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The production of sulphuric acid at Port Pirie by the contact process began in March 1924 with the commissioning of the Electrolytic Zinc Co.'s roasting and acid plant. This plant, operated by B.H.A.S. Pty. Ltd. on behalf of the E.Z. Co., continued to produce sulphuric acid from the gases evolved when roasting Broken Hill zinc concentrate in mechanically rabbled furnaces until September 1954, when the plant was closed down.In this peri9d of approximately 30 years some 600,000 mono tons of 98·5 per cent sulphuric acid was produced, most of which was used for fertilizer production at Wallaroo and Port Adelaide. During World War II 14,400 mono tons of the above was produced in the form of 20 per cent Oleum and railed to the Salisbury Munitions Factory for use in the production of nitro-glycerine, gun-cotton and T.N.T.In the early post-war period various ways of converting at least some of the sulphur in the gases' discharged to atmosphere from the lead sintering plant were considered until, in 1949, it was decided to erect a modern contact acid plant. Much work remained to be done on the roasting plant to produce a gas of suitable grade for the contact process and also on the design of a purification section suitable for the treatment of D.L. gases.The acid section itself, however, was largely of conventional design and it was therefore decided that this would be erected first. To it was then attached a sulphur-burning section to allow it to operate as a "hot gas" brimstone acid plant until the roasting and gas purification plants had been designed and erected. In this way the urgent need for sulphuric acid in the fertilizer industry would be relieved, to some extent at least, as soon as, possible.

Jan 1, 1956

The National Mining Hall of Fame will induct five mining greats on Saturday, Sept. 17, 2005 at the Museum Convention Center in Leadville, CO. The 18thAnnual National Mining Museum and Hall of Fame Induction Banquet will begin with an open house and reception at 5:30 p.m., followed by the dinner and program at 7 p.m. The five inductees are Nathaniel Peter Hill, John Munro Longyear, John McDonald, Julius Eckhardt Raht and John Dennis Ryan. Nathaniel Peter Hill (1832-1900) built the first successful smelting operation in the Rocky Mountains in1867 at Black Hawk, CO. From 1879 to 1885, he was a U.S. senator. He also taught courses at the Colorado School of Mines.

Jan 1, 2005

By Bengt H. Fellenius

The bearing capacity equation?"the triple N formula"? is now about 50 years old. It was developed from theory of plastic resistance of metal to a cone being pressed into the surface of the metal, superpositioned by resistance due to shear in an interparticulate medium (soil; note, we are not dealing with metallurgy), and tempered by work necessary to move the footing into the medium. The equation (and its coefficients) was "confirmed" by tests on small footings placed at or near the surface of the soil. The equation is a basic tenet of every geotechnical textbook, manual, and code. Over the years, innumerable variations of the N-coefficients and adjustments to the equation have been published. The main assumption behind the bearing capacity equation is that a shear plane develops between two essentially otherwise unaffected bodies: the main soil body and a body comprised of the footing with some soil. Moreover, the notion is that a model footing placed at or near the surface of a soil would behave proportionally or similarly to a full-scale footing, or to even a same size footing (pile toe) placed at some depth in the ground. This is not in agreement with factual observations. It is suggested that the behavior of a small or large diameter footing as well as a pile toe is governed by compression of the soil below the footing or pile toe and not by "bearing capacity".

Jan 1, 1999

By M. N. Abdusalyamova

The Republic of Tajikistan has large mercury-antimony deposit. The Republic takes the second place in the countries of the CIS by having antimony recourses or the fourth place in the world. Recently, on the mine bottom horizons the resources of gold were found. Gold in the data ore is submitted as nanosize particles. Results of ores enrichment of bottom horizons of Djijikrut deposit are obtained by a method of flotation. The flow sheet includes the rougher flotation, two scavenging flotation and two cleaner flotation. As a result of enrichment of ore, the mercury-antimony concentrate with the contents of 51.5% of antimony and recovery 90.3% from ore with the content of mercury of 3.5% was received. The investigation of thallium, selenium, and tellurium distributions on products of enrichment was carried out. The most effective reagents are a mixture of oksafore and butyl xanthogenate. While applying this mixture of reagents it is possible to refuse of the use of activator - nitrate lead. The behavior of gold is in details investigated during enrichment. To collective flotation concentrate is extracted only 30% of gold. The basic quantity of gold concentrates in tailings of flotation and is not taken by existing traditional methods. The alternative innovative technology of gold extraction was created. Various methods of roasting of a collective mercury - antimony concentrate oxidizing and reducing are investigated. Vacuum distillation of concentrate allocation in serial sublimates mercury and antimony was designed. In the received calcine concentrates gold. At additional roasting of a calcine up to 900°? concentration of gold makes 30.6 g/t. The offered innovational technology in a complex allows to process ores and concentrates unique mercury-antimony?gold bearing raw material. Keywords: ore, concentrate, flotation, cyanidation, roasting, mercury, antimony, gold

Sep 1, 2012

By John E. Urosek, Dennis A. Beiter, William J. Francart

In This Chapter [Designing bleeder systems Examining and maintaining bleeder systems Evaluating bleeder system effectiveness] INTRODUCTION Bleeder systems are that part of the mine ventilation network used to ventilate pillared areas in underground coal mines. Pillared areas are those in which pillars have been wholly or partially removed, including the areas where coal has been extracted by longwall mining. Bleeder systems protect miners from the hazards associated with methane and other gases, dusts and fumes, and oxygen deficiency that may occur in these mined-out areas. Effective bleeder systems control the air passing through the area and continuously dilute and move any methane-air mixtures and other gases, dusts, and fumes from the worked-out area away from active workings and into a return air course or to the surface of the mine. A bleeder system includes the pillared area (including the internal airflow paths), bleeder entries, bleeder connections, and all associated ventilation control devices that control the air passing through the pillared area. Bleeder entries are special air courses designed and maintained as part of the mine ventilation system. [This chapter focuses on the design, examination, maintenance, and evaluation of bleeder systems in underground coal mines.] The history of coal mine explosions in the United States is a reminder of the importance of adequate ventilation. Some of those disasters were the result of inadequately ventilated pillared areas. The importance of developing bleeder systems to ventilate these pillared areas and evaluating the bleeder system’s effectiveness is reflected in present-day federal regulations. For more information on bleeder systems, see Tisdale [1996] and Urosek and Francart [2002].

Jan 6, 2006

Jan 1, 1967

Recent U.S. mine disasters identified a need for improved training of miners in escape from mine fires and explosions. Researchers at the National Institute for Occupational Safety and Health?s (NIOSH) Spokane Research Laboratory (SRL) have designed fire-escape training software for use in a mine-safety training course. The software allows four trainees to work together in a virtual world via a computer network. Trainees responded favorably and showed a marked improvement in locating the proper evacuation routes on subsequent trials. In collaboration with the Pittsburgh Research Laboratory (PRL), a more elaborate fire evacuation scenario is being developed. Further study is needed to confirm that virtual training will translate to improved safety outcomes in the real world. Keywords: virtual reality (VR), safety, training, mining, mine fire evacuation

Jan 1, 2009

By G. K. Manning, A. R. Elsea, A. B. Westerman

A considerable number of high-tem-perature alloys, that is, alloys which have load-carrying ability at elevated temperatures, have been developed on an empirical basis. In order to determine why these alloys possess this particular ability, a project was started at Battelle Memorial Institute on the fundamental factors promoting high-temperature strength of alloys. .4t the time of inception of this study, the cobalt-base alloy, Vitallium, was widely used because of its good high-temperature properties. One phase of this study was to include an investigation of the structures observed in vitalliurn after various heat treatments. Howcver, before investigating the structural features of Vitallium, it appeared logical to examine the phase diagrams of the related binary systems in order to develop information as to which phases might be present in Vitallium. A preliminary survey of the pertinent alloy systems was made, with particular emphasis on the cobalt-chro-mium system, which is the base for the Vitallium series of alloys. The early work of Lewkonja and Guertler2 indicated that cobalt and chro-mium are completely miscible in the liquid state, and, within a narrow temperature range, in the solid state; that the liquidus shows a minimum; and that the alloys containing 45 to 85 pct chromium undergo a transformation at [zoo to 12 50 c More recently, Wever and Haschimoto,3 Wever andLange,4and Matsunaga5 carried Out experimental work which led to the diagrams shown in Fig I and 2. Both diagrams are based on thermal analysis, metallogra~hic, magnetic, and dilatation data; in addition, X ray diffraction results were used by Wever and Haschimoto, and electrical resistance measurements by Mat-SUnaRa. It is apparent from a comparison of the two diagrams that there was a difference of opinion as to the locations of the boundaries of the various phases, and as to the existence of a phase containing approximately 47 pct chromium. With these excep-tions noted, it might be pointed out that the two diagrams are similar, and that, in general, any particular reaction which is shown on both diagrams occurs at a lower temperature on the Matsunaga diagram than on that of Wever-Haschimoto-Lange. Thus, in view of the gaps in the data arid the questionable features in the published diagrams, it appeared desirable to start the fundamental study of Vitalhum by deter-mining the diagram for the cobalt-chro-mi~m system- Experimental Work For the convenience Of the reader, the diagram as determined by the present investigation is presented in Fig 3. The liquidus and solidus data for the low-chromium alloys were taken from the work of Wever and Haschimoto,3 while the melting point for pure chromium is the

Jan 1, 1949

By B. H. Caudle, L. G. Loncarie

Pilot flooding is one method of evaluating a proposed secondary recovery project. However, the amount and rate of oil recovery from an unconfined pilot area is not usually the same as from an equal area in a large-scale flood. This is true because fluids are free to move across the boundary of a pilot area. The result is that some of the oil produced in a pilot flood may come from outside the designated area and some of the displaced oil may leave the pilot area completely. This paper presents the results of fluid-flow model studies on a five-spot pilot flood. Mobility ratios between 0.1 and to have been studied. The effects of changing the ratio of injection to withdrawal rates are shown. INTRODUCTION A small-scale field test, or pilot flood, is an accepted method for evaluating the applicability of a secondary recovery operation and the economic potential of that operation for a reservoir. The pilot flood is carried on in the same manner, with the same injected materials and at the same pressures as would be used were the secondary recovery program to be expanded to a larger area of the field or to the entire field. If the reservoir fluid and reservoir rock properties are the same in the pilot area as in the rest of the reservoir, the production, injection and other pertinent data associated with the pilot test will represent and measure what should be expected from a full-scale development of this secondary recovery program. There is one major exception which, unfortunately, has been overlooked by many and which has been awaiting quantitative definition. This is the sweep-out pattern the reservoir engineer must use in interpreting the pilot flood and in extrapolating it to the full-scale development. The sweep-out area in a pilot flood is not contained within the five-spot pattern. Further, there is oil flow into and/or out of the five-spot during a pilot test. Thus, production data from pilots must be interpreted with this different flow system and sweep pattern in mind. We have studied the sweep-out pattern that will exist for some conditions of operation of pilot flooding a single five-spot (four injection wells and one producer). In our study, reported here, we have assumed that the reservoir is relatively homogeneous and of uniform thickness in the pilot area. The results of this study en-able the engineer to predict the recovery, injection requirements and project life for a full-scale operation from the pilot flooding data. The effects of various injection to withdrawal-rate ratios and mobility ratios in a relatively gas-free (10 per cent pore volume or less) system are shown. Experimental Method The technique used in this study was the same as that for the X-ray shadowgraph studies of sweep-out pattern efficiencies.' The model of the pilot and surrounding area was made from a uniform packing of round-grain sand consolidated with an epoxy resin. Fig. 1 shows the relation between the model and the pilot area. Only one-eighth of the pilot area had to be represented in the model because we assumed equal injec-

Common brattice cloths in use in Australian coal mines are compared by permeability measurements. The respective advantages of twill weave and tarpauling* weave cloths are listed, and the improvements to be obtained in the ventilation of a mine by using tarpauling cloths instead of the commonly used twill cloths are stressed. Plastic cloths are widely used overseas and are briefly discussed.INTRODUCTIONThe onset of extensive full-scale mechanization in Australian coal mines during the past few years has increased attention given to the ventilation of working places. Many inadequacies of the present system have been brought to light and not the least of these is connected with the use of brattice cloth, both in directing the flow of air around the face and in acting as a temporary sealing mechanism. A well-constructed line of brattice will only provide fair ventilation for a distance of 100 ft. Beyond this point the volume or air reaching the face falls off rapidly.Some of the shortcomings associated' with the use of brattice cloths are:1. Hurried installation, necessitated by a rapid advance, often results in poor workmanship with, consequently, an excessively high leakage rate.2. High places caused by falls of roof are difficult and time-consuming to seal.3. Curtains, in lines of brattice crossing transport routes, are difficult to maintain.4. Lines of brattice interfere with rock-dusting and clean-up of fine coal.5. Repair and maintenance of brattice consumes much...

Jan 1, 1959

By Axel Studeny

Geomechanical-numerical methods are an established tool for planning of underground excavations worldwide. By describing the interaction between heterogeneous layered strata and support elements it is possible to determine their suitability. The German hard coal mining industry has more than twenty years experience in investigation and using these parameters to carry out numerical calculations. Today, nearly all excavations (shafts, pit bottoms areas, bunkers, coal faces, development drivages, gate roads etc.) are calculated by geomechanical-numerical tools in combination with empirical planning methods. A high accuracy of planning results, which is a special requirement in the German coal industry with its deep-level longwalls, bedded and weak surrounding strata and multiple seam mining layouts, depends on the extensive calibration of the numerical models, which is achieved by: 1) Taking a large number of underground measurements with empirical evaluation. 2) Carrying out physical modeling. 3) Using the characteristic features of the installed support elements. This paper compares the planning approach used for multiple and single seam mining and presents the advantages of this planning tool. The main focus is on the feasibility of rockbolting as the sole means of roadway support for multiple seam mining operations, though the paper will also look at how the costs can be improved by using a low bolting density in single seam layouts.

Jan 1, 2007

The nature of the specialty glass and ceramic business magnifies the dependency of the ultimate product on the unique properties of their raw materials used to make them. This dependency has implications in the management of risk in the supply process which requires a special procurement organization and program commitment to be successful. The Coming system of managing critical materials and factors in development of alternate new suppliers and products is discussed.

Jan 1, 1989

By Hennessy F. L

It is generally recognised that slags are active participants in pyrometallurgical processes, and not merely inert liquids which must be produced. to effect separation of gangue material in smelting, or of impurities in refining. The importance attached to slag-metal reactions in steelmaking is shown by the numerous investigations in this field. However, there are still many important reactions of slags which require explanation. In this paper some new aspects of the reactions of slags will be discussed, as far as possible quantitatively.FREE AND COMBINED OXIDESMetallurgical experience indicates that variations in the composition of slags produce changes in the chemical behaviour of the various components. These variations have been generally ascribed to changes in the proportions of free and combined oxides, i.e., compounds have been assumed to be present in the liquid slag.Considerable support for this view has been adduced from the existence of compounds such as metallic silicates, phosphates, etc., in the solIdified slag. However, this does not imply that such compounds necessarily exist in the molten slag.The most direct evidence as to the nature of molten slag is to be obtained from a study of the liquid state. In...

Jan 1, 1950

By Gary B. Hemphill

The 345 km long Taiwan High Speed Rail Project will connect the island’s two most populated cities, Taipei and Kaohsiung. Kaohsiung is the world’s third busiest port. The 23 km of alignment on Contract C230 requires the construction of 5,879 m of shallow mined tunnels ranging from 137 m to 1,285 m in length. All nine of these tunnels are mined using NATM methodology. Two of the tunnels, T01 and T08 are in the Toukoshan Formation. This paper will discuss the mining methods, ground support design, and the instrumentation installed to monitor and verify its effectiveness in the two aforementioned tunnels.

Jan 1, 2003

By G-L. Wu, S-W. Wu

"The hot deformation behaviour of Nb-Ti microalloyed high-strength steel was investigated. Hot compression tests were conducted in the temperature range 900 to 1100°C under strain rates of 0.1, 1, and 5 s-1. Dynamic recrystallization (DRX) occurs as the main flow softening mechanism at high temperature and low strain rate. The hot deformation activation energy was calculated to be about 404 699 J/mol. The constitutive equation was developed to describe the relationship between peak stress, strain rate, and deformation temperature. The characteristics of DRX at different deformation conditions were extracted from the stressstrain curves using the work hardening parameter. The Cingara-McQueen equation was developed to predict the flow curves up to the peak strain. The processing maps were obtained on the basis of a dynamic materials model. The results predict an instability region in the temperature range 1010 to 1100°C when the strain rate exceeds 0.78 s-1. IntroductionThe 700 MPa grade HSLA steel is widely used in engineering machinery, automotive beams, carriages, and axle tubes, etc. (Pan et al., 2017 ). Generally, such grades contain a moderately high amount of Mn (approx. 1.4% and above), and microalloying elements like Nb, Ti, V, and Mo to impart the desired strength and toughness through solid-solution strengthening, precipitation hardening, and grain refinement dislocation strengthening (Chen and Yu, 2012; Opiela, 2014). However, the production costs can be greatly reduced by replacing part of the Nb, V, or Mo with inexpensive Ti and adopting the compact strip production CSP process (Opiela, 2014; Chen et al., 2015). Furthermore, the microalloying technology coupled with new-generation thermomechanical control processing (NG-TMCP) has proved efficient for achieving the proper balance between strength, toughness, ductility, and formability by means of a suitable combination of chemical composition and thermomechanical treatment parameters (Shukla et al., 2012; Wu, Zhou, and Liu, 2017).In hot forming processes, the complex microstructural evolutions are often induced by multiplicative hot deformation mechanisms, such as work hardening (WH), dynamic recovery (DRV), and dynamic recrystallization (DRX) (Zhang et al., 2014; Liang et al., 2015). Dynamic softening behaviour during hot processing has generated considerable interest because component properties are influenced significantly by its corresponding microstructural evolution (Wu et al., 2010). During deformation in the DRX process, deformed grains are replaced with substructures and newly formed fine and uniformly distributed grains. This occurs only when a critical strain for the onset of DRX is reached, and at the same time, the minimum rate of energy dissipating is reached (Ferdowsi et al., 2014). DRV occurs at a high strain rate and low temperature, reducing the stored energy greatly and making DRX difficult (Liang et al., 2015). The microstructural changes during DRX are sensitive to the processing parameters, such as strain rate, deformation temperature, and strain (Zhang et al., 2014; Ferdowsi et al., 2014). Therefore, in order to optimize the hot processing parameters, it is important to understand the behaviour of hot deformation visà- vis control of microstructural evolution."

May 1, 2019

By Vincent Tirolo

The proposed Second Avenue Subway is a new two-track subway line running from 125th Street and Park Avenue at the north, east along 125th Street to Second Avenue and south along Second Avenue to the Financial District in lower Manhattan, NY with 16 new stations and 13.6 km (8.5 miles) of track. The project has been broken into four construction phases. The initial Phase 1 operating segment includes three new stations (96th, 86th and 72nd Street stations) with a connection to the existing Broadway line at the 63rd Street Station at Lexington Avenue. Rehabilitation of the 63rd Street Station is also included in the scope of Phase 1. Subsequent phases extend service north and west to 125th Street (Phase 2), south to Houston Street (Phase 3) and finally to Hanover Square (Phase 4). The DMJM Harris/Arup Joint Venture (DHAJV) prepared the Contract Documents MTA for Phase 1. Parsons Brinckerhoff is providing the MTA with construction inspection services for Contract C-26002. In April 2007, NYCT awarded first Phase 1 for $337 million to S3 Tunnel Constructors, a tri-venture comprised of Skanska USA Civil, Schiavone and Shea. Contract C26002 is for the construction of the tunnel boring ma-chine (TBM) launch box and the mining of the TBM tunnels from 92nd Street to 63rd Street. The major part of the contract is to construct a shaft, commonly referred to as the launch box, from East 92nd Street to East 95th Street having dimensions of 244-m- (800-ft-) long by 18.9-m- (62-ft-) wide and a depth of 19.8 m (65 ft), including more than 91,000 m3 (119,000 cu yd) of soil and rock contained within its walls. The launch box will ultimately become the southern half of the 96th Street Station. The focus here is geological conditions at the launch box and existing structures along the launch box. These geologic conditions and existing structures had a major influence on the selection and design of the support of excavation system (SOE), the SOE bracing system, construction staging, the ground movements, dewatering and other challenges of constructing the launch box (Fig. 1).

Jan 1, 2013

In this, the centennial year of The Institute, it is appropriate that the history of the Institute in New Zealand be recorded. I am indebted to John Dew, compiler of the centenary publication æMining People A Century - Highlights of the First Hundred Years of The AusIMM 1893 - 1993Æ, for many of the early historical references in this paper. In July 1892 the Amalgamated Mining Managers' Association of Australasia held its annual conference in Ballarat, Victoria, Australia, when it was suggested by the delegate from Broken Hill that the time had arrived for the establishment of an Australasian Institute of Mining Engineers. Resulting from this meeting at Ballarat, a Provisional Committee was formed at Broken Hill with the object of forming The Australasian Institute of Mining Engineers having the following objectives. To promote the arts and sciences connected with the economic production of the useful minerals and metals, the welfare of those employed in those industries by means of meetings for social intercourse, and the reading and discussion of professional papers with the circulation by means of publications amongst its members and associates the information thus obtained.

Jan 1, 1993

By M. G. Corson

Until recently, the characteristics of cast copper have seldom been studied and such study as has been made has been inadequate. The prevailing idea seems to be that since pure copper is infrequently used in the cast stlate, there is no reason for trying to establish precise data regarding the properties of the metal in that condition. On the other hand, wrought copper either in the shape of sheets or wire rarely fails in service, except as a result of the action of reducing gases at the annealing temperatures, so there is little incentive to study the properties of the cast shapes —cakes, bars, ingots and billets—for the sake of tracing the causes of failures of the wrought metal to the cast stock. However, about a decade ago, wirebars of American origin often cracked badly while being hot-rolled in mills in Germany. This Icd to four investigations: by E. Seidl and E. Schieboldll by P. Siebe12 by 0. Bauer and G. Sachs,3 and by G. Welter.4 These authors came to the conclusion that failures in hot-rolling were due essentially to the presence of a wide zone of columnar crystals between t'he thin layer of fine crystal5 near the surfaces of the bars and the large but more nearly equiaxed grains of the central core. This macrostructural defect was explained in turn by the probable upward deviation in the temperature of the metal while it was being poured into the molds of the castling machine. More recently, cast shapes of copper were investigated by X. 1'. Allenh and by C. Blazey. Allen examined vertically cast wirebars and hori-zontally cast wedge cakes of electrolytic tough-pitch copper, but only for the distribution of densities; i.e., porosity. Blazey was interested mainly in the mechanism of the variations in electrical conductivity due to cold-work and anneal, but gave introductively an account of the composi-tion and average densities of the tough-pitch horizontally cast Wirebars used. As far as the present writer can tell, no investigation mas under-taken for the sake of presenting a picture of the distribution of mechanical characteristics in the wirebars of copper, or otherwise.

Jan 1, 1938

By M. G. Corson

Until recently, the characteristics of cast copper have seldom been studied and such study as has been made has been inadequate. The prevailing idea seems to be that since pure copper is infrequently used in the cast stlate, there is no reason for trying to establish precise data regarding the properties of the metal in that condition. On the other hand, wrought copper either in the shape of sheets or wire rarely fails in service, except as a result of the action of reducing gases at the annealing temperatures, so there is little incentive to study the properties of the cast shapes —cakes, bars, ingots and billets—for the sake of tracing the causes of failures of the wrought metal to the cast stock. However, about a decade ago, wirebars of American origin often cracked badly while being hot-rolled in mills in Germany. This Icd to four investigations: by E. Seidl and E. Schieboldll by P. Siebe12 by 0. Bauer and G. Sachs,3 and by G. Welter.4 These authors came to the conclusion that failures in hot-rolling were due essentially to the presence of a wide zone of columnar crystals between t'he thin layer of fine crystal5 near the surfaces of the bars and the large but more nearly equiaxed grains of the central core. This macrostructural defect was explained in turn by the probable upward deviation in the temperature of the metal while it was being poured into the molds of the castling machine. More recently, cast shapes of copper were investigated by X. 1'. Allenh and by C. Blazey. Allen examined vertically cast wirebars and hori-zontally cast wedge cakes of electrolytic tough-pitch copper, but only for the distribution of densities; i.e., porosity. Blazey was interested mainly in the mechanism of the variations in electrical conductivity due to cold-work and anneal, but gave introductively an account of the composi-tion and average densities of the tough-pitch horizontally cast Wirebars used. As far as the present writer can tell, no investigation mas under-taken for the sake of presenting a picture of the distribution of mechanical characteristics in the wirebars of copper, or otherwise.

Jan 1, 1938

By Lida Sun, Na Wu, Mengyang Huang, Xingxiang Fan, Yan Jiang, Shasha He, Kunbin Yang, Yang Cao

The separation of lead (Pb) and mercury (Hg) from copper (Cu) smelting acid sludge using the carbonization and acidleaching total hydrometallurgical process was investigated. The effects of the excess coefficient of sodium carbonate, excess coefficient of nitric acid, conversion time, conversion temperature, dissolution time, and dissolution temperature on the separation efficiency of Pb and Hg were studied. The test results indicated that when the dosage of sodium carbonate was 2.0 times the stoichiometric ratio, the conversion time was 1.5 h, the conversion temperature was 75 ℃, and the amount of nitric acid was 1.8 times the stoichiometric ratio. Additionally, the dissolution time was 1.0 h, the dissolution temperature was 60 ℃, the ratio of liquid–solid was 5:1, and the separation efficiency of Pb and Hg was 98.72%. This study demonstrated the advantages of a short, simple, and environmentally friendly process for separating Pb and Hg from Cu smelting acid sludge, providing complete separation and introducing a new technology.

May 30, 2024