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By D. J. Bauer

Oxidation of mixed lanthanide solutions with ozone at pH 4.5 and at ambient temperature resulted in precipitation of 98 percent of the original cerium present. Corresponding cerium purity was increased from 50 to 98 percent. A second ozone oxidation-precipitation step produced cerium of 99.9 percent purity in high yield from the 98-percent-pure material. Alternately, ozonation at pH 6.5 and 85° C differentially precipitated cerium and rare-earth elements heavier than cerium and left 89 percent of the original lanthanum in solution at a purity of 95 percent. Subsequent recovery of cerium from the heavier rare-earth elements in the precipitate was accomplished by dissolving the precipitate in dilute mineral acid and reoxidizing the cerium with ozone at pH 4.5 and at ambient temperature. The filtrate contained an enriched praseodymium-neodymium-samarium-europium mixture that is amenable to separation by ion exchange or solvent extraction.

Jan 1, 1968

By Yanjie Liang

Elemental sulfur and volatilization kiln slag(VKS)containing heavy-metal produced by smelter factories were used to produce sulfured building material. The effects of heating mode, material proportion (MSulfur:MVKS), size of waste particles and ratio of aggregate to filler(A/F) on the mechanical properties and leaching toxicities of solidified stuff were investigated. The optimal conditions for the solidification are stepped heating mode, 3:7 ratio of MSulfur to MVKS, particle size less than 150µm and 3/17 ratio of A/F. Under the above optimal conditions, the compressive strength of solidified stuff rises to 35 MPa, and water absorption is down to 4%-6%.Furthermore, when NaOH is applied as an additive in the process of solidification, the 2+concentrations of most heavy metals except Pb have reached the national leaching toxicity standard. The results of X-ray diffraction reveal that sulfured solidification is caused by the physical encapsulation rather than chemical transformation.

Jan 1, 2010

By R. Altindag

The rock brittleness is one of the most important rock properties that affect the drill-ability of rocks. It is supposed that the increase in rock brittleness causes the increase in penetration rate. The drill-ability of rocks depends on many factors. These factors can be separated as two parts depending on a machine, bit type, rotational speed, thrust, blow frequency, flushing, and rock properties, brittleness, compressive strength, structure, hardness, etc. In this paper, the relationship between brittleness and drill-ability index, which is used in the prediction analysis of the penetration rate of rotary blast hole drills, were examined using regression analysis. It is also seen that significant correlations exist between brittleness and the drill-ability index.

Jan 1, 2002

By M. Syamujulu

In 1994, Nkana smelter commissioned a multimillion US Dollar Chilean Teniente converter (CT) in its operations in order to improve its smelting technological base. The main objective was to reduce the overall smelting energy costs and increase the sulphur capture for sulphuric acid production to support the company?s leaching operations at Nchanga tailings leach plant. A decade of CT operations have since ensued following its installation and start-up. This paper provides a technical and operational audit of the performance of the CT in the first 10 years of its operations at Nkana smelter.

Jan 1, 2005

By L. Nell

Bateman, like other engineering contractors, carries out or participates in many studies of potential projects in the Minerals Industry. This paper aims to explain the contracting approach to feasibility studies as practiced by Bateman, particularly where this differs from a traditional mining company approach. A brief description is provided of the usual phases of a project and the types of estimate needed to proceed from one phase to the next. Possible organizational structures involving different forms of association between owner, contractor and consultants are then outlined. The bulk of the paper then demonstrates that the cost estimates prepared stem directly from the mining plan, metallurgical process design and engineering design philosophy. The steps to be followed in order to prepare a credible estimate which accurately reflects the design constraints are described. The importance and the methodology of carrying out value engineering and of preparing contingency estimates based on a thorough risk analysis exercise are then discussed. Financial modelling techniques are described briefly. The paper concludes with short summary case studies of two recent investigations of potential projects in Africa.

Jan 1, 1999

By S. Kahraman

The correlations between the modulus ratio and penetration rate of rotary and percussive drills were statistically investigated using the raw data obtained from the experimental works of different researchers. An inverse power law was found between the modulus ratio and the penetration rate of rotary and diamond drills. The penetration rate of rotary drills and diamond drills decrease with an increasing modulus ratio. The penetration rates of percussive drills increase with an increasing modulus ratio. There are significant linear correlations between the penetration rates of percussive drills and the modulus ratio. In one of the cases of percussive drilling, a strong correlation between the penetration rate and the modulus ratio was found for the rocks having a porosity value lower 1.23 %. It can be concluded that the modulus ratio might be a representative measure of rock drilling efficiency. However, further study is necessary to check the validity of the derived equations for other rock types. The effect of porosity on the correlations between the modulus ratio and penetration rate needs to be further investigated.

Jan 1, 2003

By P. T. Slatter

The efficient and accurate design of pipe and pumping plant for non-Newtonian mineral slurries remains a problem. The objective of this paper is to present the development of the Balanced Beam Tube Viscometer (BBTV), an instrument which could facilitate more accurate design for these slurries. The background of rotational and tube viscometry is reviewed and the fundamental principles and inherent advantages of the BBTV are given. The design, data acquisition and processing techniques are introduced and results showing the reliability of the new instrument are presented and discussed. It is concluded that the BBTV is a reliable and versatile instrument for both routine analyses and research work, and has the potential to provide data for the refinement of the design procedure for mineral slurry pipe and plant design.

Jan 1, 1998

By G. Bacon

The past decade has witnessed unprecedented growth in the development and implementation of solvent extraction technology in the extractive metallurgy of nickel and cobalt. Solvent extraction is proving to be a powerful tool, opening new opportunities for simpler, more cost efficient and environmentally sound metal refining processes. These advances, however, could not have been possible without the cooperative efforts between the nickel industry and the people and organizations involved with reagents, materials and equipment development and supply as well as solvent extraction research, aided by the accumulated knowledge and practical experience from the copper and uranium solvent extraction operations. This paper provides an overview of these developments and some of the challenges ahead.

Jan 1, 2002

By Kim Le Roux

Cemented paste backfill (CPB) is a relatively new material that is increasingly being used in open stope mining across the world. The advantages offered by this high density tailings backfill include: a lower total cost associated with backfill placement, reduction of excess water underground; and the elimination of the need to process the tailings prior to placement. However, almost all backfill design is based on the performance of laboratory prepared samples since it is difficult to obtain undisturbed samples and conduct in situ testing due to the lack of access to backfilled stopes and the safety concerns in accessible areas. The logistical problems associated with conducting in situ testing and obtaining undisturbed samples of cemented paste backfill (CPB) has lead to the reliance in the mining industry on performance data obtained from laboratory prepared CPB samples. The degree to which these laboratory prepared samples represent the actual in situ condition is not well defined, partly because the influence of the mixing, transport and placement process on the material properties it is not well understood. Therefore, there is a need in the industry to understand how the material properties and hence the performance of the laboratory prepared CPB compares with in situ material. This paper reports the findings of an investigation into the in situ properties of CPB at a gold mine in Northern Ontario. A combination of in situ and laboratory testing, conducted on undisturbed samples, was used to quantify the in situ properties and performance of the CPB. These results were then compared to those of a laboratory based investigation of the same CPB. It is evident from this investigation that the bulk properties of the in situ CPB are different from those of the laboratory prepared CPB. The most significant observed differences are that the in situ CPB has a higher void ratio and a lower degree of saturation than the laboratory prepared material. The implication of these differences on the stability and performance of the CPB will also be explored in this paper. 1

May 1, 2002

A vital ingredient in ensuring that metals exploration companies, working in the developing countries of thePacific Rim, support the development of national geologists is making such a learning program cost-effective. There is a wide spectrum of learning needed in the development of these explorationists: the technical and conceptual skills to carry out exploration efficiently, the professional and managerial skills to apply the exploration in the work situation, the personal attributes required to manage their exploration effectively, and a company organisation that allows them to learn and use these skills and attributes.

Jan 1, 1995

By J. J. Fischer

COMPOSITES containing cold-drawn, high-strength steel wires have shown promise for normal and slightly elevated temperature applications, particularly where strength-to-weight ratios or corrosion resistance are important.'-3 Although tensile strengths up to 500,000 psi may be obtained by cold drawing these wires, processing the composite at elevated temperatures will result in a rapid decrease of the wires' strength. In wrought maraging steels, high-strength levels can be obtained by aging at 900' . Because these alloys do not rely on heavy cold working to achieve their strength, and because they do not overage readily, they are of potential interest for use in composites. In view of this, the tensile strengths of composites containing The total heat effect thus represents the heat of formation, AHf of the compound at 273' . Since the heat of solution of tin in the tin solvent bath is zero, AHz = 3( - H273)Sn and Hf is given by: For LaSn3, AH3 had a measured value of 11,285 i 380 cal per g-atom while for La2Sn, the corresponding value was 33,658 870 cal per g-atom. Using the measured data for the compounds and pure lanthanum, a value of -15,150 200 cal per g-atom was calculated for the heat of formation of LaSn, at 273°K, while Hf for La2Sn3 was found to be -28,090 400 cal per g-i&om. The authors would like to acknowledge the financial support of the Army Research Office, Durham, North Carolina. under contract No. DA-31-124-ARO-D-384.

Jan 1, 1969

By H. B. Arntzen, P. O. Grøntvedt, T. Lindstad, R. J. Ishak, M. Syvertsen

Better utilisation of electric power and coke is vital in reducing production costs and CO2-emissions in production of ferromanganese. All FeMn smelting operations consume 10 to 30 % more carbon than the carbon needed to reduce MnO and FeO to metal and the carbon contained in the alloy. Potassium which re-circulates and builds up in the furnace has been shown to be the main culprit causing both excessive carbon consumption, by catalysing the Boudouard reaction, and increased electric power consumption. The reaction between CO2 and ordinary metallurgical coke or coke impregnated with potassium has been studied at temperatures from 800 to 1100°C in a thermobalance apparatus. Ordinary coke did not react to any great extent at temperatures up to 1000°C, whereas the addition of potassium (2-10 %) resulted in a huge increase in reaction rates. The ultimate goal is to fit the results into a reaction rate model containing the equilibrium constant for the solid-gas heterogeneous reaction between CO2 and a free active site on the carbon reactant producing CO and adsorbed oxygen (an occupied site). The model includes the partial pressures of CO and CO2, a reaction rate constant that is a function of both the total number of reaction sites of carbon, and the potassium content. The potassium dependency is taken care of by introducing activity coefficients for the carbon sites. As the first step towards such a model, a regression line for the Boudouard reaction rate has been established.

Jan 1, 2004

By Stephen H. Chung

The blasting performances identified above are considered to be the most practical ones for judging the effectiveness of a design combining explosives / rock / drill pattern. In a total blast design process, productivity relates closely to both fragmentation and heave / displacement of muck. In cast blasting, the more overburden displaced by explosives, the less blasted material there is left to be removed with mechanical equipment such as draglines or trucks. For wall protection and dilution control, estimates of the maximum extent of cracks / damage generated in situ due to blasting will help determine the location for drilling and loading perimeter blastholes.

Jan 1, 1994

By Mohammad Noaparast, Babak Fotoohi

"Due to certain advantages in (semi-)Autogenous-Ball mill circuits in most of the high-throughput ore grinding units of mineral processing plants, much attention is paid to optimize the mill performance. Despite the maturity of the grinding mill mechanical design, there had been made less attention to the efficiency of the grinding media in the past. In this research, the possibility of establishing a relationship between liner/lifter wear rate and variations in the composition of the iron ore (from Chadormalu mine) is investigated.Measurements and determination of liner/lifter wear rates and patterns concluded in recognition of critical liner segments exposed to much abrasion during the ore grinding. After metallurgical analysis of liner materials and correlation of wear rate with the ore composition, the homogeneity in the metallurgical microstructure of the alloyed steel (such as the uniform distribution and amounts of the constituent phases) was determined as the most influential factor in the response of the liner/lifter to the variations in the ore composition. Magnetite with greater abrasion index than hematite, in finer particles, is responsible for additional abrasion of liners; hematite with greater work index exists in the mill with larger particle sizes, thus it could produce wear on liner parts with less tolerance to impact as is the situation for martensitic steels.INTRODUCTIONThe mineralization in Chadormalu plutonic iron ore deposit is consisted of mostly magnetite, hematite, martite, apatite, quartz and carbonates. The average composition of the ore is presented in Table 1. In the processing circuit, the gyratory crushed ore reduced to 30 cm would finally be the feed to three similar 32’ semi-autogenous mills in parallel processing lines. The pulp in the mill would have the characteristics mentioned in Table 2. The quality of the mill output has its direct effect on the downstream processes either physically or chemically (e.g. in cycloning or flotation respectively). In order to take advantage of optimum performance for these circuits, a close control of the ore grinding conditions is necessary; because any shortages in throughput, liner/lifter damage or changes in ore composition could bring the unexpected casualties. In this work, it has been attempted to find (possibly) a reasonable relationship between variations in ore characteristics together with liner quality and the amount of wear rate in different liner/lifter segments of a semi-autigenous mill. Liner/lifter segments are supplied by three different domestic steel making companies. The alloy structure of the liners/lifters is made up of pearlitic chromoly steel."

Jan 1, 2005

By Richard Hosley, James Daley

Every grey haired member of the explosive’s industry has said at least once, “We have to get some younger blood into our industry, I might want to retire someday.” And many a youngster who loves to see explosions has wondered how to get involved in such an exciting, yet intimidating, industry. While there are many answers to these questions, an internship program is a great answer to both

Jan 1, 2014

By Han-Tao Hu

Keywords: RH refining process, flow of molten steel, two-phase flow, gas holdup, circulation rate, mathematical modeling A three-dimensional mathematical model for the flow of the molten steel in the whole degasser during the RH refining process has been proposed and developed with considering the physical characteristics of the process, particularly the behaviors of gas-liquid two-phase flow in the up-snorkel and the momentum exchange between the two phases. The fluid flow fields and the gas holdups of liquid phases and others respectively in a 90 t RH degasser and its water model unit with a 1/5 linear scale have been computed using this model. The results showed that the flow pattern of molten steel in the whole RH degasser could be well modeled by the model. The liquid can be fully mixed during the refining process except the area close to the free surface of liquid and zone between the two snorkels in the ladle, but there is a boundary layer between the descending liquid stream from the down-snorkel and its surrounding liquid, which is a typical liquid-liquid two phase flow, and the molten steel in the ladle is not in a perfect mixing state. The lifting gas blown is rising mostly near the up-snorkel wall, which is more obvious under the conditions of a practical RH degasser, and the flow pattern of the bubbles and liquid in the up-snorkel is closer to an annular flow. The calculated circulation rates for the model unit at different lifting gas rates are in good agreement with the determined values.

Jan 1, 2005

By Gregory Molinda

NIOSH has recently completed a study of the interaction between polyurethane (PUR) and coal mine roof in order to determine the mechanism of reinforcement, in both highly fractured rock and unfractured rock. Four case studies of PUR rein­forcement are presented. At a West Virginia site, a borehole camera revealed the location of roof voids and guided the PUR injection. By injecting polyure­thane into a zone from 0.6 to 1.8 m (2?6 ft.) high in the roof, a roof beam was created and ongoing intersection falls were halted. In another highly fractured roof in a western Pennsylvania mine, a total of 5.8 cm (2.3 in.) of rubbleized rock was found in a zone up to 3 m (10 ft.) into the roof. Untargeted PUR injection filled approximately 1/2 of the fractures. These two case studies showed that it is not necessary to fill up 100% of the void space to create stability. In the other two field sites, polyurethane was injected into weak, but unfractured roof. Post-injec­tion video monitoring showed that weak bedding planes were hydraulically wedged open and polyure­thane injected along bedding. The reinforcement value of this injection method is limited because of the wafer-thin layer of PUR introduced along bedding, and the lack of a PUR ??webbing?? which would serve as a structural framework to provide strength. It was determined that video inspection prior to PUR injection can aid in identifying the fracture zones to target, and minimize ??blind?? pumping and loss of PUR.

Jan 1, 2008

By D Craw, L C. Kerr, P Wopereis

Gold placers in the Nokomai and Nevis valleys are dominantly Quaternary in age. They occur mainly in western tributaries of the upper Nevis, eastern tributaries of the middle and upper Nokomai, and in the trunk valleys themselves. Placer gold in both valleys is dominantly a-phase Au-Ag-Hg alloy. Au-Ag alloy is absent or rare in most of the deposits, except in the lower Nokomai. Alpha-Au-Ag-Hg alloy is typically coarse-grained (up to 2 cm), angular, and rarely flattened or folded. Crystalline texture, quartz intergrowths, and psuedo-hexagonal crystal-pluck cavities are common. Fluvial transport distance predicted from the maximum Flatness Index ofAu-Ag-Hg alloy particles is typically less than 10-20 km. Coarse (up to 2 cm) cinnabar is commonly associated with the Au-Ag-Hg alloy, and both were probably derived from hydrothermal sources in western tributaries ofthe upper Nevis and eastern tributaries of the upper Nokomai. Minor secondary Au-Ag-Hg alloy occurs locally in the lower Nokomai, where it coats or cements detrital a-phase Au-Ag-Hg and Au-Ag alloy particles. Au-Ag alloy dominates over Au-Ag-Hg alloy in the lower half of the lower Nokomai alluvial plain and gravel of a raised channel incised into semischist basement adjacent to the plain. The Au-Ag alloy is rounded and commonly flattened and folded. Crystalline texture, quartz intergrowths, and pluck cavities are rare, and a fluvial transport distance of 25-40 km is estimated from maximum Flatness Index ofAu-Ag alloy particles. The Au-Ag alloy, three types of gamet, magnetite, clinozoisite and well foliated schist boulders in the abandoned channel are not found in the pumpellyite-actinolite facies bedrock in the Nokomai. These components were derived from greenschist facies schist and sedimentary sources in Otago, many tens of kilometers north of the Nokomai catchment. They were transported to the Nokomai either in Wakatipu Glacier till or fluvio-glacial outwash that entered the valley via Nokomai Saddle, the confluence with the Mataura, or both.

Jan 1, 2000

By D. M. Wyslouzil

"This paper was prepared for presentation at the 16th Canadian Mineral Processor's Annual Meeting, Ottawa, Ontario, Jan. 17 to Jan. 19, 1984.This paper gives an account of the development of treatment procedures for the differential flotation of refractory copper-zinc ores. Special references are made to the effectiveness of various zinc depressants and their combinations.Studies carried out on refractory copper-zinc ores demonstrated that conventional zinc depressants such as cyanide and zinc sulphate were not particularly effective when secondary copper minerals were present in the ore; the flotation activity of sphalerite was enhanced in the presence of cyanide.Among the various zinc depressants evaluated, the following depressant combinations were found most effective: Zn(OH) 2-S02 , 802-CaO, Na2S-Na2S03-S02, Na 2 S-S02 and Na 2S-S0rDS22.The practical application of any of these systems depends on the type of ore treated and other conditions such as pH, levels and points of collector and depressant additions.In this paper the effect of each depressant combination on different ores is described with reference to the selection of collectors."

Jan 1, 1984

By David R. Skuse, Jacek A. Kostuch, Steven M. Fortier

"Particulate ground calcium carbonate (GCC) is used as a filler and coating pigment in a wide range of applications including papers, paints, plastics and films. In this paper we will overview the requirements for GCC used in both filling and coating applications in the paper industry and highlight the processes used in the production of these materials.INTRODUCTIONCalcium carbonate is both abundant and very widely distributed occurring most commonly as limestone, marble and chalk (Harben 2002). Given, the high purity, whiteness and relative inertness of these materials it is not surprising that they are heavily utilised in a range of industrial applications. Worldwide ground calcium carbonate (GCC) capacity is estimated at 50.5 million tonnes per year (Roskill, 2002). This usage is divided between relatively coarse materials that are used in applications such as landscaping, cultured marble and carpet backing and finer grades that find application in plastics, rubbers, inks, paints and paper. Given the usage of calcium carbonate products across a very wide range of consumer products, the outlook for GCC is very promising with growth expected in many markets. Growth is anticipated across many applications in the emerging nations and more specifically in paper applications on a global basis.Over the last several decades the GCC processing industry has evolved to be well adapted to both the cost effective production and delivery of standard products and the production of high performance speciality products. Many of the standard unit operations found in the metaliferous raw material processing industry are also used, albeit in some cases in modified form, in the processing of GCC. Coarse products (diameter > 3 - 10 µm) are typically produced by dry processing routes. Whereas, the finer products are typically produced by a combination of wet and dry processing."

Jan 1, 2004