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By Preston C. Holloway

Transformational roasting involves the heating of a material along with specific additives to induce mineralogical changes in the starting material. By controlling the chemical composition, roasting atmosphere, temperature and time of reaction, the mineral transformations induced during roasting can be engineered to control the distribution of valuable, or harmful, metals and to produce new mineral assemblages that are more amenable to conventional methods of metals recovery or to environmentally safe disposal. To date, this type of process has only been applied to the recovery of a limited number of metals, but current research is looking to expand the application of these techniques to the recovery of metals from a wider range of materials. An introduction to these techniques is presented along with preliminary results from their application to metals recovery from zinc bearing wastes, such as zinc ferrite leach residues and carbon steel electric arc furnace dust.

Jan 1, 2006

By H. Y. Sohn, R. D. Hagni, M. K. Kojo

Reflected light microscopy was used to study the mineralogy and textures of experimental reactions of a nickel concentrate with a slag. Such an interaction is an important step in the bath smelting of nickel sulphide concentrate. Concentrate particles in the central portions of the pellets are rounded and develop vermicular S02 gas porosity. In the outer portions of the pellets, the original minerals of the concentrate, i.e., pyrrhotite, pentlandite, pyrite, chalcopyrite and violarite, have agglomerated and reacted to form two intergrown phases: pyrrhotite solid solution (FeO.75Ni0.18Cu0.01S) and pentlandite solid solution (Fe0.58Ni0.51Cu 0.03S). Magnetite formed euhedral crystals, skeletal crystals and dendrites at the margins of the matte. Prismatic, ferrohypersthene and octahedral Mg-Al-Fe spinet crystals and dendrites are present in the glassy slag. Key words: Nickel sulfide concentrate, Iron silicate slag, Bath smelting, Mineralogy, Microscopy

Jan 1, 2003

By E. Iasillo, R. R. Carneiro

Independent of the method chosen to forecast production, an accurate method to project metal extraction is needed in order to accommodate leach cycles that exceed leach data on hand and thus be able to accurately forecast production. Metal extraction data must be developed for each ore type identified in the deposit in order to apply the correct rate of leaching when a specific ore is being treated. Curve fitting is used to model the rate of disengagement of metal into the pregnant solution. This paper provides a description of a curve fitting algorithm developed by Mr. John T. Bartlett, inventor of the METSIM™ process simulation program. A methodology is provided by which the metallurgical data developed is evaluated to determine if accurate projections may be made from the data. A criteria has been developed to help determine when a column experiment may be terminated.

Jan 1, 2001

Research on Universal Depressant of Talc and Serpentine

Sep 13, 2010

By Joseph P. Gildner, Michael S. Kucker, Robert A. Robinson

Considerable controversy seems to exist over the extent and nature of information that should be provided in design-build type contracts. Much of this controversy may relate to the types of owners, ranging from private industry to state and federal agencies that are implementing design-build. Philosophies for the development of geotechnical information ranges from no information to a thorough investigation approaching that needed for final design. Several recent projects, such as the Channel Tunnel in Europe, Whittier Tunnel in Alaska, Tren Urbano in Puerto Rico, and Sound Transit in Seattle have taken varying approaches to providing and interpreting geotechnical information for bidders. The pros and cons of these various methods are discussed and assessed.

Jan 1, 2001

By Henry N. McCarl

Mineral aggregates are those natural and manufactured industrial mineral and rock materials that provide bulk and strength in port- land cement concrete, bituminous concrete mixes, and plaster or stucco surfaces. They may also provide special characteristics such as thermal and acoustical insulation, weight, surface textures, abrasion resistance, and impermeability to various concrete products and mixes. Most aggregates are relatively inexpensive materials, but despite their low unit value, the tonnages consumed each year in the United States and throughout the world make mineral aggregates by far the leading industrial mineral and rock materials both in terms of volume (tonnage) produced and value consumed. The major use of mineral aggregates is in concrete. The low cost, high bulk aggregates tend to keep concrete construction costs at levels competitive with other building materials. Other major uses of aggregates include highway and railroad base or ballast materials, graded fill, and various industrial uses such as metallurgical and chemical fluxes and raw materials-these latter uses are often considered nonaggregate uses of mineral aggre- gate materials. The value of mineral aggregate materials at the production plant varies from less than a dollar per ton to several dollars per ton for most crushed stone and sand and gravel, $2 to $15 per ton for slag and expanded clay or shale aggregate, to as much as $60 to $100 per ton for expanded perlite or vermicu- lite. The more specialized the use, the higher the price-although there are naturally some exceptions to this rule of thumb. The first four parts of "Construction Materials" deal with the utilization of four major mineral aggregate types: Crushed Stone, Light- weight Aggregates, Sand and Gravel, and Slag. While the focus will be on the use of these industrial minerals and rocks there will also be some coverage of sources, mining and production, especially in those cases where they are

Jan 1, 1975

By R. A. Brown

RIGHT NOW the Canadian oil business is suffering from growing pains brought on by developments outside our borders. I would like, therefore, to place our industry in perspective for you in two ways. I would like first to describe it briefly and let you see it in relation to the world oil industry. Then I would like to bring it back and place it into perspective against a strictly Canadian background. Naturally, in such a discussion, it is necessary to use a certain amount of statistical material. I'll endeavour, however, to keep it to a minimum. Eleven years ago, before the discovery of Leduc, Alberta could boast of having 21,000,000 barrels of crude oil reserves. Five years ago we had 1,810,000,000 barrels. At year end, 1957, our remaining recoverable reserves totalled more than 3,000,000,000 barrels. In 1957, our potential production in Alberta reached an all-time high of 756,000 barrels a day. Unfortunately, our actual average daily production dropped from 393,000 barrels per day in 1956 to 376,000 barrels per day in 1957. And in 1958, to date, it has dropped sharply to around 300,000 barrels per day.

Jan 1, 1958

By Fang Wu

The paper designs an extraction flow for the total recovery of nickel and cobalt and removing magnesium simultaneously from the cadthodic materials of the spent hydrogen-nickel and cadmium-nickel batteries. The separation of Co, Ni and Mg though P507 extraction .The extraction equilibrium pH is 4.5~5.0, ßNi/Co is 140~180, and ß Ni/Mg is 20~25; nickel and magnesium are scrubbed in two steps, in which the equilibrium pH of nickel and magnesium scrubbing is controlled at 5.0±0.1 and 4.4±0.1 respectively. The stepwise scrubbing technique is adopted to remove 94.5% of magnesium and to recover 99.45% of nickel and 95.35% of cobalt. During the integrated extraction and precipitation process the total recovery fraction of nickel and cobalt are 99.99% and 99.95%, and the recovery fraction of magnesium is 94.02%.The recovered NiSO4 and CoSO4 solution are enriched and crystallized.

Jan 1, 2009

A new personal respirable dust monitor developed by Rupprecht & Patashnick Co., Inc. in a multi-year project funded by the National Institute for Occupational Safety and Health (NIOSH) generated promising results in underground coal mine testing performed by NIOSH and industry representatives during the summer of 2003. The mine data showed that the personal dust monitor (PDM) performed similarly to co-located manual reference samplers for full-shift samples at all four underground coal mines at which the evaluation took place. The technology that forms the heart of the PDM, called the tapered element oscillating microbalance (TEOM system), is unique in its ability to collect suspended particles on a filter while simultaneously determining the accumulated mass with National Institute of Standards and Technology traceability. Because the monitor measures the true particle mass collected on its filter, its results do not exhibit the same sensitivity to water spray as do optically based measurement approaches. The technique achieves microgram-level mass resolution even in the hostile mine environment, and reports dust loading data on a continuous basis. Using the device, miners and mine operators have the ability to view both the cumulative and projected end-of-shift mass concentration values, as well as a short-term 15- or 30-minute running average. During underground mine trials in the summer of 2003, technical personnel used the readings from the PDM to identify and correct several abnormal dust generating scenarios. These events demonstrated the potential of the PDM to be used as an engineering tool to evaluate the effectiveness of various dust control strategies. In a separate evaluation performed by CONSOL Energy, Inc., the mine operator evaluated the benefit of a proposed new water spray-based dust control system. Engineers measured the dust concentration upstream and downstream of a production location under different dust control scenarios using two PDM units. By evaluating the change in the dust loading between the upstream and downstream monitoring sites, the company was able to determine in a few hours which hardware configuration would yield the greatest benefit to the workplace environment. BACKGROUND Measuring underground coal mine dust concentrations is an essential part of protecting miners' health. The U.S. Secretary of Labor and the Federal Advisory Committee on the Elimination of Pneumoconiosis among Coal Mine Workers has recommended that better monitoring of coal miner dust exposures be used as a method to improve miner health. In consultation with labor, industry, and government, NIOSH issued a contract to Rupprecht & Patashnick Co., Inc. (R&P), Albany, N.Y., to develop a one-piece PDM. The object was to miniaturize TEOM technology into a form suitable for a person-wearable monitor that would enable accurate end-of-shift dust exposure information to be available to miners. Furthermore, any person-wearable dust monitor should minimize the burden to the wearer by incorporating the monitor into the mine worker's cap lamp battery, with exposure data continually displayed during the shift to enable workers and management to react to changes in dust exposure. In the summer of 2003, NIOSH conducted extensive testing of the PDM to determine its laboratory and in mine performance. In addition, anecdotal information collected in the mines showed several occasions where miners were able to identify situations that produced high levels of respirable coal mine dust The PDM's response to unplanned changes resulted in action being taken to keep dust exposures as low as possible. In another case that demonstrated the PDM's versatility, a mine was seeking to find a better dust control solution on its longwall headgate stageloader. In this instance, the PDM was used as a diagnostic tool by the miners to quickly evaluate the control technology. [ ] HOW DOES THE PDM WORK? The PDM is configured to provide accurate respirable dust personal exposure information in a form that is as convenient to wear as a normal cap lamp (See Figure 1). Respirable dust exposure data displayed by the device has two main objectives: providing the miner and mine operator with timely values to avoid overexposure to dust, allowing them to make any necessary changes during the course of a work shift; and computing an accurate end-of-shift statistic for a miner's average respirable dust exposure. The mass sensor embedded in the PDM, holds the key to the accurate, time-resolved dust concentration measurements. The inertial, gravimetric-equivalent, mass measurement technique used in the device typically provides a limit of detection on par with that of the most sensitive laboratory-based microbalances.

By D. Nutakor

Rock joint stiffness is not only a poorly known parameter, but also has no established laboratory measurement procedure. This paper presents methods used to determine the normal and shear stiffnesses of healed joints filled with vapor-altered minerals obtained from the Yucca Mountain site in Nevada. Results show that these joints behave linearly up to 85% of their loading history and are stiff with strengths very close to the strength of the intact rock. Factors that might have contributed to the linear behavior of these joints are discussed and areas requiring further investigation are provided. Joint normal stiffness ranges from 7.16 to 64.77 GPa/mm with an average value of 26.93 GPa/mm, while joint shear stiffness averages 11.41 GPa/mm and ranges from 3.09 to 28.41 GPa/mm. Young?s modulus of the vapor-altered joint infilling was calculated from the stiffness of the healed joint. Young?s modulus of the vapor-altered joint filling material averages 7.89 GPa and ranges from 2.15 to 19.43 GPa. Given the pervasive presence of such altered rock, usually in the form of sub-spheroidal 3-D pockets, this property should be of value in any numerical modeling attempting to describe the mechanical behavior of these tuff formations at the level of detail where inclusions might be a factor.

Jan 1, 2008

By E. R. Darby

When bronze is melted in open-flame furnaces a considerable amount of slag is formed during the melting operation. This slag may be incidental to the melting practice or it may be formed intentionally by slag-forming constituents added to the furnace charge to provide a covering for the melted metal When this slag is removed from the furnace, it contains, in addition to the free metal carried with it by the skimming operation, a considerable amount of metal as oxide either combined or mechanically mixed with it. By the usual crushing and washing methods this metallic oxide generally goes to the tailings pile, so diluted by other foundry waste that its recovery is economically impossible. If this furnace slag is not inixed with other foundry waste, practically all of the metal oxide as well as the free metal may be recovered by some form of smelting operation. The first side of the problem to be considered is the amount of slag produced. It may not be true that the majority of foundries have no record of the amount of slag made, but it is certainly true that a very great many either have no record or pay little attention to it. Usually the collection of furnace slag for one normal week's run will be sufficient to determine the advisability of its being handled in a different manner from the crushing and concentrating generally employed. If a large representative sample of the accumulation is crushed and concentrated and the recovery compared with the results of a careful assay, it will be found that a large percentage of the total metal content was lost in the washing process. The percentage of loss will be greater than the metallic oxide content, as some free metal in extremely fine particles always is carried away in grains of slag. From such a comparison, it may be determined whether or not the slag should be melted, sold or treated as before. An example of an actual test of this kind is given below. In a foundry melting 50,000 to 80,000 Ib. of bronze per day, a week's accumulation of furnace slag and ladle skimmings amounted to 16,500 1b.—over three times as much as the foundry superintendent estimated before the accumulation was made. Two tons of this material was taken as representative of the lot. This was ground through a thoroughly cleaned ball-mill and concentrated over a Wilfley table. The

By Danny Riley, Brian Curry, Sandya Govindaraju, James Bain

Acute vibration causes vasoconstriction in naïve human subjects1. Vibration-induced decrease in skin perfusion has also been reported in the rat-tail vibration model 2. After vibration exposure, rat-tail arteries demonstrate vacuoles in smooth muscle cells, similar to that caused by pharmacological vasoconstrictors3. This study addressed the effects of different frequencies, durations and patterns of vibration on lumen size and vacuole formation using the rat-tail vibration model in male Sprague-Dawley rats (~300 g). Methods The different groups were: 4-hr continuous vibration at 30, 60, 120 and 800 Hz; continuous exposure durations of 5 min, 1 hr and 4 hr at 60 Hz; and 4-hr cumulative exposure of 60 Hz delivered intermittently in cycles of 10 min on and 5 min off. Acceleration was set at 49 m/s2 r.m.s. for all frequencies. Unanesthetized rats were restrained in cages on a nonvibrating platform with their tails placed on a vibrating stage driven by a B&K motor (4809). The sham control animals were also placed in the vibration apparatus but not vibrated. Room temperature was controlled at 25 ± 1°C. Ventral arteries from proximal tail segments 7 were immersion fixed in aldehydes, embedded in epon-araldite and sectioned (0.5 µm) for morphological analysis. Vascular lumen sizes were measured as the percent ratio of the lumen perimeter to internal elastic membrane length using Image J software (NIH). The number of vacuoles in the smooth muscle layer of each artery section was counted. Results Fig 1: Semithin sections of arteries. A. Sham control. B. 4-hr vibration 60 Hz. In vibrated arteries, the lumen decreases in size, and smooth muscle cells (SMC) exhibit vacuoles (arrow). Bar equals 40 µm for each panel. [ ]

Jan 6, 2006

By Richard J. Hartman

This presentation identifies some of the more common problems associated with cofferdam construction. After the various problems are identified, they are briefly explained and possible solutions and preventive measures are noted. Photographic slides used during the seminar illustrate the conditions. This discussion is limited to cofferdams which are braced structures excavated inside to allow access for construction. The common procedure is to drive sheet piling and then alternatively install bracing and excavate. They can be located either on land or in water. Loads are applied by soil, water, surcharge pres-sure, eccentricities, and impact loads. The loads are resisted by the sheet piling, the bracing, and the soil below the bottom of the excavation; each of these three components must be capable of resisting the applied loads.

Jan 1, 1987

By Robert Hopler

In the annual report under the Explosives Act for 1905, H.M.inspectors state that over 90 percent of the accidents causing death or personal injury occurred in the use of explosives and under miscellaneous conditions to which the controlling provisions of the Act do not apply, and that such accidents caused 43 out of the 50 deaths, and 312 out of 348 cases of injury. The number of accidents grouped under the heading of “Use and Miscellaneous” is less than that for 1904 - viz., 281 against 301. By these accidents 43 persons were killed and 312 injured, as compared with 39 killed and 343 injured in 1904

Jan 1, 2007

By R. C. Bratton, R. Q. Honaker

Hindered-bed separators are recognized as low-cost, high-capacity devices for both classification and density separation; however, since their inception, there have been few significant advances in the fundamental technology. Recently, Eriez has shown through modeling and pilot-scale testing that the innovative approach to feed presentation offered in the CrossFlow teeter-bed separator provides improved metallurgy when compared to traditional hindered-bed classifiers or single-stage coal spirals. This design feature prevents excess water from entering the separation chamber and disrupting the overall fluidization flow rate within the teeter zone. Most recently, a side-by-side industrial scale evaluation has verified that this technology improves overall efficiency and simultaneously reduces the separation cut-point. With regards to coal processing, data from full-scale units indicate that the CrossFlow offers good separation efficiency, high unit capacity, and metallurgical results consistent with laboratory- and pilot-scale separators.

Jan 1, 2006

By S. Chander, S. W. Musselman

The molecular structure of hydrophobic and hydrophilic groups in nonionic surfactants has been related to the wetting and dispersion of selected pigments. The nonionic surfactants included in this study are acetylenic diol based surfactants and ethoxylated alkyl phenols. The Langmuir model could be used to fit adsorption data. Further analysis of the data showed that the free energy of adsorption was a function of adsorption density of the surfactants at the interface. The change in free energy with adsorption density could be interpreted by considering a change in the orientation of the adsorbed molecules. Acetylenic diol based surfatants were found to have an area per molecule of 2-3 times that of similarly ethoxylated alkyl phenols. The wetting and dispersion properties of lamp black, a model hydrophobic surface, by these surfactants were investigated by contact angle measurements and particle size analysis. Acetylenic diol based surfactants with ethylene oxide contents between3.5 and 10 moles per molecule and alkyl phenol based surfactants with approximately 9 moles of ethylene oxide per molecule were found to provide superior wetting abilities. Longer ethylene oxide chains were required for superior dispersion capabilities within each family of surfactants. Complete wetting and dispersion was found to occur above the critical micelle concentration of the surfactants.

Jan 1, 2000

By Tsuchiya N, Takada Y, Okabe K

Alkalis in the blast furnace are removed mainly by the slag, Alkali removal by the slag was studied as a rate process of alkali vapor- ization from the slag flowing through the dropping zone in the blast furnace. The vapor-, ization rate of I:20 from CaO-Si02-A1203 IZ20 slag was- measured under various experimental conditions. An empirical formula for the vaporization rate was obtained as a function of slag basicity, temperature and surface area per unit mass of slag. A simulation model of IC20 vaporization in the dropping zone was evaluated using the rate equation when the true velocity and surface area of the slag was de- termined from a flow dynamic model of counter- current gas-liquid flow through packed beds. The influence of the dynamic conditions of flow, as well as the slag basicity and temperature, on alkali removal by the slag was estimated.

Jan 1, 1980

By Alberto Pacheco Pacheco

En el presente texto se analiza el fundamento de lógica fuzzy aplicada al control de molienda de minerales, la que nos permite simular el comportamiento humano en la operación molienda, con la que se plantea el algoritmo de control inteligente de molienda.

Sep 12, 2005

By A. R. Leach

Anomalous mining conditions can be described where the level of hazard is increased relative to normal conditions within a mining area. Normal conditions would be those defined as a Ground Control District in a mine’s code of practice, and for which mine standard support layouts are generally developed. It has been found that up to 80% of fall of ground accidents occur where anomalous mining conditions exists, typically in the vicinity of geological weaknesses. These areas require specific attention to ensure they are readily anticipated and identified and that appropriate strategies are used to reduce the hazards associated with them. As part of SIMRAC project GAP 607 checklists to aid identification and best practice mining methods were identified for a range of geotechnically anomalous conditions.

Jan 1, 2003

By Mark D. Hannington

Seafloor polymetallic sulfides have been found in diverse volcanic and tectonic settings on the ocean floor at water depths ranging from 3700 meters to <1500 meters. More than 100 occurrences of hydrothermal mineralization have been documented (including Fe-oxide deposits, Mn-crusts, metalliferous sediments, and massive sulfides), but high-temperature hydrothermal activity and large accumulations of polymetallic sulfides are known at fewer than 20 different sites. Chemical analyses of samples from these deposits indicate that they contain important concentrations of Cu, Zn, Ag, and Au, comparable to those of massive sulfide deposits on land. However, the lack of sufficient data concerning the distribution, size, and bulk composition of seafloor deposits precludes a meaningful assessment of their resource potential.

Jan 1, 1994