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By Alper Kirmaci, Taghi Sherizadeh, Dogukan Guner, Cameron Mitchel

Brow hazards are a significant concern in coal mine ribs and form when weak coal sloughs out of a rib face and exposes an overhanging block of more competent rock or coal. Of 36 rib failure fatalities in the last two decades, 36% resulted from rib brow failures. This highlights the need to better understand the mechanisms driving brow formations and failures to mitigate this hazard and eliminate potential fatalities. The research team at Missouri S&T worked to enhance the current CPRR system and include the potential for these brow hazards. We employed physical modeling methods to build a scaled model from critical brow cases observed in the field. The dimensions and properties of the models were scaled down by 14.4 times from the field cases. The results of the physical modeling efforts were used to assist in calibrating distinct element numerical models vital to understanding brow formation and failure mechanisms. Subsequently, three physical models were created and tested to provide data on an otherwise impossible-to-capture event at the field scale. The results of these tests provided formed brow dimensions that agree well with those observed at the field scale. The brow dimensions were 1.25 inches deep into the rib, equivalent to 1.5 feet when scaled up. Similarly, the numerical modeling efforts provided good agreement by capturing a brow forming 1.55 inches deep into the rib. The physical model results further validate the applicability of physical modeling efforts for capturing otherwise difficult and dangerous phenomena in a controlled lab setting.

Feb 22, 2026

By M. K. Han, K. N. Han, P. B. Queneau, W. J. Dawson

The development and scale up of hydrothermal synthesis processes for manufacture of high performance materials is discussed. Traditional hydrometallurgical processes are reviewed, leading into a discussion of process development concerns for manufacture of modern materials. Three case studies are presented, including a piezoelectric ceramic, barium titanate for multiyear capacitors, and high purity chromium metal. Factors for selection of reactor design are presented, as well as results of scale-up studies on the three products.

Jan 1, 1993

By P. Somasundaran, J. T. Kunjappu

Spectroscopic techniques are becoming increasingly popular for characterizing the interior of adsorbed layers of surfactants and polymers at solid- liquid interface as well as in the identification of com- pounds on mineral surfaces. This review encompasses the application of fluorescence and ESR spectroscopic techniques to reveal the microscopic environment of the adsorbed layers of surfactants and polymers on minerals with a special reference to the adsorption of anionic surfactants (e.g., sodium dodecyl sulfate) and polyelectrolytes (e.g., polyacrylic acid) at positively charged mineral (e.g., alumina) - water interfaces. Finally, the utility of XPS and auger techniques to identify the surface elemental composition of different mineral species has been related to their flotation efficiency.

Jan 1, 1987

By Y. B. He

The effect of the overflow to underflow (O/U) flowrate ratio of a dense medium cyclone on its performance is tested utilizing a 6" dense medium cyclone and density tracers. The results show that the O/U flowrate ratio is clearly correlated with the separation cut point D50, the separation efficiency Ep, the density differential 0, and short circuiting of the cyclone. Within certain limits, a higher O/U ratio results in a better separation efficiency, a higher D50 and an increased density differential. A lower O/U ratio, on the other hand, reduces the cut point shift and density differential. The phenomenon of short circuiting to the underflow, which is especially significant for fine particles, is directly connected with an excessively low O/U ratio.

Jan 1, 1992

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Jan 1, 1985

By H. A. Taylor

Bismuth, one of the heavier chemical elements, is a pinkish metalloid that is chemically related to antimony. It is a byproduct of lead and tungsten extraction and, to a lesser extent, of copper and tin extraction. Antimony is a metalloid and less heavy chemical element, an extraction coproduct of metals such as lead, silver and gold. While both bismuth and antimony are metalloids, their major uses are as chemical compounds. The most frequently updated resources that always cover bismuth and antimony are the Bismuth Advocate News (BAN) and link at www.basicsmines/bismuth and the frequently updated Basics Mines Update blog at http://basicsmines-update.blogspot.com. The Bismuth wiki on Wikipedia also can be very helpful.

Jan 1, 2010

The paper presents results of the mineralogical examination on samples from a bacterial leaching test which simulated in situ leaching for 482 days. Rock fragments (15 to 20 cm) were obtained from the top, the middle and the bottom of a bioleach column. Examination of the samples was carried by electron microscopy and image analysis. The surfaces of the rock fragments were studied to characterize the precipitation products, and cross-section cuts were studied to assess the advance of the bacteria leaching front and the dissolution of the different sulphide minerals.

Jan 1, 1991

By J. Swensen, R. Brandon, A. Wallstein, S. Bessinger, J. Pile

It is generally agreed that C.C. White was the first to describe and market coal mine roof trusses beginning as early as 1967. White was issued a patent in 1969 1. Coal mine roof trusses were extensively used in the 1970’s, and their use has proven valuable in many difficult conditions. Beginning in the mid 1990’s, several types of bar/cable trusses have been introduced. A new and innovative bar/cable truss recently introduced offers several advantages. By eliminating many small parts, and simplifying the installation, these new trusses are much easier and faster to install, thereby increasing operator safety.

Jan 1, 2004

By S. Behl

A major limitation in developing successful selective flocculation schemes is the difficulty encountered in adsorbing the polymeric flocculant only on the desired substrate. In this paper a correlation between selectivity of flocculant adsorption and separation efficiency is outlined and a potential technique to achieve selective adsorption of flocculants is discussed.

Jan 1, 1992

By N. Kuyucak

Acid rock drainage (ARD) resulting from the natural oxidation of sulfide mineral wastes has become a major concern to the mining industry, both during the operational period and after mine closure. ARD is generally characterized by high acidity and high concentrations of dissolved metals and sulfates. If the generation of acid cannot be prevented or controlled, it must be treated to eliminate acidity and to reduce the concentration of heavy metals and suspended solids before release to the environment. Microorganisms play an important catalytic role in the generation of ARD. Several prevention, control and treatment technologies that are based on microbiological activities have been developed. The role of microorganisms and biotechnology in the generation of ARD and their role in the methods used for prevention, control and treatment are discussed in this paper. Recently developed passive and biological treatment processes that have been implemented at mine sites are emphasized in this paper. Benefits, limitations and design criteria for passive biological processes are also presented.

Jan 1, 2000

By M. J. Zdunczyk

The final 1995 figures on industrial sand and gravel have not yet been compiled by the US Geological Survey (USGS). There is usually about a nine-month lag time in receiving and compiling this information. However, USGS estimates that domestic production of industrial sand and gravel will increase about 4% to 28.2 Mt(31 million st). The average unit price is expected to increase as well. The top five producers during 1995 were Unimin, US Silica, Fairmount Minerals, Oglebay Norton and Morie Co. Glass manufacturing for containers, automobiles and buildings was mixed during 1995. Containers, the largest consumer of silica sand, remained steady, with regional increases. However, silica use in glass containers face increased competition from plastic and recycled glass (cullet). It was reported that the Pepsi Cola announced plans to replace glass containers with plastic during 1996.

Jan 1, 1996

By W. L. Price

Since first introduced in the United States in 1964, rail mounted bucket wheel stacker-reclaimers have gained wide acceptance by users. The coal burning power plant group has adopted this new storage tool most quickly. The actual history is traced in this area in some detail. Installations in phosphate and steel mill ore storage and a listing of present users are included.

Jan 1, 1969

By John D. Kalasky

Island Creek Coal Company has had, for many years as a primary concern, the activity of handling large quantities of methane in the ventilation of its deep mines of southwest Virginia. Since the development of the Beatrice operation in the mid 19601s, the concern has been well founded, and through the years progress has been made in this most important facet of the extraction of the coal reserves to insure the safety of the employees engaged in the mining opera- t ions.

Jan 1, 1980

By Thomas A. Wheeler, Robert O. Keys

The choice of the flotation reagent that suits a particular coal has become more complicated with the development of new, more efficient reagents. Frothers and conditioning reagents, in particular, have experienced a dramatic reevaluation of their role in floating various types of coals. This paper offers a better understanding of how each of the following factors contributes to the reagent selection: 1. Natural Flotability 2. Degree of Oxidation 3. Size Distribution 4. Percent Solids in Feed Slurry 5. Fluctuations in Plant Feed 6. Limitations on Froth Handling 7. Clean Coal Specifications 8. Ash Content in Feed a) discrete ashable minerals b) inherent ashable minerals 9. Water Chemistry 10. Petrographic Composition of Coal 11. Free-Swelling Index 12. Convictions of Customer The application of conditioning reagents - both promoters and emulsifiers can substantially improve the coal recovery. Some low-rank, hydrophylic coal, previously considered unfloatable can be economically recovered with the use of the proper reagent.

Jan 1, 1986

By Walter E. Kramer

The advantages derived from the use of pellet burdens in blast furnaces are so great, that hematite ores are being converted into pellets in greater quantities each year. The conversion of these ores into pellets appears on the surface to be relatively simple. In reality, this is not so. Serious difficulties are encountered in drying these pellets that do not exist in the drying of taconite concentrate pellets. The ores that present problems are goethite and earthy hematites. Green pellets prepared from these ores have very law shock temperatures, 200-600° F. The shock temperature of a green pellet according to our definition is the highest initial temperature to which a green pellet may be exposed without suffering decrepitation. Decrepitation may involve spalling, fracturing or total disintegration. The poor shock properties of these green pellets result from the inability of the vaporized water to escape freely and easily as it is formed with¬out affecting the integrity of the pellet. As a consequence, the pellets must be carefully dried prior to induration. This careful treatment is costly. The slow drying process restricts productivity and requires larger furnaces than desired. The use of an additive to elevate the shock temperature of the green pellets would increase productivity. Bentonite is used in some pellet plants to improve balling but it raises the shock temperature only slightly. Nalco became interested in the shock temperature problem because of its activity in the development of organic pelletizing aids for taconite concentrates. The findings reported here are an outgrowth of our experimental work on the development of shock temperature additives.

Jan 1, 1967

By Robert R. McDougal, Anne E. McCafferty, Bruce D. Smith

Magnetic, electromagnetic, and radiometric airborne survey data have been used in regional and local (drainage basin) scales. In a regional geoenvironmental assessment of the state of Montana, magnetic and radiometric data compiled from airborne surveys were used along with other digital geologic and geochemical data to prioritize mining districts for potential acid water generation. Probability ratio mapping was done in order to integrate the interpretation of many different digital data sets. On a more local scale, the Animas (CO) and Boulder Basin (MT) watersheds have been studied using helicopter geophysical surveys. The airborne geophysical surveys show many more structural features than the geologic maps. Combined interpretation of the geophysical data sets using the probability ratio method has resulted in identification of areas of alteration. Airborne radiometric data in the Boulder Basin area suggests that rocks with high potassium and thorium also have a high acid water buffering capacity.

Jan 1, 2000

By M. S. Celik

Unlike most other minerals, electrokinetic measurements of calcium montmodonite (a clay mineral) and u1exite (a boron mineral) exhibit an unusual behavior. While the addition of monovalent salts such as NaCI and KCI is expected to compress the electrical double layer with a resultant less absolute charge, an opposite trend is observed. A set of systematic experiments with monovalent and multivalent ions has been carried out to understand the mechanism of this phenomenon Examination of the results reveals that the behavior of montmorillonite is dictated by the exchangeable divalent cations at the edges which undergo an exchange process with monovalent cations resulting in the reduction of positive charges. The solubility of ulexite, on the other hand, is found to decrease with increasing monovalent cation concentration leading to again an increase in the absolute negative charge.

Jan 1, 1996

By B. Huang, H. Sevim, R. Honaker

The use of medium-to-high sulfur coals has been negatively impacted by the 1990 Clean Air Act Amendment (CAAA). In this article, a method is demonstrated that can render these coals competitive and yet compliant with Phase II of CAAA. The method uses strategic mining and optimized preparation plant operation to minimize production costs, and it utilizes advanced coal-cleaning technology and an SO2 allowance to produce a compliant coal. The method is illustrated through an example from southern Illinois. For an annual production of 3.2 Mt (3.5 million st) and with a $150/st SO2 allowance cost, it was possible to produce a competitive coal for $0.84/million Btu. The production and allowance costs were $0.608/million Btu and $0.232/million Btu, respectively.

Jan 1, 2002

By D. S. Holmes

Biological processes for metal solubilization and ore beneficiation are in widespread use today. There are also some promising new applications of biotechnology in the areas of metal concentration and toxic metal cleanup. Recent progress in genetic engineering promises both to revolutionize the existing biological process and to expedite the adoption of the new biological applications. But before it can do so effectively, progress must be made in many areas of fundamental research and in biochemical engineering. These issues are addressed with special reference to the biotechnology of semi-enclosed containers (bioreactors), dumps, heaps, in situ and under- ground leaching, and with respect to the biotechnology of metal concentration. Finally, certain biological considerations for bacterial strain improvement are discussed.

Jan 1, 1987

By Jessica Elzea, Haydn Murray

The term bentonite was first proposed in 1898 by Knight, a year after he had named this clay taylorite, because taylorite had been previously used for another mineral. The name taylorite was after the Taylor ranch, the site of the first mine, near Rock River, WY, and the name bentonite is from the Benton Shale in which the clay was thought at that time to occur. The Benton Shale was, in turn, named after Fort Benton, MT, located more than 640 km miles north of Rock River. Early in the 20th century, several geologists recognized that bentonite, mainly in beds in Cretaceous and Tertiary rocks, originated from transported volcanic materials. This recognition led to definitions based on origin, the one most widely quoted and generally accepted by geologists is the following definition by Ross and Shannon (1926): "Bentonite is a rock composed essentially of a crystalline clay-like mineral formed by devitrification and the accompanying chemical alteration of a glassy igneous material, usually a tuff or volcanic ash; and it often contains variable proportions of accessory crystal grains that were originally phenocrysts in the volcanic glass. These are feldspar (commonly orthoclase and oligoclase), biotite, quartz, pyroxenes, zircon, and various other minerals typical of volcanic rocks. The characteristic clay-like mineral has a micaceous habit and facile cleavage, high birefringence and a texture inherited from volcanic tuff or ash, and it is usually the mineral montmorillonite, but less often beidellite." The difficulty in applying the foregoing definition to bentonite as an industrial mineral commodity is that it is based on origin and is restricted to an ash, tuff, or volcanic glass parent material. Therefore, deposits consisting of the clay minerals required by this definition, but having uncertain origin or parent materials, cannot properly be called bentonite. Furthermore, many deposits in the western United States and in other countries that have formed from rocks other than the types required by the definition are being mined and sold as bentonite. Perhaps the best definition of bentonite as an industrial mineral is one given by R.E. Grim in a plenary lecture at the International Clay Conference (AIPEA) at Madrid, Spain, June 27, 1972. According to this redefinition, which will be used in this chapter, bentonite is a clay consisting essentially of smectite minerals (montmorillonite group of some usages), regardless of origin or occurrence. This definition solves the problem of the difference between the geologic and industrial usages of the term and overcomes the difficulty in assigning a name to smectite clay that formed from igneous rock other than ash, tuff, or glass, or those of sedimentary or uncertain origin. However, bentonite, when used with this meaning is still a rock term (consisting of more than one mineral), and it will not be possible to distinguish it from fuller's earth in many instances. One way of classifying bentonite is based on its swelling capacities when wet or added to water. Bentonite having sodium (Na+) as either the dominant or as an abundant exchangeable ion typically has very high swelling capacities and forms gel-like masses when added to water. Bentonite in which exchangeable calcium (Ca++) is more abundant than other ions has much lower swelling capacities than sodium varieties. Some calcium types swell little more than common clay, and most crumble into granular masses in water. Intermediate calcium-sodium bentonites, the so called mixed types, tend to swell moderately and to form gels of lesser volumes than equal masses of the sodium type bentonite. Because of the general relationship of swelling and exchangeable ion characteristics bentonite is commonly divided into the high swelling or sodium, low swelling or calcium, and moderate swelling or intermediate types. The term sub-bentonite (Davis et a]., 1940) is used inconsistently in industry for the low or moderate swelling varieties. The authors believe the use of this term should be discouraged because of its implication of low quality or low value and the lack of a mineralogical or use basis for it. In the United States bentonite is also classified by geographic location and the uses for which it is sold. Inasmuch as most of the low swelling calcium type occurs in states bordering the Gulf of Mexico, this variety is commonly called Southern bentonite. The largest high swelling sodium bentonite deposits and the major producing districts are in Wyoming and adjacent states. Therefore, this bentonite is commonly called the Wyoming or Western type. Such terms as drilling mud bentonite, foundry bond bentonite, and taconite bond bentonite relating directly to use are applied in marketing. Other terms including high and low yield bentonite, high and low gel bentonite, and high and low strength bentonite are also used to distinguish different grades. The varied classifications notwithstanding, bentonite occurs in so many different varieties that some cannot logically be classified according to any of the foregoing groupings. One of these types is hectorite, which is a high swelling lithium-bearing variety of smectite occurring mainly in California and adjacent states. It is, therefore, not a Wyoming type, and it occurs even farther west than the so called western bentonites. Others are bentonites having magnesium (Mg++) or hydrogen (H+) as the most abundant or dominant exchangeable ion. These types are neither sodium nor calcium varieties, and apparently some are low swelling, whereas others have rather high swelling capacities. Still another type of bentonite, the so-called potassium type, K-bentonite, or metabentonite, occurs in Ordovician and other Pa-

Jan 1, 1994