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By Archie W. Fletcher, R. J. Wesely, Nathaniel Arbiter, A. D. Zunkel

In contrast to pyrometallurgy's six thousand year history in the production of metals, that of hydrometallurgy is of relatively recent origin. The earliest reference to it at all was in the 16th century, with the first applications to copper in the 17th and 18th. In the 19th century, increased demands for pure metal resulted in development of electrolytic refining, and early in this century electrowinning. The rapid growth in wpper production in the present century, paricularly in the United States and Chile, stimulated the development of new technology for leaching, and for the recovery of copper from leach solutions. Solvent extraction has become a major factor during the past quarter century by permitting novel leaching technology which produces dilute or complex solutions. In addition, solvents other than sulphuric acid, and chemical methods for precipitating copper metal are now of increasing interest. These are trends which should grow in importance in the future with the need to process lower grade and more complex materials. The evolution of copper hydrometallurgy is reviewed briefly and key factors in recent major developments are presented with details of specific operations and with trends for the future indicated. The relative importance of copper hydrometallurgy is compared to that of pyrometallurgy in the light of probable changes in ore supplies and character.

Jan 1, 1993

By J de Cuyper, S. R. Rao, J. Leja, K. S. Moon, W. Freyberger

A prolonged grinding of sulphide ores in steel mills appears harmful to flotation recovery and selectivity whenever xanthates are used as collectors. Particles finer than about 10um show a pronounced decrease in floatability. A supposition was made that the cause of the reduction in floatability of ground sulphides is the presence of metallic iron abraded during grinding and deposited on the ground particles. Electro- chemical measurements were made of mixed potentials developed by different sulphide-mineral electrodes (galena, chalcopyrite, pyrite, marmatite, pyrrhotite) in xanthate solutions, without a direct con- tact or in contact with a metallic iron electrode. These measurements showed that without a galvanic contact between the sulphide and the iron, the values of mixed potentials were in the vicinity of the xanthate/dixanthogen redax potential. When contact with iron was established, the mixed potentials shifted towards the more negative reducing or cathodic values, The shift was greater the higher was the ratio of the surface areas: iron electrode to sulphide electrode. Further, the shift in mixed potentials was greater the more reducing were the conditions on the sulphide electrode. Chemical analysis of reaction products produced on the surfaces of sulphides and in the bulk solution showed that less thiosulphate was formed in all of the sulphide-xanthate systems and that more elemental sulphur was detect-

Jan 1, 1976

By R. W. Smith

Though generally rather non-selective in nature long chain collectors nevertheless function in different ways in accordance with their own particular physical characteristics. Altering various parts of their structures such as chain length, type of chain, etc. can therefore substantially alter the adsorptive behavior of the collectors in a set environment. The effect of such structural differences of the collectors on physical parameters such as solubility, critical micelle concentration, acid or base strength, tendency to be expelled from the aqueous phase is discussed, as is also the effect of these parameters on flotation behavior.

Jan 1, 1989

By M. J. Virnig, Christopher A. Fleming

THE CIP PROCESS "IN THE RIGHT PLACE AT THE RIGHT TIME? After its tentative introduction to the precious metals mining industry in the earlier part of this century, the carbon in pulp (CIP) process has now come of age, and is the process of choice on all new gold mills. Well over 50 percent of all gold that is mined each year is recovered by adsorption on activated carbon, and the percentage will increase in the years ahead, when old mills using Merrill Crowe technology come to the end of their lives, and as the proportion of world gold production from low-grade resources increases. The pioneering process development work in this field, which was mainly concerned with carbon elution, was carried out by Zadra and his colleagues at the United States Bureau of Mines in the early 1950's (Zadra et al., 1950, 1952), and led to the commissioning of the first large-scale, industrial CIP plant, at the Homestake Mine in South Dakota, in 1973 (Hall et al., 1974). From there, the process spread rapidly, firstly in South Africa in the late 1970's. and then throughout the rest of the gold producing world in the 1980's. There were several factors that led to the meteoric (by gold industry standards) acceptance and successful implementation of this new technology into gold processing operations worldwide. Firstly, and perhaps most fortuitously, the development of the technology closely paralleled the 1968 release of the gold price from the rigid constraints of the $35/oz. gold standard. With the value of the metal allowed, for the first time in modern history, to fluctuate in response to free market supply and demand forces, the gold industry witnessed an unprecedented boom as the price of their commodity increased ten-fold in a remarkably short period of time. This had several important spin-offs as far as new process developments were concerned: The profits realized by established gold-mining companies increased enormously and, consequently, there was more to spend on research and development and exploration for new deposits.

Jan 1, 1993

By J. M. Mutmansky

The objective of this study was to produce coal dusts for laboratory research that are similar to mine airborne dusts in chemical, mineral, and physical characteristics. In this investigation, dusts produced in laboratory comminution equipment were compared with continuous-miner-generated dust for similarity in physical characteristics. Mining-generated dust (MGD) and bulk coal samples were first collected from an underground mining operation. The bulk samples were then processed in the laboratory for size reduction in various comminution devices. These laboratory-generated dust (LGD) samples were subjected to size and microscopic analyses. Physical properties of the dust particles were studied on a scanning electron microscope (SEM). A numerical shape coordinate system (SCS) was also developed and applied to 300 particles from each sample. Statistical analysis was then performed on the collected data and characteristics of the MGD and LGD samples were compared.

Jan 1, 1995

By Robert S. Hedin, David M. Hyman

Acid mine drainage (AMD) is a common water pollution problem on active and abandoned coal mine sites in the eastern United States. AMD forms when surface mining brings unweathered pyrite-containing rocks to the surface or when deep mining allows oxygen to contact buried pyritic strata. In the absence of neutralizing compounds, the drainage that results can be extremely acidic and contaminated with dissolved iron, manganese, and sulfate. Drainages with pH < 3.0 and concentrations of sulfate greater than 1,000 mg/L, iron greater than 50 mg/L, and manganese greater than 10 mg/L are common. Where water flows through alkaline materials (such as limestone) before surfacing, the drainage is less acidic and occasionally circumneutral, but it can still contain high concentrations of sulfate and metals. Current water quality standards in the United States require that mine discharges have a pH between 6 and 9, total iron concentration less than 3.0 mg/L, and manganese less than 2.0 mg/L. At thousands of active and inactive mine sites, drainage does not meet these standards and is being treated before discharge by the mining company. At thousands of other sites, which were abandoned prior to the enactment of water pollution laws or were operated by companies that have gone bankrupt, untreated AMD is polluting receiving water systems. The standard mine drainage treatment system involves the addition of a1 kal ine chemicals to the water, which raises the pH and cause metals to precipitate in a settling pond. These systems are expensive, often costing tens or hundreds of thousands of dollars per year for chemicals, operation, maintenance, and disposal of the metal- laden sludge. Because the drainage on many sites will likely be contaminated for decades, there is financial incentive to find alternative water treatment systems. In the last five years, many mining companies and engineering firms have experimented with the construction of wetland treatment systems. Very few of the several hundred wetland systems that have been built are performing well enough to justify total abandonment of chemical treatment. Nonetheless, systems continue to be built because the mining companies have found that wetlands can reduce their AMD treatment costs. It is also their hope that further research and development will eventually result in systems that will completely rep1 ace chemical treatment and offer long term performance at minimal cost. The Bureau of Mines has been actively involved, from a research perspective, with this approach to AMD treatment since its inception. In this paper, the status of constructed wetland technology is discussed with respect to the construction and performance of systems, chemical and biological processes that affect AMD chemistry within constructed wetlands, and the future of this technology as perceived by the Bureau of Mines. ORIGINAL OBSERVATIONS The constructed wetland concept has its roots in observations of natural Sphaqnum peat wetlands that received acid mine drainage and, instead of being adversely affected, appeared to cause an amelioration of the polluted water (Huntsman et al. 1978; Wieder and Lang 1982). These observations instigated the idea that wet1 and systems might be used for the intentional treatment of mine drainage. Because the discharge of AMD into a natural wetland is prohibited in the U.S. by several laws, it has been necessary to construct wetlands which act solely as water treatment systems. Initially, most wetland research and construction efforts mimicked the original observations by utilizing Sphaqnum moss and peat. Despite promising laboratory results (Kleinmann et al. 1983; Tarleton et al. 1984; Burris et al. 1984; Gerber et al. 1985), virtually all field tests of Sphasnum-dominated constructed wetlands failed to provide sufficient water treatment for more than several months. Sphasnum proved quite sensitive to the stresses associated with transplanting, abrupt changes in water chemistry, excessive or insufficient water depth, and

Jan 1, 1989

By Y. C. Kim

This paper describes the implementational aspects of a blast hole kriging system that has been developedfor the purpose of daily ore/waste control in an open pit mine. The primary goal of blast hole kriging is to improve the ore/waste delineation procedure. A complete computer program package called Blast Hole Kriging (BHK) System was developed for IBMIPC AT or XT computers, using the Fortran language and supplemented by a few assembly language routines for the bit- map manipulation. This paper emphasizes the practical implementation requirements of the system and discusses system design considerations.

Jan 1, 1991

By W. D. Blackburn

If there is a single key to managing a mineral extraction company, it is the control of productivity. American labor costs, in general, tend to be in the range of 10%-15% of total costs. American coal mining labor costs, however, exhibit ranges of 30%-60% of total costs. Is it any wonder that the industry finds itself at a competitive disadvantage? When labor costs take as much as sixty cents of every dollar of revenue, there is little room for profitability. The American coal mining industry must set as a long range goal the reduction of labor costs to the 10%-15% range of total costs in order to be competitive.

Jan 1, 1986

By J. W. Walkiewicz

The U.S. Bureau of Mines has conducted studies using microwave energy to stress-crack iron ores. In a microwave chamber which simulates a continuous throughput operation, the Bond grindability of a taconite sample was improved by 13 pct at a bulk temperature of 197? C. To further improve the economics of microwave fracturing, higher powers up to 16 kW were used to rapidly heat samples to relatively low temperatures in a continuous belt-fed applicator. A significant enhancement of grindability was obtained with a minus 1.9-cm taconite rod mill feed. At a sample temperature of 130? C, the grindability was improved a maximum of 26.1 pct over the non-microwaved sample.

Jan 1, 1993

By S. K. Kawatra, R. A. Seitz

There is considerable variation in the types of coal flotation circuits in use in various parts of the world. For example, Russian plants frequently use scavenger flotation, while this is almost unheard of in the United States. The numerous circuit designs are intended to address specific problems in coal flotation, or to take advantage of the peculiarities of certain coal deposits. As a result, it can be difficult to decide which circuit is best for a given application. For this paper, coal flotation circuits were collected worldwide from many operating plants. These circuits include varying degrees of conditioning, and complexity ranging from simple rougher flotation to multi-stage split- stream processing. The design goals of each circuit are described, and the advantages and disadvantages of each are discussed. Extensive sampling campaigns were carried out in two plants with the most common types of coal flotation circuit (simple rougher, and rougher with deslimed feed). The performance of each plant was evaluated, and the benefits of more sophisticated processing in each case are described.

Jan 1, 1993

By R. J. Sheets

In 2009 the Gold Quarry open pit mine, located 11 km northwest of Carlin, Nevada, USA, experienced multiple large-scale slope instabilities of the upper east highwall that reduced gold ore extraction for nearly 18 months. The slope instabilities occurred within a weak, consolidated sedimentary sequence that exhibits strength characteristics that are transitional between soil and rock. Instability initiated as mining exposed the lower clay-rich sub-units of the Carlin Formation (Fm.). This deformation created preferential flow paths that allowed groundwater from the upper sandy sub-units to infiltrate low permeability clay-rich sub-units, thereby enhancing deformation of the slope toe which in turn destabilized the upper portion of the highwall. The outcome was a 160 m high slope instability that had a lateral run-out of 850 m. The effort to return the pit to ore production required both the geotechnical and hydrogeological investigations and the preliminary remediation mining activity to be concurrent. This approach required the development of detailed safety procedures and a requirement to modify the remediation design as new results were obtained. An initial challenge was to mitigate a near vertical, 90 m headscarp with blast induced, localized slope failures. Back-analyses applying numerical modeling indicated that the failure surface did not coincide with initial interpretations based on field observations; drilling results eventually confirmed this alternative failure geometry. The final remediation design incorporated shallower slope geometries and an approximately 3 Mt buttress along the base of the Carlin Formation and bedrock contact to reinforce the lower clay-rich sub-units. The outcome is a stable highwall within the Carlin Fm. following nearly ten years of repeated slope instability, and an example of the necessity to conduct appropriate geotechnical and hydrogeological studies during the early stages of a new layback evaluation or new open pit development.

Feb 23, 2014

By Brian Kenner, Peter Swanson, Todd Krahenbuhl

NIOSH has developed an automated PC-based seismic event (induced earthquake) monitoring, system for use in mine ground control studies. The distribution and coordination of data acquisition and processing functions across a local area network is a central feature of the system. Mine-wide installations utilize multiple, autonomous seismic networks located both underground and on the surface. Seismic event locations, magnitude estimates, and other processed data are distributed for display and analysis on network nodes both underground and in the offices of mine engineers and managers. This paper describes the system&apos;s design philosophy, hardware and software components, examples of installations, and a few observational results.

Jan 1, 2002

By M. Robb, S. J. Bate, M. Boisvert

The never-ending quest for gold-bearing ore deposits is a primary industry in Canada, employing people of widely differing expertise. The exploration models for gold deposits are generally geologically complex and the targets have relatively small cross-sectional areas. These problems are compounded in Canada by the minimal outcrop exposure in most mineral provinces and the high percentage of water-covered areas. Naturally the chances of successfully delineating an economic gold deposit are very much greater if all parties involved can act as a team of explorationists constantly confemng amongst themselves particularly as the applicable disciplines generally overlap and complement each other. Three case histories (see Figure 1) are presented to illustrate this philosophy with emphasis placed on the role of the geophysicist in translating the exploration model as defined by the geologist into physically measurable parameters and identifying target areas with similar characteristics. The Conwest-Miminiska property in Ontario is a grassroots exploration play. Additional ore reserves needed to be delineated on the Salmita property in the Northwest Territories. At Laura Lake, near Chapais, Quebec geophysical methods were employed to trace thin high-grade mineral intersections under deep overburden and severe cultural interference.

Jan 1, 1989

By David G. Laughton, Richard Poulin, Michael R. Samis

Real options (RO) valuation is an alternative net present value (NPV) framework that is able to incorporate both management flexibility and dynamic project risks. In this paper, management is considering the development of a satellite low-grade zone while operations in a developed high-grade zone continue. If the low-grade zone is developed prior to high-grade zone exhaustion, mine capacity must be expanded before additional production from the low-grade zone can be processed. This expansion can be avoided only if low-grade zone development is delayed until the high-grade zone is exhausted. The RO model presented here allows the development and capacity expansion decisions to be reconsidered on a discrete half-year basis. It delineates price regions, for given levels of high-grade zone reserves, in which it is optimal to develop the low-grade zone, defer low-grade zone development and abandon the mine irrevocably.

Jan 1, 2002

By G. T. Adel

This paper presents the highlights of a general-purpose simulator for mineral processing plants that is being developed at the University of California, Berkeley. The state-of-the-art structured design methodogy based on a top-down design approach is being used to construct a modular and completely structured simulator such that it is independent of the unit operation models and routines. The simulator provides for two levels of operation allowing prebuilt or user-built simulation flowsheets depending upon the degree of computer knowledge expected of the user. The philosophy used in designing this simulator appears to be unique in the field of flowsheet simulation. The paper also includes a mini-example demonstrating the usage of the simulator.

Jan 1, 1982

By W. Jacobi, F. Steinhausler, A. C. James

INTRODUCTION In 1979 the Committee on Radiological Protection and Public Health of the Nuclear Energy Agency (OECD) defined a programme of work needed to improve radon dosimetry and monitoring. A Group of Experts in this field was established by the NEA and at the first meeting of the Group the authors were designated an initial task with the following terms of reference:- To review dosimetry of radon, thoron and their daughters, and in particular:- - to examine analytical models for the assessment of dose to individuals who are exposed to aerosol mixtures of these nuclides; - to examine the state of knowledge of the characteristics of aerosol mixtures of these nuclides and other factors that influence the dose to the lung, and identify those parameters which should be measured for dosimetric purposes in radiological surveillance programmes; - to identify areas where further study or research are needed. In this presentation we attempt to examine, with these objectives, the relationship between exposure to radon and thoron daughter aerosols expressed in terms of the working level month l (WLM), or its SI equivalent, and dose accumulated by sensitive tissues of the lower respiratory tract. Over the past two decades many attempts have been made to calculate the lung dose equivalent to l WLM exposure in mine atmospheres, usually in terms of the maximum dose to basal cells in a small part of the bronchial tree. The calculations have employed variously detailed models of airway anatomy, aerosol deposition, ciliary clearance and dosimetry of tissue at the bronchial surface, and are well reviewed elsewhere (Walsh, 1970; UNSCEAR, 1977; Jacobi, 1977; Fry, 1977). They agree in the conclusion that basal cells in segmental bronchi (between about the third and fifth bronchial generations) receive the highest dose, although estimates of this dose differ by more than an order of magnitude, ranging from about 0.2 to 12 rads per WLM (2 mGy to 120 mGy). The most critical parameters of these models are the assumed depths of basal cells below the bronchial surface and the fraction of the WL carried by free ions. When more realistic values of these parameters are substituted (Jacobi, 1977), the dispersion in calculated maximum doses to basal cells is reduced to give a much smaller range from about 0.3 to 1 rad/WLM (3 to 10 mGy/WLM). The parameters and methods employed in these various models, however, remain too diverse to infer the sensitivity of the dose conversion to practical variations in aerosol characteristics and the additional factors determining lung deposition and clearance. We have therefore taken the approach of developing newer models (Jacobi and Eisfeld, 1980; James et al, 1980) that can encompass the range of available experimental data on the physical and biological behaviour of radon and thoron daughters and also accommodate the different interpretations that can be put upon them. We have paid particular attention to the averaging of dose over tissues of equal sensitivity in the lung

Jan 1, 1981

By R. D. Hansen, R. R. Klimpel

This paper discusses the influence of frother type and dosage on recovery/selectivity in coal/sulfide mineral flotation as a function of particle size. It is shown that different frother structures exhibit quite different but consistent performance characteristics depending on the underlying particle size ranges involved as well as the dosage levels of both the frother and collector. The data presented on existing commercial frothers and some new special purpose experimental frothers is used to illustrate some general operator guidelines on proper frother selection and use.

Jan 1, 1987

By K. N. Han

A kinetic model for the batch leaching of various metals using different lixiviants was developed. The overall material balances for the reactants and products at the solid/ liquid interface were formulated for various types of heterogeneous reactions at the interface. The solutions to these mass balances are identified analytically, as well as numerically. Applications of these numerical solutions to various leaching systems using rotating discs or powders are discussed. The metal-dissolution systems addressed include cobalt, nickel and copper in acid, cyanide and ammoniacal solutions.

Jan 1, 1996

By III Basham

As environmental laws and regulations become more complex and the economic cost of non-compliance becomes greater, periodic assessment of environmental compliance, identification of potential liability and implementation of any necessary remedial action should be a standard part of the operational methods of any successful business. The title of this paper "Environmental Audits, A Shield, A Sword or A Trojan Horse?" is intended to draw attention to the fact that environmental audits can be used positively to shield a business operations from actual or potential environmental liability; can be used proactively as a &apos;sword" in both a marketing context ("do business with us because we conduct our business safely and professionally?) and as a mechanism for developing positive relationships with environmental regulators; and, used negatively, as a "Trojan horse", by developing information which those same environmental regulators (or the public) use in an enforcement context against your business or that of your clients. This paper will discuss the concept of environmental audits in general; the pros and cons of conducting the same; and the role of the attorney, as part of the "audit" team, to insure, to the greatest extent possible, that the audit process is productive from both a managerial and legal perspective.

Jan 1, 1992

By K. J. Reid

A historical background of the development of automated material balance packages is presented including a summary of currently available packages and a description of the present work at the Mineral Resources Research Center of the University of Minnesota. A brief mathematical statement of the problem is given and solution techniques discussed. The problems and difficulties normally associated with material balances, both hand calculated and computer calculated are described. Several aspects of the available material balance packages as related to the "user/computer" interface are evaluated in detail. Elements of the material balance packages that affect the solutions are examined and the relative performance of the main packages on specialized problems presented. Finally, areas associated with automated material balances that require further work before computer packages can be widely used in industry are outlined.

Jan 1, 1982