Search Documents

By Leonardo Carneiro Andrade

O desenvolvimento de materiais renováveis e biodegradáveis é uma vertente que almeja a diminuição dos custos e dos impactos ambientais. Nesse âmbito, o presente trabalho visa o desenvolvimento de novos materiais, fabricados com fibras vegetais e que possam substituir outros que são derivados do petróleo. Fibras vegetais foram utilizadas e devidamente modificadas por mercerização e acetilação com o intuito de produzir materiais com compatibilidade química. Foram obtidos, nesse trabalho, compósitos de polietileno reciclado reforçados com fibras de sisal[1]. Utilizamos a ferramenta estatística denominada distribuição de Weibull, para prever as falhas mecânicas dos sistemas estudados. Foi possível observarmos que o compósito resultante teve uma melhora relativa em suas propriedades mecânicas, o que pôde ser comprovado por meio dos ensaios de tração. A distribuição de Weibull foi uma ferramenta que produziu resultados de acordo com os esperados, comprovando a melhoria de propriedades mecânicas do material.

Oct 30, 2017

By Amauri Garcia, Noé Cheung, André dos Santos Barros, Clarissa Barros da Cruz, Thiago Soares Lima, Rafael Kakitani

Materiais de interface térmica (Thermal Interface Materials - TIMs) são responsáveis pela troca térmica entre a fonte geradora de calor do processador integrado e o dissipador de calor. Devido ao seu baixo ponto de fusão, boa fluidez e cumprimento com as exigências de regulamentação (Restriction of Hazardous Substances - RoHS), ligas à base de bismuto têm sido investigadas para aplicação como TIMs de alta performance. Neste contexto, a análise das propriedades dessas ligas em função de parâmetros microestruturais torna-se, portanto, de elevado interesse científico e tecnológico para o setor eletrônico. Assim, este trabalho tem como objetivo desenvolver correlações entre propriedades de resistência à tração e a microestrutura da liga Bi-0,28%Ni solidificada sob um intervalo de taxas de resfriamento usualmente obtido em processos industriais. Por meio de microscopias óptica e eletrônica de varredura foi observada uma morfologia tipicamente eutética lamelar, composta por lamelas ricas em bismuto com o intermetálico Bi3Ni nos contornos. Os espaçamentos lamelares (λL) foram, então, correlacionados com os parâmetros térmicos de solidificação, sendo propostas leis experimentais de crescimento microestrutural. Ao fim, observou-se que, para λL < 101 μm, equações do tipo Hall-Petch caracterizam a variação do limite de resistência à tração e do limite de escoamento.

Oct 1, 2019

By G. Paquet, E. Godin

"Since the mid fifty's, worlwide pellet production capacity has constantly risen (Fig. 1, Ref. 1 l. There was however at that time no real incentive to decrease production costs but only to produce as many pellets as possible. State of things changed with the iron and steel market recession, starting in 1975, and is currently leading producers to improve pellet quality and to reduce fuel and power consumption.At the Port-Cartier pellet plant, the energy needed for the induration of pellets ranks first in overall operating costs. An important step was made when starting admixing coke breeze in 1980. Oil prices justified the use of coke breeze as a direct replacement in terms of dollar/ton, however, while gaining expertise in using solid fuel a significant decrease in energy consumption was observed (Fig. 2, Ref. 2).In 1985, the ""Centre de Recherches minérales"" was commissioned to undertake research work to investigate the effects of further increasing coke addition to the pellet mix. The positive results of that work led to a 1,5% coke addition plant trial during the fall of 1985. Both laboratory and industrial results are discussed in this paper."

Jan 1, 1986

By G. Warren

"In the past, smelting and refining of the precious metals recovered from ore has been generally looked upon as a small and relatively minor component of the business of gold mining. This is not surprising when one considers that the manpower, space and capital components of a gold refinery at an operating mine can be several orders of magnitude smaller than other unit operations at the same location. This philosophy is changing however, as economic and environmental pressure are forcing a re-evaluation of all aspects of gold mining and milling.This paper describes and evaluates three furnace technologies available and used by precious metal operators. The operation of arc, induction, and reverberatory furnaces are discussed and their strengths and weaknesses with respect to capital cost, impurity removal, slag quality, and environmental concerns highlighted.INTRODUCTIONIn the past, smelting and refining of precious metals recovered from ore has been generally looked upon as a small and relatively minor component of the business of gold mining. This is not surprising when one considers that the manpower, space, and capital components of a gold refinery at an operating mine can be several orders of magnitude smaller than other unit operations at the same location. Generally, gold producers will spend a great deal of effort to squeeze the last drop of efficiency out of a leach or grinding circuit via simulation or testwork but will design and build the refinery based upon past practices or industry standards. That past practices or industry standards will provide a functional refinery is undisputed; that this philosophy achieves the efficiencies that are possible or demanded in other plant operations is debatable.Environmental and worker hygiene requirements are considerations as well. Pollution control equipment can become a substantial contributor to both the capital and operating costs of a refinery and furnace selection has a marked influence upon the type and cost of this equipment. Slag characteristics and subsequent processing options available also play a role in furnace selection as precious metal slag losses and the recovery effort can greatly influence the cost / benefit analysis of a particular technology."

Jan 1, 2001

By Guangdong Institute of Resources Comprehensive Utilization, Y. H. Tang, H. X. Hu, T. S. Dong, Z. H. Zhang

"A world class rare metals ore deposit in Africa belongs to a massive granite type poly-metallic pyrochlore-niobium resource. Successful project development in realizing the resource is vital to Africa’s economy and pyrochlore processing technology.The ore properties are quite complex due to the presence of varieties of valuable minerals, fine dissemination and intimate association of minerals and the relative abundance of easy-floatable minerals. The separation of pyrochlore from zircon, calcite and mica is generally considered difficult. Whilst studies have previously been conducted by several independent institutions overseas, no satisfactory process has yet been developed to date for the ore deposit—possibly due to the process designed being too complex; high cost of regents; lower performance.Based on process mineralogy study and extensive testwork, the authors have in recent years developed a new technology—“De-slime—Iron-rejection—Zircon (with calcite) and Calcite reverse flotation—Pyrochlore flotation”. The flow-sheet is characterized by ?1prior removal of slimes and iron minerals; ?2 Zircon (with calcite) and Calcite reverse flotation; and ?3Pyrochlore flotation applying new type of chelating collector GYX3 developed by GZRINM in conjunction with selected regulators and depressants.The process involved in the new technology is simple to implement and facilitates stable operation; the flotation reagent regime is easily adaptable; the cost of main reagent is lower largely because it is easy to manufacture and is environmental friendly. Laboratory test results demonstrated that, for raw ore assaying 0.35% Nb2O5, 0.03% Ta2O5 and 0.45% ZrO2, pyrochlore concentrate grade of >35% Nb2O5 could be obtained with >74% recovery. Meanwhile, the Ta2O5 content in pyrochlore concentrate could be recycled, and ZrO2 recovery >50% could be achieved in zircon concentrate assaying ZrO2>63%—significantly improving the technical-economic indicator. These results were verified in pilot trials of 1.44t/d throughput. The paper presents the new technology in whole, summarizes the key factors affecting its performance and discusses in simple terms the mechanism of separation."

Jan 1, 2016

By Guangdong Institute of Resources Comprehensive Utilization, Y. H. Tang, H. X. Hu, T. S. Dong, Z. H. Zhang

"A world class rare metals ore deposit in Africa belongs to a massive granite type poly-metallic pyrochlore-niobium resource. Successful project development in realizing the resource is vital to Africa’s economy and pyrochlore processing technology.The ore properties are quite complex due to the presence of varieties of valuable minerals, fine dissemination and intimate association of minerals and the relative abundance of easy-floatable minerals. The separation of pyrochlore from zircon, calcite and mica is generally considered difficult. Whilst studies have previously been conducted by several independent institutions overseas, no satisfactory process has yet been developed to date for the ore deposit—possibly due to the process designed being too complex; high cost of regents; lower performance.Based on process mineralogy study and extensive testwork, the authors have in recent years developed a new technology—“De-slime—Iron-rejection—Zircon (with calcite) and Calcite reverse flotation—Pyrochlore flotation”. The flow-sheet is characterized by ?1prior removal of slimes and iron minerals; ?2 Zircon (with calcite) and Calcite reverse flotation; and ?3Pyrochlore flotation applying new type of chelating collector GYX3 developed by GZRINM in conjunction with selected regulators and depressants.The process involved in the new technology is simple to implement and facilitates stable operation; the flotation reagent regime is easily adaptable; the cost of main reagent is lower largely because it is easy to manufacture and is environmental friendly. Laboratory test results demonstrated that, for raw ore assaying 0.35% Nb2O5, 0.03% Ta2O5 and 0.45% ZrO2, pyrochlore concentrate grade of >35% Nb2O5 could be obtained with >74% recovery. Meanwhile, the Ta2O5 content in pyrochlore concentrate could be recycled, and ZrO2 recovery >50% could be achieved in zircon concentrate assaying ZrO2>63%—significantly improving the technical-economic indicator. These results were verified in pilot trials of 1.44t/d throughput. The paper presents the new technology in whole, summarizes the key factors affecting its performance and discusses in simple terms the mechanism of separation."

Jan 1, 2016

By Moacir Alves dos Reis

O objetivo deste trabalho foi criar um projeto de um simulador do sistema de carregamento do Alto Forno 2, voltado para o treinamento de operadores e técnicos em manutenção. O principal objetivo está em produzir uma ferramenta que auxilie no processo de ensino dos operadores e técnicos de forma mais rápida e segura, reduzindo os custos do treinamento e ao mesmo tempo simulando situações de operação, alarmes de processos sem interferência no sistema de carregamento real. São apresentadas as etapas previstas para o desenvolvimento do projeto e as ações já realizadas até o presente momento. O simulador será equipado com equipamentos reais do sistema de carregamento do Alto Forno, sendo apenas simulado as entradas e saídas físicas (I/O) dos equipamentos externos (motores, limites, válvulas, etc.) e utilizará um ambiente virtual modelado a partir do PLC, SDCD e Monitores para que os operadores possam visualizar e simular todos os alarmes deste processo.

Jul 30, 2018

By Defeng Zhou, N. Trubaki, Jian Meng, Fanzhi Menga, Xiaojuan Liu, Yanjie Xia

"The microstructure and the electric conductivity of (Ce0.9Nd0.1)1 xMxO2 d (M=Mo, W) solid solutions were investigated. It has been found that their conductivity containing the grain (s gi ), the grain boundary (s gb) and the total conductivity (s t ) at 300°C- 700°C can be ranked as: (Ce 0. 9Nd 0. 1 ) 0.99 W 0.01 02- d (s gi = 0.065 S.cm·1, (s gb = 0.265 S.cm·1, s t = 0.039 S.cm-1) > (Ce0.9Nd0.1)0.99Mo0.01O2- d (s gi = 0.053 S.cm·1, s gb = 0.142 S.cm·1, s t = 0.029 S.cm-1) > Ce0.9Nd0.1 s 2- d (s gi 0.045 S.cm-1, s gb = 0.091 S.cm-1, s t = 0.018 S.cm-1) measured at 700°C. The highest conductivity is obtained in (Ceo.9Ndo.1)0.99W0.01O2 d. These results indicate that (Ceo.9Nd0.1)0.99W0.01O2- d is the most promising electrolyte materials of intermediate-temperature solid oxide fuel cells among (Ce0.9Nd0.1)1-xMxO2- d. IntroductionRare-earth (e.g. La3+, Nd3+, Gd3+ and Sm3l doped ceria-based ceramic materials have been acknowledged to be attractive electrolytes for solid oxide fuel cells operating below 600°C due to their high ionic conductivity [1, 2]. In order to improve ionic conductivity of these electrolytes further, in recent reports [3-6], some aids such as Mo03 [3] etc. in a limited amount can be used which causes extremely high conductivity. For example, Zhou et al. found that with MoO3 doping, the grain boundary conductivity of Nd3+ doped CeO2- d increased notably especially at lower temperatures due to the effect of severely undersized do pants [3]. It is well known that the size of W6+ (rw6+ = 0.60 Å) is close to Mo6+ (rMo6+ = 0.62A) because of lanthanide shrinkage. Thus, rare-earth doped ceria e.g. Nd3+ doped CeO2g with WO3 in a limited amount will be probably good and even better electrolytes. However, much less information is available about these materials. Therefore, in our paper, (Ce0.9Nd0.1)0.99 1-xMxO2- d (M=Mo, W) solid solutions have been prepared and characterized. Much higher conductive electrolytes are found in the series of (Ce0.9Nd0.1)0.99 M0.01O02- d particularly (Ce0.9Nd0.1)0.99W0.01O2- d"

Jan 1, 2012

By Filipe Sathler

O Alto Forno 3 da ArcelorMittal Tubarão (Volume interno: 3617 m3) esteve em operação do dia 21 de Julho de 2007 a 10 de Novembro de 2012 durante a sua primeira fase da primeira campanha. Após os devidos reparos e planejamento técnico-operacional, o procedimento de Blow in da segunda fase desta campanha foi realizado no dia 6 de Julho de 2014, apresentando também um processo bem sucedido de evolução de produção (ramp up) e resultados importantes com a redução do consumo de coque (coque rate) ao longo dos primeiros meses de operação.

Aug 17, 2017

By Kirk Ellison, Sherif Elfass, Ramin Motamed, Kevin V. Stanton

"The determination of accurate load transfer curves are essential for estimating deep foundation loadsettlement response using t-z style analyses. While recently developed semi-empirical methods from Ashour et al. (2010) and Ashour & Helal (2012) have shown promise in preliminary studies, they have not yet been thoroughly benchmarked against a more widely accepted approach. To address this issue, these recent procedures are implemented in the computer program CGI-DFSAP to predict the results of four Osterberg-cell (O-Cell) load tests. These predictions are compared to outcomes obtained following the recommendations from Reese & O’Neill (1988) for t-z analyses of drilled shafts in sand and clay which are carried out with the program TZ-PILE. Overall, the results suggest that the new approach offers improved accuracy regarding predictions of drilled shaft response to axial loading.INTRODUCTIONThe behavior of axially loaded deep foundations is often analyzed using a technique known as the t-z method. In this method, deep foundation elements are broken into multiple segments which are supported by discrete nonlinear springs to capture the contribution of both side-friction (t-z springs) and end-bearing (Q-z springs). Hence, the t-z and Q-z relationships dictate the predicted load-settlement response. A number of different approaches have been developed to estimate load-transfer curves with some relying solely on empirical data from laboratory and field experiments (i.e. Coyle & Reese, 1966; Vijayvergiya, 1977) and others based mainly on analytical frameworks (i.e. Kraft et al., 1981; Randolph, 1994). Reese & O’Neill (1988) provide recommendations which are widely used for developing t-z and Q-z curves for analyzing drilled shafts. This method is hereafter referred to as Method 1 (M1). It should be noted that these empirically derived relationships are only applicable for problems associated with drilled shafts and are therefore not appropriate for developing load-transfer curves for other types of deep foundations (i.e. driven piles). This is because of the difference in the frictional resistance which can be developed between a circular concrete-soil interface as opposed to that of other materials (i.e. steel) and/or different cross sectional geometries.The M1 load-transfer curves form the basis for the t-z analysis of drilled shafts implemented in the computer program TZ-PILE (Ensoft, 2014). In light of this, TZ-PILE is employed herein as a reference to compare against the capabilities of another method of implementing t-z style analyses. This method is based on a semi-empirical framework for soil behavior developed by Norris (1986) and is implemented using the program CGI-DFSAP (Computers & GeoEngineering Inc., 2011). More information concerning this approach, hereafter referred to as Method 2 (M2), is given in subsequent sections."

Jan 1, 2017

By Ricardo Filipe Teixeira Moreira

O trabalho mostra um estudo de caso da ArcelorMittal Tubarão onde, com o objetivo de incrementar a reciclagem de escórias de dessulfuração, foram analisadas as influências do processo de beneficiamento por separação magnética de forma a obter um coproduto com menor presença de S e maior concentração de Fe e assim permitir sua maior reutilização na Sinterização. O projeto se desenvolveu em etapas de amostragem, caracterização, testes experimentais de laboratório, processamento em escala industrial e, por fim, com a adição do coproduto na Sinterização e compilação de resultados. O trabalho conclui a viabilidade de alteração das configurações de processamento com resultados positivos permitindo incremento de consumo de escórias de dessulfuração na Sinterização com ganhos financeiros e ambientais.

Aug 16, 2017

By C. H. Ash

"The Red Chris Cu-Au deposit (522.7 Mt at 0.35% Cu and 0.27 g/t Au), northwestern British Columbia, is one of several pre-accretionary porphyry systems in the Cordillera of westernCanada. It is hosted by an Early Jurassic hornblende monzonite to quartz monzodiorite porphyry which forms part of a suite of dikes and stocks that intrude Late Triassic volcanic strata. Major and trace element chemical data suggest that these Early Jurassic intrusions have compositions which fall on the boundary between alkalic and calc-alkalic compositions. Alteration and mineralization in the Red Chris deposit are more typical of calc-alkaline porphyry systems with abundant potassic, sericitic and argillic assemblages and quartz-rich stockworks. It lacks Na- and Ca-bearing silicate assemblages which characterize the alkalic porphyry deposits of British Columbia. One of the more unusual features of the deposit is the abundance of carbonate alteration and veins which occur throughout the hydrothermal history of the deposit. This type of alteration and veining is more typical of alkalic porphyry deposits.The composition of the carbonates vary both temporally and spatially with different alteration zones. Potassic zones, which are characterized by orthoclase±albite±quartz±chalcopyrite±bor-nite±magnetite±hematite and Au/Cu ratios of 1:1 (g/t Au:% Cu), contain minor siderite veins and alteration. Quartz-sericite-carbonate (QSC) zones overprint earlier potassic alteration and comprisequartz+ankerite+sericite+pyrite+chalcopyrite with Au/Cu ratios of 0.5:1 (g/t Au:% Cu). Ankerite isthe main carbonate in this stage but has a variable composition with a more Fe-rich variety associated with mineralized veins. Localized chlorite-carbonate alteration zones, characterized by chlorite+carbonate+quartz±kaolinite±pyrite±gypsum and high Au/Cu ratios [2 to 3.5:1; (g/t Au:% Cu)],contain predominantly calcite. Late stage carbonate-gypsum veins have an ankerite to dolomite com-position which is very similar to the regional carbonate alteration and veins."

Jan 1, 1997

By Li Keqiang

Among the pile foundations of the 156 tall buildings over 18 storeys in Shenzhen, 86. 5% of them are constructed by slurry drilled piles, bored piles and excavated piles (hand-dug caissons). Based on the experiences of the engineering practices, the paper points out that the main quality problems of pile foundations in Shenzhen are: insufficient bearing capacity of single pile; poor concrete quality of pile; damage of the precast pile; pile tip not reaching the required bearing stratum and the thickness of bored/drilled sediment exceeding the specified. etc. The quality inspection methods that have been used include: check of construction records and excavating; static loading test; core sampling test; non-destructive test, etc. Treatments of quality problems used in Shenzhen are also introduced in this paper.

Jan 1, 1991

By Y. Bai, J. J. Liu, D. Q. Li, S. Z. Liu, X. T. Wang

"This paper presents the results of an industrial test using 8 t/d of Baotou concentrate (50% REO) of a clean metallurgical process, which includes: 1. Roasting with H2SO4 at low temperature (220~260 0C) in a batch roasting furnace followed by water leaching to obtain a leach liquor as feed with a yield of >95% RE and Th, recovering F as fluoride, producing a leach residue amounting to 1/3 of an equivalent high temperature residue and containing <0.03% Th and radioactivity < 3×104 Bq/kg compared to the normal high temperature residue containing 0.2-0.3% Th and 1×105 Bq/kg. 2. Separating Th with N1923 and extracting RE by P507 has been completed in mixer-settlers. Test results indicate that the ThO2 product has a purity of > 95% with a yield of 99%, and the RE has a yield of >95%, in which ThO2/REO <5×10-6, and that P507 loaded RE connect straight with separating RE using P507-HCl system. 3. Treatment and multipurpose use of "three wastes" (water, gas and solids) are discussed in some detail."

Jan 1, 2014

By Ariella Vianna Fontes

Os dutos de plástico reforçados com fibra de vidro, devido a sua boa relação entre resistência mecânica, peso e resistência à corrosão, são amplamente utilizados, por exemplo, na indústria petrolífera. Todavia as conexões de vários trechos desses dutos, realizadas por juntas adesivas, podem apresentar defeitos como a falta de adesão e a falta de adesivo, tornando-se pontos propícios ao colapso. Até o momento ainda não há uma metodologia de ensaio não destrutivo consolidada, capaz de avaliar a integridade das juntas adesivas. A técnica mais utilizada é o ensaio de ultrassom, porém com fortes limitações. Dentro desse contexto, o presente trabalho apresenta a caracterização dos defeitos utilizando a técnica de microtomografia 3D, visto que esta permite examinar a estrutura interna do material. Foram confeccionados e avaliados corpos de provas contendo os defeitos típicos encontrados em campo. Os resultados mostraram que a técnica utilizada é adequada para caracterização qualitativa e quantitativa dos defeitos típicos em juntas adesivas encontrados em campo.

Aug 16, 2017

By Sidiney Nascimento Silva

O trabalho descreve os principais resultados dos testes industriais realizados na Usina Presidente Vargas, CSN, Brasil, envolvendo a adição de um catalisador à mistura de carvões, em termos da qualidade do coque e do processo da coqueria. O catalisador em questão é o produto Thermact, que possui partículas nanométricas em sua composição, fornecido pela empresa Abhitech Energycon Limited, Índia. O catalisador foi dosado e adicionado à mistura de carvões via correia transportadora, na proporção, em peso, de 1kg de catalisador para 4.000kg da mistura de carvões. Os resultados dos testes realizados nas Baterias # 1, 4A, 4B e 5 com a adição de um catalisador à mistura de carvões, sinalizaram a viabilidade técnica e financeira da sua aplicação no processo da coqueria. Os principais benefícios decorrentes da adição do catalisador foram: i) aumento potencial da capacidade de produção de coque ao redor de 10% ou, alternativamente, melhoria da qualidade do coque - aumento de 1,4% do valor médio do índice de resistência mecânica a frio do coque, DI150/15, mantendo-se o tempo total padronizado do processo de coqueificação, visando à preservação das Baterias, ou ainda, a utilização de uma mistura de carvões de menor custo, sem prejuízos ao atendimento à especificação do coque para os Altos-Fornos; b) aumento da geração e redução do consumo de gás de coqueria, GCO; iii) aumento na produção de BTX (Benzeno, Tolueno, Xileno) e redução da produção de alcatrão na Planta de Carboquímicos; iv) limpeza do sistema “PROven”, “goosenecks”, tubos de ascensão e paredes dos fornos, sinalizando a sua viabilidade técnica e econômica.

Aug 1, 2018

By Mônica Aline Magalhães Gurgel

A crescente preocupação da indústria automobilística com questões ambientais e com a segurança do condutor e passageiros, fez com que o setor siderúrgico desenvolvesse aços com maior valor tecnológico, entre eles surgiu os aços avançados de alta resistência, onde encontra-se o “Dual Phase” (DP) utilizado nesse estudo, que é caracterizado por uma microestrutura associada a uma matriz ferrítica com ilhas dispersas de martensita. Neste trabalho utilizou-se amostras de um aço baixo C e Mn, com micro adição de Nb e Mo, em desenvolvimento, onde se propôs uma avaliação das propriedades mecânicas através de um Ultramicrodurômetro, as amostras extraídas após a laminação a frio seguiram para o recozimento intercrítico, em escala laboratorial, com auxílio de forno Mufla e um equipamento de análise termomecânica (TMA), com 7 temperaturas de encharque distintas e subsequente resfriamento com patamar isotérmico a 600°C por 20 minutos. Onde observou-se que a utilização do ultramicrodurômetro instrumentado mostrou ser uma ferramenta com grande potencial para a avaliação almejada.

Aug 17, 2017

By C. M. Moncrief, B C. Craft

A bentonite-clay drilling mud when treated with tetrasodium pyroarsenate underwent substantially the same reduction in viscosity and water loss as when treated with the complex phosphates. The complex arsenate showed a slightly higher reversion after heating; the other arsenates showed poor viscosity-reducing properties. Introduction During the past 10 years the chemical control of drilling mud has become of major importance in affecting the successful drilling and working over of wells. The desired properties of drilling mud have been well established, and in obtaining these characteristics there has developed a large market for viscosity-reducing chemicals. Viscosity reduction produced by humic acid, tannic acid, sodium silicate, sodium tannate, Calgon, and the complex phosphates has been described by Loomis, Ford, and Fidiam.l The effects Of treatment with complex phosphates and ammonium PolyPhosPhates on the rheological properties of muds were investigated by Fancher2 and the alkali vanadates have been described by Williams.3 Laboratory Investigations It is the purpose of this paper to point out the effects of arsenates in controlling the viscosity and gelling characteristics of a drilling mud. Viscosities and gel strengths were measured at room temperatures with a Stormer viscosimeter calibrated in centipoises and operated at 600 r.p.m. Water loss was determined at 80°F. with the Baroid low-pressure wall-building tester at a pressure of I00 lb. per sq. in. for 30 min. The hydrogen-ion concentration was measured with a glass electrode. The bentonite-clay suspensions were prepared in the laboratory and allowed to age several days before testing. Members of the Arsenic Group in the periodic Table include arsenic, antimony and bismuth, but this investigation was limited to arsenic. Phosphorus also occurs in Group V of the Periodic system and phosphorus and arsenic form many closely related compounds such as pH3 and AsH3, P2O5 and As2O5, H3PO4 and H3AS04 Samples of tetrasodium pyroarsenate were prepared by fusing c.p. disodium arsenate (Na2HA5O4.7H2O). According to Friend,&apos; this re-forms the ortho-arsenate on dissolution in water. Sodium trihydrodiorthoarsenate was prepared as described by Mellor,5 from arsenic pen-toxide as follows: As2O5 + 3H20 -> 2H3AsO4 2H3AS04 + 3NaOH Na3H3(AsO4)2 .3H20 Sodium dihydrogen orthoarsenateWaHz-As04) was obtained by fusing together equivalent quantities of arsenious Oxide and sodium nitrate, dissolving the residue in water and allowing it to crystallize.

Jan 1, 1946

By C. M. Moncrief

A bentonite-clay drilling mud when treated with tetrasodium pyroarsenate underwent substantially the same reduction in viscosity and water loss as when treated with the complex phosphates. The complex arsenate showed a slightly higher reversion after heating; the other arsenates showed poor viscosity-reducing properties. Introduction During the past 10 years the chemical control of drilling mud has become of major importance in affecting the successful drilling and working over of wells. The desired properties of drilling mud have been well established, and in obtaining these characteristics there has developed a large market for viscosity-reducing chemicals. Viscosity reduction produced by humic acid, tannic acid, sodium silicate, sodium tannate, Calgon, and the complex phosphates has been described by Loomis, Ford, and Fidiam.l The effects Of treatment with complex phosphates and ammonium PolyPhosPhates on the rheological properties of muds were investigated by Fancher2 and the alkali vanadates have been described by Williams.3 Laboratory Investigations It is the purpose of this paper to point out the effects of arsenates in controlling the viscosity and gelling characteristics of a drilling mud. Viscosities and gel strengths were measured at room temperatures with a Stormer viscosimeter calibrated in centipoises and operated at 600 r.p.m. Water loss was determined at 80°F. with the Baroid low-pressure wall-building tester at a pressure of I00 lb. per sq. in. for 30 min. The hydrogen-ion concentration was measured with a glass electrode. The bentonite-clay suspensions were prepared in the laboratory and allowed to age several days before testing. Members of the Arsenic Group in the periodic Table include arsenic, antimony and bismuth, but this investigation was limited to arsenic. Phosphorus also occurs in Group V of the Periodic system and phosphorus and arsenic form many closely related compounds such as pH3 and AsH3, P2O5 and As2O5, H3PO4 and H3AS04 Samples of tetrasodium pyroarsenate were prepared by fusing c.p. disodium arsenate (Na2HA5O4.7H2O). According to Friend,&apos; this re-forms the ortho-arsenate on dissolution in water. Sodium trihydrodiorthoarsenate was prepared as described by Mellor,5 from arsenic pen-toxide as follows: As2O5 + 3H20 -> 2H3AsO4 2H3AS04 + 3NaOH Na3H3(AsO4)2 .3H20 Sodium dihydrogen orthoarsenateWaHz-As04) was obtained by fusing together equivalent quantities of arsenious Oxide and sodium nitrate, dissolving the residue in water and allowing it to crystallize.

Jan 1, 1946

By Flávio de Castro Dutra

Este artigo apresenta a influência da temperatura e da atmosfera de secagem sobre a resistência mecânica de um aglomerado esférico, com diâmetro entre 3 mm e 8 mm, constituído de pellet feed e silicato de sódio, produzido através de pelotamento em discos e endurecido em temperaturas até 550ºC. O aglomerado obtido a partir deste processo apresenta características que permitem que o mesmo possa ser transportado a longas distâncias e manuseado até a sua utilização na sinterização. As principais técnicas experimentais utilizadas neste estudo foram difração de raios-X, espectroscopia Raman, microscopia eletrônica de varredura e análise térmica. O aglomerado foi submetido à secagem em temperaturas entre 100°C e 550ºC e atmosferas constituídas de ar atmosférico e/ou CO2. Durante o processo de secagem, observou-se a influência da temperatura e da atmosfera sobre a resistência à compressão do aglomerado após exposição à água, assim como na morfologia do silicato de sódio, evidenciando uma dependência entre elas. O uso de CO2 durante a secagem mostrou-se eficiente para a formação de um aglomerado com maior resistência mecânica após exposição à água.

Aug 2, 2018