor. 8. Turnings were taken for each X-ray sample. After each set of turnings, the sample was heated in an oil bath for about 3a hr. at 300°C. It was then etched in 25

Jan 1, 1942

By M. J. Stewart, F. Weinberg

PREVIOUS investigations into convective flow in molten metals have examined systems in which the length-to-height ratio of the enclosure is large, usually using long graphite boats.&apos;&apos;2 In normal castings this ratio is generally small and it is not possible to extrapolate the results of previous work to casting configurations. The present investigation was undertaken to examine liquid flow in systems of low length to height ratio. The apparatus used for the experiments is shown in Fig. 1. The molten zone of tin is contained in an aluminum mold of inside dimensions 6.4 by 6.4 by 0.31 cm. A heating block containing a resistance coil is attached to one end of the mold and a cooling block is attached to the other end. These are used to produce a wide range of temperature differences across the mold. The mold is contained in a stainless steel tank which is heated from the outside by resistance heaters to give the required operating temperature during the experiment. Temperature measurements in the molten tin are made with an iron-constantan thermocouple PT equal to 5 atm. The phase diagram derived by us was the same as that found by Krivsky and Schuhmann, except for a similar discrepancy in one boundary line representing the gas composition in equilibrium with SO a. The vapor pressures of the pure components can be neglected at 1700°K, 1 atm and 2500°K, 5 atm. There-fore, in these cases PT is essentially the total pres-sure in the system. This is valid for all the diagrams presented by Krivsky and Schuhmann except for the one at 2500°K and 0.01 atm, where the vapor pressure of silicon is comparable to PT.6 This work was supported in part by the American Iron and Steel Institute. &apos;C. E. Wicks and F. E. Block: Thermodynamic Properties of 65 Elements, U S. Bur Mines, Bull. No. 605, 1963. R. P. Elliott: Constitution of Binary Alloys, 1st supplementary, McGraw-Hill Book Co., New York, 1965. 3W. A. Krivsky and R. Schuhmann, Jr.: Trans. TMS-AIME, 1961, vol. 221, pp. 898-904. 4M. F. Ancey-Moret, M. Olette, and F. D. Richardson: Mem. Sci. Rev. Met., 1964, vol. 61, pp. 169-76. 5J . F. Elliott and M. Gleiser: Thermochemistry for Steelmaking, vol. 1. Addison-Wesley, Reading, Mass. 1960. 6 J.Drowart, G. De Maria, and M. G. Ingraham: J. Chem. Phys., 1958, vol. 29, p. 1015. probe of 0.4 mm diam inserted into the open top of the mold. Radioactive sn113, in the form of a small sphere, was gently lowered into the molten tin at point A in Fig. 1 THERMOCOUPLE> WATER ARGON END HEATER QUENCH ARGON Fig. 1—Apparatus for detecting liquid flow. Point A indicates position the tracer was introduced.

Jan 1, 1970

By T. R. Cass, M. R. Achter

A technique for measuring the creep and rupture strength of nickel specimens bonded by sintered oxide layers has been developed for the investigation of the role of grain-boundary oxide in the oxidation strengthening of nickel during creep at 817 °C. Prom the inverse dependence of the rate of bonding on the thickness of the starting oxide, it is suggested that the rate of diffusion of Ni++ through NiO is the controlling process at the start of sintering. Cornparisons of the creep and rupture strength and of the microstructure of sintered couples with conventionul creep specimens suggest rupture in nickel is prevented by load-bearikzg, ikltergranular layers of oxide. A number of recent investigations have shown that at high temperature and low stress the creep-rupture strength of nickel and nickel-base alloys may be much greater in air than in an inert gas or vacuum.&apos;-7 For example, at 817°C and 2500 psi, nickep failed in vacuum in 48 hr but not in air after 4000 hr, and a Ni-Cr-A1 alloy5 at 1038°C and 3000 psi failed in vacuum in 4 hr but not in air after 731 hr. Fig. 1 is a typical creep curve in air for materials experiencing this pronounced environmental strengthening. A common feature of these curves is the entry into a third stage of accelerating creep, concurrent with the for-

Jan 1, 1962

By E. B. Mayo

David LeCount Evans (Consulting Petroleum and Mining Geologist, Wichita, Kans.)-—Not only E. B. Mayo but also W. C. Lacy, who apparently urged the preparation of this analysis, is to be commended. Regional thinking of this type is needed to assure future success in the never-ending search for new mineralized and petroliferous districts. As is usually the case, here is a regional study that will be read by the mining geologist alone. It is ironic that several of the trends established in this study have suggested themselves in northern mid-continent, detailed, and regional studies. These, where established, have offered new keys to petroleum exploration and have provided a possible basis for unraveling a number of broad generalities. The oil geologists, active in Colorado, Kansas, and Oklahoma, would find much food for thought in Mr. Mayo&apos;s projections. To be more specific: 1) The parallelism between E. B. Mayo&apos;s Texas Lineament and the Amarillo Uplift, the Wichita Complex and the Arbuckle Complex of the Texas Panhandle and Southern Oklahoma is viewed with interest and appears especially significant when compared with the similar northwest trend of the Central Kansas Uplift, a major trend of production. 2) Considering the various northeast zones of Fig. 2, and with particular reference to Mayo&apos;s C-C, the Jemez Zone is on direct line with one of several northeast-southwest controls which the present writer has been using with some success in Kansas subsurface correlations. Considering zones of shearing, with no apparent vertical displacement, but suggesting strike-slip movement, because of the staggered effect on other features which cross such trends, Mayo&apos;s philosophy presents regional possibilities for lines of weakness, considered to this time of only local significance. 3) And, finally, in an area as distant from the Southwest as central Kansas, the north-south trends of the Fiarport-Ruggles anticline, the Voshel-Hol-low Nikkel-Burrton structures, the Dayton to Stut-gart trend, the north, slightly east trend of the Ne-maha structural complex, and others all seem to approach the north-south alignments, a through f, of Mayo&apos;s Fig. 3. Mayo&apos;s employment of structural intersections to pinpoint crustal weakness, to localize igneous activity and its accompanying mineralization is not, perhaps, a new concept, but it is a 1958 model, produced by tools improved from the ever-increasing accumulation of geological observations. The use of intersecting trends in petroleum geology is not a new idea, since much production in earlier days was encountered via the straight line projections of established trends to centers of intersection. A tragedy in this age of specialization is that iron curtains have been raised between groups, all seeking raw materials, all acolytes at the altar of structural geology, but all smugly content in and protected by the ivory towers of petroleum geology, engineering geology, mining geology, and geophysics. Mayo presents basic ideas which can stimulate mid-continent structural thinking and, in the case of cen- tral Kansas. he provides a key to replace the broad and overworked simple monoclinal, sinkhole-dotted, Karst topography credo, which is not finding its share of new oil in a state where the declining discovery ratio is disconcerting. The American Association of Petroleum Geologists would do well to add E. B. Mayo to its list of Distinguished Lecturers. Evans B. Mayo (author&apos;s reply)—In reply to David LeCount Evans&apos; comments, it is pleasing to learn that some of the elements discussed in my paper may interest petroleum geologists as well as mining geologists. This should not be surprising, however, because the lineaments make up the framework of the continent, and the oil-bearing sediments must reflect to varying degrees adjustments of basement blocks along their boundaries. A further possibility that petroleum geologists must have considered is that the slow escape of heat from buried lineaments and their intersections has aided the separation of oil from the sediments and started the migration into traps. Regarding the specific points listed by Evans, the following are suggested: 1) The branch of Texas Lineament marked 1&apos; (Fig. 3) is thought to extend eastward through the Capitan Mts., New Mexico, through the long Tertiary dikes east of Roswell, and beyond via the Matador and Electra ranges of the Red River Uplift, Texas. Its further continuation might be the eastern flank of the Ouachita Fold Belt. The Amarillo-Wichita-Arbuckle zone of uplifts appears to continue east-southeastward the Spanish Peaks belt (3-5, Fig. 3). The northwest-trending Central Kansas Uplift would not belong to the above set, except insofar as the Central Kansas Uplift is traversed by west-northwest folds, possible continuations of the Uinta belt (5-5, Fig. 3). 2) The possible continuations into Kansas of the Jemez zone are new to me and are most welcome suggestions. 3) Most of the nearly north-south Kansan structures mentioned by Evans are unfamiliar to me, but the Nemaha Uplift itself appears to be part of a very pronounced structure traceable from the Cerralvo Fault Zone, south of the Rio Grande, through the Bend Arch, Texas, and the Nemaha Uplift, into the Pre-Cambrian of Minnesota (?). This nearly meridional zone is crossed and broken by the Rio Grande Embayment and by the Red River-Wichita Syntaxis. Petroleum geologists realize the economic importance of these features. Perhaps it is inevitable that some papers of general interest be buried in the journals of specialized groups. Moreover, papers dealing with regional, or lineament, tectonics and its applications to exploration for economic mineral deposits are as yet few in the American literature. The opportunity to advance this field is open to all those who are not ultra-conservative and who have a lively curiosity, plenty of patience, and not too many business restrictions. In conclusion, much appreciation is extended to D. L. Evans for his comments.

Jan 1, 1960

By G. H. Cutter

SAFETY in mining depends on wire rope to as great, if not greater, extent than in any other industry. Sudden failure of a shaft-hoist rope might easily result in death or serious injury to the operators and workmen, extensive damage to expensive equipment, and a loss in production while repairs are being made. A wire rope is only as good as its component parts. It must be made from wire properly drawn and treated. It must be fabricated on machines large enough and capable of imparting the necessary qualities to meet the stringent service conditions. However, unless the fundamental requirement of good ropemaking is recognized, all other operations, no matter how carefully performed, will not impart reliability and quality to the product. This fundamental requirement is steel that is homogeneous, of high resistance to fatigue, and of a type suitable for rope wire. Most wire-rope manufacturers agree that rope wire should be made from acid-open-hearth steel. It is comparatively easy to meet the same physical properties with basic steel, but such properties are only part of the requirements for good wire. It is absolutely necessary, particularly for rope service such as mining, where reliability is essential, that the wire be uniform throughout its entire length. Most manufacturers feel that this highly important requirement is better met by acid-open-hearth steel.

Jan 1, 1936