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By Gernot Kostorz

In a recent paper, Raffo and itcheell1 compared solid solution hardening of various bcc alloy single crystals at room temperature and concluded that the expression for localized elastic interaction between dislocations and solute atoms2 that gives the critical resolved shear stress (CRSS) 7,: to = Z . µE3/2 C1/2 where c = concentration, e = misfit parameter, (µ = shear modulus, Z = numerical constant Fig. 1—The slope dT0/dc1/2 for niobium alloy single crystals deformed at 570°K plotted against the misfit parameter € = In' I + 1616 I. from Ref. 6, •estimated from Ref. 7. Table I. Plateau Hardening and Alloy Parameters for Niobium Alloys dT0/dc1/2, kg/mm2 Solute Ref. 6 Tantalum 3.7 ± 0.3 1.9 0.73 + 0.06 9 0.0 ± 0.5 15 Vanadium 16.1 ±1.4 - 0.69 i 0.01 9 -7.4 ± 0.5 16 Tungsten 12.5 ? 1.5 20.9 0.92 i 0.05 10 -5.0 t 0.4 17 Rhenium - 25.9 1.24 11.12 -8.5 ± 0.4 I5 Molybdenum - 14.6 1.04 13,14 -4.6 s†±?˜µ?fF?? 0.5 17 Hafnium - 13.9 0.37 12 4.8 ± 0.5 17 Table 11. Solid Solution Hardening and Alloy Parameters for Tantalum Alloys i)' dTo/dc1/2 kg/mm2, dTp/dc1/2 kg/mm2, Ref. 22 1006 Solute ˜570°K Ref. 7 See Text Ref. 25 Rhenium 44.3 32.5 0.65 -8.5 Tungsten 32.1 24.3 0.34 -4.6 Molybdenum 29.3 19.1 -0.19 -5.9 Niobium 5.8 5.5 -0.43 0.I

Jan 1, 1970

By S. Rupprecht

"This article addresses the prevalence of poor public reporting practices of coal exploration results, coal resources and coal reserves in southern Africa. Currently, the reporting of coal tonnage without supporting coal qualities or saleable tonnes and quality is a poor reporting practice that occurs far too often. Not all coal is equal — therefore it is extremely important that investors or potential investors are provided with the full details of both run-of-mine (ROM) and saleable coal tonnage, their associated qualities and other material and relevant information.Competent or qualified persons should note that publicly reported information should be sufficient to enable an informed reader to make a reasonable and balanced assessment of the significance of the information provided. “Companies are encouraged to provide information in their public reports, which is as comprehensive as possible (CRIRSCO, 2013).” However, too often this isn’t the case, and material matters are either not reported or inadequately disclosed.According to the South African National Standard (SANS) 10320:2014 draft document, “tonnage and coal quality that will be available for sale, either in the raw ROM state (raw saleable) at a specified moisture content, or after beneficiation of the ROM coal by processing operations to produce materials at specified qualities, size ranges and moisture contents. The assessments must demonstrate that at the time of reporting, the marketing of the products is reasonably justified. The basis of the predicted practical product yield to achieve the saleable coal reserve must be stated. The moisture basis of reporting shall be stated.” An example as to why coal qualities are so important to the public, the requirements of South Africa’s electric public utility (Eskom) power stations are detailed in the followint paragraphs. The Kendal power station, commissioned in 1988, operates at a calorific value (CV) range of 19 to 20 MJ/ kg, an ash content between 29 and 34 percent and volatiles between 20 to 21 percent. Other power stations, such as Kriel or Hendrina, may require different qualities, such as a CV range of 22 to 23 MJ/kg, an ash content between 20 and 28 percent and volatiles between 22 to 23 percent. Thus, in terms of domestic saleable coal, it is not just about reporting the coal qualities but also informing the investor as to which power station the coal is intended to be sold as “boilers are designed to burn particular qualities of coal” and “it is not always possible to transfer coal between stations because of different quality requirements at each station (Chetty, 2010).” Sulfur content is another important quality with the ideal coal content having a quality of less than 1 percent sulfur."

Jul 1, 2019

By Carl R. Peterson

[In lTI n,v und I'gr'oun nllnin~ Opt'I'ali n' the high . t cost is the loading and I 3ulage of t tln-of -D"'line ot'. 01' hauling costs can be r duced signifi-cant\v with the us ~ (r \) >It corn'e)'OI' " a COnlTllOn pl'acti c i.n coal and other s 0 t'L rn I n r' a l III i, n e , '. Jf 0 vel s i z ' () f' e can bee 1 i 11.11 tl ate I rH'i 0 I' lO C n v e . in g, ]

Jan 1, 1976

By Sarah Bélair, Denis Beltrami, Deka Moussa Ragueh, Valérie Weigel

"Scandium is a highly valuable element belonging to the rare earth elements (REE) but it has different chemical and physical properties from those of lanthanides. This metal is generally used in aluminum-scandium alloys and in fuel cells but the development of its market is slowed down by its high price (more than 1000 US$/kg for a 99.0% grade product). Indeed, the low scandium content in the continental crust (an average of 22 ppm) and the difficulties to extract it selectively from solutions containing high impurity concentrations increase the cost of the recovery processes. Nowadays, scandium is primarily recovered as a byproduct.ERAMET is developing a hydrometallurgical process in Gabon (Mabounié) in which the scandium content in the deposit reaches 10 to 100 ppm. The Maboumine project consists in the extraction and purification of uranium, niobium, tantalum and REE from Mabounié ore. In the frame of this hydrometallurgical project, ERAMET had also studied the feasibility to recover scandium as a byproduct. During the ore leaching, uranium and rare earth elements including scandium are solubilized into the pregnant leach solution (PLS). Among the various methods investigated to recover scandium from the PLS, liquid-liquid extraction using Primene JM-T as extractant was chosen and tested first at laboratory scale and then at pilot scale. Selective stripping of the loaded organic was carried out by using phosphoric acid solution, allowing the selective recovery of scandium from thorium and zirconium partially extracted from the PLS by Primene JM-T under the process conditions."

Jan 1, 2016

By F. G. Miller

[Petroleum technoloF;istz and 1 rot-re s s ive OT e:?ztors. con stantl;, are striving to increase the percentage of oil that y to recovered from reservoir rocks throe::;:: wells. The exhaustive studies that have been made of the function of natural r:; as in t h-_ T r odI action of oil, for cx<n.mTnle, have aidedd of.erators greatly in incroasin,&apos; the q-:Arrntity of oil recovered from reservoirs. i.rtural gas dissolv3d in ar--d otinerwwisa &apos;1s&apos;.,ocintjd under rre3suro with oil in roscrvoir roci.s, howover, i:; not the only source of energy available for moving oil through sa&apos;:&apos;l to wells. l becoming "reservoir-energy conscious&apos;t engineers hr-vo -d o^.rued t}:-Lt in many petroleum reservoirs the edgewater flanking t -,e oil accum.-,lation conetitutos a potential source of onergy capable, tL-ou;_h rro? gr control, oil&apos; increasing oil-recovery efficiencies materially. i o ]enter is ti-.-,, on-cronchinunt of water into the oil- and gas--fillod ?art of the reservoir considered as an evil to be combatted by devious mot&apos;:r:ci :i,.t r,ttL er a natural conseque::c4, incident to the withdrawal of oil nna gas from the wells, that nay be T.usod advantrt eou ;ly in lonr`t}toning tr e r&apos;lowin g lift of wells a.nd, i norcas in:; the economic recovery of oil and Little is known about the by which water off: oratos in driving nil throe:gh reservoir roc:-.:,, nd i:. a scorcity of rubli:;Lad informs-¬t .on nn rates of :)Ov.:m.,:- t of : r.tcr ..at v:1:11 res,-_lt in ^r i-nu oil recoveries. Bureau of :fines engine_:? ; - reciate. the r,aucity of scientific knowledge or. the &apos;test methods of a,r.lying the natural water arive to in¬crease oil-recovery efficiencies ant ,i.;?l __-itir?,~ ting irties that will, they hope, Contribute to t.1&apos;.e T ros?Jr.t. small _ %nd of information now av tilable on tt:e cubjoct. This r».crt a oyno-.::is or brief comrilnt.ion of r,ublished data and thought accuinulnt.~d so far, to la)or;~.tory ox-:erimnntrr¬tiorn and, further rosoarch on the z_rrinciplos unri;rlyir..g the natr.rr+1 eater drive no it nffocts oil recovery. :Lie writer:: Lore that t.i.c cx-nositiorn of a?rzilable inforr-at ion i rcs?r.toi in the rernrt r .-II .i ,.1rtt cor_jt_-i:ctive tho.-_.I_t and efforts loadir,-z to -:ard more con.r .ote extraction n;&apos; o tl from reservoirs.]

Jan 1, 1938

Domestic: Middle West-,11.. B. Newcombe Eastern District-J. French Robinson1 Kansas-Henry A. Ley 2 Oklahoma-Henry A. Ley 3 Texas, except Gulf Coast and Panhandle-M. G. Cheney 5 Texas Panhandle-W. E. Hubbard and H. E. Crum 6 Gulf Coast-L. P. Teas 7 South Arkansas, North Louisiana and Mississippi-H. K. Shearer 8 Foreign Mexico-V. R. Garfias and C. 0. Isakson 9 Canada-Line M. Farish 10 Venezuela-C. W. Hamilton 10 Colombia-J. T. Duce 12 Peru-O. B. Hopkins 12 Trindad-Williaim J. Millard 13 Dutch East Indies-Fred B. Ely 13 Rumania-I. I. Gardescu . .. . 14 India-Eric J. Bradshaw 14

Jan 1, 1931

By Tyler Luxner

Stillwater Mining Co. (SMC) is the largest primary producer of platinum and palladium in North America. SMC operates two underground mines in south central Montana, along the 45-km (28-mile) platinum/palladium J-M Reef in the Stillwater Complex. The Stillwater Mine exploits 9.6 km (6 miles) of deposit strike length and East Boulder Mine exploits 4 km (2.5 miles) of deposit length. The two mines are 20.4 km (12.7 miles) apart with SMC controlling a considerable length along the entire J-M Reef trace. Production at the Stillwater Mine began in 1986 and in 1988 the first tunnel boring machine (TBM) was commissioned, becoming an integral part of mine development at SMC. TBMs have been used for developing production footwall laterals (FWL) to access new mining blocks at the Stillwater Mine, as well as boring twin crosscut ac-cess tunnels at the East Boulder. Two TBM development expansion projects are currently in progress: the Graham Creek project at the East Boulder Mine, which will extend footwall lateral development 2,591 m (8,500 ft) to the west, and the Blitz project, where a TBM will be commissioned to extend east out of the Stillwater Mine to 3,658 m (12,000 ft) beyond the current production mining front. General strike and dip of the Reef is west to east and to the north, respectively.

Jan 1, 2012

By Ana Clara Petrucelli

O reator EOF foi desenvolvido no Brasil nos anos 1980 com características únicas. O pré aquecedor de sucata e a distribuição dos pontos de injeção de gases oxidantes e combustíveis conferem estas características. O objetivo deste trabalho é reproduzir o comportamento do banho metálico de um EOF de 45 t comparando seus três pontos de injeção: lanças supersônicas, lanças atmosféricas e ventaneiras. A lanças supersônicas e ventaneiras promoveram uma grande agitação do banho quando comparado com os injetores atmosféricos uma grande oportunidade de melhoria.

Jul 29, 2018

By Larissa Rodrigues de Carvalho Rocha, Mauro Vivaldino Fernandes, Maurício Covcevich Bagatini, Beatriz Fausta Gandra, Adriano Cesar Carvalhido

O combustível com menor granulometria, denominado small, pode ser carregado juntamente com a carga metálica, em substituição ao coque, no intuito de melhorar as condições de permeabilidade do gás e a redutibilidade da carga no alto-forno. Na Usiminas, o equilíbrio na geração e no consumo desse material limita o seu uso em taxas abaixo da média nacional. Nesse sentido, foi avaliado o efeito do coque verde de petróleo (CVP) em substituição ao small coque no consumo de combustível e na estabilidade operacional do alto-forno. Os resultados do teste industrial indicaram a possibilidade de substituição até 45 kg/t gusa, com manutenção do fuel rate, da permeabilidade e da produtividade do alto-forno.

Oct 1, 2019

By Pei-Yung Huang, Carle R. Hayward

IN order to understand more fully the actual state of copper lost in copper reverberatory slags, a systematic study on the various reactions between certain metallurgically important copper compounds and synthetic copper reverberatory slags was undertaken by the authors in the Massachusetts Institute of Technology from 1942 to 1945.1 This paper, being only a part of the work completed, is published first because it furnishes the first experimental evidence of the formation of copper ferrite from reactions between cuprous oxide and copper reverberatory slags. CHOICE OF SLAG COMPOSITION The choice of the composition of the synthetic reverberatory slags to be used was much deliberated. Commercial copper reverberatory slags, neglecting minor constituents, average:2.3 45 to 47 pct FeO; 38 to 42 pct Si02; 5 to 6 pct CaO; 5 to 6 pct A1203. Since the ternary system CaO-FeO-SiO2 has been much more thoroughly studied4 and is much simpler than the quaternary system CaO-FeO-Si02-A1203, it was decided to use calcium oxide only instead of calcium oxide and alumina in the synthesis of the slags. Fortunately the composition of the average copper reverberatory slag with calcium oxide substituted for alumina lies in the region of the phase diagram clarified by the investigators. A survey of the phase diagram (Fig I) suggested two compositions: (I) the com¬position near the invariant point S, which is made up of 46 pct ferrous oxide, 37 pct silica and 17 pct calcium oxide; (2) the composition near the invariant point K with 45.5 pct ferrous oxide, 43 pct silica and 11.5 pct calcium oxide. Composition S has the advantage that the percentages of ferrous oxide and of silica almost exactly coincide with those of the average reverberatory slags, and that of the lowest melting point (1093° ± 3°C) in the whole ternary system. The calcium oxide content, however, obviously is high. Since we have already substituted calcium oxide for alumina, and since calcium oxide is more basic than alumina, the resulting slag is decidedly too basic. Composition K has a slightly higher melting point (1105° ± 3°C) and a higher silica content, but this is preferred because the slag is saturated with respect to tridymite and thus should not corrode siliceous refractories. Besides, it is less basic than composition S. The final slag composition, therefore, was chosen to

Jan 1, 1947

By N. Damiano, C. Zhou, B. Whisner, M. Reyes

"The industrial Internet of Things (IIoT)—a concept that combines sensor networks and control systems—has been employed in several industries to improve productivity and safety. NIOSH researchers are investigating IIoT applications to identify challenges of and potential solutions for transferability of IIoT from other industries to the mining industry. Specifically, NIOSH has reviewed existing sensors and communications network systems used in U.S. underground coal mines to determine whether they are capable of supporting IIoT systems. The results show that about 40% of the installed post-accident communication systems as of 2014 require minimal or no modification to support IIoT applications. NIOSH researchers also developed an IIoT monitoring and control prototype system based on low-cost microcontroller Wi-Fi boards, to detect a door opening on a refuge alternative, activate fans located inside the Pittsburgh Experimental Mine, and actuate an alarm beacon on the surface. The results of this feasibility study can be used to explore IIoT applications in underground coal mines based on existing communications and tracking infrastructure. INTRODUCTION The nation’s approach to health and safety in mining has historically been reactive in the sense that health and safety regulations and mandates have traditionally been passed as a result of tragic mining accidents. An example of this is the Mine Improvement and New Emergency Response Act (MINER Act) of 2006, which was passed as a result of several mining accidents where tracking of and communications with underground personnel were severely limited. While this reactive approach has led to the development and implementation of highly impactful safety interventions and safety practices, there currently exists a technological revolution that can shift the paradigm toward a proactive approach based on preventative methods: Internet of Things (IoT). IoT is the network of physical objects or ""things"" embedded with electronics, software, sensors, and connectivity to enable that network to achieve greater value and service by exchanging data with the manufacturer, operator, and/or other connected devices [1, 2]. It should be noted that IoT has been defined from various perspectives, and hence numerous definitions exist in the literature. The apparent ambiguity of the IoT definition might be due to the fact that IoT is syntactically composed of two terms: internet and things. The first one pushes towards a network-oriented vision, while the second tends to put the focus on generic objects. The traditional internet can be viewed as an internet of computers —i.e., “things” connected to the internet are computers only. IoT “extends” the internet by allowing other generic things that are commonly found in our daily life, such as refrigerators and cars, to be interconnected via the internet, and thus creates a bridge between the virtual word and the physical world."

Jan 1, 2017

By R. P. Beyer

[The Bureau of Mines has measured the low-temperature heat capacities and high-temperature enthalpies of crystalline K2Si2O5 as part of a program for advancing mineral resources technology with energy economy. High-temperature enthalpies of glassy and liquid K2Si2O5 and crystalline K2SiO3 were also mea¬sured. An adiabatic calorimeter operating over the range 5 to 308 K was used for the heat capacity measurements for K2Si2O5 from which the standard entropy at 298.15 K, S°298 = 45.55 ±0.05 cal/deg-mole, was calculated. Tabulated values of Cp°, S°, -(G° -HO°)/T, and H°-HO° from 5 to 300 K are given for K2Si2O5. A copper-block drop calorimeter was used in the enthalpy measurements, operating from 298.15 to 1,198 K for K2SiO3 and from 298.15 to 1,453.8 K for K2Si2O5. No transitions were found for K2SiO3. The KI2Si2O5 showed two reversible first order transitions, one at 510 K with a heat of transition of 0.29 kcal/mole and one at 867 K with a heat of transition of 0.38 kcal/mole. The heat of fusion for K2Si2O5 20 5 was calculated to be 8.42 kcal/mole. Relative enthalpies are given in equation form, and high-temperature values are tabulated for Cp°, S°, - (G°-H°298 )/T, and H°-H°298 . Also tabulated are ?H°, ?G°, and log K for formation of K2SiO3 and K2Si2O5 from both the elements and the oxides.]

Jan 1, 1979

By Carolina Passanante

Aços Inoxidáveis Supermartensíticos surgiram na indústria petroquímica como um material alternativo para confecção de dutos, devido principalmente ao sinergismo de suas propriedades mecânicas e de corrosão. Com esta nova demanda, tornou-se necessária a caracterização deste material em suas diversas propriedades, destacando-se neste trabalho o efeito da microestrutura na resistência à corrosão. Objetivou-se, portanto, o estudo da resistência à corrosão por pite de um aço inoxidável supermartensítico 13Cr-5Ni-2Mo-Nb em função da fração volumétrica de ferrita-delta (d) presente na microestrutura. A variação da ferrita-delta foi alcançada através de tratamentos de recozimento, a 1.050°C, durante diferentes tempos (de 0,5h a 48h). As amostras foram submetidas a ensaios de polarização potenciodinâmica em eletrólito contendo 3,5% NaCl, naturalmente aerado. Quantificou-se, ainda, a porcentagem de ferrita em cada uma das condições através de ataque eletrolítico com solução 20% NaOH. Os resultados obtidos evidenciaram a diminuição desta fase com o aumento do tempo de recozimento, chegando praticamente à sua eliminação com tratamento de 48h. Paralelamente, a resistência à corrosão por pite deste aço foi melhorada de modo proporcional à diminuição da fase ferrita, resultando em um aumento de aproximadamente 115 mV da pior para a melhor condição, comprovando que, de fato, a presença de ferrita-delta prejudica as propriedades de resistência à corrosão localizada.

Aug 7, 2018

By Belmira Benedita de Lima

Estudos no sistema Nb-B mostram a fase Nb5B6 com formação peritética a partir do líquido, porém sua estabilidade abaixo de 2.000°C não é comprovada experimentalmente. Há também dúvidas sobre a ocorrência da fase Nb2B3 neste binário. Este trabalho tem como objetivo o estudo da estabilidade das fases Nb5B6 e Nb2B3 nas temperaturas de 1.400°C e 1.800°C. Amostras com composições nas estequiometrias Nb5B6 e Nb2B3 foram produzidas através de fusão a arco assim como confeccionadas a partir de misturas de pós de B e NbB. Pastilhas com composição Nb5B6 foram produzidas com e sem adição de semente da fase Nb5B6. Os tratamentos térmicos em 1.400°C foram realizados por até 10h enquanto aqueles em 1800°C por até 1h, todos em atmosfera estática de argônio. As microestruturas das amostras, tanto no estado bruto de fusão como após tratamento térmico, foram caracterizadas por difração de raios X (XRD). Os resultados confirmam a formação fase Nb5B6 a partir do líquido e nas amostras produzidas via metalurgia do pó. A fase Nb2B3 não é observada nas amostras no estado bruto de fusão e nas amostras produzidas via metalurgia do pó tratadas termicamente a 1.800°C, porém, esta fase se estabiliza nas amostras produzidas via metalurgia do pó tratadas a 1.400°C, indicando sua estabilidade com formação peritetóide a partir das fases Nb3B4 e NbB2, abaixo de 1.800°C.

Aug 8, 2018

By Alexandre Silva Guimarães

O presente trabalho avaliou o comportamento de extração dos metais cálcio, magnésio e níquel, contidos em licores sintéticos sulfúricos, utilizando-se o extratante Cyanex 272 (0,64 mol/L) e misturas entre Cyanex 272 (0,64 mol/L) e ácido versático (0,53 mol/L). Os resultados revelaram que a adição de ácido versático ao Cyanex 272 provocou um aumento nas extrações de cálcio, que atingiram cerca de 40% em pH = 5,1, decrescendo com a elevação do pH do licor até atingir aproximadamente em 15% pH = 5,9. As extrações de níquel (em torno de 80% em pH = 7,1) foram favorecidas, enquanto as extrações de magnésio permaneceram em torno de 75-80%, numa faixa de pH entre 6,0 e 7,0, em comparação com a utilização de apenas Cyanex 272 como extratante. O níquel pode ser separado dos metais cálcio e magnésio, pela mistura dos extratantes nas concentrações estudadas, em pH = 5,1, utilizando-se de 2 a 3 estágios de contactação.

Aug 7, 2018

By Douglas Batista Mazzinghy

O moinho vertical normalmente é dimensionado através da aplicação de um fator de eficiência sobre o Índice de Trabalho de Bond (BWI) ou sobre o consumo específico de energia (kWh/t) obtido através de teste em moinho de bolas de laboratório. Para confirmar o dimensionamento do moinho vertical são realizados testes em escala piloto com grandes volumes de amostras. O presente trabalho apresenta uma metodologia para simulação de moinho vertical através de testes de moagem em escala de laboratório utilizando um moinho de bolas convencional e amostras bitoladas em diferentes faixas granulométricas. A amostra de minério de ferro estudada foi utilizada em uma campanha de testes em escala piloto com moinho vertical. As simulações realizadas utilizando a metodologia de Austin apresentaram muito boa correlação com os resultados dos testes em escala piloto.

Aug 1, 2018

By R. G. Knickerbocker

[The Electromet l&apos;.ur.::ic&apos;l.l LC:tt:n~ to:!&apos;"&apos; of&apos; the BUl~6au 0: M_nes, Boulder City, ..rev. I invest~.f-&apos;8tes th~ r.: nc= I (l.op itr. in tr.e redon around Boulder Dam, and thi" p2pe:.. ., &apos;est.3nttl t rt") d.c-velo !l&apos;\CtltR of n seriAl of studies on "Joron uineral~ mario n.~ t~l"&apos;t f1tn.: ... o]

Jan 1, 1940

By Vantuil Manoel Thebas

A automatização do laminador Machine duo reversível de 8 toneladas passa pela determinação da força de laminação em seus cilindros durante processo de deformação da chapa metálica não ferrosa, o que se faz pela medição direta da força nos cilindros do laminador através de um sensor de força ou pelo uso de modelos matemáticos aplicados ao processo de laminação das ligas metálicas. O presente trabalho tem por objetivo o estudo dos modelos de Orowan, Ekelund e Bland & Ford aplicados à predição da carga de laminação de ligas metálicas não ferrosas. Amostras em barras chatas extrudadas com 6,35 mm (14/') de espessura da liga de Alumínio 6063-T5, com 300 mm de comprimento e 50,8 mm (2’) de largura, foram laminadas. Suas dimensões finais foram obtidas por uma escala de medição e paquímetro universal, sendo os dados tratados por rotinas computacionais especificamente desenvolvidas para a implementação dos modelos matemáticos citados. Os resultados deram conta de que a implementação dos modelos de Orowan, Ekelund e Bland & Ford através de rotinas computacionais podem ser muito úteis na predição da carga de laminação de ligas metálicas não ferrosas.

Aug 8, 2018

By José Ricardo Nunes de Macedor

Com o crescente zelo ambiental, os polímeros biodegradáveis ganharam importante papel no mercado mundial. Em especial, o amido é um destaque por apresentar preço baixo e alta demanda, contudo possui grande fragilidade mecânica e os seus filmes são muitos hidrofílicos. Outro importante polímero biodegradável é o poli(ácido lático) que possui, alta resistência mecânica e transparência, quando comparado com o amido termoplástico, permitindo sua aplicação em embalagens alimentícias. Contudo, o PLA ainda possui custo elevado, quando comparado ao amido e até commodities, como o PET, PP e PE. Estudos com algodão, material em grande produção e baixo custo, retratam ganhos nas propriedades mecânicas sem perda da biodegradabilidade em compósitos. Assim, este trabalho objetivou preparar, por meio de homogeneizador termocinético KMixer e prensa térmica, placas de compósitos de PLA contendo amido (0, 3 e 5% m/m) e fibras de algodão in natura processadas (0, 10 e 20% m/m). As amostras foram caracterizados por espectroscopia na região do infravermelho com transformada de Fourier (FTIR), ângulo de contato estático e ensaios mecânicos (módulo de Young, resistência à tração e alongamento na ruptura). As análises mostraram que a adição de fibra de algodão compensa a perda de resistencia à tração ocasionada pela adição de TPS. Tanto a fibra como o amido aumentaram a molhabilidade do compósito.

Aug 8, 2018

By Emma Arakelova

An increase in concentration of a Zn-containing volatile complex for synthesis of ZnO films was investigated when processing their target by ultraviolet radiation emitted by mercury lamp. The experiments were carried out using a flow-type quartz reactor. ZnO tableted target was preliminarily irradiated during 2 to 7 hours. H2O2 (98%) vapor at 25Pa passed through the reactor with ZnO target at 373K. As substrate material, five subsequent quartz cylinders were used at 423K. The experiment lasts 4 hours. H2O2 decomposition on ZnO surface was accompanied by formation of a Zn-containing volatile complex which passed in gas phase and decomposed on the substrates with isolation of final ZnO. The concentration of the Zn-containing volatile complex (N) in gas phase increases with UV pre-irradiation time (t) (without irradiation N = 1.05 1011 particles/cm3; after t=2 hours, N = 5.19 1011 particles/cm3, after t=4 hours, N = 9.95 1011 particles/cm3; after t=7 hours, N = 1.86 1012 particles/cm3.

Jan 1, 2006