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By G. B. Harris

In recent years, increasing attention has been focused on the hydrometallurgical treatment of base metals feeds, especially nickel laterites and polymetallic sulphides. One approach that has received some attention is the use of high?concentration chloride solutions (brines), which are now showing some promise after initial setbacks. Iron is usually the major component in the base metal feed to such processes, and if physical means cannot be used to remove it, then the iron concentration in the pregnant leach solution is always significant. This paper presents some of the background theory on the hydrolysis of iron in high-strength (>3M) chloride brines, and discusses the roles of temperature, solution concentration and free acidity. It is shown that the system is complex, but that crystalline and readily-filterable hematite can be generated, and that the system has a low energy requirement.

Jan 1, 2006

The C.S.I.R.O. acid alumina process employs the essential steps of digestion, hydrolysis and calcination to produce pure alumina from ores too high in silica or too low in grade for the Bayer process. The two latter stages have been described in some detail previously but the digestion stage requires separate discussion since ores vary widely in composition and reactivity. Kaolinitic clays require roasting to 800°C to render the alumina soluble in the 11 per cent sulphuric acid used in the process while some ferruginous laterites require roasting to reduce the reactivity of iron minerals.The iron content of pregnant solutions is kept at a low figure by digesting at temperatures where the solubilities of ferric oxide or basic ferric sulphates are small. A two-stage, counter-current digestion is necessary to extract a high percentage of alumina from the ores and to produce a basic pregnant liquor with an SO3 : AI 203 ratio of 1'\1 suitable for high temperature hydrolysis. The second stage of digestion, called the modification stage, treats slightly acid liquors with excess of ore in the temperature range 1200-1400C.The first stage operates at 170°-1900C to extract further alumina from modification residues, using recycled acid obtained from later steps of the process. Both temperature ranges are critical for economic operation and for proper control of the iron content of solutions. In batch experiments, 30 min is regarded as a suitable retention time for digestion and modification; ores which require much longer than this are less suitable for the process. Impurities such as silica, and titanium and vanadium oxides are discarded in the residue along with iron oxide, and do not contaminate the final product. Bivalent metallic sulphates such as MgSO4, can build up in the circuit to a very considerable degree without affecting product purity.Comparison with other processes shows that the C.S.I.R.O. process is superior for control of contamination by iron, which is the major problem in acid processes. The pure intermediate product (3Al203.4S03.9H20) is also more convenient for calcination to alumina than the hydrated aluminium sulphate usually recovered in other processes. Detailed cost comparisons must await pilot-plant evaluation of the C.S.LR.O process.

Jan 1, 1964

By Willard C. Lacy

A mining operation begins with prospecting and exploration-stages with long periods of investment and high risk of failure. However, success in exploration ultimately determines survival of the mining industry. Prospecting and exploration may discover evidence of a mineral occurrence and outline its size and character, but ore deposits that support mining are "made" through the collective efforts of project geologists, geophysicists, geochemists, metallurgists, engineers, chemists, lawyers, and even politicians (Joralemon, 1975). Some deposits may go through multiple cycles of rejection and recommendation, discovery and development, decline and abandonment, rediscovery and development, etc., as economic, technological, or political conditions change or geologic understanding is improved. Peters (1987, p. 233) graphically illustrates the normal life cycle of a mine and the position of exploration in the cycle (Fig. 4.0.1). During the past fifty years, mineral exploration has evolved from comparing evidence of mineralization of prospects with that of known deposits to a more quantitative science employing many facets of geochemistry, geophysics, multispectral sensing from space, computer data storage, analysis, modeling, and most importantly, a better understanding of ore genesis. This modem approach to exploration began in the late 1940s and continues to develop. Exploration efforts peaked in the 1960s with emphasis upon the search for porphyry copper deposits, Mississippi Valley lead-zinc deposits, and volcanogenic massive sulfide copper-lead-zinc deposits. It peaked again in the middle and late 1980s with emphasis upon micron-size disseminated gold and epithermal and stratiform precious metal deposits.

Jan 1, 2008

By Alvin W. Schillinger

Drilling was not entirely satisfactory in the search for native copper in the Osceola amygdaloid footwall as mining showed oreshoots to be more continuous than drilling indicated. The Geophysics Department of Michigan Technological University developed a portable induced polarization drill hole probe with a 3 electrode configuration and a sampling radius of 5'± A 20 ma current of alternately reversed polarity is pulsed at 3.5 sec. intervals and readings are taken every two feet. Potential is read during the "on" cycle for resistivity determinations. During the "off" cycle, after 10 ms delay, the I.P. potential is sampled for 10 ms and recorded. Resistivity (ohm-feet) and "S" values (mv/v) are plotted on semi-log paper. A lithologic log is plotted based on resistivity and anomalous "S" values noted. The low resistivity amygdaloid contains sills of high resistivity basaltic trap. Verified by core logs, amygdaloid-trap contacts could be picked to ±.5' from resistivity alone. Lithologic logs of long steel holes, based' on resistivity, now replaced sludge logging. An "S" value of 30 mv/v was established as the lower limit of diagnostic I.P. effects in mineralized amygdaloid and 50 mv/v as a threshold value for ore. Of 914 footwall zones drilled, 315 were probed yielding 203 anomalies. Success increased from 34% for drilling to 72% for drilling and probing. As checked by mining, 46 probe results were 78% correct. Failures were due to the instrument not detecting copper or to the misinterpretation of an anomaly. No false anomalies were found.

Jan 1, 1964

By M. L. Mellish

In 1989, for the third consecutive year, both the production and consumption of coal in the United States reached record levels. Domestic coal consumption totaled 806.5 Mt (889 million st) in 1989, a 5.4 Mt (6 million st) increase from the year before (Table 1). US coal exporters also had a banner year. For the first time since 1982, exports ex¬ceeded 91 Mt (100 million st). US coal production in 1989 rose by a surprising 27.3 Mt (30 million st), reaching 889 Mt (980 million st) for the year. To a certain extent, the sizable difference between production and demand growth was due to smaller consumer stock withdrawals. Coal consumers withdrew only 12.7 Mt (14 million st) of coal from their stocks in 1989, com¬pared to 22.7 Mt (25 million st) in 1988. Despite strengthening coal consumption, exports, and production, coal prices to all domestic sectors declined slightly during the year. That essentially continued the trend of the past several years. On the labor front, the United Mine Workers of America struck the Pittston Coal Group in 1989. It was a bitter work stoppage that was not settled until February of 1990. This was the first major coal strike since 1985. The strike also precipitated a series of wildcat outages by UMWA members in June and July. At their peak, more than 40,000 UMWA members participated in the wildcat strikes. Except at Pittston, however, most miners were back to work by August. It is estimated that perhaps 4.5 to 9.1 Mt (5 to 10 million st) of coal production was lost due to the Pittston and associated wildcat strikes. However, some of this production may have been recouped by other coal companies not affected by the wildcat strikes, and by the affected companies after the strikes ended.

Jan 1, 1990

By F. J. Reichhardt

Abstract -The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterozoic intrusion which is totally covered by sediments of the Karoo and Kalahari Formations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Transvaal Supergroup sediments and lavas. Multiphase deformation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE +Au concentrations.

Jan 1, 1994

By Robert McClure

The detection, recovery and disposal of commercial explosives and explosive waste has always carried a level of risk and requires specialized equipment and technical expertise. Improperly stored, discarded, deteriorated, misfired, stolen or surplus products are often the primary sources of explosives that require safe disposal. Detection and disposal tools available today have advanced significantly due to developments in Counter-Improvised Explosive Devices (C-IED) operations and commercial blasting technology. These technologies have provided safer more efficient ways to detect, investigate and dispose of commercial explosives products in order to minimize property damage and potential harm to disposal personnel and the general public.

Jan 1, 2015

By E. García-Ramos, P. Flores-Sánchez, E. G. Palacios, B. Zeifert, A. Romero-Serrano, M. Hallen-López

Chromium containing slags from stainless steelmaking may eventually be leached by acidic environments, therefore they should be treated before being stockpiled or land filled. In this work, synthetic slags were prepared and the effect of CaO/SiO2, Cr2O3, MgO and Al2O3 contents on the stability of the mineralogical species formed was analyzed. The morphology and composition of the slags were analyzed by XRD and SEM-EDS, whilst their chemical stability was evaluated by leaching with an aqueous acetic acid solution. It was found that CaCr2O4 and CaCrO4 are present in slags prepared with neither MgO nor Al2O3. The Al2O3-based slags mainly produced Ca2Al2SiO7 and the Cr(VI)-containing oxide complex Ca4Al6CrO16, whilst MgO-based slags produced MgCr2O4 as main mineralogical species. Additionally, Eh-pH diagrams for the Ca-Cr-H2O and Mg-Cr-H2O systems at 25 °C were constructed. The lowest Cr concentration levels in the leaching liquors corresponded to MgO-based slags owing to the stable binding of Cr in spinel with MgO. It was also observed in the Al2O3-based slags that increasing the slag basicity from 1 to 2 the leachability of the slags are notably increased.

Jan 1, 2008

By D. I. Bardos, Paul A. Beck

A MARK, Boren, and westgrenl in their X-ray diffraction study of manganese alloys with 10 to 25 at. pct Si reported the occurrence of a phase with complex crystal structure in a Mn + 14.5 at. pct Si alloy after annealing at 800° or at 600°C. Recently Kuzma and Gladyshevskii2 identified Mn6Si as an R phase,3,4 the second binary R phase known. (A binary R phase was previously found in the Mn-Ti system by Waterstrat.5) A ternary R phase was reported earlier0 near the Mn-Si binary border of the Ti-Mn-Si system at 1000°C. In the light of the Russian work it now appears that this "ternary" R phase may be in fact an extension of the binary (Mn6Si)R phase. As already found by Amark, Boren, and Westgren, the corresponding binary phase is absent at 1000°C; the effect of titanium is evidently to stabilize it up to higher temperatures. In a recent paper Wieser and Forgeng7 gave the boundaries of this binary phase, which they referred to as 6. In order to re-examine the identity of this phase, an alloy of Mn + 14.5 at. pct Si was prepared by induction melting in helium atmosphere and annealed for 3 days at 800°C. The powder pattern, taken with an asymmetrical focusing camera of large dispersion and shown in Table I, was found to be that of the R phase, in agreement with the results of Kuzma and Gladyshevskii. For comparison, Table I also lists

Jan 1, 1965

By Hector M. Henao

The FeOX-CaO-SiO2 base slag at intermediate oxygen partial pressures is very often used in non-ferrous smelting processes. This slag would also contain Al2O3 and MgO because these compounds are normal components in the ore and the refractory of a furnace. The objective of the present work is to determine the effect of Al2O3 or MgO addition on the liquidus temperatures of the plain FeOX-CaO-SiO2 slags in the atmosphere between intermediate pO2 of 10-6 and that of iron saturation at 1250 and 1300 °C. The experiments were carried out at given mass%CaO/(mass%CaO+mass%SiO2) ratios ranging from 0 to 1 and at spinel-tridimite double saturation. The experimental results show that the effect of Al2O3 or MgO addition on the plain FeOX-SiO2-CaO slag is not uniform and depends on the content of Al2O3 or MgO, the oxygen partial pressure and the mass% CaO/mass% SiO2 ratio. It is apparent that Al2O3 or MgO addition enlarges the spinel or wustite saturation area at almost all the oxygen partial pressures and temperatures of this research. The obtained phase diagrams will be useful in the metallurgical industry to assist in the selection of slag chemistry, operation condition and development of new processes.

Jan 1, 2006

COUNCIL OF SECTION DELEGATES Jack A. Criehton. Chairman Allen T. Cole. Vice Chairman M I. Signer, Secretary EXECUTIVE COMMITTEE W. C. Leonard, North Pacific W. K. Beck, Cleveland W. W. Leonard, Southwest Texas

Jan 1, 1952

By cheng Peng-fei, TANG Hai-yan, guo Xiao-chen, LI Jing-she, Liang Yong-cang, Zhao Baojun

The origin and evolution of non-metallic inclusions for Al-killed casing steel during EAF-LFVD- CC process were studied by industrial tracer experiments. The formations of Al2O3 and MgO·Al2O3 micro- and macro-inclusions from ladle slag were analyzed by theoretical calculations. The results show that micro-inclusions were formed during deoxidation and temperature decreasing in the process of casting, most of the macro-inclusions come from entrapped ladle and mold slags. In addition, most of the Al2O3 formed were modified into 12CaO·7Al2O3 and 3CaO·Al2O3 inclusions which are liquid at steelmaking temperature. MnS cannot be fully modified to CaS and it was only wrapped outside the alumina or calcium aluminate in the form of (Ca,Mn)S with the amount of Ca-Si wire fed during the test.

Jan 1, 2016

By E. A. Nesbitt

A new permanent-magnet material has been developed with unusual mechanical as well as magnetic properties. Specimens that have been cast or subjected to a small amount of hot reduction by rolling or swaging may be machined, punched, tapped or drilled. The composition range of the alloys is 30 to 52 per cent iron, 36 to 62 per cent cobalt and 4 to 16 per cent vanadium. After being either quenched, annealed or given the usual cold finishing passes and then heated for 2 hr. at 600°C., such materials have a magnetic energy product of 1.0 X 106 gauss-oersteds. This product is equivalent to that of the well-known Honda steel (36 per cent Co, 4W, 2 Cr, 0.8 C. 0.3 Mn, balance Fe). Material handled in the manner just described does not depend on cold-working for its magnetic properties, and is known as Vicalloy I. The preferred composition for Vicalloy I is 38.5 per cent iron, 52 per cent cobalt and 9.5 per cent vanadium. When the alloys are first hot-worked, then considerably reduced in area by cold-swaging, drawing or groove rolling and then heat-treated, the magnetic energy product measured in the direction of previous extension is increased to 2.0 to 3.5 X 106 gauss-oersteds. These higher values have been obtained only after cold reductions in area of 75 to 95 per cent. Material handled in this manner is known as Vicalloy II and the preferred composi-

Jan 1, 1947

By E. A. Nesbitt

A new permanent-magnet material has been developed with unusual mechanical as well as magnetic properties. Specimens that have been cast or subjected to a small amount of hot reduction by rolling or swaging may be machined, punched, tapped or drilled. The composition range of the alloys is 30 to 52 per cent iron, 36 to 62 per cent cobalt and 4 to 16 per cent vanadium. After being either quenched, annealed or given the usual cold finishing passes and then heated for 2 hr. at 600°C., such materials have a magnetic energy product of 1.0 X 106 gauss-oersteds. This product is equivalent to that of the well-known Honda steel (36 per cent Co, 4W, 2 Cr, 0.8 C. 0.3 Mn, balance Fe). Material handled in the manner just described does not depend on cold-working for its magnetic properties, and is known as Vicalloy I. The preferred composition for Vicalloy I is 38.5 per cent iron, 52 per cent cobalt and 9.5 per cent vanadium. When the alloys are first hot-worked, then considerably reduced in area by cold-swaging, drawing or groove rolling and then heat-treated, the magnetic energy product measured in the direction of previous extension is increased to 2.0 to 3.5 X 106 gauss-oersteds. These higher values have been obtained only after cold reductions in area of 75 to 95 per cent. Material handled in this manner is known as Vicalloy II and the preferred composi-

Jan 1, 1947

By Frank Marotta, Louis B. Lesem, Frank Greytok, John J. McKetta

Although one of the primary variables in the calculation of the flowing bottom-hole pressure in gas wells from surface measurements is the temperature at any point and its distribution in the flow-string, only few experimental data are available in the literature and little attention has been given to analysis of the problem. Virtually all of the recently published methods of calculating flowing bottom-hole pressures depend on the assumption that either the temperature is constant at some average value or that the variation is linear with depth. The purposes of this work are to analyze the problem theoretically and to verify the analysis by comparison with experimental data so that practical problems in the analysis of the behavior of gas wells can be solved with greater accuracy, reliability, and ease. MATHEMATICAL OUTLINE OF PROBLEM Assuming that: 1. The mass velocity and chemical composition of the gas stream are constant and in normal gas well operations, the change in linear velocity in the entire flow-string is trivial, 2. The product of the density and heat capacity of the gas is constant, 3. No horizontal temperature gradient exists in the gas stream, 4. Net flow of heat by conduction within the formation and in the gas stream in the vertical direction is trivial in magnitude and can be neglected, 5. The regional vertical geothermal gradient is constant, and 6. The temperature of the gas entering the borehole is constant, and equal to that of the reservoir, a set of two simultaneous, linear partial differential equations with appropriate boundary conditions was derived to describe the temperature distribution in the gas stream and the surrounding formation. These equations were solved by operational techniques for the distribution of temperature in the gas stream. The resulting integrals were evaluated numerically on an IBM 604 at the Machine Accounting Div. of the Railroad Commission of Texas. DERIVATION OF FUNCTIONS FOR THE DISTRIBUTION OF TEMPERATURE The physical system is a circular hole of radius a in an infinite medium with thermal conductivity K, density p8, and heat capacity c,. Under shut-in conditions the well is in thermal equilibrium with the surroundings and the increment in temperature is given by - ?T3/L x. Gas of density pg and heat capacity c.. flows upwardly through this hole in the direction of increasing x with a linear velocity W. Writing a heat balance on an element of gas ?x in thickness, convective heat transfer + conductive heat transfer + energy required to lift a unit mass of fluid = change in energy content. pa2W po Co To - pa2Wpo Co To x+xx - 2apK?x ?T8/?r r=a - Wpa2 po?x/778 = CoPopa2?x?To/?t... Dividing by (copopa2?x) and taking the limit as ?x tends to zero, -W (?To/?x + 1/778Co) + 2 K/a Po Co ?T3/?r r=u = ?To/?t

Jan 1, 1958

By Viktor Lishchuk, Olof Martinsson, Tobias E. Bauer, Elena Haller

Freely accessible and non-confidential real-life geological data sets from mineral deposits are desirable for the wide range of applications in research and education. However, publicly available statistical data are limited in their number and quality—they contain reduced information about geological, geophysical, geotechnical, chemical, mineralogical, and other relevant properties of deposits. This makes such data insufficient for scientific purposes. However, the amount of geological knowledge obtained for a variety of deposits in the past allows the construction of an idealized synthetic ore body model using analytical approach. Such a model could be used for education purposes and testing basic scientific theories, e.g., visualization of deposit structure; teaching sampling strategies; testing new algorithms for mine planning; or comparing geostatistical modeling methods. This paper presents an analytical approach to simulate volcanic massive sulfide (VMS) deposits and shows how synthetic deposit model can be constructed and further used for studying sampling with drilling and simulating folding and faulting.

Jan 14, 2021

By Bhargav Dhavala, Sristy Raj, Ashok Kumar, Suman Krishna Sit, Adity Ganguly, D. P. Chakraborty

"Tatasteel’s West Bokaro washery#3 is designed to deslime raw coal at 0.5mm; the oversize (+0.5mm) is beneficiated in dense media cyclones (DMC) while the undersize (-0.5mm) is beneficiated in froth flotation (FF) cells. Nearly, 80% of the raw coal feed reports to the DMC circuit consisting of four parallel streams. Presently, the performance of DMCs at washery#3 is interpreted by: (a) comparing the actual plant yield w.r.t the lab predicted yield and (b) misplacement of clean coal to middllings.However, the comparison between actual & lab predicted yield is fallacious given the fact that the lab predicts yield of the borehole sample while the feed received at the plant has different characteristics altogether due to the dilution during mining. To mitigate the said limitations, a quick diagnosis tool using the past data has been developed that will give a prediction of performance of different coal seams in the DMCs, inputs being feed ash to DMCs and stream wise feed specific gravity (coal & magnetite combined).The tool also will help in identifying the root cause on real time basis thereby helping the operator to take necessary corrective actions. The operator can intimate the mining personnel in cases of shale reporting to the feed as a result of dilution during mining. In events of higher standard deviations between the parallel streams w.r.t feed specific gravity, the operator can adjust the parameters accordingly to minimize the yield loss. INTRODUCTION West Bokaro came into existence in 1948, as an independent coal company, managed by M/S Anderson Wright. Tata Steel acquired the Company in 1956 to meet its requirement of metallurgical grade coal for Iron making. Subsequently, in 1976, it was made a division of Tata Steel. In 1974, when coal mines were nationalized, West Bokaro was exempted as it produced coal only for captive consumption of the Steel Works. The first washery of India was set up in West Bokaro. The business objective of the West Bokaro division is to produce clean coal at optimum cost for captive use in the steel plant of Tata Steel at Jamshedpur. The strategy is to reduce ash with minimum loss of yield so that quality of coal improves and yet the cost is beneficial vis-a vis imported coal. The primary product is the metallurgical grade coal for coke ovens, which converts coal into coke for use in the Blast Furnaces."

Jan 1, 2018

By S. E. Olsen, K. Tang

Slag-metal and slag-metal-gas heterogeneous equilibria involving MnO-containing slags have been simulated using recently developed Mn-based alloy and IRSID oxide thermochemical databases. A large number of experimental equilibrium data have been used to verify the calculation results. The experimental slag-metal and slag-metal-gas equilibria in MnO-SiO2binary, MnO-SiO2-CaO and MnO-SiO2-Al2O3ternary, MnO-SiO2-CaO-Al2O3quaternary andMnO-SiO2-CaO-Al2O3-MgO higher-order system can be reproduced within experimental uncertainties. The influence of temperature, CO partial pressure and slag chemistry on the Mn-and Si-distribution equilibria have been quantitatively evaluated. This leads to a sound basis for optimizing the manganese ferroalloy production processes. Key words: MnO-containing slag, manganese ferroalloy, equilibrium simulation, thermochemical database

Jan 1, 2004

Editor?s note: Each year, the June issue of Mining Engineering features an industrial minerals review. Several people put in a fair amount of time in developing the material for this issue, all the while doing their own jobs. Thank you to the industrial minerals annual review editor, to the Industrial Minerals and Aggregates Division technical committee chair and vice-chairs, and to the authors of the individual commodity profiles. Jim Norman, member SME, of Tetra Tech, is the industrial minerals annual review editor. Candace Trimble, member SME, of Oil-Dri Corporation of America, is chair of the Industrial Minerals and Aggregates Division?s Technical Committee.

Jan 1, 2012

Winzes are usually sunk 9 ft. 6 in. long by 6 ft. 0 in. wide and are divided into two compartments, 4 ft. 0 in. by 5 ft. 0 in. inside the timbers. The general practice is to sink the winze to a depth of from 9 to 12 ft., put in bearers and three or four rings of timber, and then erect a sinking headframe before continuing sinking operations.GENERALThe main feature governing the design of the headframe was that all parts could be transported on timber trolleys in No. 2 Shaft. Except for some minor details the structural members consist of steam pipe. Joints are sections of steam pipe welded to one member and into which the other member fits and is held in place by a 1-in. bolt. The headframe consists essentially of two bedpieces to carry the winch and to form a seat for the four legs. The legs support the sheave bearers, the tipping door and the brace.Except during tipping operations the door is in a nearly vertical position. For tipping it is lowered to an inclined position and a hook suspended from one of the bracing members of the headframe is attached to a "D" welded to the bottom of the kibble. This causes the kibble to tip when it is lowered on to the tipping door. The capacity of the kibble is 4 cubic feet.THE HEADFRAMEThe dimensions of the headframe are:Height to top of sheave .. .. 14 ft. 10 in.Distance centre to centre of legs 4 ft. 4 in.Length of bedpieces .. .. .. .. 8 ft. 9 in.The weight is approximately 2,000 lb., the tipping door and bedpieces being the heaviest members. They weigh 240 lb. and 170 lb. respectively.One compartment of the winze is decked over, and the bedpieces, which are 8 ft. 9 in. lengths of 6 in. pipe with three short lengths of plate welded to the underside, are placed over the sinking compartment, either transversely or parallel to the winze. Three 3 inch pipes act as spreaders between them.Welded to the top of each bedpiece is a 6-in. by iHn. plate 3 ft. 0 in. long with four 4-in. by 1.5-in. slots cut longitudinally at 10 in. centres. Two 10 in. by 4-in. timbers are bolted to these plates, the distance between them being adjusted to suit the holes in the winch bedplate, which is bolted to the 10-in. by 4-in. timbers.Two short lengths of 3 in. pipe are welded to each bedpiece at 4 ft. 4 in. centres. These form the seats for the legs of the headframe, which are...

Jan 1, 1941