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By T. McCallum, B. Wellbrook, T. Ratnaweera

"Pressure oxidation (POX) leaching of copper (Cu) concentrates continues to be explored as the next generation of leaching processes to sustain existing Cu Solvent Extraction/Electrowinning (SX/EW) operations as easily leachable ores become scarcer. The leach liquors produced, particularly from total pressure oxidation, contain elevated concentrations of Cu and acid, making solvent extraction processing more challenging. Addressing this challenge will require innovative processing techniques and continuous improvement to be successful in achieving satisfactory physical and metallurgical performance in the SX plant. The ability to efficiently process these feeds via SX plays an important role in the continued success of POX technology. Characteristics of a concentrate leach pregnant leach solution (PLS) are discussed, along with best practices that should be considered for processing by SX. Findings discussed in this paper will shed light on ways to reduce process risk and bring additional improvement to the industry with minimal change to the SX plant. INTRODUCTION Hydrometallurgical processing of copper concentrates continues to gain interest from the industry. Treatment by smelting and electro refining continues to dominate, accounting for ~80% of global copper production, but is faced with its own challenges. The case for increased hydrometallurgical processing has been discussed as high grade ore deposits are diminishing, capital costs for smelting are high, and the environmental aspects present challenges for sustainable practice. The hydromet copper industry is also turning a corner as easily leachable copper oxide deposits are depleting, and excess SX-EW capacity exists in certain regions. The transition to hydrometallurgical processing of copper concentrates will take a bit of effort as leaching of copper sulfides is difficult and byproduct credits must be considered. Various POX leaching processes have been studied and proposed to the industry as viable practices. Of the many processes, commercial use has been practiced with the Mount Gordon Copper Process, total and partial pressure oxidation by Freeport-McMoRan at their Bagdad and Morenci, Arizona complexes, the Sepon Copper Process in Laos, and the bioleach BIOCOP™ process in Chile. The experience related to the current paper centers around Cu concentrate leaching performed by Freeport McMoRan (known as CLP). The patented process was developed as an alternative to smelting and refining in 1998. The technology applies to both molybdenum and copper concentrates. Commercial CLP research and development began with Phelps Dodge in 1999 to 2001. The first commercial plant was commissioned in 2003 at the Bagdad operation. Initial operating conditions of the Bagdad CLP were under high temperature conditions before converting in 2005 to medium temperature conditions. In 2007-2009, the CLP technology was commissioned in Morenci, operating medium temperature and high temperature lite conditions until shutting down due to the economic downturn. The Morenci CLP restarted operation in April 2015 due to acid production benefits for the Morenci leach operations. Renewed solvent extraction test work initiated well before restart and has been an ongoing focus for further SX plant optimization."

Jan 1, 2018

By F. M. Doyle, S. Duyvesteyn, K. Sreenivasarao

Toxic metals entering surface or ground water from sources such as metal finishing shop spills and abandoned mines can pose a significant threat to public health and the environment. Ion flotation and similar foam separation techniques show great promise for treating dilute, metal-contaminated solutions, and could also be used to treat effluents from many minerals and metallurgical processing operations prior to discharge. In ion flotation, an appropriate collector is added to the solution to form hydrophobic complexes with the metal ions. These metal-bearing species are then removed by flotation, usually with trace addition of a frother to stabilize the foam. In an effort to better understand the underlying scientific and engineering principles that determine the performance of ion flotation, the removal of Cu(II), Pb(II), Cd(II), Cr(II) and Cr(VI) has been studied using laboratory scale flotation columns in batch mode. The effects of the superficial air velocity, solution and froth height, nature of the collector, collector: metal-ion ratio, ionic strength and several frothers at low concentrations on the flotation kinetics are reported. Finally, results are presented on methods that might allow regeneration of collector and recovery of by-product metal from the foam product.

Jan 1, 1995

By D. M. Avant, A. J. Solomon, S. M. Pickering, W. R. Fox

Introduction Most high purity silica is produced from crystalline quartz, generally from sand. However, there is a small area of southern Illinois where a porous, friable white chert rock is found that is very different in physical form from quartz sand. This microcrystalline material, commonly referred to as tripoli, is more easily ground to micron sizes than sand. Although of similar Moh's hardness, microcrystalline tripoli is less abrasive than either ground quartz sand or many synthetic abrasives. Location The southwestern corner of Illinois is underlain by extensive deposits of very porous chert; in some places the material is quite white. Two companies, Illinois Minerals Co. and Tammsco Inc., mine and process this white material. The Illinois Minerals plant is located at Elco, and the Tammsco plant is in Tamms, IL. Both companies mine from various locations within a 10-mile truck haul of their plants. Production from this district has been continuous since at least 1915. Malvern Minerals Co. mines and processes a generally similar microcrystalline, friable novaculite near Hot Springs, AR. Geology The southern Illinois white tripoli area is on the southern flank of the Illinois Basin. The commercial silica zone is a facies of the Clear Creek chert of Lower Devonian Age. To the north, where it occurs deep in the basin, the Clear Creek is a siliceous limestone. In the mining area, thin overburden has allowed access by surface ground water, which has leached away the carbonate content and left a quite pure silica residue. Fossils characteristic of sea bottom deposition, such as brachiopods and trilobites, are occasionally encountered in mining. The structure of the mining area is poorly known, due to infrequent outcrops. Strata in most mines are inclined at dips of 5° to 20°. There appear to be occasional high angle normal and reverse faults, but these are seldom of any significance in mining. The friable white silica zone mined in the Clear Creek chert is overlain by dark brownish-red chert and siliceous shale. Exploration drilling to date has not encountered the base of the microcrystalline tripolitic zone. Chemical content Leaching by ground water solution has removed virtually all the carbonate from the original siliceous limestone. Impurities encountered are red to yellow iron oxides, aluminous clays, and occasional black manganese oxides. The silica has no detectable formula water. A typical chemical analysis and physical properties are listed in Tables 1 and 2. Mineralogy and crystallinity Southern Illinois friable tripoli appears amorphous under the polarizing microscope. No crystal structure and only occasional, vague, patchy anisotropism is evident. However, the material gives an excellent quartz X-ray diffraction pattern. Thus, so far as X-ray mineralogy is concerned, the material is clearly

Jan 1, 1987

By Jasinder S. Jaspal

The United States has very large coal reserves in seams that are less than 1065 mm (42 in.) thick. These reserves are often not mined because of the difficulty of working in low heights and, in most cases, the seams are beyond the technical or economical limits. It is estimated that the remaining reserves in 355 to 710 mm (14 to 28 in.) thick seams that are not faulted or intruded, dip less than 15° and under a cover of 610 m (2000 ft) or less are nearly 910 Gt (1 trillion st). This is a very large percentage of coal reserves in the United States (Unrug, 1985; DuCarme et al., 1990). The US Bureau of Mines is attempting to develop new techniques for mining 150 to 1065 mm (6 to 42 in.) thick coal seams. Research has focused on existing thin seam mining techniques, testing of small- and full-scale physical models of the Bureau's slot mining concept and computer modeling of the full-scale process. In 1986, only 21 % of the total US coal production came from -1065 mm (-42 in.) thick seams. Of that, 355 to 710 mm (14 to 28 in.) thick seams share of production was minimal, probably 5% or less (Mayercheck et al., 1990). This shows that the thin seams, particularly the seams 355 to 710 mm (14 to 28 in.) thick, have not been mined to the extent of the available reserves. Thin seam coal, generally, is of premium quality. As thicker seams are depleted, the mining of thin seams could become more important. Thus, there is a need to develop technology to mine these seams (J. Farinelli et al., 1987). A successfully applied technology could change reserve categorization. In the Appalachian Plateau there are 417 Gt (460 billion st) in 355 to 1065 mm (14 to 42 in.) seams. This represents nearly 9.2% of the US remaining reserves (Unrug, 1985). At depths of 152 m (500 ft) or less, the Appalachian Plateau has about 214 Gt (236 billion st) of reserves in 355 to 1065 mm (14 to 42 in.) thick seams. Other mining areas also have substantial coal reserves in this seam thickness category. Those, however, are not as attractive for mining as the Appalachian Plateau. In the past, most of the reserves of the Appalachian Plateau region were partially worked by contour and highwall auger mining. It is estimated that these mining systems had left some 40,230 km (25,000 miles) (Readers Digest, 1987) of unreclaimed highwalls. The Bureau recognized this situation. In FY1987, the agency initiated a research project to develop anew technology for mining thin seams of the Appalachian Plateau.

Jan 1, 1992

By Donald L. Meredith, Jeffrey Harris, Donald A. Stanley

Principal Components Analysis (PCA) is a versatile, multivariate statistical method that the Bureau of Mines is applying to mineral processing data to achieve data simplification and pattern recognition. The principal components are obtained from an eigenanalysis of the data matrix. To achieve data simplification PCA replaces a larger number of measured variables with a smaller set of principal components and at the same time removes a significant amount of experimental error. Data simplification and error reduction make PCA useful in process control. Plots of the individual principal components form the basis of a pattern recognition technique that allows detection of significant variations in the structure of the data. These applications of PCA are illustrated with appropriate mineral processing data.

Jan 1, 1993

By J. Harrison Daniel

Increasing mechanization of underground mining operations throughout the years has reduced the dependency on large, concentrated working forces. Fewer workers in scattered locations, coupled with the versatility of diesel equipment to load and haul personnel, supplies, and mineral ore, has made diesel equipment attractive in mine feasibility and design studies. The use of the mobile equipment along with higher production or "bulk" mining methods provides for more efficient mineral extraction systems. These systems are expected to become more widespread until long-term research provides a further evolution to more complete automation of underground mining. The U.S. Department of the Interior, Bureau of Mines, has been conducting research to reduce the health and safety hazards posed by increasing use of diesel equipment and the higher power ratings being proposed. The goal is to provide for safe and efficient use of the equipment. The National Institute for Occupational Safety and Health has recommended that diesel exhaust be regarded as a potential occupational carcinogen adding importance to the Bureau's research program. The paper describes advances in engine design, the use of diesels in mining operations, and significant health and safety research accomplishments of the Bureau of Mines. These accomplishments will help assure that diesel equipment remains an option for determining the most efficient system to mine an ore body.

Jan 1, 1989

By A. D. Davis, G. A. Zabolotney

A ground-water flow model was developed to simulate the postmining recharge rate from precipitation at the Belle Ayr surface coal mine, which is located in the Powder River Basin near Gillette, WY Wyoming state regulations require that reclaimed lands should provide a rate of recharge that approximates the premining rate. Steady-state calibration and transient simulations showed that the postmining recharge rate through spoil is at least 50 mm (2 in.) per year, exceeding the original infiltration rate of 4 mm (0.16 in.) per year to shallow overburden aquifers. Major reasons for the increase include the flat topography of the reclaimed areas and the decreased spoil density. It is expected that the backfill will disaggregate and settle over time, eventually resulting in a nearly constant recharge rate that is less than 50 mm (2 in.) per year but still somewhat greater than the premining rate.

Jan 1, 1997

By P. Legast

Serpentinite minerals are available in large quantities from asbestos mining activity. The granular or fibrous serpentite, at temperatures greater than 700°C, will recrystalize into olivine, forsterite and enstatite. These minerals have been used and studied for decades and are environmentally safe. The thermal process changes the composition and properties of the original mineral. Therefore, the substitution of the original mineral cannot simply be made and the applications for these new synthetic minerals need to be redeveloped. The two original mineral forms allow a wide range of new synthetic raw materials which can be adjusted to specific applications or custom needs.

Jan 1, 1993

By Ethan Steward, Kyle Perry

The study investigates the effects of high-velocity impacts of common mine materials on a reinforced mine seal rated to 120 psi. It found that materials propelled during an underground explosion could generate enough stress to crack or damage seals, even with little visible damage. This highlights the need for careful evaluation of mine seals after any impact or high-pressure event.

Aug 1, 2023

By Klaus Schönert

Experimental investigations of single particle and interparticle breakage show that the microprocess in mills demands an energy input between 1 J/g and 10 J/g, if particles below 100 pm have to be comminuted. A system analysis of grinding media and roller mills is given in respect to the energy supply to the microprocess and the influence of the back stream caused by the compression of the material inside the active volume. The back stream diminishes the probability for capturing the particles in very fine grinding processes. Some possibilities are discussed how to solve this problem.

Jan 1, 1989

By Jim Oehler

The US minerals industry, as well we know, has been hit hard by the recent recession and is faced with what is projected to be a slow recovery. Even so, there was an underlying feeling of optimism at American Mining Congress' International Mining Show in Las Vegas, NV, Oct 11-14. More than 25,000 people attended during a particularly rough financial year, dispelling fears that attendance would dip sharply below 1978's 30,000 plus tally. The equipment expositionheld every four years-was the largest show of its kind this year in the Western Hemisphere in terms of exhibit space, providing an extensive view of mining-related equipment. In addition to the nearly 700 exhibits occupying more than 445 hm2 (11 acres), 20 technical sessions were held covering topics ranging from minerals availability and the state of the mining industries to communications, computers, and accounting. Government officials were well represented, with six US senators and five US representatives participating in various convention functions. Sen. Paul Laxalt (R-NV) was the keynote speaker at the welcoming luncheon. Other senators involved in the show included Howard W. Cannon (D-NV), Pete V. Domenici (R-NM), James A. McClure (R-ID), Frank H. Murkowski (R-AK), and Steven D. Symms (R-ID). Representatives on the program were Joseph M. Gaydos (D-PA), Guy Vander Jagt (R-MI), Don Young (R-AK), Jim Santini (D-NV), and Ceil Heftel (D-HI). There were also many international vistors at the show, including exhibitors from Australia, Austria, Canada, England, Finland, Sweden, South Africa, and West Germany. Equipment Highlights Equipment and services featured at the exposition ranged from aerial mapping to wire rope. Aisle space alone between exhibits exceeded 8 km (5 miles). And the companies represented ranged from small businesses to large corporations. Some of the company products described here are representative of the many exhibitors in attendance. Atlas Copco's extensive display of rock drilling and tunnel and shaft boring equipment featured its Boomer H-201, the newest addition to its line of underground drifting rigs; the ROC 306, a new track-mounted, high pressure down-the-hole drill rig; a new hydraulic surface crawler drill, the ROC 712H, designed for small and medium-size holes in quarries and small open-pit mines; a computerized analysis system, CARE (see page 1570), designed to project productivity and operating costs for various mining operations; several electro-hydraulic loaders, including the new rail bound LM E60 and LM E80, and two Hagg-loaders-the 7HR and 10HR-that use two digging arms to rake and guide muck; a mechanized blasthole charging system; rock bolting equipment and its new Swellex roof bolting method; Sandvik Coromant drill steel and bits; and its new Jarva R200 raise boring machine.

Jan 11, 1982

By C. Bazin, D. Hodouin

Dynamic experiments were performed in a continuous open-circuit 40x40-cm ball mill using a pseudo-random binary sequence of the feed rate and measuring the variations of the discharge particle-size distribution. The impulse response is calculated by a cross-correlation technique. Then a model involving a discrete transferfunction and a time-series stochastic equation is calibrated using maximum likelihood methods. Based on this empirical model, a minimum variance controller with constrained input is designed and its performances are compared, by simulation, to the performances of a conventional PID regulator.

Jan 1, 1987

By S. Su, S. Natansohn

This report describes a process for tungsten recovery from Searles Lake brines and upgrading its concentration to useful levels. The method consists of a combination of a liquid-solid and liquid-liquid extraction step and results in a product stream containing more than l00g W03/1. This technique is also effective in substantially reducing the concentration of objectionable impurities in the tungsten product. An ion exchange extraction mechanism is postulated.

Jan 1, 1983

By Howard W. Earnest

The Rio Blanco Oil Shale Company completed a modified in situ oil shale retorting demonstration at its Tract C-a Lease in the Piceance Creek Basin of northwestern Colorado during the spring of 1982. This demonstration was the first MIS project with shafts rather than adits for access to the mining operation, and it involved several potential hazards which required that particular attention be paid to mine ventilation. Methane was first encountered during shaft sinking and ultimately resulted in the mine being classified gassy by MSHA. Secondly, we encountered hydrogen sulfide in association with the ground water, and this proved to be a more persistent problem than did the methane. Thirdly, in order to burn the underground retorts, it was necessary to provide for potential leakage of retort gases and to obtain a modification to the MSHA standard which forbids fires under- ground. This modification had a significant effect on the ultimate ventilation procedures at Tract C-a. An extensive under- ground air monitoring program was included in the ventilation system.

Jan 1, 1983

By Jeffrey P. Carstens

INTRODUCTION Thermally induced fracture of rock is one of the oldest rock breakage techniques known to man. Primitive underground miners used fires to heat and crack rocks as early as the third century B.C. (Ref. 1). History aside, however, present-day tunneling and mining interests are reconsidering the use of modern heating units for rock fracture for some very good reasons. One of the most important advantages of many heating techniques is the lack of direct contact between the heating device and the rock. This means a lower wear rate relative to mechanical cutters, and no large reactant force to be supplied by the tunneling machine. In addition to avoiding physical contact, some heating systems (e.g., electron-beam guns and lasers) can deliver energy to a rock face much more intensely than can be conveniently handled mechanically. Thus, heating power densities of the order of lob to 107 watts/in.2 and greater can be achieved with high-power lasers. These high power levels allow much higher instantaneous penetration rates than can be achieved by mechanical cutting. Another advantage that accrues to some thermal techniques, such as, for example, surface spalling, is that the thermal fracture process works particularly well in certain rock types (e.g., granite) that are particularly hard to cut mechanically. Other methods, involving high power density, are able to cut any rock type, and are relatively

Jan 1, 1997

By Ken Bright

This paper is an overview of approaches to assessment of ore grade for gold and the platinum group at the exploration stage of a project. Proper sampling techhniques must be complemented by good assaying. In turn, correct assaying has its roots in thoughtful, systematic sampling and sample preparation procedures. While intricacies of the subject matter could occupy a book, we will comment on acceptable sampling approaches, outline a lab hand- ling scheme, and discuss preferred analytical methods. Pitfalls previously encountered by the mining and exploration industry will be highlighted with emphasis on a perceptive under- standing of the nature of ore occurrence. Lastly, focus will be centered on reliable assay approaches.

Jan 1, 1988

By Boris M. Vorobjev

The paper in question discusses a wide range of topics on the coal mining environment in general and on computerized coal mine environment systems in particular. The emphasis is being made on methodological aspects of coal mine environment with reference to computerized monitoring systems Classification of computerized coal mine environment monitoring system is suggested by the author with specific reference to coal mining operations. Coal quality control system at all levels (coal face to regional levels) is also discussed briefly hereunder, since coal quality is one of the major factor for environmental management. An integrated coal mining economic and environmental management super-system is presented in this paper Review Of the UN/DTCD, UNDP European Regional project "Computerized Coal Mining Systems" is presented here. Conceptualization of a new European Regional project on Coal Mining Environment and Economic Management is also a topic discussed in the paper.

Jan 1, 1992

By L. Lichty, R Bhappu, R. Rowan, G. Ramadorai

Treatment of refractory gold ores containing arsenic have always presented a major problem in their processing to recover the contained precious metal values. The major difficulties are concerned with lower recoveries, production of hazardous fumes, effluents and residues. Because of'these arsenic related problems, many otherwise economically attractive precious metal deposits and dumps all over the world are not exploited. In recent years, treatment processee for refractory gold ores and concentrates have been explored and a few commercial operations employing roasting or pressure leaching have resulted. Roasting has limitations due to environmental constraints related to off gases. Pressure leaching involving high temperatures (180% to 200%) and pressures (400 psi) is accompanied by high capital and operating costs. An alternate route to roasting for treating pyrite and arsenopyrite ores and concentrates ia the "lime-oxygen hydromet" process carried out at a moderate temperature (100%) and pressure (100 psi). A simplified process for treating such arsenic containing ores and concentrates utilizing low temperature and pressure oxidation is presented. This low cost treatment with compressed air and lime renders arsenic as an inert component in the residue, meeting all the requirements of the EPA Toxicity Test. The precious metal values are then extracted from the autoclaved residue by standard cyanidation. This paper discusses this new development.

Jan 1, 1990

By C. D. Harrison

The 1990 Clean Air Act Amendments specify national objectives for reducing sulfur dioxide emissions from coal-fired power plants System-wide reductions can be achieved by combining various emissions controls technologies and allowances, or compliance credits, that can be purchased, sold, or traded. As part of the Coal Quality Expert development project funded by U.S. Department of Energy and the Electric Power Research Institute (EPRI), Black & Veatch has developed an interactive computer tool, the Acid Rain Advisor (ARA). ARA allows the user to develop integrated system-wide compliance plans by comparing the costs and emissions reduction benefits for emissions allowances and various SO2 control technologies such as coal cleaning, fuel switching, and scrubber retrofits.

Jan 1, 1992

By L. M. English, Y. J. Wang

When plotted as head vs. volume, fan curves start high and decrease with increasing volume, while mine head curves start low and rise with increasing volume. Their intersection is the system operating point. However, as every ventilation instructor knows, the fact that head loss is a negative number (debit) and fan head is an energy addition (credit) is often a stumbling block to student or audience comprehension since the curves seem to reflect the opposite. It is possible to use the intuitively correct curves- pressure losses as negative values and energy additions as positive values - and still obtain the correct operating point. Adding the two curves produces a third curve that intersects the x-axis at the operating point, the point at which the fan energy input exactly matches air circulation energy loss. Using this technique also makes it easier to account for outside influences on the system, such as natural ventilating pressure. With the standard approach, it is quite easy to add or subtract such influences to the wrong curve. This approach can be extended to the graphical solution of any series/parallel ventilation network. The results are the same, and the approach is logically consistent and less confusing.

Jan 1, 1999