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By Spencer R. Titley

Porphyry copper deposits in the southwestern Pacific area represent relative newcomers to the growing number of occurrences of this mineral deposit type. In addition to firmly establishing the importance of this region and its potential influence within the framework of world copper resources, the deposits of this region are significant from a scientific point of view because of their close relationship to the phenomena of Island Arc evolution. Since the discovery of Panguna on Bougainville in 1964, the list of prospects, proven and unproven, and developments, has grown to more than twenty and the number continues to increase. At the time of this writing, the number of prospects is imperfectly known but the following localities and numbers are fair minimum approximations: Manus (Admiralty Islands) (3); New Britain (5); New Ireland (1); Guadalcanal (2); New Guinea Highlands (6); Misima (1); and Fiji (2); Proven prospects are present in the new Guinea Highlands (2); one deposit is being developed in Test Irian, and one orebody, on Bougainville, is in production. This summary paper concerns a discussion of some of the geological characteristics of producers, developments, and prospects on the Islands of Nets Guinea, New Britain, Bougainville, Guadalcanal, and Manus. I am not aware of publishable data for Misima or Fiji. As so many variables ultimately determine whether or not a porphyry copper occurrence becomes an orebody, not the least of which is geography, this summary treats the characteristics of these occurrences which alloy; their assignment to the porphyry copper category. For purposes of this discussion, I have considered those copper occurrences which are apparently genetically related to talc-alkaline intrusions and in which the content of copper has been upgraded 50 to 100 times the Clarke for that particular host rock. Some of these occurrences are shown on Figure 1.

Jan 1, 1973

By Jamie Bonner, Ray Hutton, Taro Nonaka

The Nancy Creek Tunnel is a deep tunnel, designed to store and convey wastewater by diverting flows from trunk sewers currently at or near capacity in the northwest of the City of Atlanta. The tunnel, constructed in hard rock, has an overall length of 13,300 m (43,700 ft), and a finished diameter of 4.9 m (16 ft). The project is currently under construction by a joint venture of Obayashi/CJB for the City’s Department of Watershed Management. This paper describes the contractor’s techniques and equipment, as well as discussing challenges which were overcome. The project is scheduled to be complete in October 2005.

Jan 1, 2005

By Mark McComb, Geoffrey R. Lane

"Over the years many differing approaches have been developed to clearly understand the nature, mode of occurrence, associations and deportment of both free-milling and refractory gold in a wide variety of differing geologic environments and plant products. Many approaches can be taken to characterize the ore which may occur as complex fine grained gold, ultra-fine grained gold, coarse nuggetty gold, complex Asrich refractory gold and double-refractory gold. The approach taken in assessing small drill core composites from Novo Resources Beaton Creek Paleoplacer gold project located in the Pilbara region of Australia was complicated by the nature of the ore, the small amount of sample available from current exploration work, and the gold grade and the grain size distribution. In this case the scope of the study was limited by sample availability although significant amounts of valuable information was also gained. This gold characterization study included the following elements:??Size fraction assays??Ore microscopy??Preparation of heavy mineral concentrates from sized fractions (screening) of crushed or milled head using heavy liquids and Superpan table.??Systematic scans of the heavy mineral concentrate, middling, and tailing fractions using TIMA Automated Scanning Electron Microscopy integrated with an Energy Dispersive Spectrometry to provide semi-quantitative elemental analysis of the individual grains found in the sample.The unique methodology employed to detail the gold deportment was the combination of the Tescan Integrated Mineral Analyser (TIMA) and the Oxford INCA GSR software. This technique not only allowed us to document the deportment of gold but recognize other associated minerals, which included gersdorffite, chalcopyrite, uraninite, coffinite, brannerite and several Rare Earth-bearing minerals.INTRODUCTIONGold deportment studies are commonly carried out on preliminary gold exploration projects in order to determine the various limitations, which may effect processing of the potential ore. This is often because it may be expected that there may be a refractory component to the gold, which may limit physical separation techniques and suggest more costly hydrometallurgical techniques. Often when carrying out gold deportment studies the mineralogical methods may be limited to assuming that the gold will be fine and easily found using standard techniques of optical microscopy or Scanning Electron Microscopy. This may not always be the case as various geological environments may pose their own individual problems to determining the deportment of the gold grains."

Jan 1, 2015

By J. Mitchell Linnet

Bureau of Mines personnel examined mines, prospects, and mineralized areas to determine the mineral resources and potential of deposits in the Bucks Lake and Chips Creek RARE II areas in Plumas and Butte Counties, California. These areas lie along the west slope of the Sierra Nevada on opposite sides of the North Fork Feather River and encompass an area of 62,800 acres (25,400 ha). Metasedimentary and metavolcanic rocks of the Pennsylvanian Calaveras Formation are intruded by plutons of Mesozoic age. Mineral; of economic iterest are in quartz veins in metasediments close to these plutons; they are principally gold and silver with minor amounts of copper, lead, and zinc minerals. Molybdenum, copper, silver, and tungsten minerals occur in tactite along metasedimentary-granitic rock contacts. In both areas, auriferous Tertiary channel gravels have been extensively developed. Asbestos occurs in ultramafic rocks in both areas, and a limestone deposit was explored in the Chips Creek area. Gold is the principal economic mineral in the Bucks Lake RARE II area. The Shenandoah Mine (fig. 1, no. 19) contains 7,500 tons (6,800 t) of indicated and inferred subeconomic gold resources in sulfide-bearing, silicified metamorphic rocks of the Calaveras Formation (table 1). Similar rocks have yielded gold at the Edman and Megowen Mines, adjacent to the area. A high potential exists for additional lode resources in the area around the Shenandoah Mine. Callahan Mining Corporation personnel believe a multi-million ton disseminated gold deposit underlies the property.

Jan 1, 1983

By D. K. Steele

An 18-in-diam column water elutriator was designed, tested, and operated by the Bureau of Mines for recovering nonferrous mixed metals from automobile shredder rejects. The waver elutriator separated metals from nonmetals contained in shredded nonmagnetic rejects. The unit was constructed and integrated into a local automobile shredding operation. Nonmagnetic rejects from the automobile shredder were fed onto the surface of a column of rising water. Dense materials fell through the rising water and were collected as a sink product at the bottom of the column; medium-density materials were removed as an intermediate product in a water flow through a discharge port located between the overflow and sink; and light materials were immediately carried out in the overflowing water at the top of the column as a float product. Nearly 99 pct of the mixed metals were recovered from the nonmagnetic rejects as a 70-pct-metal concentrate. Other operating conditions yielded a 93.7-pct-pure-metal product resulting in a 93.1-pct metal recovery. Float rejects are combustibles, light plastics, foam rubber, and minimal amounts of coated and uncoated copper wire. The middling discharge contained mainly medium-density rubber, plastics, glass, rock, coated and uncoated copper wire, and frequently some thin-sheet stainless steel and wrought aluminum. Maximum metal recovery in the operating program was achieved using a water velocity of 52 fpm (650 gpm). Maximum purity was obtained with a velocity of 88 fpm (1,100 gpm). .Water was recycled through a 12,000-gal baffled clarifying tank. Entrainment water losses with the float and middling rejects averaged 50 gpt of reject feed. Records maintained by the shredder operator show a 34-pct increase in nonmagnetic metals recovery during a 1-yr operation of the water elutriator as compared to recoveries from a previously used air classification system.

Jan 1, 1983

By Paul J. Fopiano

SOME relationships between the flow characteristics of iron single crystals of 99.9 pct purity and the behavior of imperfections have been investigated. X-ray rocking-curve measurements and etch-pit counts were made as a function of plastic strain, and compared to the stress-strain curve obtained on a modified Polyani tensile machine. Crystals grown from rolled strips of vacuum-melted iron by the strain-anneal method1 had a high preference for a (110) longitudinal direction and a (211) face normal. The tensile specimens were prepared from 2 by i by 0.040 in. single crystals having a gage area of 3 by \ in. Rocking-curve measurements were carried out with a highly perfect germanium monochromating crystal in which the dazz spacing was matched to that of the dZl1 in the ir0n.l Well-collimated CuKal radiation was used throughout. These procedures practically eliminated errors due to geometrical and wavelength resolution. Inasmuch as the rocking-curve half breadth may vary markedly from point to point in the specimen being irradiated, the crystals were strained in place by mounting a hydraulic loading device on the double-crystal spectrometer. The rocking curves were taken after each increment of strain in the unloaded condition, since no observable difference was found in the rocking-curves between the loaded and unloaded states. The rocking-curve half breadths of the as-grown specimens were in the range 90 to 120 sec of arc when the beam irradiated an area of about -£ by -& in. on the specimen. DeMarco and weiss3 have shown that, for a well-colli- mated X-ray beam, irradiating about 10"! sq in. of the very same material, half breadths within 10 pct of the Darwin natural half breadth were observed. Since the rocking-curve specimens were stressed by the load-unload technique, the strain achieved at any given stress depended on the time of holding because of low-temperature creep. Fig. 1 shows the rocking-curve half breadth (also area/peak height) as a function of plastic strain for a relatively short holding time (2 to 5 min) at each stress level. For strains less than 0.1 pct the rocking-curve breadth is essentially constant; it is only for larger strains that there occurs a significant increase in this breadth. Where the holding times at each stress level were longer (by well over an order of magnitude) there occurs a significant increase in the rocking-curve breadth only after plastic strains of the order of 0.6 pct had been introduced into the specimen. This observation is related to the time dependence of creep phenomena and emphasizes the difficulty in comparing data obtained by two such different straining methods. Etch-pit results were obtained using a 2 pct nital etch on specimens strained in the range of 0 to 1 pct. Prior to etching, all specimens were annealed for 3 hr at 150°C, the carbon content being sufficient to decorate the dislocations for strains of at least 1 p~t.~ The data points were all taken from parts of the same single crystal which had been strained with short holding times at stress in increments of strain of the order of tenths of 1 pct. The (211) plane is particularly difficult to etch-pit in vacuum-melted iron and therefore it is felt that these values are as much as an order of magnitude low. Fig. 2 shows the etch-pit density as a function of plastic strain. The smooth curve passing through the data points is not meant to infer a quantitative correlation with the rocking-curve data. What is of interest, however, is the change in etch-pit density in the region of 0.2 pct plastic strain. The first three increments in strain (points 2,3, and 4) did not produce a measurable change in the etch-pit density while subsequent increments did produce a measurable change. While the absolute values of these results do not appear to be cor-

Jan 1, 1967

By Eugene Honeycutt, David Gallagher, R. E. Melley, Nick Madison

Drummond Co. Inc.'s Shoal Creek Mine slope conveyor is the highest lift, highest horsepower, highest tension conveyor system in North America. The system has a capacity of 4950 t/h (5500 tph), a vertical lift of 360 m (1180 ft) and a total connected power of 6000 kw (8000 hp). The mine will include 2 longwall machines and 5 to 7 development sections. Annual raw production will approach 9 million tly (10 million tpy). This paper describes the early investigation of system capacity, haulage system options, and the final selection of a single flight belt conveyor. It will review the basic system de- sign and equipment selected. Also included will be some highlights of the installation of the conveyor system.

Jan 1, 1996

By E. Sengier

At the Director's dinner of the A.I.M.E. on. April 22, Mr. Sengier of the Union Minière du Haut Katanga was a guest. Though a member of the Institute for sev-eral years this was the first occasion on which he had had opportunity to meet with it, and in response to an invitation from President DeGolyer, after expressing his pleasure at being present, he told informally of the present development of the Congo with which he has been so closely related. From his remarks the follow-ing has been prepared.-EDITOR. AS you know, the Belgian Congo, a fairly large colony compared with the territory of Belgium, is in the center of Africa. Natural waterways, railroads now built and new railroads under construc-tion, give increasing means of transportation and are helping toward development. The mining industry is by far the most important part of our colonial activity. Considering that we are all engineers, I will confine my figures to mining enterprise. First I will show you the relative importance of the mining industry com-pared with the total exports of the Belgian Congo. During 1925 there was exported 100,000 tons of cop-per, valued at about $25,000,000; 900,000 carats of diamonds, 8000 lb. of gold, 1700 tons of cassiterite, 300 .tons of cobalt, and 20 grams of radium, of a total value of about $35,000,000. Other products to a value of about $12,000,000 and consisting mainly of palm nuts, palm oil, cotton, ivory, copal, rubber, were also exported. From this you will see that mineral products account for about 72 per cent of the total exported value. Copper alone amounts to 52 per cent of the total and 72 per cent of the mineral exports. All minerals, with the exception of gold, which is mined by the government, belong practically toy two mining companies in which American and British capi-tal is interested with Belgian. These two companies (one called Forminière, interested in the diamond busi-ness, and the other called the Union Minière, interested in copper, cobalt, tin and radium) were formed twenty-five years ago. They started producing in 1911, but the war prevented normal operations, and active de-velopment could only be carried on after the Armistice.

Jan 5, 1927

By B. C. Peterson

Calumet Division, Calumet & Hecla, Inc., whose operations are in Houghton and Keweenaw Counties, Mich., is a highly integrated and complex organization. This division operates mines, a railroad, a concentrating mill, a reverberatory smelter, and the auxiliary generating plants and shops to service these operations. In addition, it operates a sands reclamation plant, leaching plants, a foundry, and a machine shop that serves varied industries with castings and parts for many applications. Calumet & Hecla, Inc. has produced over 60 percent of all the copper that has been produced in Michigan since discovery of the ore in 1864, and in 1959 the company ranked eight among the country's producers with a production of 17,407 tons. To keep abreast of modern accounting systems developed elsewhere in industry and to combat increasing costs due to higher labor and supply costs, as well as increased costs due to deeper mines and lower grade ore, the company has developed a modern machine cost accounting system. This not only provides the usual bookkeeping and cost accounting facilities but offers accurate cost data for engineering evaluation of the mining operation. This system is credited with being instrumental in permitting continued operation of these high-cost mines in a period of increasing costs with no corresponding increase in the price of metal.

Jan 1, 1962

By J. C. Engel

Recent innovations in mine safety include the use of mercury vapor lamps for mine vehicle illumination. Such lamps, however, extinguish whenever the line voltage at the machine momentarily sags or is interrupted. The lamps must then cool for several minutes before they will restart. By supplying reduced high frequency power to the lamps from an auxiliary source, it is possible to maintain ionization in the arc tubes preventing the lamps from extinguishing. Essentially an auxiliary high frequency supply, the keep alive system provides additional power to the lamps automatically whenever the lamps are in danger of dropping out. The system can also provide the operator with the ability to dim the lamps at will for periods of up to three minutes by simply interrupting the 60 Hz power to the conventional ballasts. Each unit, housed in a steel explosion proof enclosure with a volume of approximately 0.6 ft3, is capable of servicing up to six 175 watt H-39 mercury lamps and two 100 watt H-75 reflector flood lamps. A total of 16 units were produced for the USBM under this contract and its extension.

Jan 1, 1979

By James C. Norman

The boron review arrived too late to appear in the June issue. The US was the world's second largest producer and the largest consumer of boron compounds during 1990. Boron mineral concentrate and chemical production in the US totaled 1.13 Mt (1.2 million st), including 565 kt (662,800 st) of boric oxide (B2O3) in 1990, according to US Bureau of Mines estimates. Total value amounted to $404 million. This was slightly higher in production than 1989 but down in value, reflecting a softening in boron product prices. Total world production of boron mineral concentrate and chemical tonnage in 1990 was estimated at 3 Mt (3.3 million st), which corresponds to about 1.3 Mt (1.3 million st) of BO,. World production in 1990 was about the same as in 1989.

Jan 1, 1991

By Paloma Lazaro, Moe Momayez

Interactions between human beings and their work environment require the body to regulate its temperature by balancing heat production and loss. Comfortable environmental conditions are crucial for keeping workers safe and healthy and to maintain a suitable level of productivity. However, achieving a proper core body temperature may become challenging under different conditions, especially in high heat-generating workplaces such as hot underground mines. Because hot underground mines have the potential to expose workers to heat stress, compliance with standardized and regulated indices and criteria is distinctly required. The objective of this paper is to provide an overview of the current research on heat stress and strain in hot underground mines, collected from published and specialized literature. General definitions, statistics of heat-related accidents in mining, overview of the indices, standards, and recommendations for heat stress are provided herein.

Oct 6, 2020

In attempting the predict coal cleat orientation in the subsurface for effective methane degasification of the coal beds in the Warrior coal field of Alabama, approximately 150 rock joint orientations and 45 coal cleat orientations were measured in each of 37 7 ½ minute quadrangles in Tuscaloosa, Walker, Jefferson, Fayette, Winston, Blount, and Bibb Counties. Data from these surface locations, and coal cleat data from eight underground mines was corrected for magnetic declination and titled beds rotated to the horizontal where necessary and plotted on rose diagrams for comparative analysis. Data collected on each joint and cleat consisted of attitude, quality, type, spacing, persistence, lithology, bedding thickness, surface texture, and filling. File data and published and unpublished reports from the State Survey and the State Mine Inspector's Office were re-viewed. Twenty-seven mining companies, most of which supplied information pertinant to the project were also contacted. The information obtained consisted of crop line information structure, and underground mine outlines, all of which were put on 7 ½ -minute topographic quadrangles. LANDSAT-1 imagery and Skylab photography were compared to dominant joint and cleat trends in the study area. Detailed results can be found in an open-file report entitled "Fracture Analyses in a Selected Area of the Warrior Coal Field, Alabama." A master's thesis entitled "The Relationship Between Surface Joints and Subsurface Structure in a Selected Area of the Warrior Coal Field" is being prepared to illustrate the relation-ship of the fracture system to the structure in the Warrior coal field. A proposal has been submitted for research on a project entitled "Rock Fracture Systems and Their Affects on the Extraction of Fossil Fuels in the Warrior Basin, Alabama"

Jan 1, 1976

By Dale William Avery

Thirty mines and prospects were studied; 22 are within the Dolus Lakes RARE II area. Three properties within the area and one adjacent to it were determined to have indicated or inferred gold, silver, or molybdenum resources (fig. 1 and table 1) associated with quartz veins and shear zones or quartz-pyrite stockworks in granodiorite. Five other properties in the area and three just outside have potential for the discovery of gold and silver resources. Minor amounts of very fine-grained placer gold are in glacial outwash in and near the area. The John G. Carlisle Mine (fig. 1, no. 9) produced 120 oz (3.7 kg) of gold between 1897-1899. The Independence Mine produced 481 oz (15 kg) gold, 197 oz (6.1 kg) silver, and 189 lb (86 kg) of copper between 1926 and 1935. These mines are adjacent to the study area's northern boundary.

Jan 1, 1983

By R. L. Rickel

The Bureau of Mines, as part of its minerals environmental technology research, conducted a study of mine waste tailings disposal. Part of the investigation evaluated the sand bed dewatering technique for disposal of alumina mini plant tailings as a means to increase consolidation rates and contain effluents. The technique employs a bed of sand resting on an impervious bottom. The tailings slurry is impounded over the sand layer and is dewatered through bottom drain piping. The study employed a single 10-ft-high, 6-in-diam, clear polyvinyl-chloride (PVC) column, and thickener wastes from the acid leaching of calcined kaolin clay. Results showed a consolidation rate of 41 in in 186 days for a total volume reduction of 37 pct. Sand bed dewatering was an efficient technique for solid consolidation and effluent containment when compared with data obtained from other dewatering studies.

Jan 1, 1982

Discrete Element Method - Computational Fluid Dynamics Modelling of Flow Behaviour in a Stirred Mill - Effect of Operation Conditions

Sep 13, 2010

US 4,135,913-Extraction of nickel values from iron-containing nickel sulfide ore, particularly pentlandite or nickeliferous pyrrhotite A mixture of raw ore, roasted ore, or iron powder, and coal as a reductant is heated to a temperature of 800- 1000° C in a nonoxidizing atmosphere to convert the bulk of the iron content to metallic iron while diffusing into the iron the bulk of the nickel, the mixture cooled, and the cool material separated into a magnetic fraction containing most of the nickel and a non-magnetic gangue fraction A Illis arid L S Renzoni, assigned to International Nickel Co, Inc Jan 23, 1979 7 pp (75-21) Filed 10-10-75 (621,343) Priority Canada, 10-27-72 (155,032) Same Canadian 981,910, dated Jan 20, 1976 Same British 1,389,145, dated Apr 3, 1975 US 4,135,917-In the recovery of gallium from a solution obtained by the digestion of bauxite or nepheline in an alkali solution for the production of alumina, the digestion solution is neutralized, the neutralized solution evaporated to an op¬timum caustic alkali concentration and adjusted to a ratio of alkali metal oxide to alumina of above 2, the corrected solu¬tion contacted with a gallium-aluminum alloy, arid high-purity gallium recovered from the solution by electrolysis or cemen¬tation K A Badaliants, et al Jan 23, 1979 6 pp (75-109) Filed 12-19-77 (862,201) Priority USSR, 12-22-76 (2,428,¬006) US 4,135,918-Extraction of copper from copper sulfide ore containing also one or more of the metals iron, nickel, arid cobalt Ore is roasted at a temperature of 750-800° C to expel sulfur, the sulfur-free calcine slurried in water containing a sufficient amount of sulfuric acid to supplement any sulfuric acid formed in situ, the slurry heated at 150-165° C in the presence of a reducing gas to form soluble sulfates of metals other than copper while reducing copper to elemental form, arid the slurry filtered to recover copper solids Any precious metals present in the ore will report with the copper solids V A Ettel, A P Devuyst, R Sridhar, arid C. E O'Neill, as¬signed to International Nickel Co, Inc Jan 23, 1979 5 pp (75-117) Filed 3-2-78 (882,610) Priority Canada, 5-13-77 (278,360)

Jan 1, 1980

By A. P. Whittlestone, J. D. Johnson, R. J. Pine, M. E. Rogers

standpoint. The effect on efficiency of collisions

Apr 1, 1995

By G Stovpchenko, G Jianjun, L Medovar

Electroslag remelting (ESR) today and into the future, will still be the main process for producing high-quality ingots by suppressing segregation, not just refining chemical composition from impurities. This paper analyses state-of-the-art electroslag refining with a focus on ESR with consumable electrodes, and recent technology with liquid metal supply (ESR LM) in view of their refining abilities and development trends, taking into consideration that the size of the ingots required by industry continues to grow, and the composition of new materials sophisticates to withstand increasingly higher mechanical and temperature loads . The yield of suitable metal in large ingots produced by conventional casting is low due to problems of element segregation by height and crosssection. For example, conventional ingots for nuclear powerplant rotors today reach nearly 700 t in weight. Attempts to directly replace such giant ingots with big-diameter ESR ingots weighing approximately 400 t were also unsuccessful because of growing segregation. Modern ESR equipment and technologies produce 200–250 t of ingots of satisfactory quality, reaching 2.5 m in diameter, implementing the change of consumable electrodes during remelting to increase ingot length. Another way to mitigate segregation is to enlarge the smaller diameter ESR ingot by a 500– 800 mm coaxial layer to the desirable diameter by ESR in the current-supplying mould (CSM). Modelling and experiments prove that refining from impurities and non-metallic inclusions at ESR most effectively occurs at the slag bath and liquid metal pool interface because the ESR LM has provided the same desulfurisation. ESR’s special refining capabilities in CSM come from the much longer time of LM residence shown at titanium purification from hard-melting nitride inclusions that are unremovable in vacuum arc remelting (VAR) and electron beam melting (EBM). Implementation of ESR technologies in CSM, especially with LM supply, is prospective to produce heavy enlarged and hollow forging ingots with prevented development of segregation due to dividing cross-section and reducing overheat of solidifying metal.

Jun 19, 2024

By H. Siebel, N. A. D. Parlee

MIZIKAR, Grace, and parlee' studied rates of absorption of oxygen in stagnant liquid silver in a new type of open-ended gas-liquid metal diffusion cell, where the capillary diameters used were 1.5, 2, and 3 mm. They reported that the rates appeared to be controlled by the rate of diffusion of oxygen atoms in liquid silver and they used their data to arrive at the following equation as a reasonably good representation of the diffusivity (D) of oxygen in liquid silver: D = (14.7)10-4 exp (-7100 ± 3200)/RT cm2/sec Since this type of diffusion cell offers a promising method of measuring diffusivities of gas atoms in liquid metals, the senior author of this note and his students are carrying on a critical examination of the method, and are attempting to improve and extend the technique. The research reported briefly here was designed to examine more carefully the earlier conclusion1 that the absorption rate is diffusion-controlled, and to find out whether the diameter of the cell could be greatly increased and thus extend the method to systems where gas solubilities and diffusion rates are much smaller than in the case of oxygen in silver. For the purpose of these experiments, the open-ended capillary cell used by Mizikar, Grace, and Parlee was replaced by a small cylindrical crucible (1 to 1.7 cm in diam) containing pure silver (to a depth of 1.3 to 3 cm) resting in the bottom of a closed-ended vertical quartz tube, with an evacuated quartz filler tube just above the crucible to reduce dead volume. The method of measuring the rate of absorption was otherwise very similar to that of Mizikar, Grace, and Parlee and all the same precautions were taken. A much smaller and shorter tube furnace was used for heating, but simi- lar precautions about temperature gradients were observed. This technique was nothing more than the application of a Sieverts apparatus to the measurement of rates of absorption in small crucibles of stagnant liquid silver. In each run the volume of gas absorbed (V) was plotted against the square root of time (vt) and apparent diffusivities were calculated from the slope of the line, as described by Mizikar, Grace, and parlee.' Care was taken to use only the data obtained during the early part of the total absorption period while the cell functioned as one of infinite depth. The results at 1000°C are summarized in Table I and Fig. 1. The following conclusions may be drawn: 1) Diffusion cells up to 1.7 cm in diam yield, within experimental error, the same values for the diffusivity of oxygen (D) as the capillary cells of 1.5, 2, and 3 mm in diam employed by Mizikar, Grace, and Parlee. Cell diameters as large as 1.7 cm are probably not desirable for the most precise work. Intermediate sizes, perhaps 0.5 cm, will be most practical. 2) All absorptions measured were consistent with a model where the rate is controlled by the diffusion of gas atoms in the metal. The fact that runs at absorption pressures ranging from 0.1 to 1 atm (at any one temperature) give

Jan 1, 1965