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By G. A. Campbell

This paper considers the international market trends of the rare earths and how they are strongly influenced by the by-product/co-product nature of their mining and processing. The two main economic minerals for the rare earths are bastnasite and monazite. Monazite is primarily a by-product of mining ilmenite and rutile and is affected by changes in these markets as well as the presence of thorium. Bastnasite is a by-product of mining iron ore in China and a stand-alone product in the USA. The paper will use conceptional relationships and empirical data to delineate the various by-products/co-products relationships and how they determine observed international market behavior.

Jan 1, 1996

Projections of coal reserves in Central Appalachia are essential for long-term planning in the region. Annual production is declining in some states, such as Virginia, and mineable reserves for the Central Appalachian Coalfield are challenged by difficult geological, mining, and market conditions. In order to project coal mining longevity in this region, interviews with mining companies were conducted to assist in the determination and assessment of technical and economic factors that impact coal seam mineability. This information was applied to seam and coal reserve data developed by state and federal governments. The results were carefully analyzed to determine the effects of various factors on the overall mineable coal reserve base.

Jan 1, 1998

By D. W. Fuerstenau

In mineral processing, the last century of the current millenium has been the century of froth flotation. The process did not result from fundamental research, but was developed over the years by empirical methods. In more recent years, our understanding of the fundamental principles of the flotation process have made significant strides. This paper reviews some of the historical perspectives of developments in flotation reagents, the development and application of experimental tools for delineating flotability and interfactial phenomena, advances in flotation fundamentals, and the development of flotation kinetics, both macroscopic and microscopic subprocesses. Through the application of surface chemistry, the flotation process has permitted economic utilization of a vast array of complex ores.

Jan 1, 1999

By Leonard H. Hoyle

The American Society of Association Executives is a professional society composed of nearly 10,000 individuals who serve as salaried executives on the staffs of more than 6,500 associations. Represented is the full range of international, national, regional, state and local associations...including trade associations, professional societies, philanthropic organizations and others. The dramatic growth of ASAE during the past 15 years is a manifestation of the growth of the association movement during the past two decades. This is not to imply that associations are a new phenomenon, because they have existed for thousands of years. Ancient civilizations show evidence of groups formed for mutual protection and advancement. In the transition from ancient to medieval time, trade associations and guilds came to serve an important function for the craftsmen and merchants they represented, encouraging the growth of new industries, improved processes and education.

Jan 1, 1981

By K. L. Bickel

Catalyzed diesel particulate filters (CDPFs) are used for reducing diesel particulate matter (DPM) concentrations in underground mines. The U.S. Bureau of Mines is conducting research on how catalyzed diesel particulate filters perform. Two CDPFs, with two different catalysts, are used on vehicles in two mines. The CDPFs are periodically removed from service and evaluated in the laboratory to determine their DPM collection efficiency, regeneration temperature, and effects on gaseous hydrocarbon (HC) and carbon monoxide (CO) emissions. This report summarizes the results of the laboratory evaluation, and the mines' experience with the CDPFs. Both CDPFs have operated over 2,000 h. One was evaluated after 1,646 h; its collection efficiency at one operating condition was 87.3 pct. After 2,135 h of operation it was removed from service because it was damaged. The second CDPF continues to be used after 2,328 h of service. The laboratory evaluation indicated its collection efficiency decreased after 1,584 h of use and its regeneration temperature increased from 405' C to 420' C. The mines' experiences with the two CDPFs varied. While being used on mine vehicles, both CDPFs became plugged with DPM on a number of occasions because of insufficient regeneration. CDPFs are capable of lowering DPM concentrations in diesel exhaust. They can also lower emissions of CO and HC, depending on the type of catalyst used. In this study, the performance of the CDPFs changed with use. Recommendations are given in this report for proper use of CDPFs in mines.

Jan 1, 1994

By G. Buchan

This paper discusses the design of long panels for longwall mining at Twentymile Coal Company (TCC) from conception to implementation. The case study of the long panels at Twentymile includes extensive mine plan reengineering in the early 1990's to world record production months in 1996 and 1997. The obstacles of subsidence engineering, environmental regulations, conveyance, ventilation, equipment design, and continuous miner (CM) development timing had to be overcome to successfully begin longwall production within a 4 year time frame. The background and some detail for each of these areas listed will be discussed to show how the coordination of many facets must be pulled together to implement a successful long panel mine plan.

Jan 1, 1998

By S. M. Robinson

Wollastonite is recognized as one of the most unique, non-metallic minerals in the world. Its history for use in industrial applications is recent compared to other minerals, however, its distinctive physical properties, such as acicular particle shape, and alkaline pH creates incorporation possibilities ranging from bowling balls to automotive fascia, from ceramic tiles to automotive brakes, and from thermal insulation board to industrial and trade sale coatings. Its future use will be impacted by the exploitation of deposits which will ensure maintenance of the acicularity and purity of this naturally occurring mineral. Additionally, closely held surface treatment technology will open up additional niches requiring highly engineered performance.

Jan 1, 1995

By Stephen B. Castor

The rare earth elements (REE) which include the 15 lanthanide elements (Z = 57 through 71) and yttrium (Z = 39) are so called because the elements were originally isolated in the late 18th and early 19th centuries as oxides from rare minerals. Most REE are not as uncommon in nature as the name implies. Cerium, the most abundant REE (Table 1), comprises more of the earth's crust than copper or lead. Many REE are more common than tin and molyb¬denum, and all but promethium are more common than silver or mercury (Taylor, 1964). Promethium (Z = 61) is best known as an artificial element, but has been reported in very minute quantities in natural materials. Lanthanide elements with low atomic numbers are generally more abundant in the earth's crust than those with high atomic numbers. In addition, lanthanide elements with even atomic numbers are two to seven times more abundant than adjacent lan¬thanides (Table 1) with odd atomic numbers. The lanthanide elements traditionally have been divided into two groups: the light rare earths (LREE), lanthanum through eu¬ropium (Z = 57 through 63); and the heavy rare earths (HREE), gadolinium through lutetium (Z = 64 through 71). Although yttrium is the lightest REE, it is usually grouped with the HREE to which it is chemically and physically similar. The REE are lithophile elements (elements enriched in the earth's crust) that invariably occur together naturally because all are trivalent (except for Ce+4 and Eu+2 in some environments) and have similar ionic radii. Increase in atomic number in the lanthanide group is accompanied by addition of electrons to an inner level rather than the outer shell. Consequently, there is no change in valence with change in atomic number, and the lanthanide elements all fall into the same cell of the periodic table. The chemical and physical differences that do exist within the REE group are caused by small differences in ionic radius, and generally result in segre¬gation of REE into deposits enriched in either light lanthanides or heavy lanthanides plus yttrium. The relative abundance of individual lanthanide elements has been found useful in the modelling of rock-forming processes. Comparisons are generally made using a logarithmic plot of lanthanide abundances normalized to abundances in chondritic (stony) meteorites. The use of this method eliminates the abundance vari¬ation between lanthanides of odd and even atomic number, and allows determination of the extent of fractionation between the lanthanides because such fractionation is not considered to have taken place during chondrite formation. The method is also useful because chondrites are thought to be compositionally similar to the original earth's mantle. Europium anomalies (positive or negative departures of europium from chondrite-normalized plots) have been found to be particularly effective for petrogenetic modelling. REE were originally produced in minor amounts from small deposits in granite pegmatite, the geologic environment in which they were discovered. During the second half of the 19th century and the first half of the 20th century, REE came mainly from placer deposits. With the exception of the most abundant lanthanide el¬ements (cerium, lanthanum, and neodymium), individual REE were not commercially available until the 1940s. Since 1965, most of the world's REE have come from two hard rock deposits: Mountain Pass, United States, and Bayan Obo, China. GEOGRAPHIC DISTRIBUTION OF REE DEPOSITS More than 70% of the world's REE raw materials come from three countries: China, the United States, and Australia. China emerged as a major producer of REE raw materials during the 1980s, while Australian and United States market share decreased dramatically (Fig. 1). Table 2 gives recent annual production figures along with estimated reserves by country, and Fig. 2 shows loca¬tions of significant REE mining. MINERALS THAT CONTAIN REE Although REE comprise significant amounts of many minerals, almost all production has come from less than ten minerals. Table 3 lists minerals that have yielded REE commercially or have po¬tential for production in the future. Extraction from a potentially economic REE resource is strongly dependant on its REE miner¬alogy. Minerals that are easily broken down, such as bastnasite, are more desirable than those that are difficult to dissociate, such as allanite. In general, producing deposits contain REE-bearing min¬erals that are relatively easy to concentrate because of coarse grain size or other attributes. For more thorough discussions of REE¬bearing minerals see Mariano (1989a) and Cesbron (1989).

Jan 1, 1994

By C. I. Basilio

The adsorption of dialkyl di-and mono-thio-phosphinates on gold, silver and gold-silver alloys has been studied in the present work. These reagents, which are selective collectors for sulfide flotation, have been found to improve precious metals recovery from ores. Voltammetric studies have indicated that dithiophosphinate adsorbs on gold at much higher potentials than on silver, while monothiophosphinate adsorbs only on silver. However, both adsorb on gold-silver alloys with the adsorption potential decreasing with increasing silver content. Using FTIR spectroscopic measurements, the surface species formed during the interactions of these collectors have been identified. The results of the electrochemical and spectroscopic measurements have been compared with the contact angle data obtained at controlled potential conditions.

Jan 1, 1992

By J. A. Bowersmith

The environment in which the surface mining industry operates today is considerably different than that of a few years ago. Increased pressure from the public, government, labor and internal industry factors calling for the fulfillment of rapidly changing expectations is especially intense in the surface coal mining industry. Such things as requirements for increased production, the Mine Health and Safety Act, environmental concerns and land reclamation, shortages of qualified and enthusiastic employees and market cycles coupled with price competition are but some of the specific items that are requiring the surface mining industry to better utilize equipment, materials, and labor resources available, There is one technical tool available which will assist management to increase productivity, improve cost control and assist in planning, organizing and operating surface mines. Industrial Engineering is that tool. Before a discussion of specific applications of Industrial Engineering to surface mining is conducted, it is worthwhile to review a definition of Industrial Engineering and the history of its development. The following definition has been adopted by the American Institute of Industrial Engineers: "Industrial Engineering is concerned with the design, improvement and installation of integrated systems of men, materials and equipment. It draws upon specialized know- ledge and skill in the mathematical, physical and social sciences, together with the principles and methods of engineering analysis and design, to specify, predict and evaluate the results to be obtained from such systems."

Jan 1, 1976

By R. R. Oder, R. J. Gray

We report measurements of the effects of rank, type, and grade of coal on grinding energy and grinding media consumption in a Pitt Mill. The rank of coal has a greater effect on grinding energy than does coal type. The effect of coal grade on grinding energy depends upon the relative grindability of the mineral matter and of the hydrocarbon components of the coal. The mineral matter is primarily responsible for abrasive media wear in a Pitt Mill. The widely recognized HGI test for coal breakage may yield misleading results, particularly for multiple-banded bright and dull coal where the screening procedure used in sample preparation favors the testing of the hardest coal fraction. The work reported here indicates that the Pitt Mill, which grinds the whole coal in a single stage and which yields easily interpreted results, is an excellent candidate for testing coal pulverization characteristics including energy requirements and equipment wear. The measurements of the effects of coal characteristics on grinding energy and on media consumption have been used to estimate the cost of fine grinding in a Pitt Mill. The results, based on a conceptual level evaluation of grinding at the rate of 1 TPH, show that there are trade-offs possible between the cost of energy and cost of media consumption which involve choice of grinding media size. The use of fine-size grinding media to lower grinding energy and to increase throughput can be deceptive because the total cost of grinding must consider both energy and media consumption.

Jan 1, 1992

By X. Zhu, Chen. L., R. Guru, M. Peiravi, M. Mohanty, L. Ackah, B. Xu

"The overall goal of this study is to develop a suitable flow sheet to extract rare earth elements (REEs) from coal ash. A total of 14 coal samples of different ranks were examined for REE concentration, and an anthracite coal sample with the highest REE concentration of more than 700 ppm in the coal ash was selected for REE extraction tests. This paper reports on the results of the experimental program completed in the first part of the study, which included hightemperature leaching with nitric acid followed by solvent extraction tests using various organic extractants, namely, tributyl phosphate, Cyanex 572, di-(2-ethylhexyl)phosphoric acid (D2EHPA) and their combinations. A 4×2×2 experimental design was used to conduct a total of 32 high-temperature leaching tests by varying acid molarity at four levels, solids content at two levels and leaching time at two levels. The highest recovery rates of 90 percent for light rare earth elements (LREEs) and 94 percent for heavy rare earth elements (HREEs) were obtained from the optimum leaching test conditions while maintaining impurity recovery to the leachate at less than 40 percent. D2EHPA was found to be the best extractant in this solvent extraction test series, providing an REE recovery rate of nearly 99 percent.IntroductionGlobal demand for rare earth elements (REEs) and other strategic metals is increasing rapidly due to their use in a variety of advanced technological applications, with more than 100 kt of rare earth oxides used worldwide on an annual basis. The United States has less than 10 percent of the world reserves of REE mineral deposits, and in 2013 imported more than 60 percent of its rare earth oxides from other countries, mainly China (United States Geological Survey, 2017). China’s institution of export quotas has significantly reduced supply to the United States, raising the urgency of finding new ways of producing REEs and/ or substitutes. Coal combustion byproducts, which are usually discarded as waste materials, are known to contain REEs in low concentrations that could be extracted with a suitable process flow sheet. This may be a worthwhile route to pursue, considering the short supply of rare earth minerals and the abundance of coal ash in thousands of ash ponds in the United States. More than 110 Mt of coal combustion byproducts are produced annually in the process of satisfying the country’s need for electricity (American Coal Ash Association, 2016), and less than 50 percent of these byproducts are being successfully used in various applications, with the remainder dumped as waste materials in landfills and ash ponds."

Jan 1, 2017

By S. Chander

The use of various electrochemical techniques to study mechanisms of sulfide mineral- flotation reagent interactions is briefly reviewed in this paper. Prior to such studies it is desirable to thermodynamically determine solution conditions favorable for formation of hydrophobic species deemed to be responsible for flotation. The thermodynamic equilibrium involving both the stable and metastable species can be conveniently represented by an Eh-pH diagram. Thermodynamics can also be used to predict conditions where a mineral might not float if depressants are present. Under favorable conditions of flotation there is competition between reactions leading to formation of hydrophobic species with reactions that lead to formation of hydrophilic species. Due to the sluggish nature of the reactions involving sulfide minerals, a knowledge of the kinetic behavior of the system is necessary. Electrochemical methods of investigation are wed in laboratory studies to (1) control the state of oxidation, (2) determine the type and amount of electroactive species present at the mineral surface, and (3) study kinetics of electrode processes. By combining electrochemical techniques and wetting measurements the identification of hydrophobic species that might be present at the mineral surface could be achieved. Both contact angle measurements at mineral electrodes or flotation in a cell equipped with a particulate bed electrode can be used for the wetting measurements.

Jan 1, 1987

By Robert W. Leonardson

The Questa Molybdenite Mine provides a unique opportunity to study the geochemical dispersion of various hydrothermal events, utilizing drill hole analyses. Numerous post-ore factors have altered the primary ore-related geochemical dispersions to the present day configuration, e. g. dikes, faults, hydrothermal convection cells, and weathering. Due to the interaction of an andesitic volcanic pile with the silicic-alkalic generated volatiles, the geochemical haloes of the Goat Hill deposit demonstrate a marked divergence from the classic Climax-type molybdenite ore body. Certainly, however, the similarities to the Climax-type ore body are apparent as potassically-rich fluids have invaded the highly reactive country rock.

Jan 1, 1984

The purpose of this paper is to describe two systems designed to provide estimations in stratigraphic orebodies for the purposes of detailed mine planning. The first is a completely geostatistical approach and the second is a combined geostatistical/deterministic approach. The essential features of both systems are the estimation of stratigraphic ore boundaries and the subsequent use of those boundaries to provide stratigraphic (or zonal) control for block and point grade estimation (kriging). Both systems are illustrated by application to a section of, the Hilton orebodies, Queensland, Australia.

Jan 1, 1989

By T. K. McMahon

Formally, a mathematical model could be defined as: A set of equations whose solution will approximate the response of a physical process or system to a set of stimuli which appear as parameters in the equations. The purpose of a mathematical model is to permit the rationalization of experience to proceed by simulation rather than by physical experimentation. In the application of digital computer control to an industrial process, the mathematical model of the process (subsequently called the process model) is needed to calculate the present process performance from the measured variables and to predict the response of the process to a control change. Functionally, the cardinal element in process model development is a concise set of control objectives. These, besides implicitly defining the boundaries of the system to be modeled, will determine the accuracy demanded of the model its nature: dynamic or steady-state, and so forth, The objectives should explicitly define what process efficiencies, production rates, qualities are to lie within the scope of the computer control project, thereby providing a basis for simplifying assumptions in the development of the model. This requirement, a limited set of control objectives, is so often disregarded in formulating industrial control problems that its repetition can scarcely be avoided.

Jan 1, 1965

Refractory gold concentrates often contain sub-microscopic gold that is encapsulated within the crystal matrix of iron sulphide minerals such as pyrite, pyrrhotite and arsenopyrite. To recover the gold, the host mineral must generally be broken down chemically, by oxidative processes such as roasting, pressure oxidation or bacterial leaching, which expose the gold for subsequent recovery by leaching in cyanide solution. The focus of attention in these pre-treatment processes is usually the oxidation of the sulphides to elemental sulphur, sulphur dioxide gas or sulphate ions. Less attention is paid to the deportment of iron and the changes in its oxidation state, although this can have a profound effect on gold and silver liberation, as well as down stream operating costs. Iron sulphide minerals break down completely during pressure oxidation, and dissolve in the sulphuric acid solution that is generated from oxidation of the sulphides. This liberates the tiny gold particles that were originally trapped in the sulphide crystals, and gold recovery during subsequent cyanidation is usually very high (>95%). Iron goes into solution in the oxidation process, initially as ferrous sulphate, but this is rapidly oxidized to ferric sulphate, which then hydrolyzes and re-precipitates. The form of the precipitate varies depending on the operating conditions in the autoclave and the presence of certain metal cations. When the acidity in the autoclave is quite low (<20 g/L H2SO4) and the temperature is high (>200OC) the formation of hematite is favoured. When the acidity is high (>20 g/L H2SO4) and the temperature is relatively low (160 to 200OC), the formation of basic iron sulphate is favoured. If the ore or the leach solution contain significant levels of certain cations (such as Na+, K+, NH4+, Ag+ or Pb2+) and the acidity is high (>20 g/L H2SO4), jarosite compounds are favoured. Hematite is the desired iron product in the autoclave discharge, for both metallurgical and environmental reasons, but it is difficult to operate an autoclave under the conditions required for effective liberation of gold without converting some of the iron to basic iron sulphate and/or jarosite. These compounds fall into a category of iron compounds known generically as iron hydroxy sulphates, all of which can cause significant processing and environmental problems in the downstream gold process. This paper deals specifically with basic iron sulphate; the conditions under which it is formed in an autoclave, the problems that are caused by its presence in the feed to a cyanidation plant, and possible remedial strategies that can be adopted, both in the autoclave and downstream.

Jan 1, 2010

By Tsuneyoshi Funazaki, Takayoshi Nakamura, Keizo Miki, Takashi Imaishi

The underground portion (about 10 km) of Tokyo Wan Aqua-Line consists of eight shield tunnels connected with Kawasaki Man-Made Island in between, at four underground locations. The connection work had to fulfill strict precision and safety requirements in the ground about 60 m below soft seabed, but was completed successfully in May 1997. This report describes the connection work in detail, featuring the method of investigating shield machines’ relative positions, ground freezing method and connection mechanism and procedures. It also mentions the present state of Tokyo Wan Aqua-Line that was put in service on December 18, 1997.

Jan 1, 1999

By S. J. Ristorcelli

Historically, geologic data has not been adequately considered in resource estimation. More recently, with the use of computers and sophisticated estimation algorithms and geostatistical justifications, geology has been downplayed further. Many reasons are given for not using geology including cost, time and irrelevance. None are valid. Boundaries defining mineral domains should be used in computer-generated resource estimates. Selected case histories show how the failure to honor geology has caused discrepancies in resource estimates of actual in-place resources. After-the-fact differences have included decreases in tonnage of up to 50% and increases up to 300%; partial to complete recategorization of material; and 50% decreases in grade. The costs of gathering and using geology are trivial compared to the potential consequences.

Jan 1, 1994

By C. L. Karr

Establishing suitable control of pH, a requirement in a number of mineral and chemical industries, poses a difficult problem because of inherent nonlinearities and frequently changing process dynamics. Researchers at the U.S. Bureau of Mines have developed a technique for effectively controlling such systems. This technique successfully combines the process control capabilities of fuzzy logic and the search capabilities of genetic algorithms. Fuzzy logic offers an effective mechanism for handling nonlinearities, while genetic algorithms can provide fuzzy logic controllers with real-time adaptive capabilities. This Bureau-developed technique is applied to a laboratory acid-base neutralization experiment. Nonlinearities in the laboratory system are associated with the logarithmic pH scale and the changing process dynamics are due to alterations in pH and buffering capacity input solutions. Results indicate fuzzy logic controllers augmented with genetic algorithms offer a powerful alternative to conventional process control techniques in such nonlinear, rapidly changing systems.

Jan 1, 1992