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By Osvaldo Benedito Dib Melo

O trabalho tem por objetivo de mostrar uma otimização da performance de sistema de lavagem de gases (conjunto espessador e filtro a vácuo) do Alto Forno de uma siderúrgica localizada no Nordeste, a CSP, Cia Siderúrgica do Pecem. A unidade entrou em operação no ano de 2016, inicialmente com orientações/informações de projeto, tendo muito desvios no controle da turbidez e sólidos suspensos da água da saída do espessador, em função da tecnologia aplicada, que não estava funcionando adequadamente para a realidade da região e ocasionava custo elevado, além de muitos problemas operacionais. A metodologia aplicada baseou-se em teste na planta com produtos químicos, ensaio de laboratório com teste de jarro e análises físico-químicas da água de recirculação. Os resultados obtidos foram excelentes na redução da turbidez e sólidos suspensos, aumento da retirada de lama pelo filtro rotativo, maior tempo de uso da manta dos filtros a vácuo e uma redução de custo com produto químicos e mão de obra, totalizando uma economia significativa em reais/ano.

Oct 30, 2017

By Fernanda Moreno Rodrigues

A adição de elementos microligantes para o controle do crescimento do grão austenítico vem sendo largamente utilizada nas últimas décadas. O Nióbio é tido como o elemento mais importante deste grupo, pois produz precipitados finos na matriz que ancoram os contornos de grão, retardando o seu crescimento. O presente trabalho avalia o efeito do Nióbio no tamanho do grão austenítico do aço VEX, um aço ferramenta para trabalho a quente utilizado para extrusão de alumínio. O estudo baseou-se na comparação entre duas composições químicas, uma sem Nióbio e outra com microadição de 0,02%. Ambas foram caracterizadas microestruturalmente e quanto à tenacidade. O tamanho de grão foi avaliado após austenitização entre 980°C e 1.200°C. Os resultados mostram que a adição de Nióbio é efetiva no refino de grão em elevadas temperaturas, o que é relevante para a aplicação industrial do aço em questão.

Aug 7, 2018

By Mariane Abreu Alves Campos

A utilização do wBN como ferramenta de usinagem pode eliminar a necessidade de retífica das peças. Portanto, neste trabalho, os experimentos realizados tiveram por objetivo o estudo e caracterização de compósitos à base de wBN, diboreto de titânio (TiB2) e alumínio (Al) para obtenção de pastilhas para usinagem. A composição utilizada para a investigação utilizou 70% de wBN. Os compósitos foram obtidos sob altas pressões e altas temperaturas via aplicação cíclica . As patilhas atingiram aproximadamente 4,5 mm de diâmetro, e altura de 4,0 mm. As amostras foram caracterizadas por ensaio de dureza Vickers, microscopia eletrônica de varredura, microscopia confocal e densidade. De forma geral, os melhores resultados foram para amostras com ciclos de um minuto cada, para os três ciclos, sendo pouco dependente do valor da pressão aplicada. Foi observada dureza maior que 17GPa, baixa porosidade e um valor de densidade aparente muito próxima à teórica.

Aug 16, 2017

By John B. Umhau

In 1930 , 65,448 long tons of virgin or primary tin were consumed by 1,292 establishments in the United States , representing about 91 per cent of the total consumption as computed from imports , exports , and stocks at the beginning and the end of the year . The reported consumption was equivalent to 38 per cent of the world's tin production in 1930 , estimated at 171,000 tons , and was 12 per cent less than the 74,369 tons consumed by 1,307 establishments in 1928 . Decreased consumption of new tin in 1930 ás compared to 1928 was a reflection of the general industrial depression . All of the tin- consuming industries showed substantial decreases except tin plate and terneplate , white metal , and tinning , which showed small tonnage increases aggregating only 1,200 tons . The largest tonnage decrease was in the use of new tin in babbitt which declined 33 per cent in 1930 as compared to 1928. This was largely attributable to the decreased production of automobiles and trucks , which was 24 per cent lower in 1930 than in 1928. Percentage decreases in other important tin- consuming industries were as follows : Solder 18 per cent , bronze 19 per cent , tin foil 40 per cent , chemicals 23 per cent , tin oxide 44 per cent , and type metal 46 per cent . The distribution of the amount consumed by various uses during 1927 , 1928 , and 1930 is shown in table 1 . Consumption studies indicate the fact that variation in tin consumption from year to year parallels the fluctuations in demand for the already wellestablished tin products . For example , the manufacture of motor cars and trucks3 required only 11,000 tons of tin in 1930 compared to 19,000 tons in 1928 ; the canning industry continues to require the greater portion of the tin plate and much of the solder . Recently developed industries , while affecting total consumption of bearing metals , solders , etc. , to some extent , have made little change in the relative importance of these commodities as consumers of tin .

Jan 1, 1932

By Peter R. Morris, Alan J. Heckler

THREE angles are required to specify the orientation of a crystallite with respect to a physical reference frame. The distribution of crystallite orientations in a polycrystal is thus a function of three angular variables. The most widely used experimental techniques for studying orientation in polycrystals lead directly to the pole figure representation, i.e., the distribution of the poles of certain crystallographic planes in terms of two angular variables. In recent years1-5 methods have been developed which permit determination of the (three-angle) crystallite orientation distribution from several (two-angle) pole figure distributions. In this work Roe's method has been applied to the study of orientation in hcp materials. The method is illustrated for commercial purity titanium sheet (Ti-70) which was cold rolled (65 pct reduction), annealed at 1450°F for 3 min, and air cooled. The grain shape was observed to be equiaxed after this treatment. EFFECTS OF PHYSICAL, CRYSTALLOGRAPHIC SYMMETRY In Roe's method the crystallite orientation distribution, w(?,?,F), is expanded in a series of generalized spherical harmonics 11(?,?,F) = E E E W^Zirmtye-tote-in* [l] 1=o ,,,=-I ,,=-I where { = cos 8. The set of Euler angles employed here is illustrated in Fig. 1. The axis for each rotation is denoted by a double arrowhead. The positive sense of each rotation is that of a right-handed screw advancing in the direction of the double arrowhead. The X, Y, and Z directions correspond to the rolling direction, cross direction, and normal direction, respectively. In the initial orientation (10.O), (12.O), and (00 . 1) planes are perpendicular to the X, Y, and Z directions, respectively. The IC/ rotation about the Z axis is carried out first by rotating X into X', Y into Y', and leaving 2 unchanged, i.e., Z' = Z. The 8 rotation about the Y' axis is carried out second by rotating X' into X", 2' into Z", and leaving Y' unchanged, i.e., Y" = Y'. The I$ rotation about the Z" axis is carried out last by rotating X" into X"', Y into Y"', and leaving 2" unchanged, i.e., 2"' = 2". Any specified orientation of the X'", Y'", and Z'" crystal-fixed axis system relative to the X. Y, and Z physical axes (rolling direction, transverse direction, and sheet normal direction, respectively) can be obtained by appropriate IC/, 8, and (F rotations. The Zl,, of Eq. [l] are the Jacobi polynomials, augmented by the square root of the weight function. The Zl,, are symmetric in m,n, i.e., Zl,,= Zlnm. For orthotropic physical symmetry and hexagonal crystallographic symmetry, the coefficients, W!,,, of the series are all real, W!mn = Wzfi, = Wlm~ = Wlfi~, 1 and m are even and n is restricted to 6k, where k = ...,-2,-1, 0, 1, 2, .-.. The determination of the Wlmn from pole figure data has been previously described.'~~ The Zl,, may be written in multiple angle form

Jan 1, 1970

By Anna Carolina Cerqueira Neves

Muito se tem estudado sobre materiais alternativos, como os compósitos de matriz polimérica reforçados por fibras lignocelulósicas. Isso se justifica pelo fato das fibras naturais terem vantagens no que tange ao meio ambiente, bem como relativo baixo custo. Além disso, a fibra natural apresenta características de interface com a matriz polimérica que favorecem as propriedades mecânicas pela estrutura do compósito. Esse presente trabalho objetiva analisar as propriedades de tração de compósitos de matriz de poliéster reforçados com 10,20 e 30% em fração volumétrica de fibras de cânhamo, que foram preparados alinhando as fibras em moldes e deixando-os curar por 24 horas em temperatura ambiente. Os corpos de prova foram testados numa máquina de ensaios Instron e os resultados mostraram um aumento na tensão máxima de ruptura com o aumento da porcentagem de fibra incorporada.

Aug 17, 2017

By Sérgio Luis de Moura Paiva Júnior

A reciclagem de materiais provenientes de combustíveis fósseis é essencial para a redução do impacto desses materiais no meio ambiente. Utilizar materiais reciclados exige, não somente a reutilização direta do produto, mas a criação de processamento e técnica desses materiais no intuito de produzir materiais melhorados após o tempo de uso, justificando o desenvolvimento de tecnologias nesse âmbito. Esse trabalho de conclusão de curso foi executado no intuito de auxiliar nas técnicas utilizadas por uma empresa de reciclagem de polietileno para a produção de pellets reciclados. Foram avaliadas as propriedades mecânicas e espectroscópicas de cada uma das fases e os processos realizados para a produção do material final: uma blenda polimérica constituída de diferentes tipos de polietileno reciclado. As técnicas de caracterização utilizadas foram Ensaios de Tração para a avaliação da tensão máxima e módulo de elasticidade dos materiais, Microscopia Eletrônica de Varredura (MEV) para avaliar dimensionalmente a região de fratura dos polímeros, Infravermelho com Transformada de Fourier (FTIR) para identificar os grupos funcionais presentes nos polímeros analisados, TG/DTG para o estudo das propriedades térmicas das fases separadamente e da blenda e determinação do grau de cristalinidade por meio da densidade. Foi possível não só identificar as funções orgânicas do polietileno na técnica de espectroscopia de infravermelho, mas também analisar um pico desconhecido em um dos polietilenos envolvido na mistura da blenda, que pode se relacionar com o seu resultado obtido no ensaio de TG/DTG, o qual aponta uma maior porcentagem de resíduo após a degradação total da massa do mesmo.

Oct 30, 2017

By Anna Carolina Cerqueira Neves

Atualmente, materiais alternativos têm sido pesquisados, sendo os compósitos dematriz poliméricas reforçados com fibras naturais um desses tipos de materiais. Ofato que torna as fibras naturais uma ótima opção são suas vantagens ambientais eseu relativo baixo custo. No caso do eu eucalipto, este também possui um altocultivo no Brasil. Além disso, as fibras naturais apresentam características deinterface com a matriz polimérica que favorecem as propriedades mecânicas pelaestrutura do compósito. Esse presente trabalho analisa as propriedades de tração docompósito de matriz poliéster reforçado com a incorporação de fibras de eucaliptoem 10,20 e 30% em fração volumétrica, que foram preparados alinhando as fibrasnas matrizes e curadas por 24 horas em temperatura ambiente, por volta de 25ºC.Os corpos de prova foram testados numa máquina Instron e os resultadosmostraram um aumento na resistência à tração conforme o aumento do volume defibras incorporadas.

Aug 17, 2017

By Rodney J. Ishak

The reduction of Mn3O4 to MnO has been investigated in a thermobalance apparatus, The charge was composed of manganese ore (decomposed by heating/calcination or pre-reduction to mainly Mn3O4) and coke. The material was charged to a crucible, which was suspended in the balance. CO-gas was distributed through a grid in the bottom of the crucible. Two sizes of ores were used; 2.4-4.8 mm and 6,7-9.5 mm. Coke particles were in the size range 4.8-6.7 mm. Experiments were conducted in the 900-1100°C temperature range. The composition of the product gas was monitored continuously. External mass transport between bulk gas and particle surface does not seem to limit the rate of reduction. Assuming that both diffusion through product layer and chemical reaction at the interface between MnO and Mn)04 are rate controlling, the data was tried both in a shrinking core model and in a grain model using regression. The grain model gives the best physical description of the process, because the reactant is in fact a porous medium. With this model the effective diffusivity was calculated to be in the 1.5-6.10.5 m2/s range. The pore size was mainly between 0.1 and 10 um,

Jan 1, 2003

By Janet Torma-Krajewski, Pauline Lewis, Paul Gust, Lisa Steiner, Kean Johnson

Since 1990 and the publication of the Ergonomics Program Management Guidelines for Meatpacking Plants by the US Occupational Safety and Health Administration, numerous reports of companies implementing ergonomics program have been published. However, despite these numerous reports, no examples of implementing an ergonomics program in the mining industry have been reported. In 2000, NIOSH initiated a long-term project to demonstrate the implementation of an ergonomics process designed to identify and reduce exposures to ergonomic risk factors found in mining. The mine selected for this project was the Jim Bridger Mine, a surface coal mine located 35 miles northeast of Rock Springs, Sweetwater County, WY. This paper discusses how a large, surface coal mine implemented an ergonomics program and the lessons learned while doing so.

By P. L. Hofmann

The National Waste Terminal Storage (NWTS) Program was established in 1976. The objective of this program is to develop the technology and provide the facilities for the safe, environmentally acceptable isolation of civilian- and defense-related, high-level and transuranic nuclear wastes, including spent fuel elements, for which the federal government is responsible. The principal emphasis of this program is on disposal in mined geologic repositories. Technology development in support of the NWST program includes the formulation and management of a strong basic science and engineering program to generate an appropriate data base to aid in understanding of the key geological processes and major engineering structures involved. The current status, problems, and future plans of the technology program will be summarized.

Jan 1, 1984

By M. Okido, R. Ichino, K. Kuroda

"Compound semiconductor, ZnTe, was electrodeposited in an acidic solution with K2TeO3, ZnSO4 and Na2SO4 solution. Since the reduction potential Te(IV)/Te(O) is remarkably noble from the solution comparing to Zn(II)/Zn(O), code position of Te and Zn was thought to be difficult from this solution. Resulting from EQCM analysis, furthermore, Te(IV) reduced to Te(O) and Te(-II) in this order so that Te catholically dissolved from the electrode surface at more negative potential. But ZnTe alloy were formed by the UPD of Zn at -0.7V at 298K on Te surface in lmM K2TeO3, 100mM ZnSO4 and 100mM Na2SO4 solution adjusted at pH 4. Content of Te in the deposits is, however, more than 80%.Electrolytic temperature is well known to affect on the deposits characteristics. The higher bath temperature was, the better ZnTe crystal was detected in this study. Thermal electrode method is a. process of heating only substrate by flowing ac current in substrate. This process makes the surface temperature of substrate higher than boiling point of the solution, 373K. From EDX analysis, deposits without thermal current were Te-rich, Te content in the deposits with thermal current decreased with increasing of thermal current. Te content was 62% for 5A ac current, 51 % for I OA and 45% for 20A, respectively. The deposits that produced with ac current of IOA were closed to the stoichiometric ratio, i.e. ZnTe.Consequently, thermal electrode method is more effective to obtain a good crystallized ZnTe without heat treatment after deposition.IntroductionThe current subject of solar cell materials is silicon. Compound semiconductors including GaAs and II-VI group are generally used in the developing field of digital information such as the rapid cellular phone and car telephone. Compound semiconductors consist of more than 2 kinds of element. There are many materials for these compound semiconductors such a SiC, InSb, CdS for binary system and CuinSe2 for ternary system. It becomes generally difficult, to produce high quality crystal with increasing of kinds of element due to a complicated structure and a compound ratio of element. Semiconductor materials as a device are usually simple binary compounds and/or these mixed crystals. Properties of compound semiconductors have variety of the forbidden band and lattice constant and that can be change easily by addition of another element for the usage of the solar cell. Since most compound semiconductors are direct interband transition type, which has steep optics absorption edge and large light absorption coefficient."

Jan 1, 2000

By Ta M. Li, John D. Wiebmer

Record high prices, burgeoning exploration programs, mine-mill openings, and plant expansions have all characterized a dramatic: resurgence of the US uranium industry in recent years. But while the bull is leading the way on the production side of the nuclear fuel cycle, there is reason for caution from the end-users' viewpoint. How fast will electrical demand grow in the years to come, and what portion of that will nuclear generators supply? How do utilities play their cards when the government holds two of the largest jokers in the deck-a policy on spent fuel reprocessing and a timetable for the fast breeder reactor? Is there a shortfall in domestic uranium supplies on the horizon?

Jan 10, 1978

By Kazue Moriya

At the 1980 TMS-AIME world symposium, Dr. Davey mentioned that the traditional lead blast furnace is now being challenged by direct smelting processes. In the copper smelting field both the blast furnace and reverberatory furnace are also disappearing in favour of direct smelting processes such as Outokumpu flash smelting, Mitsubishi continuous smelting, Noranda furnace, Inco furnace and so on. Those new processes all have the following in common: (1) High degree of mechanization (2) Metallurgical reactions carried out in closed vessels (3) Application of oxygen and/or oxygen enriched air (4) Minimization of handling materials and gaseous volume (5) Minimum energy requirements (6) Removal of workers from near the furnace (7) Reduction of emissions of harmful gas to meet environmental regulations. (8) Improvement to the work place environment to avoid occupational hygiene hazards. Direct and continuous smelting of powdered concentrate in one vessel was a romance of the metallurgist since early times. However as mentioned above, in the copper field this objective is being achieved in practice. The industry however can't deny that the serious and severe regulation of environmental pollution in every country was the prime motive for the modernization of smelters. In early days, to meet regulations, it was anticipated that many economic difficulties such as higher capital and energy costs and extravagant use of resources and waste disposal would be the result. "Turn a misfortune into a blessing" is an old saying which reveals the current thinking and reacent developments in the nonferrous industries. In the last ten years in the lead smelting field, about two decades later than copper, commercial scale smelting using new furnance technology has started. The KIVCET process and QSL process, which is flash smelting and bath smelting respectively, are becoming major competitors. They will be sure to upgrade their processes to remain economically and environmentally viable in the comming decade.

Jan 1, 1990

By T. S. Mackey

The industrial types, sources, and quantities of US tin residues are identified and the methods of treatment reviewed. The effect of a lower tin price, due to a current major world surplus of tin metal, is mentioned and covered in some detail. The names and locations of over 100 US firms recovering tin residues are listed. Current smelting and refining charges are included to convert the residues into tin metal and alloy. The impact of the complete with-drawal of the LME daily tin price since Oct. 24, 1985, and the collapse of the International Tin Council, which at one time supported the Buffer Stock Manager, are reported with comments.

Jan 1, 1987

By R. E. Hucko

Introduction The principal thrust of the US Department of Energy (DOE) coal preparation R&D program is to develop technology to reduce ash and sulfur content of US coals to levels where the resultant product can be formulated into a high quality solid or slurry fuel that could replace oil or natural gas in both new and retrofit applications. The coal preparation program is implemented by the Pittsburgh Energy Technology Center (PETC) and is conducted both in house and by a cross section of industrial organizations, universities, and national laboratories. Research is subdivided into three areas - coal characterization, beneficiation, and ancillary unit operations.

Jan 1, 1985

By K. S. Fraser, H. J. H. Pieterse

"A pressure oxidation plant to pretreat refractory sulphide ore at the Goldstrike plant in Nevada, was commissioned in early February 1990. The plant, with a nominal capacity of 1363 t/d, was commissioned over a one-week period and achieved design capacity and availability within ten weeks an unusually short period for a plant of this complexity.The pressure oxidation process is conducted under elevated temperature and pressure conditions, and in a corrosive environment. These conditions demand that the process and engineering design of the plant be carried out in a much more sophisticated and detailed manner than is normally required in a conventional gold plant.This paper provides an account of the process and engineering design of the Goldstrike pressure oxidation plant with special emphasis on the design of the vessels, slurry pumps, piping, valves, and control systems.BackgroundLocationThe Goldstrike property is located in Eureka County in northcentral Nevada on the Carlin geological trend. The mine is approximately 40 km northwest of the town of Carlin which is situated on Interstate Highway 80. The minesite is located 1700 m above sea level in the Tuscarora Mountains.Initial Goldstrike OperationsShallow, low-grade mineralization was discovered by diamond drilling in the Goldstrike area in the 1960s. A heap leach operation was established in the mid-I970s by the previous owners. The Post deposit was discovered in 1982. Gold production by mining and heap leaching reached I t/a (40 000 oz/a). American Barrick purchased the property in 1987 and started an aggressive program of deep drilling. This led to the discovery of the Betze and Deep Post deposits and established sufficient reserves to justify an initial 4100 t/d mill and a 5 500 000 t/a heap leach operation"

Jan 1, 1992

By N. A. Gokcen

THE data of Chaudron,1 Tonosaki,2 and Collins³ on the thermodynamic properties of MOO, disagree widely. These authors, by using essentially similar methods, studied the following reaction: 1/2MoO2(s) + H2(g) == i/2Mo(s) + Ph,o H2O(g),K = —----- [1] Ph2 Tonosaki used a vacuum system consisting of a furnace containing MOO, and a water saturator whose temperature was kept at 25 °C with a thermostat. After repeated evacuation, hydrogen was admitted slowly into the system. The experiments were based upon the fact that at a constant furnace temperature and constant partial pressure of water, the total pressure of gas mixture over MOO? + Mo is constant. Any attempt to vary the pressure by external forces would vary only the amounts of MoO2, and Mo, after which the pressure should return to the equilibrium value in accordance with the equilibrium constant of reaction 1. The actual value of K was determined from the total equilibrium pressure (sum of Ph2o + Ph2) at each temperature. The total pressure of gas was varied within the range of 80.2 to 125.4 mm Hg, within a temperature range of 645" to 823 °C. The results were summarized as log K = 0.9413 — 1444.6/T for reaction 1. The ratio of H2O/H2 was considered to be uniform in spite of the presence of a thermal gradient across the static gas phase. It was shown by Rosenqvist and Cox,' however, that in somewhat similar circumstances the error resulting from thermal diffusion may be large. Collins³ improved Tonosaki's method by attempting to avoid thermal diffusion errors. His equilibrium data were obtained at 700°, 800°, and 900° C, and the result for reaction 1 was expressed as log K = 1.258 — 1822/T. The purpose of this investigation was to study reaction 1, avoiding the thermal diffusion errors, and to obtain equilibrium data in a considerably wide temperature range for the reliable extrapolation of the resulting thermodynamic functions. Experimental Procedure The diagram of the apparatus is shown in Fig. 1. Tank hydrogen was passed through a tube containing platinized asbestos at 425 °C in order to convert a trace of oxygen into water vapor. The flow rate was carefully controlled with a capillary-type flow-meter B and a bubbling column D. The gas was then presaturated sufficiently at P and led into a condenser system immersed in a thermostat, controlled to within ±0.002C. The temperature of the thermostat was measured with a thermometer calibrated against a certified standard. The temperature of P was adjusted to avoid the condensation of unduly large amounts of water as judged from the rate of flow out of the capillary tube M. Argon was purified by passing it through magnesium chips kept at 630°C. After passing through the flowmeter B', it was mixed with moist hydrogen emerging from the thermostat. The resulting gas mixture was then led into the hot zone of the furnace through the heated glass tubing and the silica tube S, thus insuring the same ratio of PII2o/Ph2 from the condenser to the reaction chamber, thus avoiding thermal diffusion. The entire gas system was of all-glass construction, except at the magnesium train. The furnace comprised a glazed alumina tube over which a 15-in. platinum coil was wound. The lower end of the alumina tube was tightly closed with a brass bottom and a silicone rubber gasket, and the upper end with two glass disks, each with a hole of 1/16 in. in diameter, through which the gas mixture escaped into the atmosphere. A back-up coil of kanthal wire facilitated the temperature control of the furnace. A coil of annealed molybdenum strip of 99.99 pct purity, 0.005 in. thick and 0.050 in. wide, and weighing 17 g was hung in the furnace with a 0.010-in. platinum wire attached to one end of a sensitive analytical balance. The temperature of the furnace was measured with a Pt-Pt-10 pct Rh thermocouple checked against a standard. The experimental procedure consisted of heating the gas purification trains, adjusting the gas flow rates, attaining a constant thermostatic temperature, flushing the entire system for 2 hr while heating the furnace to well above the expected equilibrium temperature and then cooling it at a rate of 0.3°C per min during which time the change in the weight of molybdenum was observed on the balance. For a given thermostatic temperature, i.e., a constant Prr,o/Px,, molybdenum oxidized upon cooling slightly below the equilibrium temperature. The procedure was then repeated by heating the furnace and thus reaching a temperature slightly above the equilibrium value. The average of the two temperatures, differing by 2" to 3"C, was considered to be the true equilibrium temperature. In order to determine the stoichiometric composition of the oxide phase present in this investigation,

Jan 1, 1954

By R. L. Grayson

Based on the relationships between severity measure vs. productivity and other factors, this paper presents a comprehensive analysis of US underground coal mine injuries in 1996 by mine size. From the 1996 data, it was concluded that, generally, the larger the mine, the more productive it is (in tons per employee-hour) but the more severe is its injury experience (r = 0.65). However, within very large, large and medium mines, the more productive the mine, the less severe is its injury experience (r = -0.43, - 0.36 and -0.26, respectively). For small and very small mines, a deeply nested analysis would be required to understand relationships. Other interesting relationships and comparisons are presented.

Jan 1, 2002

By Yuanyuan Zhang, Patrick J. Masset

"The reduction of FexO in slag is one of the fundamental reactions in iron and steelmaking technology, including the blast furnace process (BF). Experiments on the reduction reaction of iron oxide using CaO-SiO2-Al2O3-FexO-C mixtures were carried out using thermogravimetric analysis (TGA) under reducing conditions at temperatures up to 1100°C. The composition of the primary slag was chosen so that the FexO concentration varied between 0 and 75 wt % and the CaO/SiO2 ratio being kept constant to 0.90. From the TGA curves recorded isothermally at different temperatures the kinetic parameters of the iron oxide reduction were determined.IntroductionIn blast furnace the iron ores and coke are charged in layers from the top. The reduction of iron oxide by coke is one of the fundamental reactions in the blast furnace process. Although a great amount of work has been done on the topic of reduction of composites [1, 2, 3], gasification of carbon [4, 5] and reduction of iron oxides by CO [4, 5, 6], the mechanism of reduction in iron oxide - carbon powder mixtures is not fully understood. Fruehan [1] and Rao [2] studied the reaction rate of the reduction of iron oxide by different types of carbon and concluded that the reaction mechanism is controlled by the oxidation of carbon at temperatures up to 1200°C. Rao [2] studied the reaction of hematite with graphite as carbon source up to 1080°C. An activation energy close to 300 kJ/mol was calculated within the temperature range of 950°C to 1087°C. In his study, Fruehan [1] determined the rate of reduction of Fe2O3 and FeO by coal, coke and coconut charcoal as carbon sources within the 900°C to 1200°C temperature range. He found that the reduction of Fe2O3 by carbon occurs in two stages and that the reduction of Fe2O3 to FeO is faster than that of FeO to Fe. This is due to the fact that the CO2/CO equilibrium ratio is higher, and hence, the rate of oxidation of carbon is faster. Fortini and Fruehan [3] have studied the reduction reaction of wustite by graphite and wood charcoal. They found that the wustite reduction can have a significant effect on the overall rate of reduction in composites at high temperatures or in the presence of a large excess of carbon. The calculated activation energy of the reduction reaction by wood charcoal was close to 368 kJ/mol, while the activation energy of the reduction reaction by graphite was 444 kJ/mol."

Jan 1, 2011