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The typical reactions which the reductants undergo during ferroalloy production are reviewed, and identified as reaction with CO2 and with SiO, and dissolution in metal. Available reactivity tests for these three reactions are reviewed. It is proposed that it is worthwhile considering dissolution kinetics as a reactivity parameter. Greater crystallinity of the reductant decreases CO2 and SiO reactivity, but increases dissolution rates.

Jan 1, 2002

By Cao rong-jiang, Tang Xin-he

"In ordinary manufacture process of tungsten powder, a preferable intermediate product used is ammonium paratungstate (APT). The particle size of tungten powder made from it through W2OO58 is larger than 1. 0 um. In order to obtain ultrafine tungsten powder with narrow size distribution, a new type of tungstate, hydraziniull tungstate, was studied. Its formula is 5(N2H5)2O·12 WO.s , with tetragonal crystal structure of a=5.821 , c=18. 468. Three methods for preparing hydrazinium tungstate (ART) were set up and ART can be produced by current industrial APT process with little modification of operation and without any change of equipment.Under certain PH and operation condition of the solution from which ART was produced, an autoreduction of tungsten occured, which produced a lower valency tungstate with blue color when ART was heated at different temperatures, in N atmosphere, tungsten bronze, tetragonal W0290 and W02.7E could be obtained respectively. They all have the superiorities, in the production of tungsten powder, of superfine size and narrow size distribution [average size of 0.5um or even smaller.The rate of autoreduction of ART is very fast at elevated temperature. The reduction reaction, which gaves tetragonal WO290, could be handled smoothly without explosion. To research their behaviors at autoreduction temperatures and the products of autoreduction will be new advances of tungsten chemistry and may also serve tungsten industry with new processes and materials."

Jan 1, 1988

By David Cole, Paul Cooper, Dale Preece, Jerome Stofleth

The Explosive Destruction System (EDS) has been designed at Sandia National Laboratories for the disposal of chemical munitions (phosgene, mustard gas, sarin etc.), many dating back to World War I. EDS is a portable system that is trailer mounted and consists of a vessel into which a chemical munition can be loaded and opened for neutralization with linear and conical shaped charges. Gases are contained within the sealed chamber. The linear shaped charges split the munition in two and the conical shaped charge (CSC) is aimed at the explosive burster, in each munition, which is detonated by the resulting shaped charge jet, Toxic chemicals remaining in the vessel following detonation are neutralized and disposed of. This paper documents the development of a new CSC needed to reliably detonate explosive bursters in an expanding array of chemical munitions that are beyond what the EDS device was originally designed to eutralize. Design of this new CSC was controlled by the need to deliver energy above the detonation threshold into the explosive after penetrating the outer steel casing, fluid, the burster casing and finally the explosive. Design considerations were driven by jet conditions at the steel/explosive interface inside the burster. Parameters to consider in CSC design include: 1) diameter, 2) liner thickness, 3) liner position in body, 4) explosive weight, and 5) liner shape or interior (apex) angle. The effects of these parameters on final CSC performance are examined in detail. CSC’s that meet the design specifications have been manufactured and tested. The performance of these charges are compared with the original design requirements.

Jan 1, 2002

By Jennifer B. Leinart

Sixty percent of the mines responding to the sixth annual Mining Cost Service labor survey reported increases in wages averaging 3.4% over the preceding 12 months. Only one mine reported a decrease in wages and this was accompanied by initiation of a substantial profit-sharing plan. Thirty-nine percent reported no change in wages. Thirty-seven percent reported using some form of incentive bonus plan. Mining Cost Service annually surveys coal, metal, and industrial mineral mines throughout the United States. Information about wages, benefits, and incentive bonus plans is part of an extensive data collection program to monitor cost areas of significance to the mining industry. This year, 131 mines responded to the survey. The data is collected by sending questionnaires to personnel managers at active mining operations. The information included in this article was taken from the returned forms, from labor contracts provided by some of the mines, and from followup telephone calls. This year's data was collected between November 1988 and February 1989.

Jan 1, 1990

Analysis of rock discontinuities, collected using a scanline method, has been undertaken at the Iron Duke open cut mine, on the southern margin of the Middleback Range in the Gawler Craton, South Australia. The iron mineralisation, which is a product of supergene enrichment of carbonate sediments, is located on the W (western) limb of a gently N plunging D2 macrosyncline. Mesofolds plunge shallowly to the NE or steeply to SE, suggesting two shortening events, of which the second produced significant macrofolds. Discontinuities include:faults and shears which display variable orientations, mainly striking WNW dipping steeply N; mesofractures or joints maintaining a well constrained orientation, dipping steeply S, subvertical striking E-W; and bedding surfaces which are folded about a gently N plunging axis. Through this example of the regional control exerted on local discontinuities, it is clear that discontinuities are not randomly distributed as often assumed in purely statistical approaches. Commonly for rocks of any age there is a distinct discontinuity pattern, reflecting the geological deformation history. If the controls exerted on local rock discontinuities can be determined and assigned a number related to their significance, the way forward is available to develop a site specifc knowledge base that can make realistic predictions for any position in a given rock mass. Such a procedure would involve assessment of the regional geology, linked to scanned discontinuities either via manual or automatic means. Recent advances in automatic scanning rock faces (eg by the I-SiTE Laser Radar) to determine discontinuities distributions, enable the rapid calculation of rock characteristics. This is a significant advance in rock engineering, providing a method of safe and quick collection of data. However it creates problems in the presence of an increase in the geotechnical data available, which should be assessed in the context of the regional geology. Although techniques are underway to analyse post-blast discontinuities, the next signifant potential advance in this area could be the integration of a knowledge based system to assess discontinuities ahead of mining, incorporating regional assessment and human intuition.

Jan 1, 2000

By M .. Hori, H. Onishi, Y. Goda

The split-lining structure was newly developed for the air-tight lining of the underground compressed air storage cavern. This structure consists of separated reinforced concrete (RC) segments and air-tight membrane. It is most important for the Compressed Air Energy Storage Gas Turbine (CAES-G/T) system to develop the economical lining. In order to verify the applicability of split-lining structure, CAES-G/T pilot plant was constructed and operated for 6 months. We confirmed the practical usefulness and safety of this system through the operation. This paper presents the mechanical behaviour of surrounding rock mass and the lining structure observed through the operation of CAES-G/T pilot plant. Nous avons mis au point une structure de revêtement modulaire pour le revêtement des cavernes souterraines hermétiques à pression. Ce revêtement est composé de segments de béton armé et de membranes hermétiques. Il était très important, pour le CAES-G/T (Compressed Air Energy Storage Gas Turbine), de développer un revêtement économique. Afin de vérifier l’aptitude d’application de notre revêtement modulaire, nous avons construit un système pilote CAES-G/T et nous avons effectué des essais de fonctionnement pendant six mois. Ces essais nous ont permis de confirmer l’utilité et la sécurité du système. A travers le présent rapport, nous rendons compte de la structure de ce nouveau type de revêtement et du comportement mécanique de la masse rocheuse environnante que nous avons pu observer au cours desdits essais. Als luftdichter Druckbehälter wurde eine gegliederte Belagsstruktur für tief unterirdisch liegende Felshöhlungen entwickelt. Diese Struktur ist aus Stahlbetonabdeckung und luftdichter Plane aufgebaut. Bei der Entwicklung des Pressluftgasturbinen – Stromerzeugungssystems (CAES-G/T) war es die wichtigste Aufgabe, einen wirtschaftlichen Belag zu entwickeln. Deswegen wurde zum Nachweis der Effektivität der gegliederten Belagsstruktur eine Pilotanlage errichtet und 6 Monate lang betrieben. Durch den Betrieb konnten wir die Praktikabilität und Sicherheit des Systems bestätigen. Dieser Aufsatz ist ein Bericht über das Verhalten der durch Betrieb der CAES-G/T Pilotanlage beobachteten Belagsstruktur und umliegenden Felsmasse.

Jan 1, 2003

By J Petrolito

"To improve the economic and environmental performance of underground mining operations, it is common practice to return the metallurgical waste material underground as backfill. This is called hydraulic backfill and is used to fill the mined-out areas not exposed to further mining. To provide mechanical support for underground mining a cemented backfill is normally used. Since its introduction, cemented backfill has allowed mining companies to increase their ore extraction and improve working and environmental conditions. However, cemented backfill represents up to 50% to 85% of the mine’s operating cost compared with 5% to 10% for hydraulic backfill.These economic pressures have led mining companies to carry out research into the partial or total replacement of cement using a variety of alternative materials. The materials are generally site-specific materials, readily available, and cost-effective relative to cement. Such investigations have led to reduced cost of many backfill mixes while maintaining, and in some cases improving, the physical properties of cemented backfill. However, in most cases, cement still remains an integral part of any binder combination. This can be attributed to the alternative binders investigated being either non-binding materials or capable of generating only low-strength backfills, except when used in conjunction with cement.This paper provides a historical review of backfilling binder materials and their characteristics. In particular, it reviews the many alternative materials that have been proposed to either partially or fully replace Portland cement as the main binder."

Jan 1, 2005

New York Meets first Wednesday after first Tuesday of each month. Chairman. PERCY E. BARBOUR, Vice-Chairman. A. D. BEERS, Secretary, 55 Wall St., New York, N. Y. C. A. BOHN, Treasurer. JOHN V. N. DORR, LEWIS W. FRANCIS. Boston Meets first Monday of each winter month. R. L. AGASSIZ, Chairman. JAMES G. CARLETON, Vice-Chairman. E. E. BUGBEE, Secretary-Treasurer, Mass. Inst. of Technology. Cambridge, Mass. W. E. C. EUSTIS, G. A. PACKARD. Columbia Holds four sessions during year. Annual meeting in September or October. W. H. LINNEY, Chairman. OSCAR LACHMUND, Vice-Chairman. LYNDON K. ARMSTRONG, Secretary-Treasurer, P. O. Drawer 2154, Spokane, Wash. STANLY A. EASTON, S. SHEDD. Puget Sound Meets second Saturday of each month SIMON H. ASH, Chairman. I. F. LAUCKS, Vice-Chairman. CHARLES SIMENSTAD, Secretary-Treasurer, 425 Lyon Bldg., Seattle, Wash. GLENVILLE A. COLLINS, JOHN N. POTT

Jan 6, 1917

By P Tzeferis

An exploratory laboratory work was carried out on microbial leaching of poor non-sulphide nickel ores, not amenable to conventional mineral processing operations. The results have shown that domestic low-grade lateritic ores of limonitic or haematitic type are amenable to bioleaching by fungal strains of Aspergillus sp and Penicillium sp. Maximum nickel and cobalt recoveries achieved were 60 per cent and 50 per cent respectively. Losses of soluble nickel in the fungal biomass were found in the range 3 - 11 per cent. Chemical analysis of the leach liquors showed the presence of significant amounts of citric, oxalic and other organic acids, indicating the role which certain metabolic products of fungal activity may play in the process. Possibilities for future investigations are discussed.

Jan 1, 1997

By R. S. Montgomery

Laboratory experiments simulating rock drilling were conducted on a number of commercial grades of tungsten carbide in order to determine their wear rates when they are used as inserts in percussive rock drill bits. The test rock was Barre granite and tests were made at conditions similar to those of the carbide buttons near the periphery of a large, down-hole, button bit. In addition, some wear rate measurements were made at a low blow energy. Wear rates of these carbide buttons were an extremely sensitive function of their cobalt contents and hardnesses and were proportional to e-°.57Hup to a hardness of about 91 RA. The point of minimum wear rate, which occurs at about 92 RA, corresponds to the point of maximum compressive strength. Modern percussive rock drill bits have inserts of cemented tungsten carbide on their wear faces. These inserts have drastically reduced bit wear in comparison to that of earlier all steel bits. The most common cemented carbide grade used in percussive rock drill bits contains about ten weight percent cobalt, although grades containing more or less cobalt are also used. Contrary to the case with carbide in metal-cutting tools, alloying materials are rarely used in mining grades. There are a number of designs of rock bits in current use. The most common form is an X bit which has four chisel-form radial wings. The button bit is another important design and one which has been recently developed. This design uses a flat steel face studded with relatively small hemispherically tipped carbide buttons. These types are illustrated in Fig. 1. Studies have been made of the sliding wear of cemented tungsten carbide on rock 1-4 and multiple-impact fracture', 5-6, b~t there has been comparatively little published on the percussive wear of this material although the wear of the impact face is the most important. There is some available data on the rate of dulling of rock bit inserts in actual drilling 7 but no laboratory studies. Sliding wear studies are useful for understanding the wear of coal and mineral cutting tools and gauge wear of percussive drill bits. but the

Jan 1, 1970

By Jim Nickerson, James McCleish, Tom Abkemeier, Nicholas Willig

The purpose of this project is to convey sanitary sewage from an existing pump station to a new waste water treatment plant. This paper will discuss the design and construction aspects of the project. The scope includes construction of three main shafts ranging from 34 to 100 feet in diameter at depths of 200 to 230 feet and 21,000feet of tunnel. Shaft construction consisted of slurry wall excavations keyed into claystone and limestone at depths ranging from 114 to 130 feet, followed by rock excavation utilizing drill and blast methods. The tunnel is being excavated in the Warsaw and Salem shale and limestone formations utilizing a 12'-6" diameter Wirth hard rock TBM.

Jan 1, 2005

By A. J. Van Der Merwe, J. F. Erasmus

One of the valuation approaches applied to Advanced Exploration Areas and Pre-Development Projects is the so-called ?in situ Mineralization Method? or the ?Yardstick Method?. This method is based on the concept of a known undeveloped Mineral Resource being worth a certain fraction (the ?Yardstick?) of the contained commodity value (?metal in ground?), using commodity prices ruling at the date of valuation. The Yardstick value is derived usually from an average market-based figure obtained from an analysis of recent transactions and is expressed as a monetary value per ounce or per tonne. It maybe modified to accommodate the quality (e.g. grade) and category (e.g. confidence level) of the Mineral Resource/Reserve involved and the time, effort and expenditure expected to be involved in bringing the project to fruition. Some eighteen recent and relevant transactions were analysed, allowing the following general conclusions to be reached: ? a Yardstick with which to value undeveloped PGE mineral resources is likely to range between 0.5% and 2.5% of the in-ground contained metal value ? the expected method of mining (especially with regard to mining costs) and the grade of the mineralization both have a strong influence on the Yardstick ? the status (classification) of the Mineral Resource has some influence on the Yardstick and ? the ruling price of platinum and the regional location of the deposit appear to have insignificant influences on the Yardstick.

Jan 1, 2006

By H. Möhle

Premier Mine is a large underground diamond mine, situated at Cullinan in the Gauteng Province of South Africa. The mine hoists over 3 millions tons of diamond bearing kimberlite per year, from a modern, mechanized panel retreat block cave mining operation. Troughs sited at the base of the cave are developed into the overlying caved ore, allowing loading access to the ore through draw points. Trough opening is therefore a vital aspect of the mining operation. Most of the production is dependent on fast, reliable and safe trough opening. Successful trough openings are achieved under difficult mining conditions due to restricted void, long up-holes and the inherent properties of kimberlite?soft, elastic rock with a high swell factor. Early in 1998, Premier Mine undertook a joint development project (with an electronic initiation system supplier) to determine whether the use of a fully programmable electronic detonator system would enhance the mining cycle in the trough opening process. Blasting commenced in February 1998, initially with blasts of a similar size and duration to those that had been previously blasted with shock-tube systems, to confirm the operational capabilities of the blasting system. The accuracy, reliability and flexibility of the electronic delay detonators (EDDs) minimized associated risks for re-engineering of the trough opening process. Further, as blast timing was optimized, larger blasts were successfully initiated. To date over 20 troughs have been opened successfully with the use of EDDs. Not only did it take less time to open troughs, but also drilling and blasting operations have been optimized, as well as an overall improvement in safety. This paper details the benefits that EDDs have delivered to Premier Mine in this area. The logic followed is: ?Review of the original trough opening practices ?Re-engineering of the trough opening process ?Implementation of EDDs ?Evaluation of improvements and conclusions.

Jan 1, 2000

By David H. Tang

Massive pillar failures were observed at two underground coal mines. The results of stability analysis using traditional pillar design formulae did not agree with the underground observations. Finite element models were used to analyze the causes and mechanisms of the pillar failures. The results were confirmed by the underground observations. Finally, the improved mine plan for each case was derived to ensure the stability of the underground structure.

Jan 1, 1990

By Scott D. Thomson

The client for this project specializes in the use of state-of-the-art technology to fabricate and assemble composites and metal-bonded structures for commercial and military aircraft programs. One of the key components for this operation at the client's plant is a highly precise computer-numerical-controlled router known as the Shoda Machine. This machine tool was installed at the plant in July 1998 for the manufacture and inspection of aircraft parts, and it is extremely sensitive to deflections. To monitor the occurrence of deflections, an internal laser system continuously checks the machine calibration. Deflections in excess of 5/1000-inch in the foundation on which the machine rests require costly periodic re-leveling and recalibration of this tool. Therefore, a significant problem arose when measured deflections during machine operation were as large as 20/1000-inch. In addition, the foundation was cracked in at least three places as a result of elastic foundation movement caused by dynamic loading as well as shrinkage and loss of base support. Deciding on a remediation procedure to alleviate or eliminate these problems involved the following important considerations: (1) achieving the client's need for reducing deflections to less than 5/1000-inch, (2) minimizing the repair cost as much as possible, and (3) reducing the time required for implementation of the foundation remediation solution. After evaluating the advantages and disadvantages of several alternatives, jet grouting was selected as the most suitable solution. The jet grouting program provided columnar elements of soilcrete to remediate the Shoda Machine foundation.

Jan 1, 2003

By R. J. Kline

Most accidents are the result of risk taking. They can happen anywhere. Our coal industry categorizes accidents by type, occupation, commodity, age, every way you can imagine. We now know, how many were injured and when, for all the different types of accidents. We have ask ourselves many times, why are we having accidents, how can we stop the accidents and fatals in our industry? Present numbers and projections do not show that this will happen. Serious accidents can result in fatalities. Fatal accident can be prevented, and the coal industry can achieve zero fatalities. How soon this happens, depends on a great number of factors. I will discuss accidents and reasons for us having accidents in an attempt to get to the root causes. The historical perspective will be touched on, and the risk and analysis of accidents will be probed.

Jan 1, 2000

By Aalbert Zwijnenburg

One of problems connected with the use of gold/titania-based catalyst systems is the low yield in propene oxide (up to 2 wt %). It is shown that the low propene oxide yield is due to product inhibition. New options for propene epoxidation with hydrogen and oxygen are discussed. INTRODUCTION The direct gas-phase synthesis of propene oxide (PO), by the use of molecular oxygen, is still aimed for. Agbased catalysis is in principle possible, but selectivity at present is not promising. Highly dispersed gold on titanium containing catalysts show an extraordinary selectivity in the oxidation of propene to the corresponding epoxide (> 99 %), using a combination of H2 and O2 as oxidation mixture [1]. Additional studies of the epoxidation reaction have indicated several drawbacks of the Au/TiO2 catalyst. Firstly, the low conversion (1- 2 %) obtained under typical reaction conditions (atmospheric pressure, 323 - 423 K) cannot be increased by increasing the reaction temperature, because this leads to extensive by-product formation. Secondly, the low efficiency of hydrogen (relatively large amounts of water are formed) is hard to prevent. Finally, significant deactivation of Au/TiO2 catalysts within several hours on stream has been observed. Deactivation can be almost completely prevented by using dispersed TiO2 supports, such as TiO2/SiO2 and Titanium-Silicalite-1 (TS-1) [2]. In recent literature [2,3] a hydroperoxide-like intermediate has been proposed to be responsible for the selective epoxidation. This oxidising species is said to be formed over gold and subsequently used for epoxidation over the Ti-containing support. The support is responsible for the slow desorption of PO. One of the problems for future industrial application might be the low yield in propene oxide. Furthermore, the presence of minor amounts of by-products, not detected on lab-scale catalyst testing, might complicate the separation unit in an industrial process. The reason for the low PO yield over Au/TiO2-based catalysts will be discussed in this paper. Temperature Programmed Desorption (TPD) and micro-flow experiments have been carried out to study PO desorption and catalyst performance, respectively. A catalytic cycle is proposed together with its consequences for the maximum yield in PO. Finally, several process and catalyst options are discussed in view of potential future industrial application.

Oct 1, 2003

The status and outlook for mining, in your view. Minerals remain a major part of the world’s economic foundation. The fortunes of the mining industry rise and fall with general economic trends, but mining is no less important today on a global basis than it has been historically. Certainly, portions of the industry are critically depressed — domestic copper to name one area —but other sectors are prospering. Mineral consumption, both worldwide and in the United States, has increased steadily since the Great Depression, hitting all-time highs in 2000, the last year for which I have seen data. The highly developed economy in the United States tends to obscure the continuing importance of minerals here. But in less developed nations the critical nature of minerals is obvious and well accepted. In short, although there is no shortage of problems or challenges facing mining — there never has been — mining remains an essential business with great global opportunity.

Jan 1, 2003

In constructing a financial model of a project significant effort is expended on capital and operating cost estimation, commodity price forecasts, and choice of discount rates while uncertainty in the primary input, the reserve, is often completely overlooked. The aim of this paper is to highlight the impact of uncertainty in the resource/reserve estimation process on the assessment of the financial performance of a project. Four qualitative processes have an impact on resource/reserve uncertainty. These stages are: 1.Ore definition 2.Geological interpretation 3.Resource estimation 4.Ore reserve estimation and mine planning. Each stage contains a number of tasks that may be considered as key performance activities (KPAs). Optimizing the manner in which these KPAs are completed can remove a great deal of uncertainty and error from the resource/reserve process. Examination of these KPAs within a company can also provide an insight to the quality of the information underlying the project. This will allow the company to identify any shortcomings in the data and to assess the resulting risks (Gilfillan, 1998). A hypothetical financial model based on a gold operation has been used to estimate the potential effect of resource/reserve uncertainty on revenue. Monte Carlo simulation has been employed to simulate a number of hypothetical scenarios: 1.a base case scenario which assumes no major errors or biases, but contains realistic margins for uncertainty that would exist in any project where work is being completed to the limit of best endeavours 2.a poor sampling scenario which assumes poor sampling practice and lack of understanding of sample preparation 3.a poor resource estimation scenario which assumes poor modelling and inappropriate choice of interpolation technique, and 4. a ?typical? scenario which represents a project where the majority of KPAs are not performed as best as they could be. The results show that realistic uncertainty ranges can generate changes in the estimate of potential revenue of plus or minus 30%.Therefore, it is important to allow for errors in these processes in any financial analysis or feasibility study. It is recommended that, when building a financial model, are view of relevant resource/reserve KPAs be carried out and appropriate ranges for uncertainty be applied to provide a range of potential outcomes. These outcomes can then be factored into the detailed cash flow analysis in order to ensure that technical uncertainty is built into financial decisions.

Jan 1, 1999

By Z X. Zhang

Ground vibrations from the blasts of the LKAB mine at the Malmberget town had reached 18-19 mm/s from year 2000 to 2002. From 2004 to 2010 the maximum vibrations had been reduced to 9 mm/s and most vibrations lowered to about 5 mm/s, indicating that the technical measures used in the mine are effective in vibration control. The major measure that has always been used in Malmberget mine is the method called Changing Initiation Sequence (CIS in short). Another method named Dividing Ring Blasting (DRB in short) is often applied to some special blast rings in the mine. Both methods have been proved to be successful in vibration reduction, and they do not need any additional costs. Because of the two methods, both maximum vibrations and average ones have been reduced by around 50% since 2004.

Jan 1, 2012