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By H. B. Heller, T. J. LaChapelle

Phosphorus nitride has been used as a diffusant for introducing phosphorus into silicon under various conditions. It has a temperature -dependent rate of decomposition beginning in the 500°C range, increasing very rapidly above 1000 C, producing gas -eous phosphorus and nitrogen. Best control was obtained with a two-temperature arrangement, with silicon at the proper higher diffusion temperature. It is an easier compound to use than the usual P2O5 because it is nonhygroscopic and yields temperature-controlled surface concentrations together with excellent final surfaces. Surface doping nearly as high as that produced by phosphorus pentoxide has been observed for sources at 850" to 900°C. Reproducible high sheet resistances were obtained by using slow flow rates (1 linear in. per min) and staggered-baffle gas mixing with the nitride at 550°C. Both inert gas (argon, nitrogen) and oxidizing ambients have been examined. Oxygen reacts to produce anhydrous P2O5, consuming the source at a rapid rate. Nitrogen, except for short diffusion times, suppressed the dissociation reaction and sometimes produced inferior surfaces. Argon appears to be a more useful ambient. PHOSPHORUS is a common impurity atom which may be introduced into a semiconductor lattice to create a p-n junction or an nn contact region. Various investigators1-4 have described techniques which can be used with either elemental phosphorus or certain of its compounds. This paper discusses a newly available compound of phosphorus, phos- some processes silicon wafers are precoated with a phosphate glass which acts as the doping source. Although a nonoxidizing form like elemental phosphorus or a phosphine can be used, most diffusion methods usually involve the use of phosphorus pentoxide. Because of the rapid volatility of this compound, a two-step process is often used, combining a gaseous deposition to introduce a predetermined quantity of phosphorus into the silicon with a later redistribution to obtain the desired distribution and surface concentration. Such a process usually involves predepositing phosphorus at surface concentrations greater than 1020 cm-'. At such doping levels the phosphorus-diffusion coefficient appears to be strongly concentration-dependent.596 Distribution profiles5'9 for these high concentrations of phosphorus do not follow Fick's laws, having extended subsurface regions which appear electrically to be nearly uniformly doped with ionized impurity atoms. Radioactive-tracer experiments also show near-surface anomalies in the distribution profile. Additionally, it has been shown1' that the introduction of very high surface concentrations of impurity atoms into silicon (a step necessitated by the subsequent lowering of concentration during the redistribution) creates dislocations, even in material having no dislocations originally. For device fabrication the use of oxide masking introduces certain difficulties and limitations.7'8 The standard practice of using phosphorus pentoxide as an impurity source adds other problems to these because of the speed and ease with which this compound reacts with moisture present in any gas in contact with it. In fact, P2O5 is one of the fastest and most effective drying agents for gases. Because it is such an excellent desiccant, completely anhydrous phosphorus pentoxide is difficult to obtain and is even more difficult to keep dry. Adequately dry gloved boxes must be used for storage and transfer of the chemical. The presence of even traces of moisture will cause formation of phosphoric acids which, during the high-temperature diffusion, results in polyphosphoric acids of variable composition. Such reaction by-products end up as gradually accumulating viscous fluids in the cooler parts of the diffusion furnace. The calculation of the final solute distribution for

Jan 1, 1964

By Ángel Bravo

La simulación es un programa virtual que permite evaluar los costos de perforación y soldadura para el costo final del proyecto minero. El modelo fue diseñado en hoja electrónica, cuyos datos de entrada son estándares de perforación y voladura, tipo de equipo, ciclos de minado, ciclos de avance en túnel, método de explotación, sección de túnel, costos, etc. En este sentido, el presente texto describe el diseño de simulación que buscará determinar la flota óptima de jumbos, asi como la organización óptima para asegurar una máxima utilización de equipos y establecer un sistema de mantenimiento y servicio de máxima disponibilidad. Su función de probabilidad está orientada específicamente para un método de explotación o tunelería.

Sep 13, 2001

By Dave Capstick, Ken Garner, Jim Porter

Technologies and systems used in the management of energy consumption in the mining and metal processing industry are well understood and documented from the supply side of the business. It is our contention that in many instances, through a more complete understanding of the demand side of the business, based on the detail of the operations plan, will provide greater lead time in terms of the design, implementation and utilisation of power supply infrastructure. Thus, optimal management of demand in a proactive manner, based on production requirements, will ensure both security of supply as well as continuity of operations. This paper describes the technology and methodology that is being developed to enable the above statement to be achieved. We use a case study to demonstrate the ability of the tools and methodology and conclude by outlining the business benefits achievable as well as the future developments emanating from this initiative.

Jan 1, 2005

By K. E. Kolm, W. H. Langer

Developing natural aggregate resources (sand, gravel, and stone) creates environmental impacts. A systems analysis method has been designed to characterize the components of the environmental system, identify potential impacts to those systems, and evaluate the extent of those impacts. The step-wise method consists of problem definition, data collection, preliminary conceptualization and characterization, additional data collection, data analysis, and refinement. The method requires analyzes of various systems making up the environment, including land surface, geomorphic, subsurface, and groundwater systems. After system characterization is complete, the method focuses on identifying and evaluating potential environmental impacts to determine acceptable mining strategies.

Jan 1, 2001

By David Rahal, Des Erasmus, Ken Major

"Over the past twenty years there has been an increased emphasis on fine grinding in the minerals industry. This spurred the development of a range of new fine grinding equipment in the 1990s. At that time, the Knelson-Deswik mill was developed in South Africa for the pigments industry.Knelson Milling Solutions currently offers a wide range of laboratory, pilot and production scale mills. These mills bridge the gap between traditional low speed vertical mills and the high speed horizontal mills (tip speed < 3 and > 15 m/s respectively). They are designed to run at tip speeds between 10 and 12 m/s and are capable of operating with very dense grinding media. The result is a power intensity that is higher than the low speed mills and overlaps that of the high speed mills. This allows the mill to be customized for a wide range of grinding applications.A case study at Aquarius Platinum’s Kroondal Mine shows that the Knelson-Deswik technology can produce a consistent product size despite feed variations. It also shows that the throughput was proportional to the slurry density at Kroondal. The case study identified increasing the slurry density as a process change that can increase throughput and reduce the specific energy consumption.INTRODUCTIONThe increasing complexity and finer grain sizes of modern ore bodies have increased the importance of effective mineral liberation in obtaining acceptable grades and recoveries (Jankovic, Valery and La Rosa, 2003; Lichter and Davey, 2006; Napier-Munn, Morell, Morrison and Kojovic, 1996). This trend has increased the significance of fine grinding technology because the input energy increases exponentially as the required product size decreases from 100 to 10 microns (Gao and Weller, 1993a).The US Department of Energy recently provided the context for the potential energy savings in the US Mining Industry (BCS, 2007). They reported that grinding consumes approximately 494 TBtu/year. This was over double the consumption of the second highest equipment category, diesel materials handling systems (211 TBtu/yr). The proportion of grinding energy allocated to fine grinding can only be expected to increase as finer ore deposits are mined. It is therefore critical that fine grinding efficiency continue to improve through the selection of appropriate equipment and the development of best practices for existing applications."

Jan 1, 2011

Simulator technology has advanced to the point where the cost of mining equipment simulators is beginning to make commercial sense. Simulator-based evaluation allows operators or potential employees to be assessed in a pseudo-real environment under surface and underground mining conditions. Simulator training also allows operators to be exposed to emergency and advanced situations such as brake or steering failure or a tireblowout. ThoroughTec, of South Africa, provides simulator equipment to the mining industry. The company’s various packages of simulator products provide an unbiased evaluation score that removes human error from the assessment process. This same evaluation score is also presented at the end of normal training or refresher training sessions. In this way, the simulator helps eliminate bad habits and improve efficiencies.

Jan 1, 2003

æSustainabilityÆ is one of those words that has gained more usage in popular discourse than in the dictionary. In fact it is not in many dictionaries at all. Typically, given this, it also seems to mean different things depending on whose lips it emerges from. It is now like a code word in that if people say it, you donÆt have to think about its meaning; it is just æthereÆ and is taken for granted. This is a problem for the mining industry as we are now using the term too and to be effective in what we do, we need to have a reality check and see how those outside who have views on us (æstakeholdersÆ maybe) use it. The core issue seems to be æsustainability of whatÆ: the industry?, a company?, the global environment?, particular ecosystems?, the community? At these levels, the term seems almost meaningless. If we do not even agree on what it is, at least broadly, our communication and possible partnerships for going forward will be difficult to say the least. One reference to æsustainÆ in my thesaurus is: æTo keep from failing during stress or difficultyÆ. This may be a clue to something approaching a common notion. I suggest that to use æsustainabilityÆ we make the following assumptions:that we are talking about human activity aimed at making a living that has an impact on the natural and social environment; that humans must make a living (though what this needs to include is problematic); that the impact of particular activities has been problematic to date and needs to be monitored, altered, stopped, etc; that there is stress on both social and natural environments; and that change can be effected in order that particular activities such as mining minimise their negative effects and maximise their positive. This is why we are taking part in sessions such as this one today. Two more initial observations: First, it strikes me that even with the above assumptions laid out, æsustainabilityÆ and æsustainable developmentÆ are too abstract and general as concepts. We have to break these high and mighty ideals down into workable, bite-size chunks, into practical ways of dealing with the world outside our sites and companies. Second, sustainability, on both sides of the fence, too often focuses on nature and environment as though they are independent of people and community. I would argue, perhaps provocatively, that sustainability is primarily a people issue and has to be tackled as such. I want to look at the overall climate for business today and how it has responded before I return to what we can and need to do as the mining industry to make æsustainabilityÆwork.

Jan 1, 2002

By S W. Robertson, A Vercuil, P Craven

Mintek is currently developing a design approach for the heap leaching of low-grade primary copper sulphide material. Since the leaching of chalcopyrite requires elevated temperatures, the generation and management of heat within the heap is crucial. Furthermore, the precipitation of iron needs to be managed to prevent premature blinding of the heap, and acid consumption needs to be limited to contain cost and limit the dissolution of gangue impurities. Standard column tests using jacketed 1-m and/or 6-m columns do not allow accurate prediction of temperature changes and heat generation in an actual heap. Mintek therefore utilizes a computer model to calculate the energy balance and heat generation with time, based on the measured sulphide oxidation rates in the column. The temperature in the column is then adjusted to reflect the computer-predicted temperature in an actual heap. Using this approach, an overall copper extraction of 70% was achieved in 120 days, using 1-metre columns, when treating an ore blend containing 1.36% chalcopyrite, 0.23% chalcocite, 0.07% covellite, 3.8% pyrite and silicate gangue (92%). The chalcopyrite contribution to the total copper content in the feed was 75%. This was followed by 6-m columns using a similar approach, and the column results will be validated on a 23,000 tonne test heap. Key Words: heap; bioleach; chalcopyrite

Jan 1, 2005

The overwhelming weight of scientific opinion indicates that human activity is having a discernible and negative influence on the earthÆs climate system. The Australian Government, together with about 100 other nations, has accepted the findings of the Intergovernmental Panel on Climate Change third assessment report, released in 2001. This report was prepared by several hundred eminent scientists from all over the world, from various scientific disciplines and with differing opinions on global warming. The IPCC third assessment report contains a series of relevant, significant conclusions; for example, it finds that there is an increasing body of observations that gives a collective picture of a warming world and other changes in the climate system. Global average surface temperature increased over the past 100 years by about 0.6¦C. This may not seem much, but in the 900 years beforehand, the EarthÆs temperature remained relatively stable. The 20th century was the warmest of the past 1000 years in the northern hemisphere (there is much better information available from the northern hemisphere than the southern hemisphere). The 1990s were the warmest decade of the millennium in the northern hemisphere and 1998 was the warmest year. Although many factors influenced the EarthÆs climate, scientists are confident that greenhouse gas increases were the main factor contributing to global warming in the last 50 years of the 20th century. Increases in carbon dioxide, methane, troposhperic (lower atmosphere) ozone, halocarbons and nitrous oxide have all contributed to global warming. Combating climate change cannot be done without the cooperation of industry and the community at large. It is important that Government and industry work together to achieve greenhouse gas abatement while ensuring continued economic growth. The cause of the problem û the generation of greenhouse gas emissions û lies at the heart of the structure and size of modern economic activity. Greenhouse gas emissions are embedded in our way of life from our energy consumption patterns to the basic production of food. Moreover, the costs of the impacts of climate change to the earth will be potentially revolutionary, not merely evolutionary. It is in this light, acknowledging both the seriousness and nature of the problem before us that I want to reflect on the key drivers in the international climate change negotiations. A consideration of the past, present and future from what I see as the mid-way point in the process. In 1997, Parties agreed to adopt the Kyoto Protocol, which sets out mandatory targets for greenhouse gas emissions for developed countries.

Jan 1, 2002

The underwater test method for the determination of energy content of explosives is a very useful method. It’s also the only one which can separate shock and gas heave energies from each other. The total energy can be determined as a sum of these partial energies. Because of this special feature, the test method can be used to develop the energy content of explosives for different purposes; the military high explosives should contain more shock energy whereas the gas heave energy is a very important feature for the blasting explosives. The goal of this study was to find out the effects of aluminium and sodium perchlorate increments to the shock, gas heave and total energy values of an emulsion explosive and detect the particle size effects of two different aluminium powders to the total and partial energies as well. Both partial energies as well as the total energy were observed to increase linearly as a function of aluminium (A-80) concentration. The fine aluminium powder (A-100) (6%) also seemed to increase the shock energy of the explosive slightly whereas the gas heave energy was observed to remain unchanged to compared to the normally aluminazed (A-80) (6%) emulsion explosive. Therefore the fine aluminium powder also increased the total energy, but only very silightly. The fine aluminium powder can probably take apart to the chemical reactions more easily during the detonation. (3%) of sodium perchlorate (NaClO4) mixed with (6%) of (A-80) aluminium powdered emulsion explosive was observed to effect to the gas heave energy content of the explosive, but only very slightly. The shock energy was observed to remain unchanged.

Jan 1, 2005

By Jogeshwar P. Singh, Ahmed AlaaEldin, Mohamed Ashour

The presented methodology allows the determination of the response of laterally loaded battered long piles in sandy soils based on the soil-pile interaction. The Strain Wedge (SW) model which was originally developed for laterally loaded vertical piles is modified to assess the behavior of laterally loaded battered piles with the consideration of soil and pile properties. The method predicts the pile-head response and associated p-y curves. The presented soil-pile model accounts for the variation of the direction and magnitude of the batter angles from the vertical position. Unlike current practice, the proposed technique also provides the p-y curves for battered piles in sandy soils based on soil and pile properties (i.e., sand relative density, friction angle, pile geometry, etc.). The proposed methodology has been validated through a number of comparisons with full/model-scale pile load tests. INTRODUCTION The influence of pile battering on the lateral response of piles is rarely studied in the literature. Over the last decades and as suggested by Kubo (1962) and Zhang et al. (1999), a p-y multiplier is applied to predict the response of laterally loaded battered piles from an equivalent vertical one. Several researchers conducted model-scale piles load tests to understand the behavior of battered piles subjected to lateral load (Juvekar and Pise 2008; Meyerhof and Ranjan 1973; Meyerhof and Yalcin 1994). However, such tests were conducted on model piles with diameters less than 30 mm which may not have reflected actual soil-pile interaction. Battered piles are generally categorized as positive or negative battered piles according to the angle of pile installation as shown in Fig. 1. From the small-scaled and numerical models of battered piles, it was found that the lateral capacity of negative battered piles is larger than that of vertical ones. On the other hand, the positive battered piles have lower lateral capacity when compared to vertical piles (Fan-ren and Ji-Ming 2011; Juvekar and Pise 2008; Manoppo 2010; Reese et al. 2004; and Reese and Van Impe 2011).

Jan 1, 2018

By Patrick O. Shires, Harry W. Schnabel

With stable building sites becoming scarce in the greater San Francisco Bay Area, the new Summit Senior Care Facility is being built into the side of an unstable hillside adjacent to the San Ramon Regional Medical Center in San Ramon, California. This hillside has had a long history of instability and the site of the new Senior Care Facility required excavation into both a historic old landslide and a more recent active landslide. After a thorough geotechnical study, it was concluded that the best way to build the new facility would be to construct a tied-back retaining wall in the area of the old landslide, since it extended off-site onto two adjacent properties, and remove the active landslide and replace it with compacted fill before cutting into its toe area with an additional tied-back retaining wall. The design was further complicated by the proximity of the site to several active faults. In the area of the old landslide, the combination of an ascending slope behind the wall, landslide forces and seismic forces resulted in total design pressures between 365 to 4,575 PSF for a wall with a maximum height of 30 feet. The wall for the old landslide was constructed by first drilling and placing steel soldier piles in concrete. The tip of the soldier piles extended a minimum of 12 feet below the landslide plane that was up to 36 feet below the bottom of the wall. Permanent double corrosion protected tiebacks were then installed through the soldier beams and anchored below the slide plane. A shotcrete facing was then installed on the face of the wall. BACKGROUND The site of the Summit Senior Care Facility is located on the southwest flank of Mount Diablo adjacent to San Ramon Valley which is characterized by gently rolling hills. The San Ramon Valley Regional Medical Center, which opened in 1990, is located to the north and an existing church is located to the southwest. There are also private residences located to the southeast. The site is shown in Figure 1. Numerous faults run close to the site, the most significant of which are the Calaveras and Pleasanton faults. The site has also had a long history of slope instability and has been the subject of numerous investigations. Studies conducted in 1979 and 1984 concluded that there was a landslide in the area and recommended that a buttress shear key be constructed between the subject site and the existing church for a sewer main as well as removal and replacement of the head area of the old landslide to stabilize the hospital site. While two previous geotechnical studies in 2008 and 2016 identified slope instability, they did not recognize the genesis and limits of the old landslide on the western portion of the site or the limits of the active landslide on the eastern portion of the site.

Jan 1, 2018

By J. R. G. Williamson

The Mining Division of Iscor, an integrated minerals and metals company, has recently completed a feasibility study for the establishment of a new heavy minerals mine and smelter in the Richards Bay area of KwaZulu-Natal, South Africa. The mine will produce a heavy mineral concentrate containing ilmenite, zircon, rutile and leucoxene which will be beneficiated at a central processing complex close to Empangeni. The ilmenite will be smelted to produce high-grade titania slag and pig iron for export. The ancient dune containing the mineral deposit is located some distance inland of the coastal dunes, and the sands contain a high proportion of extremely fine material which must be extracted ahead of the gravity separation process. Of the 56 million tonnes to be mined annually over the ten-year life of the mine approximately 23,4%?a total of 13,1 million tonnes of minus 45 micron residue fines?will have to be disposed of in a containment facility. The origin of the fine material is from the weathering of amphibole minerals. The remaining coarse sands will be returned to the mined area to re-create the original dune configuration. A number of options for the disposal of the residue fines have been examined and specialised laboratory tests undertaken to determine the deposition behaviour of the fines. The final solution involved the use of a ?sub-aerial? technique for deposition of fine material in a disposal facility. The resulting arrangement will adequately meet technical and environmental criteria. Upon closure after 10 years of operation, the surface of the disposal facility will be returned to sugar cane cultivation The paper refers to the various options considered and describes the problems associated with competent disposal of the residue fines and the development details of the final disposal facility.

Jan 1, 1997

By F. Calizaya

The PT Freeport Indonesia‘s Deep Ore Zone(DOZ) copper deposit is located in the province of Irian-Jaya, Indonesia. Currently, a block cave mine is being developed around this deposit. Production is scheduled to start in year 2000 and to ramp up to25,000 tpd by year 2003. The air quantity requirement for this mine is equal to 780 m3/s. To supply this quantity, the mine will require five centrifugal fans (one 450 and four 750 kW fans). This study summarizes the technical aspects related to the installation and commissioning of one of these fans. The fan was installed on the surface in a parallel arrangement with two others. It has a design capacity of 240 m3/s of air at 2.2 kPa of static pressure. The study presents the installation details from the underground shaft excavation and portal development through fan testing and commissioning. It also presents the results of a monitoring system that was installed to determine the fan duties.

Jan 1, 2000

By M. K. Seguin

The study described in this paper is first centered on the determination of the physical properties (gravimetric, magnetic, electrical, and electromagnetic) o f metamorphosed iron ores of the Carol Lake-Labrador City District. Different geophysical surveys available in the Carol Lake-Wabush area were interpreted quantitatively and the dimensions, attitude, and tonnage of the ore bodies investigated were determined. A geophysical-statistical study was undertaken which permitted the determination of the grade of iron, magnetite, and, subsequently, specularite in the ore bodies. A discussion of the theory and logical progression of the study and the application of the results to actual geophysical data is presented. The conclusions, which are of real significance from the economic standpoint, may be predicted from the data obtained from geophysical surveys before any diamond drilling is undertaken. An integrated interpretation of this type is useful in planning future exploration work and selecting the most favorable geological structures. It also serves as a guide to minimize and determine tonnage drilling patterns. The general conclusion that a restricted range of residual gravity and magnetic anomalies are a key to exploration is valid. Indeed large depths to the top of deposits are absent since all the ore bodies are overturned synclinal structures with tops located close to the surface. Certain irregular geometries do occur but they are not common and the alignment of the iron ore bodies is sub parallel so that magnetic anomalies are evenly reduced in the earth&apos;s magnetic field vector.

Jan 1, 1975

By W. G. K. Fleming

The general history of piling is traced up to the present time with regard to the evolution of methods and materials. The processes have been strongly influenced by developments in basic equipment and industrial change. It is noticeable that in the twentieth century more progress has taken place than in the many previous centuries. It has been strongly influenced by the general development of Soil Mechanics. Test loading is probably the most effective way to assess the success of designs and many empirical relationships have been challenged through it. As we approach a new century it appears that it will be an age of rapid equipment development, with much enhancement of understanding of what has been done. Processes of automatic construction and testing will becoming commonplace. These changes will narrow the limits of conventional scatter that have come to be accepted and to a large extent will be driven by political efforts to curtail energy consumption, to raise standards of quality and reliability, and to conserve the environment. 1. Ancient history. Piling is an ancient art. Its first mention in history is from Herodotus, the first person to commit an account of his times to the written word in the years 557 to 479 BC. He evidently had a strong interest in engineering matters because he wrote of building, brick making, reinforced brickwork, river training, canal building, bridge construction, tunnelling and its acoustic detection and piling. The piling reference comes from Book 5 at paragraph 16.

Jan 1, 1999

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

Few people in the industry today are competent to comment on the O.G. system for vessel covers, but with papers as well prepared as Mr. Bradley&apos;s we will soon be well informed. I would like to direct these comments to Mr. Klaes of Ford Motor Company. Mr. Klaes&apos; description of their steaming hood agrees with our experience at Weirton. We have been able to stay within design limits and, as a result, have had few problems with our auxiliary equipment. Our main problem, as with Ford, has been thinning of our vessel cover tubes. At Weirton, controlled circulation, high pressure boilers are in use as heat recovery units above the BOP vessels. The boilers are provided with "off cycle&apos; oil firing equipment. A Venturi type wet gas scrubber follows the boiler to complete the vessel draft system.

Jan 1, 1972

By K. Yathavan

Fracturing of rock at low stress levels can be a source of unexpected problems in rock engineering: • the resulting instability can be a safety hazard; • in very brittle rocks it may be associated with violent failure of the rock and strainbursting (rockbursting); • it usually leads to an unexpected requirement for rock support, with time and cost implications; • in rock boring projects, it may result in fracture of the rock ahead of the bored face and in the walls of the bore behind the face. This may lead to cutter head vibration, increased cutter wear and consequently decreased performance and increased costs. Examples of situations in which fracturing of rock at very low stress levels has been observed will be described. This will include details or estimates of the in situ stress magnitudes and the rock strengths involved. La brisure de roche sous faibles contraintes peut être l’origine de problèmes inattendus en génie minier : • L’instabilité résultante peut devenir un danger • Elle peut provoquer des éclatements violents des roches fragiles • Elle nécessite souvent une infrastructure de soutien de la roche, ayant des implications sur les coûts et les délais • Les forages de la roche peuvent provoquer une brisure de celle-ci au niveau de la surface forée mais ainsi à l’intérieur de la roche, causant parfois des vibrations et une fatigue de la tête de forage, induisant une baisse de performance et un accroissement des coûts. Nous avons décrit ci-après des exemples de situations de brisure de roche sous faibles contraintes. Cette description comprend des détails ou des estimations des forces et des contraintes impliquées. Cette étude représente la base du travail de recherche effectué sur le phénomène. ißbildung im Gestein unter niedrigen Stressbedingung kann eine mögliche Ursache sein für unerwartet auftretende Probleme in der Felsmechaniklehre: • Die resultierende Instabilität stellt ein mögliches Sicherheitsrisiko dar; • In sehr sprödem Gestein kann es verbunden sein mit einem plötzlichen und gewaltsamen Zerfall des Gesteins; • In den meisten Fällen ist eine nicht eingeplante Gesteinsabstützung erforderlich, und damit ein Zeit- und Kostenaufwand verbunden; • Bei Bohrungsprojekten kann es dazu führen, daß es während des Bohrvorganges zu einer Rißbildung im Gestein hinter und vor der gebohrten Felswand kommt. Dies kann Bohrkopfvibrationen, eine erhöhte Bohrkopfabnutzung und folglich eine Bohrleistungssenkung, sowie Kostenerhöhung zur Folge haben. Das Phenomen von Gesteinsrißbildung unter niedrigen Stressbedingung wird anhand von einigen dokumentierten Beispielen erörtert. Diese beinhalten zudem Details oder Schätzungen bezüglich der Stärke des in situ Stressfeldes, sowie der gegebenen Gesteinsstärken. Die mit diesem Beitrag dokumentierten Ergebnisse formen eine Grundlage zur weiteren Forschung dieses Phenomens.

Jan 1, 2003

By R. L. Montgomery

The heats of solution of erbium chloride in water and in hydrochloric acid and of erbium oxide in hydrochloric acid were determined. The results reveal a discrepancy of 10.5 kcal. per gram-atom between the heats of combustion and solution of erbium reported in the literature, the heat of combustion being more negative. The heat of combustion of erbium t4)4 and its heat of solution in hydrochloric acid (1, 18) have been reported in the literature. The heat of solution of erbium chloride was determined in two studies (2, 19). The present work was undertaken to check the reported heats of solution of erbium chloride and to determine the heat of solution of erbium oxide in hydrochloric acid. The latter quantity permits the heats of combustion and solution of erbium to be compared for mutual consistency. It was also desired to determine the degree of similarity between the thermochemistry of yttrium and erbium.

Jan 1, 1961