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By John R. Koehler

Available barrier pillar design methods do not adequately account for overburden caving characteristics, the timing and magnitude of associated load transfers, the occurrence of unusual geologic features, or the effects of multiple-panel/multiple-seam mining. To address this problem, the Bureau of Mines, in cooperation with Cyprus Plateau Mining Corporation, conducted a barrier pillar study in a multiple-seam mine setting. Insufficient barrier width resulted in excessive load transfer to an adjacent/underlying section. Consequent entry and pillar deterioration resulted in the section being prematurely abandoned. This paper proposes an approach based on in situ measurements, which includes mine-specific loading conditions in the barrier design process.

Jan 1, 1989

By Miklos D. G. Salamon

If all stratifications are horizontal, the computation of surface deformation induced by coal mining involves the prediction of roof and floor convergence and then the transfer of the effects of this relative displacement to the surface through the use of the appropriate influence functions. A laminated model, in the form of a quasi- continuum, provides a simple means of computing the approximate convergence distribution and leads to the Gaussian distribution as the influence function. The ideas presented in this paper represent a subtle but fundamental generalization of the influence function Method. It is postulated that the influence of a small area of extraction is proportional to the roof and floor convergence and not to the thickness extracted. This difference in definition removes many conceptual difficulties associated with the influence function method. To demonstrate the utility of the model, the surface disturbances induced by the extraction of a parallel sided long panel are derived. Formulae giving subsidence, tilt, horizontal displacement and strain are given.

Jan 1, 1989

By C. E. Munroe

In order to meet the emergencies of the world wr, tne quantities of explosivea produced in the Unitecl States, and the number of explosives plants were onti:.1.1.:l,lly ncreased so that when the armistice was declared the Government had on hand larg ..mounts oi militazy explosives in excess of existing military needs. Tle stor3.gs of these explosives entailed a liirge expense and their protection neessitatei the employment of m'3.l'lY men who could be better employed otherwise in the military estlish.11ent. Moreover, mar.y ex.ploives, like QJ.l other material, deteriorate on prolonged storage, They lose tht precise definiteness of properties and behavior on which reliance· is placed in military operations, The continued expen3e and d3.nger ttending storage of theae explosives might be diminished by dcst1et1on of the surplus beyond immediate needs, but such·deetniction is danger• ou5 qnd coetly. Hence, the evident solution o! the problem was the salvage d prompt ut111zation of the ru.rplua •

Aug 1, 1922

By G Small, A Lazamanana, C Greet

When conducting gold leach tests on free milling gold ores which method is the best, bottle rolls or the stirred beaker test? Recently, a client requested that gold leach tests be conducted using the stirred beaker methodology. When asked why, because the laboratory was set up to conduct tests using the bottle rolls technique the reply was that the stirred beaker leach test would replicate the plant more closely. Not wishing to upset the client, the instructions were followed. However, the opportunity was taken to complete additional tests so that the two leach procedures could be compared. Further, this comparison was completed on two different gold ores as well as a number of different grinding media types.This paper provides a description of the two laboratory techniques employed, and presents the results of these parallel tests. Interestingly, the assertion that the stirred beaker methodology more closely replicated plant performance was not validated. In fact, the results obtained using this procedure were noticeably different from those observed in the plant, with lower recoveries and significantly higher cyanide consumptions. The bottle rolls test however more adequately replicated plant performance in terms of recovery and cyanide consumption. The reasons for this are discussed in the paper.CITATION:Greet, C, Lazamanana, A and Small, G, 2015. Bottle rolls versus stirred beaker leach testing – which is best?, in Proceedings MetPlant 2015, pp 188–196 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 7, 2015

By Lawrence D. Hoy, Armand Savoie, Pierre Trudel, Ghislaln Tourigny, Robert Crépeau, Lao Kheang

"Recent fluid inclusion and stable isotopic studies in the Bousquet mining district have identified spatial and temporal trends in mineralization temperatures and isotopic compositions of vein forming fluids. These studies indicate that mineralizing temperatures were lower during sterile vein formation (T=200-300°C) than during auriferous vein formation (T = 300-400°C), and that 8 80 values of minerals in sterile veins are lower by 1-3 %o than in associated auriferous veins. In addition to these small differences in 8 80 within individual mineralized zones, a trend of increasing 8 80 values of vein minerals is identified from west to east across the district, with 8 80 of vein minerals increasing by4-6%o. Quantitative evaluation of potential causes of the observed oxygen isotopic shifts suggests that the best explanation for these trends is the derivation of the mineralizing fluids from an isotopically inhomogeneous terrain in which the fluid isotopic compositions are controlled by the isotopic compositions of the host lithologies due to high rock/water ratios in these source terrains. This inhomogeneous source terrain is interpreted as consisting of the Blake River Group volcanics (low 8 80 component) and the adjoining Kewagama and Cadillac Group sediments (high 8 80 component).The genesis of the hydrothermal fluids is attributed to crustal heating during metamorphism, with the fluids representing metamorphic dewatering products and/or fluids incorporated during deposition and burial of the host lithologies. Ductile deformation of the fluid source regions impeded fluid migration during metamorphism; the ultimate release of the mineralizing fluids is attributed to the penetration to depth of vertical structures (fault and shear zones) during brittle deformation of the crust under waning metamorphic conditions. Release of fluids caused by this puncturing of the closed hydrologic source regime produced a localized zone of lowered pressure, drawing fluids from adjacent lithologies toward the fault zones, feeding further hydrothermal fluid upwelling. Au mineralization resulted from chemical processes related to cooling of the hydrothermal fluids and/or interaction with lithologies encountered during fluid migration; the level of crust at which Au deposition occurred likely migrated upward with the thermal anomaly caused by hydrothermal fluid upwelling, eventually reaching the level of current exploitation. Cessation of fluid flow along the vertical structures is attributed to inadequate recharge of the hydrothermal systems as fluid contents were depleted in the lithologies proximal to the vertical structures and/or sealing of the structures by mineral deposition."

Jan 1, 1990

By T. P. Floridis, J. H. Young

The need for close control of the phosphorus content of steels has led to numerous investigations on the equilibria of the dephosphorization reactions. Winkler and chipman1 have established the general conditions for effective dephosphorization of steel. They are high slag basicity, high oxygen potential, and low temperature. Other investigators have made additional contributions to the understanding of the dephosphorization process. The current status of the understanding of the dephosphorization of steel is concisely presented by Bodsworth2 and by Ward. The investigation reported in this communication was undertaken with the purpose of establishing the effect of additions of barium oxide and calcium fluoride on the dephosphorizing capacity of slags. Esin and Gel'd4 proposed that barium oxide, being more basic than calcium oxide, should cause an increase in dephosphorizing capacity when added to steelmaking slags, or when used as a substitute for calcium oxide. Derge5 has also proposed that in the future conventional slags might be replaced by BaO-Al2O3 slags. There is, however, no experimental evidence confirming the effect of barium oxide on the dephosphorizing capacity of slags. The effect of calcium fluoride on the dephosphorization of steel is not clearly understood. It is generally recognized that additions of calcium fluoride are beneficial. It is not clear, however, whether calcium fluoride affects the equilibrium of the dephosphorization reaction, or whether it simply causes an increase in the fluidity of the slag and, consequently, faster approach to equilibrium. The experimental procedure consisted in equilibrating synthetic molten slags with liquid copper at 1550°C under a gas stream containing argon, hydrogen, and water vapor. In all experiments the argon to hydrogen ratio was approximately 4:1, and the hydrogen to water ratio was 5.42:l. Molybdenum crucibles were used as containers for the slag and metal. Under the above-described conditions of temperature and composition of atmosphere, there was no observable attack of the crucibles by the metal, slag, or atmosphere. Copper was used instead of iron, because iron attacks molybdenum. The equilibration was made in a tubular furnace consisting of a recrystallized alumina tube. The alumina tube was heated by electrical resistance. A Pt-40 pct Rh wire winding was used for most runs. A silicon carbide tubular resistor was also used for some runs. Temperatures were measured with a Pt-Pt-Rh (10 pct Rh) thermocouple and kept constant within ±5°C. Equilibrium was approached from both sides, i.e., by adding the phosphorus either as oxide in the slag or as a phosphorus-rich alloy of phosphorus and copper. The holding time at the equilibrium temperature was 6 hr. At the end of each run the crucibles were rapidly cooled and removed from the furnace. The slag and metal were separated and analyzed. The experimental results are shown in Table I. The phosphorus content of the slag is expressed both as percent phosphorus pentoxide and as percent phosphorus. The basicity ratio is computed by dividing the number of moles of basic oxides-oxides of barium, calcium, magnesium, and sodium—by the number of moles of acidic oxides- oxides of aluminum, phosphorus, and silicon. Calcium fluoride is not included in the computation of the basicity ratio; i.e., calcium fluoride is assumed to be neither basic nor acidic. The distribution ratio of phosphorus—percentage of phosphorus in the slag divided by the percentage of phosphorus in the metal- is plotted in Fig. 1 against the basicity ratio. The results indicate that slags containing barium oxide have greater dephosphorizing capacity than slags containing calcium oxide. The high dephosphorizing capacity of slags containing sodium oxide and the low dephosphorizing capacity of magnesia-containing slags which already have been reported in the literature2 are confirmed by the results of this investigation. It appears that calcium fluoride has a beneficial effect on the distribution of phosphorus between slag and metal in acid slags only. Although the obtained distribution ratios between the phosphorus contents of slag and copper are not directly applicable to the dephosphorization of steel, they are sufficient for evaluating the effect of slag additions on the dephosphorizing capacity of slags in general. An increase in the ratio of distribution of phosphorus between slag and metal indicates lowering

Jan 1, 1968

By Liu Yulin, Zhao Yi, Tan Qi, Liu Lei

"Hydrotalcite is one kind of layered double hydroxides, and has special crystal chemical characteristics. Due to its good thermal stability, hydrotalcite used as the PVC heat stablier has attracted scientists’ attention. In this study, nano-hydrotalcite was synthesized by the method of mechanochemistry/crystallization, using brucite, Al(OH)3 and Na2CO3 as raw materials, and added into PVC to investigate the effect of hydrotalcite on thermal stability of composites. The synthesis mechanism was suggested by virtue of XRD, FE-SEM, FT-IR. It has been indicated that at the first of dry milling process, the parical sizes of brucite and Al(OH)3 decrease, while specific surface areas of them increase by the action of mechanical force, until produced amorphous particles. In the process of wet milling, metal ions in the amorphous body, which has high surface energy, can easily react with H2O, and produce the precursor of Mg6Al2(OH)18•4.5H2O, which has the same crystal structure as hydrotalcite. Under the hydrothermal condition, anions of OH- in the interlamination of precursor are exchanged by CO32- in the solution and nano-hydrotalcite is generated at last. The thermal stability was characterized by Congo red method. The results have revealed that hydrotalcite is one kind of long-term heat stabilizer, and residual stability time increase with the rise of added hydrotalcite amounts.INTRODUCTIONHydrotalcite, one kind of anionic clays, has been attracted a great interest for researchers because of their unexpected physical and chemical properties. The general formula is Mg6Al2(OH)16CO3·4H2O, where Mg2+ and Al3+ occupy octahedral positions in the brucite-like layers, and CO32- is an interlayer anion (Hoyo, 2007). Hydrotalcite is widely used in the fields of chemical engineering, materials engineering, environmental protection, medicine, and so forth, owing to its unique capability of adsorbability, ion exchange and thermal stability (Rozov, Berner, & Taviot-Gueho, 2010; Iwasaki, Yoshii, & Nakamura, 2012; Ay, Zümreoglu-Karan, & Temel, 2011; Cavani, Trifiro, & Vaccari, 1991; Li & Duan, 2005; Lin, Wang, & Evans, 2006). As a result, the study on synthesis and application of hydrotalcite has received considerable attentions."

Jan 1, 2016

By K Haga, G Danha, A Shibayama, L L. Godirilwe

The hydrometallurgical separation and enrichment processes provide an effective way to selectively recover metals from relatively dilute multicomponent sulfuric acid leach solutions. The multicomponent leach solution utilised in this study contained 0.3 g/L Cu, 0.34 g/L Ni, 0.13 g/L Co, and 2.96 g/L Fe, which was obtained after high-pressure oxidative acid leaching (HPOAL) of the copper-nickel smelter slag. The solvent extraction (SX), precipitation, and xanthate complexation processes were employed to recover and upgrade Cu, Ni, and Co from the leach solution. Batch SX tests were carried out using a countercurrent two-stage mixer settler extraction column, and LIX 984N (10 per cent v/v) as a copper extractant. Fundamental parameters influencing the extraction process such as pH, mixing speed, H2SO4 concentration, and organic/aqueous (O/A) phase ratio were investigated. For copper enrichment in solution, a combination of two extraction stages and two stripping stages were employed. Copper was successively separated from Fe, Ni, and Co under optimised extraction conditions (pH 2, 400 rev/min, O/A 0.25, and 20 min contacting) and stripping conditions (175 g/L H2SO4, 400 rev/min, O/A 4, and 20 min contacting). About 97 per cent of copper was extracted with low co-extraction of Fe, Ni, and Co of about 5.90 per cent, 1.47 per cent, and 2.53 per cent, correspondingly. A final Cu-rich solution containing 23 g/L Cu was obtained with a very low Fe concentration of 0.05 g/L. Additionally, for iron removal from the Ni/Co raffinate solution, more than 99 per cent of iron was precipitated at pH 4 by the addition of a calcium carbonate (CaCO3) suspension, with low co-precipitation of nickel and cobalt of around 3.68 per cent and 2.27 per cent, respectively. Furthermore, about 83.6 per cent of nickel and 99.4 per cent cobalt were co-precipitated from the solution by potassium amyl xanthate (PAX) solution at pH 6. The Ni and Co xanthate complexes were thermally decomposed and recovered as cobalt oxide (CoO) and nickel sulfide (NiS) solids.

Aug 24, 2022

Leading Article from "British Medical Journal," London, 4th, November, 1944.Assuming that silica exerts its injurious effect upon animal tissue through a slow transformation into silicic acid, Denny, Robson, and Irwin thought that if the solubility of siliceous material retained in the lungs could be suffciently reduced the usual fibrotic response could be diminished or prevented. They discovered that aluminum powder rendered siliceous material insoluble in vitro by coating the silica particle with a thin film of gelatinous hydrated alumina, which on drying formed crystalline alpha aluminum monohydrate. The presence of this adsorbed layer on the surface of the quartz was shown by staining it with aurin. That metallic aluminum dust produced no fibrosis in the lungs was demonstrated by dust-inhalation experiments on eight rabbits. Attempts were therefore made to prevent silicosis by mixing quartz with metallic aluminum dust.Animals exposed to quartz dust developed typical silicosis in about five months, but the addition of 1 per cent. aluminum powder prevented this even after exposure had been lengthened up to 22 months, provided the aluminum powder was of a particle size below 5. This year Crombie, Blaisdell and MacPherson have reported the treatment of 34 silicotic miners by the daily inhalation of fine aluminum powder freshly ground from small aluminum pellets in a specially constructed mill. Daily treatment began with five-minute inhalations, which were gradually increased to 30 minutes. Some of the men received 300 treatments, but the majority only 200. Out of the 34 cases thus treated clinical improvement was manifested by lessening or disappearance of shortness of breath, of cough, of pain in the chest, and of fatigue. In 15 cases the condition became stationary and remained so in spite of continuous employment in silica dust throughout the treatment. The progress of the disease was assessed by means of tests for respiratory function repeated at three-monthly intervals. Obviously this treatment cannot be regarded as a cure for silicosis, since it cannot restore lung tissue which has undergone fibrotic change; but Crombie and his colleagues believe that the inhalation of finely particulate aluminum powder offers every prospect of preventing the development of human silicosis.In view of these findings, it is surprising that repeated papers by Goralewski from Germany describe various types of lung disease attributed to aluminum dust, and press for them to be scheduled under the Workmen's Compensation Act in that country. Seven hundred workers were investigated. They were making, probably by a stamping process, aluminium powder containing about four milliards of particles of dust per grain, and are reported as complaining of dry cough with pain on breathing, shortness of breath, poor appetite, and gnawing abdominal pain. Spontaneous pneumothorax developed in four workers. No abnormal physical...

Jan 1, 1945

By C. B. Dudley

bas shown us that the railroads of this country can save several milt liohs a par by adopting uniform rail sections, and as unfortunately for him, he cannot patent his idea, it only remains for the railroads to adopt it, and to thank him for his payer. Dr. C. B. Dudley, Altoona, Pa. : 111 rising to close this interestin~ discussion, I want, in the first place, to thank every one who has contributed to it for his full and open criticism. The work tvhich has been done on steel rails, and which has been diwu&e,l here Juring thee two days, was not done to establish any pet theories, nor to make out that any person was great or any person small, but with a sincere desire to get at what is the truth in regard to the wedring capacity of steel rails. There are enormous commercial coneiderations invoIved in this question, and, as I look at the matter, the more honest criticism and fair discussion there is, the Inore likely it is that the truth will appear. Ad first I would like to say that it seems to me very little has been said here upon the main conclusion of the paper, namely, that the softer rails give the better wear. All sorts of side issues have been discussed; but this poiat, which is really the principal one at issue, has been largely ignored, aid I cannot But feel that it still remains unshaken. Witb regard to ohemists end chemical work, there has been considerable said tending to throw discredib on chemists and their work; and while I believe that there have been in the past, are now, and may be in the futnre, a good many poor chemical analyses made, X also believe that chemists are, as a rule, as honest and competent as gentlemen who belong to other professiomc. There are chemisb who are chemists, and who are not chemists. The determination of -manganese has bee* called in question. Now I think the chemist at almost every steel works in the country will tell you that, in his experience, the manganese diffe1.s in different parts of the same ingot. Mr. T. T. Morrell, chemist of the Camhria Iron Company, whom I believe to be s thoroughly competent and hone6t chemist, tells me that he has often found different amounts of manganese in different parts of the same ingot. Come with me to Altoona, and I will take you into the machine shop where steel is king cut aud shaped, and I will show you that it is often necessary to stop the lathe or planer and take a cold chisel to cut oat a hard spot, or else ntn the risk of breaking the tool. This hard spot is simply a pttrt of the syiegel which was not thoraughiy mixed with the ma

Jan 1, 1881

Briefly, can you relate how you got into the minerals industry and some of your experiences as an executive, engineer, and administrator? Also would you tell ME about your affiliation with the Society of Mining Engineers of AIME? Roseburg, Ore., was where I was born and raised. It was, and still is a lumbering town; it couldn't have been any farther from mining. Upon graduation from high school, I turned 18 and, having already signed up with the Army Corps of Engineers, I was in the service eight days after my birthday. Four months later I was in New Guinea. As an amphibious engineer, I saw many of the Pacific and Philippine Islands, and ended up in Japan just a few days after the war was over. In later years, my work took me back to several of the places I had been during the war.

Jan 3, 1978

By Neil White

South Africa (SA), a country in which all three commercially important asbestos minerals have been mined and milled, has retained proven cases of mesothelioma linked with environmental exposure to asbestos. This study illustrates the importance of fiber type in the occurrence of environmental mesothelioma. Four studies have reviewed the source of occupational or environmental asbestos exposure in 504 histologically proven cases of mesothelioma in South Africa. One hundred and eighteen cases (23%) were thought to be related to environmental exposure to asbestos. In the vast majority of these cases, exposure was linked to crocidolite mining activities in the Northern Cape Province. Two cases were thought to have occurred in relation to amosite and Transvaal crocidolite exposure in the Limpopo Province. In the balance of cases there was some uncertainty. No cases were reported with exposure to South African chrysotile. Consequently, in the vast majority of cases of mesothelioma, environmental exposure to asbestos occurred in the Northern Cape Province, in proximity to mines, mills and dumps where crocidolite was processed. Crocidolite appears to be far more mesotheliomagenic than amosite, and chrysotile has not been implicated in the disease. This is true for both occupationally and environmentally exposed individuals. ©2007 Elsevier Inc. All rights reserved. Keywords: Crocidolite; Mesothelioma; Chrysotile; Amosite; South Africa

Jan 1, 2007

By J. L. Fuentes-Cantillana, Á. Rodríguez, P. Morillo

Evacuation operations from work places in the case of an emergency are the key to minimising the effects of catastrophic type accidents such as fires, explosions, cave-ins, floods, etc. The correct planning of these operations, having the necessary means for sounding alarms and communicating and suitable training of personnel are the key factors for guaranteeing successful evacuation. The article gives an analysis of the problem in the case of subterranean mining and various types of work developed by AITEMIN in this field, including the development of new alarm and communication means specially adapted to the characteristics of mining operations, development of tools for help in the preparation of emergency plans and experiences in the education and training of personnel.

Jan 1, 2003

By C. Sima, M. Legoabe

Keywords: Pyrometallurgy, furnace, platinum Mortimer Smelter is one of the three smelting operations in the Anglo Platinum Group. It is located in the Limpopo Province, approximately 100 km north of Rustenburg, and approximately 15 km west of Northam. The smelter operation is the smallest of the three smelting operations in the group, with a smelting capacity of 170 kt/annum. The operation consists of a Larox filtration plant, a Drytech flash drying plant, a modified Elkem / Hatch 19.5 MVA furnace, and a 60 t/h matte crushing plant. The operation does not convert its furnace matte, and hence the final sulphide rich matte is transported to and processed further at the Anglo Platinum Converting Process (ACP) within the Waterval Smelter Complex in Rustenburg. Furnace slag is granulated, and processed through a slag mill, or transported to a slag dump.

Jan 1, 2006

By Xianzhong Hu, Qingbo Yu, Qin Qin

"Oxy-fuel combustion is one promising option among different CO2 capture technologies. The object of this work is to show the effect of CO2 dilution on the laminar flame speed, flame structure and reaction pathway for methane oxidation at O2/CO2 atmosphere. In this paper, kinetic simulations were made using CHEMKIN with GRI-Mech 3.0 mechanism, which was validated by experimental data of laminar flame speeds. The reaction pathway of CH4/O2/CO2 mixture was derived from reaction flow analysis. Results showed that CO2 decreased the flame speeds, lowed concentration of major intermediates and increased flame thickness. The major chemical pathways of CH4 to CO2 have not changed at O2/CO2 atmosphere comparing with O2/N2 atmosphere, but contributions to major intermediates formation from each related elementary reaction have changed a lot. In addition, the secondary chemical pathways of CH3 oxidation became different at O2/CO2 atmosphere.IntroductionNowadays, as the global economy is developing fast and the pollutant levels (especially global warming gases) are increasing, a lot of researches are focusing on new technologies which can cut greenhouse gas emissions [1]. New technologies have been developed, such as high Mild combustion, flameless combustion and Integrated Gasification Combined Cycle (IGCC) technology. Oxy-fuel combustion using carbon dioxide as dilution of oxygen is considered as a promising approach for reducing CO2 emission. The properties of CO2 in flue gas are different from N2 in air. On one side, the transport, thermal and radiative properties of CO2 are different from N2 in air. On the other side, CO2 is not inert but directly participates in chemical reactions and recent researches [2-5] also present the chemical effects of CO2 on oxy-combustion. For these differences above, the characteristics of oxy-combustion are not alike with traditional combustion. It is necessary to develop the investigation of oxy-combustion.In all combustion processes, laminar flame speed is an important parameter, which links to combustion behavior. Analysis of this parameter can provide a better understanding of the effect of CO2 dilution in the process of oxy-combustion. Several investigations of laminar flame speeds of oxy-fuel flame have been improved, including experimental measurements and numerical computations. A.A.Konnov et al. measured the flame speeds of oxy-methane and oxy-ethane mixture using the heat flux method with a flat burner [6-8]. V. Ratna Kishore et al. used heat flux method to measure the adiabatic laminar flame speeds of hydrogen [9] and H2/CO mixture [10]. Adiabatic laminar flame speeds of hydrogen in O2/CO2 atmosphere are much smaller than in O2/N2 or in O2/Ar. The burning velocity of H2/CO mixture decreased with increase in CO2 content in mixture. Jeongseog Oh et al. [11] used Bunsen flame to measure the laminar flame speeds of premixed oxy-methane mixture with angle methods in atmospheric condition (300k, 1atm). The results were SL=29.1cm/s and SL=29.5cm/s respectively derived from oxy-methane from CH* images and Schlieren photos."

Jan 1, 2014

By Adam Shang Robert Fu

The Yung-Chung-Tunnel in Taiwan, constructed for the Taiwan-East Railway Bureau, collapsed during construction when a water bearing, fractured marble zone was intersected. The inflow was approximately 4,000 liters/second. In spite of 30 relief holes the total inflow into the tunnel remained constant. The pre-excavation grouting through the re-aligned tunnel had to be conducted under extreme flow-conditions. A hot bitumen grouting program was selected for technical and economical reasons out of 13 international proposals. The technical challenges were: grouting under severe flow conditions high formation water pressures to be injected with hot bitumen at high temperatures and pressures The hot bitumen grouting program resulted in a dramatic reduction in the hydraulic conductivity and stabilization of the formation and facilitated a problem-free excavation.

Jan 1, 2007

By R. Immele-Meziou, G. J. Long, D. G. C. Robertson, O. A. Pringle

The reduction of naturally weathered ilmenite concentrate occurs in two steps: reduction of Fe3+ to Fe2+, followed by reduction of Fe2+ to Fe. Small amounts of a magnetic phase were also observed and may correspond either to an Fe3O4-FeTiO3 ilmenite phase or to an Fe3O4-Fe2TiO4 spinel phase. The total amount of metallic iron produced after 12 hr was only 50% of the total iron present in the sample.

Jan 4, 1992

By João Queiroz, Cristian Marquez-Sarmiento, Luiz Teixeira

The removal of various metals from process waters and effluents is usually done by precipitation of the corresponding hydroxide. Manganese however is one metal that does not respond efficiently to that approach. It may be seen in its eH X pH diagram that the way of oxidation to Mn IV rather than hydrolytic precipitation of the Mn II ion as its hydroxide, is the way to efficient precipitation of Mn in the pH range 6 to 10. We studied the use of oxidants O2; NaClO; H2O2; Caro´s Acid (H2SO5) and the combinations of O2 or H2O2 with Na2S2O5, and H2O2 with NaClO, for the oxidative precipitation of Mn from synthetic solutions starting with 10 mg/L Mn, at 25 oC. In adequate conditions, which include pH > 8, it is possible to reach final [Mn] less than 0.1 mg/L in 60 minutes of reaction time.

Jan 1, 2014

By R. S. Goodrich, G. S. Ansell

The microstructure of three Al-Al2O3 SAP-Type alloys (containing 2.0, 3.0, and 5.7 wt pct alumina, respectively) was studied utilizing transmission electron microscopy. These alloys were fabricated from aluminum powders by powder-metallurgical techniques, cold-rolled into thin strips, and recrys -tallized. Thin foils suitable for an electron-transmission study were then prepared from the strip material by electropolishing. The microstructure of these alloys is shown to consist of small (0.1 mean diameter) plate -shaped alumina particles finely distributed in an aluminum matrix. In the higher-oxide content alloys the platelets are somewhat larger and more irregular in shape. The distribution of oxide particles is not uniform and there is an increasing tendency toward clumping SINCE the discovery by Irmann1 that aluminum alloys produced by compacting, hot pressing, and extruding fine aluminum powders possess remarkable high-temperature mechanical properties, the Al-A12O3 SAP-Type alloys have been utilized extensively as model dispersion-strengthened alloys in both experimental and theoretical invest igations.2-8 The use of the SAP-Type alloys as model dispersion-strengthened alloys implicitly assumes that their microstructure has been completely delineated. This is, however, not the case. with increasing oxide content. In all the alloys studied, the mean center-to-center spacing of particles was quite small (0.2 u) due to the very fine oxide debris present. Selected-area diffraction of the specimen identified the oxide as either y Al2O3 or y' Al2o3. The re crystallized MD-5100 alloy exhibited a mean grain diameter of only 0.7u, while the grain size of the other alloys was several hundred microns. Severe pinning of the grain boundaries by oxide particles was rarely observed, and the grain boundary triple points in the small-grained MD-5100 alloy were often particle -free. Diffraction contrasts visible around the particles are attributed to elastic strain fields set up by differential thermal contraction during cooling from the recrystallization anneal. Early investigation demonstrated that optical metallography did not possess sufficient resolution to observe the microstructure of the SAP-Type alloys.' Later, extensive use was made of replication techniques to study the microstructure by means of electron microscopy.7-9 These studies indicated that the SAP-Type alloys consist of a dispertion of irregular Al2O3 platelets, approximately 150A thick 9 and a micron or so on edge,9 distributed in a matrix of commercial-purity aluminum. These oxide platelets tend to be oriented in the aluminum matrix, with their largest dimension parallel to the extrusion direction. 8,9 A study employing polarized-light techniques1' indicated that the grain size of a series of as-extruded SAP-Type alloys was several microns in diameter, while the grain size after re-crystallization was several millimeters in diameter. A more recent study 12 utilizing surface-replication techniques examined the particle morphology,

Jan 1, 1964

By Bertram Price

Libby, Montana is the site of a large vermiculite deposit that was mined between 1920 and 1990 to extract vermiculite for commercial applications such as insulation, gardening products, and construction materials. The Libby vermiculite deposit also contains amphibole minerals including tremolite, actinolite, richterite, and winchite. Historically, Libby mine workers experienced high exposures to amphibole structures, and, as a group, have experienced the health consequences of those occupational exposures. It has been suggested that Libby residents also have been and continue to be exposed to amphibole structures released during the vermiculite mining operations and therefore are at increased risk for disease. The Agency for Toxic Substance and Disease Registry (ATSDR) conducted two epidemiological-type studies of residents living in Libby and the surrounding areas to assess these risks. The Environmental Protection Agency (EPA) collected and analyzed exposure data in Libby and used those data to project risks of asbestos-associated disease for Libby residents. The EPA has placed the Libby Asbestos Site, which includes the mine and the town of Libby, on its National Priority List of hazardous waste sites in need of clean up. This article presents a review of the exposure studies conducted in Libby and an analysis of health risks based on the data collected in those studies. Libby mine workers have experienced elevated levels of asbestos-associated disease as a consequence of their occupational exposures to amphibole structures. Libby residents? exposures typically are substantially lower than mine workers? historical exposures, and the health risk projections for residents are, accordingly, substantially lower. © 2007 Published by Elsevier Inc. Keywords: Libby; Montana; Vermiculite; Amphibole minerals; Asbestos; Asbestos-associated disease

Jan 1, 2007