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By James R. Welty

Heat content values were experimentally determined for yttrium metal between temperatures of 400° and 1,300° K and for iron pentacarbonyl between 301° and 380° K. The drop technique was used; that is, a sample of material sealed in a protective capsule was heated to 3 desired temperature in a furnace and then dropped into an ice calorimeter. A revised technique for determining heat content values from calorimetric data is described. Heat content and corresponding entropy-increment data above a reference temperature of 298.15° K are presented in tabular form. Equations for heat content and heat capacity as functions of temperature were derived for each substance. These equations are [Y (c): HT-H298.15 = 1.2041T 1 3.393 x 10-3T2- 0.4176 x 10' T"1 + 739.9 cal/mole Cp = 1.2041 + 6.786 x 10-3T + 0.4176 x 106-T-2 cal/deg mole Fe (CO) E, (1) : HT - H298.15 = 55.636T - 16,588 cal/mole Cp = 55.636 cal/deg mole]

Jan 1, 1963

By Misra V. N, Cheng C. Y

Two types of Mt Tom Price hematite iron ore from Hamersley Iron P/L were tested using a Humboldt Wedag Jones P40 wet high intensity magnetic separator (WHIMS). The parameters tested were magnetic intensity (7000, 9000 and 11 000 Gauss), groove plate type (8R and 12R) and gap width (2.5 and 1.8 mm). It was found that at 9000 gauss magnetic intensity, reasonably high-grade and recovery in the concentrate were obtained. At 2.5 mm plate gap width, the 12R groove plate performed slightly better than the 8R groove plate. Further testwork is recommended to optimise the magnetic intensity, feed flowrate and pulp density, wash water pressure and flowrate with 12R and 8R groove plates at 2.5 mm gap width.

Jan 1, 1999

By Herty, C. H.

Iron oxide (FeO) plays an extremely important part in the manufacture of iron and steel. In the three major processes- blast-furnace, open-hearth, and Bessemer converter-iron oxide is the chemically predominant compound and controls to a large ex- tent the operation of the furnaces and the composition and quality of their respective products. In order to emphasize the importance of iron oxide in each process, they will be considered individually in some detail. THE OPEN-HEARTH FURNACE. Iron oxide is introduced into the open-hearth furnace in four ways : 1. The scrap charged into the open hearth is oxidized by the furnace gases, the amount of oxide formed depending primarily on the amount and type of scrap charged. It has been found' that with large scrap, 1.7 Ib. of FeO is formed per 100 Ib. of scrap charged, whereas with scrap of medium size about 5.3 Ib. of FeO is formed per 100 Ib. of scrap charged, when the period between the charging of the scrap and the addition of hot metal is 3 hours. 2. The decomposition of the limestone sets free CO, by the reaction

Jan 1, 1957

By K. Janghorban

Multilayered ceramic-metal composites were produced by solid state diffusion bonding of polycrystalline alumina and three Al alloys containing 1 to 2%Sr, 2% Mg and Mg + Si (5057 Al alloy), The multilayered structures were fabricated at 610°C under a compressive stress of 3 MPa for 2 hours in He-5%H atmosphere, The ceramic-metal interfaces were studied by SEM and TEM equipped with energy dispersive spectrometer (EDS). Addition of 1 wt % Sr to Al promoted good adhesion, without producing any interfacial products, while the Al-2%Sr was poor in this regard due to the presence of dispersed A14Sr which is an intrinsic phase in the Al-Sr phase system, The Al-2%Mg alloy produced a continuous film at the interface, which was characterized to be MgAl2O4. Al alloys containing Mg and Si (5057 commercial alloy) produced not only the spinel structure (MgAl2O4), but another phase rich in Mg and Si (close to Mg2Si), These latter interfacial reaction products were not the intrinsic phases in Al-Mg alloys, and were reaction products at the Al2O3 ?Al alloy interfaces.

Jan 1, 2005

By J. F. Hutwelker

A pilot plant was constructed and operated to investigate the column flotation of 20 x 200 mesh North Carolina phosphate ore, using high throughput, high solids operating conditions developed at the NCSU Minerals Research Laboratory. Flotation was performed at 45% solids in a 9.5 cm (3.75 in.) diameter by 2.26 m (7.4 ft.) tall column at throughputs of 19.1 t/hr/m2 (2.0 stph/ft2) and 31.7 t/hr/m2 (3.3 stph/ft2). Recoveries in excess of 98% of the phosphate value were obtained at the lower throughput -- while obtaining concentrate grades containing over 28% P205 (61.2% BPL) at that recovery. Recoveries of about 95% of the phosphate value were obtained at the higher throughput, while making a concentrate averaging 27.6% P209 (60.3% BPL). In addition, a better understanding of the variables governing the column flotation of coarse nonmetallic minerals was gained. Low air flow rates adversely affected concentrate grade at the lower throughput. At the higher throughput, phosphate recovery decreased at an elevated air flow rate. An unexpected result of the study was the effect that frother type had upon phosphate metallurgy. Use of Nottingham Econofroth 925 provided better flotation selectivity than American Cyanamid F-65 at the low throughput. This is significant since the high' throughput tests were conducted with F-65 exclusively. It is reasonable to expect further improvement in high throughput performance when the optimal frother type and dosage are determined.

Jan 1, 1993

By B. Birol, M. N. Saridede

"Slag density is a significant factor in determining the process efficiency of the electroslag remelting (ESR) process, where calcium fluoride (CaF2)-based slag is formed synthetically to refine metal ingots. Although there are some former studies investigating the density of CaF2-containing slags, the prediction models focusing on them are applicable only to some specific systems. The present study aims to build a model to predict density for a wide range of CaF2-containing ESR slags. To investigate density for various slag compositions, CaF2-Al2O3-based and CaF2-Al2O3-CaO-based slag compositions were prepared. Additionally, some minor constituents like FeO, MgO and MnO were added to a 5:3:2 CaF2-Al2O3-CaO slag in order to investigate the effects of these constituents on the slag. The volumes of the prepared slags were measured in a tube furnace at 1450-1550 °C using the sessile drop technique, and their densities were calculated. The results showed that for the slags, density is related to optical basicity, and therefore a prediction model based on an Arrhenius equation was built. The model was tested with data from literature, and its limitations and validity are discussed.IntroductionThe electroslag remelting (ESR) process is a refining method in which a metal ingot is remelted under a synthetic slag. These synthetic ESR slags are mainly composed of calcium fluoride (CaF2), calcium oxide (CaO) and aluminum oxide (Al2O3). Other constituents like iron oxide (FeO), magnesium oxide (MgO), manganese oxide (MnO) and chromium oxide (Cr2O3) are added to this system in relatively low amounts, according to the type of steel ingot to be refined. The prediction of slag properties, such as electrical conductivity, viscosity and density, is crucial for the selection of the synthetic slag in order to obtain the required process parameters, like temperature, the passing time of the molten metal droplet through the slag, and metal-slag separation (Akbari, Reitz and Friedrich, 2009; Hara and Ogino, 1981; Mattar, El-Faramawy and Fathy, 2002; Mehrabi, Rahimipour and Shokuhfar, 2005; Presoly, Korp and Schneider, 2008).As slag density affects metal-slag separation in the ESR process, predicting the density of an ESR slag is important for appropriate refining and improved product quality. Although there are many studies investigating the density of slags (Akbari, Reitz and Friedrich, 2009; Aune, Hayashi and Sridhar, 2005; Hara and Ogino, 1981; Matsushita, 2011; Mills and Keene, 1987, 1981; Seetharaman et al., 2013; Shu, 2007; Shu and Chou, 2013; Sikora and Zielinski, 1974; Xu et al., 2012; Zhang and Chou, 2010), the prediction models built are generally valid for oxide-containing slags (Aune, Hayashi and Sridhar, 2005; Bottinga and Weill, 1970; Mills and Keene, 1987; Seetharaman et al., 2013; Shu, 2007; Xu et al., 2012; Zhang and Chou, 2010). These models were built on either the molar volumes of the constituents (Bottinga and Weill, 1970; Mills and Keene, 1987) or the thermodynamically calculated enthalpy or free energy of mixing, which can be applied to a system containing constituents sharing an ion, such as an O- ion for oxide systems (Aune, Hayashi and Sridhar, 2005; Hillert, 1980; Persson et al., 2007). Some recent studies modeled the density of some oxide slags on their optical basicity (Shu, 2007; Shu and Chou, 2013; Xu et al., 2012; Zhang and Chou, 2010)."

Jan 1, 2016

By J. S. Browning

The pegmatites of the Kings Mountain-Lincolnton, N. C., area constitute the largest known domestic reserve of beryl and spodumene. The reserve is estimated to contain 90 million tons of pegmatic material with 1,280,000 tons of recoverable Li2O (lithia) as spodumene.1 The pegmatites also contain 0.4 to 0.5 pct beryl disseminated throughout the orebodies. The pegmatites may contain a potential reserve of 240,000 tons beryl, equivalent to approximately 34,000 tons of BeO. Different flotation methods for separating beryl from feldspar or quartz, or both, have been developed by various investigators.2,3,4,5,6,7 On the other hand, published information is limited on concentration of spodumene-beryl ores. As the response of beryl and spodumene to flotation is essentially the same, a successful separation of the two minerals depends upon use of a selective depressant or a selective collector for one of the minerals.

Jan 7, 1961

By J. Brent Hiskey

Thiourea is a reagent capable of complexing gold and silver. With the proper oxidant, thiourea can effectively dissolve metallic gold and silver. A thiourea leaching system possesses potential advantages over conventional cyanidation including acidic solutions instead of alkaline, cationic complexes in contrast to metal-cyanide anoionic complexes, and faster leaching rates with acidic solutions of thiourea. Generally, the rate of metal dissolution in thiourea solution is fastest when ferric ion is employed as an oxidant. Acidic thiourea solutions for certain applications could offer a nontoxic and noncorrosive option for processing gold and silver. This paper provides information regarding the fundamental chemistry of the acidic thiourea system, and reviews the dissolution of both silver and gold in acidic solutions of thiourea. The recovery of gold and silver from acidic thiourea solution is discussed.

Jan 1, 1981

By Yuanbo Zhang, Zhixiong You, FENG ZHOU, Guanghui Li, Zhengwei Yu, Zhiwei Peng

Reduction disintegration of sinter significantly affects the coke consumption and productivity of blast furnace smelting. As we know, the reduction disintegration index (RDI+3.15) of sinter obtained from titanomagnetite concentrate is relatively worse than those from ordinary iron ores. In this study, the effect of sintering parameters, mainly involving coke breeze dosage and basicity on sintering indexes was investigated using titanomagnetite concentrate as raw material in an experimental-scale pot. Subsequently, RDI+3.15 of the sinter was detected according to the Chinese standard of GB/T13242-91. The results show that RDI+3.15 rises with the increase of coke breeze dosage, while it decreases with increasing basicity from 0.5 to 2.0 and then increases in the basicity range of 2.0-3.0. Finally, the microstructure of sinter before and after reduction was studied. And the mechanism of reduction disintegration was preliminary revealed by analyzing the morphologies and distributions of minerals in the sinter.

Jan 1, 2015

By D. T. MacRoberts

A simple disturbance in a gas reservoir travels with a finite velocity which is nearly independent of the amplitude of the disturbance. As a result very complex transients may be set up which seriously affect observation at a well. The time of transient is much longer than commonly supposed. INTRODUCTION A change in pressure at a gas well is not propagated through the reservoir instantaneously but with a definite fin- ite velocity. Knowledge of the period ! of this transient is of value because: 1. Observations of pressure and flow-rate during the transient may affect interpretation of back-pressure tests. 2. Interference effects between wells may be used to determine continuity of formation. 3. Additional information concerning the physical characteris- tics may possibly be deduced from the behavior of a well during the transient. MATHEMATICAL DEVELOPMENT It will be assumed that the well is initially closed in and that the pressure is constant throlughout the reservoir. As the initial disturbance passes outward from the well it is further assumed that a logarithmic pressure distribution is established between the most distant point reached and the well, so that: <l> = ((/)r-<t>w) I ------------ + (/) . (1) Manuscript received at office of the Branch September 15. 1948. Paper presented at Branch Fall Meeting, Dallas. Texas. Oct. 4-6, 1948. r. = distance to any point between r and rw r = radius of drainge iw= radius of well (/) = potential (P for incompressible fluids, P2 for perfect gases) Up to the time the effect reaches the point r the production from the well will be: W= (Pr-P,,,) . (2) i b W = volume produced t = sand thickness F = fractional porosity Pr = reservoir pressure Pm = average pressure between r and rw Pb = atmospheric Pressure All pressures will subsequently be stated in atmospheres and the constant Pb will be omitted. This will be produced at a rate: dw t k (Pr³-PW2) do d 0 - . (3) log — Pw = pressure at the well k = permeability 0 = time = viscosity

Jan 1, 1949

By D. T. MacRoberts

A simple disturbance in a gas reservoir travels with a finite velocity which is nearly independent of the amplitude of the disturbance. As a result very complex transients may be set up which seriously affect observation at a well. The time of transient is much longer than commonly supposed. INTRODUCTION A change in pressure at a gas well is not propagated through the reservoir instantaneously but with a definite fin- ite velocity. Knowledge of the period ! of this transient is of value because: 1. Observations of pressure and flow-rate during the transient may affect interpretation of back-pressure tests. 2. Interference effects between wells may be used to determine continuity of formation. 3. Additional information concerning the physical characteris- tics may possibly be deduced from the behavior of a well during the transient. MATHEMATICAL DEVELOPMENT It will be assumed that the well is initially closed in and that the pressure is constant throlughout the reservoir. As the initial disturbance passes outward from the well it is further assumed that a logarithmic pressure distribution is established between the most distant point reached and the well, so that: <l> = ((/)r-<t>w) I ------------ + (/) . (1) Manuscript received at office of the Branch September 15. 1948. Paper presented at Branch Fall Meeting, Dallas. Texas. Oct. 4-6, 1948. r. = distance to any point between r and rw r = radius of drainge iw= radius of well (/) = potential (P for incompressible fluids, P2 for perfect gases) Up to the time the effect reaches the point r the production from the well will be: W= (Pr-P,,,) . (2) i b W = volume produced t = sand thickness F = fractional porosity Pr = reservoir pressure Pm = average pressure between r and rw Pb = atmospheric Pressure All pressures will subsequently be stated in atmospheres and the constant Pb will be omitted. This will be produced at a rate: dw t k (Pr³-PW2) do d 0 - . (3) log — Pw = pressure at the well k = permeability 0 = time = viscosity

Jan 1, 1949

By S. R. S. Sastri, D. K. Senguta, S. K. Bhaumik, G. V. Rao

The amenability of a calcite-bearing ore to the reduction of silica to below 0.2% by physical beneficiation was studied. The objective was to use the ore as a raw material for seawater magnesia production. The ore contains complex gangue minerals such as diopside, forsterite, phlogopite, clinohumite, graphite and quartz. These contribute to around 25% acid insolubles with 6% SiO2. Reverse-flotation studies using various cationic collectors with tannin as a depressant indicated the possibility of reducing the acid insolubles to around 5%. Direct flotation of calcite with anionic sodium oleate in the presence of sodium silicate and lactic acid as a depressant indicated the possibility of reducing the acid insolubles to below 3% and the SiO2 to from 0.2% to 0.3%. Lactic acid was found to be an effective depressant of the complex gangue minerals in the ore.

Jan 1, 2000

By L Matthews, D O’Dea, P C Hayes, J Manuel, B Monaghan, T Honeyands, D Pinson, J Leedham

Many different approaches have been used in the past to characterise iron ore sinter mineralogy to predict sinter quality and elucidate the impacts of iron ore characteristics and process variables on the mechanisms of sintering. Characterisation techniques include optical image analysis and point counting, X-ray diffraction and scanning electron microscopy. Each technique has its advantages and disadvantages depending on the objectives of the measurement. It is generally acknowledged that silicoferrite of calcium and aluminium (SFCA) is very important to the quality of the sinter produced; however, strict definitions of the phases and textures of SFCA are not generally agreed. This paper summarises the state-of-the-art in sinter characterisation applied in Australia by both academics and industrial researchers. The results from various techniques are compared and the relationships between the measurement results are discussed.CITATION:Honeyands, T, Manuel, J, Matthews, L, O’Dea, D, Pinson, D, Leedham, J, Monaghan, B, Li, H, Chen, J, Hayes, P C, Donskoi, E and Pownceby, M I, 2017. Characterising the mineralogy of iron ore sinters – state-of-the-art in Australia, in Proceedings Iron Ore 2017, pp 49–60 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By John V. Beall

Hard as the Revett quartzite are conditions governing the deep mines of the Coeur d&apos;Al6ne. In fourscore years of mining, heat and pressure have been the rewards of preseverance. Such obstacles are the natural concommitant to search for ore at depth. But high cost and shortage of miners is a creeping frustration of the decade. These grim observations were made on a trip to the mines of the Coeur d&apos;Al6ne in the first week of May. But the bouncy optimism of competent mining engineers and geologists overrides by far the tough conditions. This is the story of what they are doing. I think they are setting the stage for the wonder mines of tomorrow. I didn&apos;t meet all the people or see all the mines, so there are unfortunate gaps in the story. Then too, sometimes the muck and water blotched my notes, or I couldn&apos;t write fast enough or I was too tired. No matter. There is much to tell and, because it is basically a human story, I am flouting the rules of technical journalism and couching it in the neglected "I" person. First then, a little history . . . .

Jan 7, 1966

By H. K. van Poollen, H. C. Bixel

A treatment is given of the transient pressure behavior of a well located at the center of a circular region surrounded by a radial discontinuity. On either side of the discontinuity, the values of permeability, viscosity, compressibility and porosity are uniform but may be different from those on the other side of the discontinuity. The results are obtained by solving a pair of finite difference equations. The numerical solution to these equations is obtained using a digital computer. The results are compared with previously published, approximated analytical solutions to the same problem. Solutions, presented graphically, show pressure decline for constant rate fluid production. The range of variables studied include dimensionless time from &apos;0.001 to 100 and storage capacity ratio from 0.001 to 1,000. The well behaves as if it were in an infinite reservoir for dimensionless times less than 0.25. Reservoir properties near the well can be estimated in the usual manner. An overlay technique is used to match an experimental curve with one of the theoretical curves. It is possible to estimate the distance to a discontinuity by substituting the actual time t and the corresponding dimensionless time tD at which a match occurs into the equation a = (0.000264 tk1/tD , µ1 cI)I/2 where kI/ I µI cI is the diffusivity near the well, and may be estimated from data taken at early time. Several buildup curves are computed. These curves show that for early shut-in times, correct values for transmissibility are obtained from conventional analysis. However, erroneous values of static reservoir Pressure are obtained unless data at large shut-in times are taken. INTRODUCTION A mathematical treatment of the transient pressure response of a well located at the center of a region bounded by a circular discontinuity is given. Within a region (Fig. 20) the properties of both the rock and the fluid are considered to be constant on either side of the discontinuity. While these properties are considered constant, they may be different on opposite sides of the discontinuity. A discontinuity of this type could be a fluid-fluid contact or a sudden change in rock characteristics such as thickness, porosity or permeability. Analytical solutions to this problem are available. 1-3 However, they are so involved that they are of little practical use. An approximate solutionl is available but the range of times over which it is valid has not been specified. A numerical solution to a pair of finite difference equations is used to obtain the solution given in this paper. PREVIOUS WORK One of the first solutions to the problem was published by William Hurst.1 Hurst considered unsteady-state flow of fluids through two sands in series with different mobilities in each sand. He used Laplace transforms to obtain a solution for a single well located at the center of the circle enclosing the first of the two sands. In this case, the solution for the pressure change in Region I (Fig. 20) is2

By D. H. Forbes, I. B. Cadoff, H. M. Manasevit

Single-crystal silicon films have been obtained on several natural crystal faces of BeO using the thermal decomposition of silane and the hydrogen reduction of silicon tetrachloride. From an analysis of X-ray diffraction data it was determined that the following film-substrate orientation relationships exist: (111) Si 11(0001) BeO, (111) Si 11(1011) BeO, (100) Si 11f1010) BeO. and (110) Si 11(1010) BeO. An analysis of the crystallographic relationships between the film and substrate indicates that a match occurs between the silicon atoms in the film and the berylliuni ion sites in the substrate. This correspondence is in agreement with previous work on the deposition of silicon on sapphire.1-3 silicon on spinel: and tungsten on sapphire. The high resistivity, thermal conductivity, and radiation resistance of beryllium oxide make it an important substrate material for the deposition of thin films of silicon or other semiconductors. The importance of semiconductor-insulator composites to the field of integrated microelectronics has been well-documented in the case of silicon on sapphire.&apos;-&apos; The successful growth of large-area single-crystal silicon on an insulator, sapphire, was first reported in 1963.1,2 Since that time studies have been made of the crystallographic relationships between the deposited film and the sapphire substrate. On the basis of the observed relationships, a model has been proposed relative to the crystallographic requirements for epitaxy between the semiconductor film and the metal oxide substrate.3 It is proposed in this model that epitaxy is the result of a match between atoms of the deposited film and the metal ion sites of the substrate plane. This match is not limited to a 1 to 1 correspondence between sites in the two lattices. Sub- sequent studies of the deposition of silicon on spinel4 and tungsten on sapphire5 have yielded data which support this model. On the basis of this previous work it was felt that silicon on BeO should also fit this model. In the present study, the choice of substrate orientation was limited to the natural faces of synthetic BeO crystals. Of the faces available, the (0001) plane seemed the most favorable for epitaxial growth. EXPERIMENTAL PROCEDURE Silicon films were deposited from silane and silicon tetrachloride in the apparatus shown in Fig. 1. The hydrogen ambient gas was purified by passage either through a DEOXO unit, molecular sieves, and a liquid nitrogen cold trap, or through a heated Pd-Ag thimble. The gas was then mixed with the silicon source materiai and passed over the substrate which lies on a spacer above an inductively heated silicon pedestal. The following deposition conditions were used: a hydrogen flow rate of 3 liters per min with silane and silicon tetrachloride concentrations of 0.2 mole pct and a pedestal temperature of 1175" * 5°C as observed with an optical pyrometer assuming an emissivity of 1.0. Deposition was preceded by a 15- to 30-min hydrogen-etch period conducted at a temperature of 1275°C (obs). Adherent silicon films from 2 to 10 u were grown on the various BeO faces. The substrates were synthetically grown beryllium oxide single crystals ranging from 5 to 10 mm in

Jan 1, 1967

By S. Fugleberg

As a result of research work done during the planning of the Kokkola zinc plant it was found that a very efficient cementation of impurities from the suspension obtained after leaching copper and cadmium cakes was achieved by adding zinc dust to the batch without filtration after the leaching. All elements nobler than cadmium are precipitated with the exception of lead, which must be removed in a separate step. Using pure zinc dust, free from noble metals, the cadmium sponge produced will only contain elements that can be re- moved from cadmium by meltrefining. The process is thus : 1. Leaching and purification 2. Removal of lead (with BaCO3) 3. Precipitation of cadmium sponge with pure zinc dust 4. Meltrefining of briquetted sponge with NaOH for removal of Zn (and others) The paper deals with the removal of the most critical elements, i.e. Co, Ni, As, Sb, Cu, Pb, T1 in the liquid phase and Zn and T1 in the melt. A survey is also given of the behaviour of most of the other elements normally found in Cd raw material, such as Ge, Te, Se, Sn, In, Ga. It is shown that in most cases the benefit of an electrolysis in Cd production is very limited. In Kokkola 99.998% Cd is achieved by this method, but in favourable cases it may be possible to come quite close to five nines.

Jan 1, 1973

By Francis Foley

INTRODUCTION DURING the summer of 1919, the late Dr. Henry M. Howe, then Chairman of the Division of Engineering of the National Research Council, organized a committee to obtain a better insight into the behavior of carbon steels under the influence of various treatments by a proper control of the time and temperature factors. During part of 1919 and 1920, work in connection with this investigation was carried on at Dr: Howe&apos;s laboratory at Bedford Hills, N. Y. During 1921 there was an enforced hiatus in the work, occasioned by the illness which resulted in Dr. Howe&apos;s death in 1922. At that time one of the present authors compiled the results of the work which had been done and this was published in 1923.1 Following the publication of this work, it seemed desirable to carry on in the same manner an investigation of steel of C 0.75 per cent., which steel had not been as fully treated as had the other steels of C 0.34 and 0.52 per cent., used in the published work. Furthermore, certain unusual results have been obtained in the treatment of C 0.52 per cent. steel by quenching and drawing, and repetition of this part of the work seemed advisable. This has been done during the past year at the School of Mines and Metallurgy of the University of Missouri at Rolla, Mo., by a cooperative undertaking of the School and the Bureau of Mines, working in conjunction with the Committee on Heat Treatment of Carbon Steels of the National Research Council. The present paper is a report of the results obtained in this work.

Jan 2, 1926

By E. H. Rennhack, J. F. Libsch

Definite transition behavior was found in unalloyed titanium at 0.13 pct 0 equivalent. The addition of 0.5 Sn, 1.0 Al, 0.5 Al, and 1.0 Sn lowers the tvansition temperature of titanium at oxygen equivalents exceeding 0.22, 0.29, 0.40, and 0.51, respectively. Metallographic evidence indicates that progressive amounts of oxygen restrict deformation at low temperatures resulting eventually in brittle fracture. The presence of tin or aluminum is thought to alter the atomic distribution of oxygen within the titanium lattice in such a manner as to facilitate some degree of slip and twinning. 1 ITANIUM-like iron and zinc experiences a transition from ductile to brittle fracture with decreasing temperature. The presence of sufficient quantities of the interstitial elements, carbon, oxygen, and nitrogen in solid solution, has been shown to progressively lower the room-temperature impact resistance of titanium with increasing interstitial content.1"1 Ogden,et al,2 reported finding no transition from ductile to brittle fracture with decreasing temperature in iodide titanium. However, a definite transition was found to occur at 0.36 pct 0 equivalent in an alloy containing 0.47 pct carbon in solid solution. The oxygen equivalent in this case was obtained by assuming the effects of carbon, oxygen, and nitrogen in combination on the impact properties of titanium to be additive on the same basis as their separate effects on tensile strength, namely: Oe = 2/3 (pct C) + pet 0 + 2 (pet N) They concluded that the tendency toward transition behavior is dependent on the total interstitial content in solid solution and not on any one particular interstitial element. Rennhack,4 however, recently found transition behavior in iodide titanium at an oxygen equivalent of 0.17 pct. Ogden, etal3, reported that the strengthening effects of carbon, oxygen, and nitrogen in titanium decrease with the addition of tin. They showed that tin additions increase the tolerance of titanium for the interstitials, that is, 10 pct Sn permitted individual additions of up to 0.4 wt pct of the interstitial elements without any significant loss in ductility. Aluminum tends to decrease ductility and impact strength of titanium for a given interstitial ~ontent.3 Van Thyne and Kessler5 found that the solid solubility of carbon in titanium doubled in the presence of 10 pct Al. The precise effects of tin and aluminum in the nrespncp of rorvfen nn the impact properties of titanium had previously not been determined. The high oxygen tolerance of titanium containing tin may provide a suitable means for improving the impact properties of titanium containing the interstitial elements, particularly oxygen. Unlike tin, however, aluminum has a high affinity for oxygen and will reduce rutile titanium dioxide (TiO2)by a thermit-type reaction.6 Thus, the atomic distribution of oxygen in titanium might be different in the presence of aluminum. The present work was undertaken to: 1) Determine the effect of oxygen on the transition behavior of unalloyed iodide titanium. 2) Determine the effect of small amounts of tin and aluminum on the transition behavior of iodide titanium in the presence of oxygen and other interstitial~. EXPERIMENTAL Three different lots of iodide titanium were employed to prepare the alloys studied in the present work. Their chemical composition is presented in Table I. The compositions of the tin and aluminum used for alloying are shown in Table 11. Oxygen additions were made using calcined rutile titanium dioxide (TiO2)of 99.7 pct purity. Alloy Preparation—Four titanium-base alloys containing separate additions of 0.5 and 1.0 pct each

Jan 1, 1960

The Annual General Meeting of the Branch was held in the Witbank Golf Club on Thursday, 28th August, 1969 at 5.00 p.m. Mr C. G. Sowry (Chairman) was in the Chair. There were also present: Ten Members: Messrs J. Meintjes (Vice-Chairman), J. E. van Aswegen, A. C. Hofmeyr, I. Botha, B. F. v. d. Merwe, C. H. Coxon, R. Canny, R. C. J. Goode, A. Bain, G. E. Carlyon. Six Associate Members: Messrs B. T. Hosking, R. E. Powell, W. Weber, T. Bulloch, E. J. Jackson, P. J. Muller. Fourteen Visitors. Total Present: 31. The Chairman declared the meeting open and extended a welcome to all visitors including Mr R. C. J. Goode, President of the Institute. MINUTES OF PREVIOUS GENERAL MEETING The Minutes of the General Meeting held on the 26th June, 1969, were read and adopted. CHAIRMAN&apos;S REPORT The Chairman presented a report outlining the activities of the Branch during the past year. Membership of the local Branch had increased from 80 to 99 during the year. DECLARATIONOF OFFICEBEARERS The Chairman announced that owing to his transfer out of the Witbank area, he was unable to accept the nomination as Chairman for a further year of office. The outgoing committee had elected Mr J. Meintjes Chairman and Mr A. Bain Vice-Chairman for the ensuing year. Mr J. Meintjes then took the chair. Mr J. Meintjes thanked Mr C. G. Sowry for his successful steering of the Branch during its period of inauguration. ELECTION OF COMMITTEE MEMBERS The Chairman then read the Scrutineers&apos; Report and declared the following eight members elected as Committee Members for the 1969-1970 year: Messrs I. Botha, A. W. Brereton, G. E. Carlyon, B. T. Hosking, E. J. Jackson, B. D. McNeice, P. J. Muller, B. F. van der Merwe. TALK The Chairman then called upon Mr A. Bain to present his talk and film show on &apos;Impressions of the mining and metallurgy congress tour to Australasia&apos;. CLOSURE After thanking the speaker for an interesting talk, the Chairman declared the Meeting closed at 8.40 p.m.