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By Adrian Smith, Debra W. Struhsacker

13.1 INTRODUCTION Cyanide is, a generic term indicating the presence of the cyanide ion (CN-). Cyanide is a very common, naturally occurring compound produced by many biochemical reactions. Many plant species synthesize organic compounds which contain cyanide in the form of cyanogenic glycosides (Knowles, 1976). For example, trace amounts of cyanide are present in the seeds and leaves of many members of the Rosaceae (rose) family (Kingsbury, 1964). Many common items such as lettuce, maize, sweet potatoes, kidney beans, (Oke, 1969) almonds, and cigarette smoke contain cyanide. As examples, a recent chemical analysis of chocolate-covered almonds measured a total cyanide content of about two ppm (Steffen Robertson and Kirsten, 1987); and the U.S. Surgeon General (U.S. Department of Health, 1964) has shown that cigarette smoke contains up to 1,600 ppm total cyanide. The chemistry of cyanide solutions is complicated because the cyanide ion forms compounds and complexes with many elements. Some cyanide species are highly toxic whereas others are relatively inert and harmless. Molecular hydrogen cyanide (HCN) is the most toxic form of cyanide. Under most conditions, HCN exists as a gas which readily dissipates or reacts with the environment to form less toxic or nontoxic forms of cyanide. Thus HCN is an ephemeral toxin, and many naturally occurring geochemical processes reduce the HCN concentration of a heap system with time. As discussed below, free cyanide includes the two species, ionic cyanide (CN-) and molecular hydrogen cyanide. Free-cyanide toxicity in man, mammal s, and aquatic species is we1 1 documented (Doudoroff, 1976; Ecological Analysts, 1979; Towill et al., 1978). The lethal doses reported for human adults vary with the type of exposure as follows: • One to three mg/kg body weight if ingested; • One hundred to 300 ppm if inhaled; and • One hundred mg/kg of body weight if absorbed. Acute toxicity of free cyanide to freshwater invertebrates ranges from 0.028 to 2.295 mg/l, depending on species and test conditions. Generally, free-cyanide concentrations greater than 0.1 mg/l are expected to kill sensitive species in freshwater or marine environments (Doudoroff, 1976;

Jan 1, 1988

By Wang Dianzuo, Luo Lin, Hu Yuehua, Qiu Guanzhou

This paper introduces a novel classification approach named the flotation classification approach which works by controlling interactions between particles. It differs considerably from the conventional classification processes operating on mechanical forces. In the present test, the micro-bubble flotation technology is grafted onto hydro-classification. Selective aggregation and dispersion of ultrafine particles are achieved through governing the interactions in the classification process. A series of laboratory classification tests for -44 pm kaolin have been conducted on a classification column. As a result, about 92 percent recovery for minus 2 pm size fraction Kaolin in the final product is obtained. In addition, two criteria for the classification are set up. Finally, a principle of classifying and controlling the interactions between particles is discussed in terms of surface thermodynamics and hydrodynamics.

Jan 1, 1995

By Regina N. Tempel, Timothy E. Eastep, R. Craig Ford, Bryce R. Roming, Geoff Clothier, Maggy F. Lengke

The Climax Mine, near Leadville, Colorado treats acid drainage in a lime neutralization chemical treatment system. Chemical treatment has been successful in reducing the concentration of metals to below surface water discharge effluent limits, but lime usage has not been optimized. A geochemical modeling approach has been developed to increase the efficiency of lime neutralization. The modeling approach incorporates two steps: (1) calibration, and (2) calculation of amount of lime needed to increase pH and remove metals. Results of our work quantify the lime treatment process and improve our ability to predict overall water quality.

Jan 1, 2000

By Elza F. Burch

Feeding 600 pm X 0 raw coal to heavy media cyclones, along with the +600 pm size coal, produces an efficient separation of both the +600 pm and 600 pm X 150 pm sizes. Major advantages of the process include the elimination of desliming screens and secondary fines circuitry for cleaning the 600 pm X 150 pm size coal, and result in a very simple circuit. Incorporating four 660 mm diameter heavy media cyclones, the Providence Plant of Island Creek Corporation has operated efficiently for ten years with a magnetite consumption rate of less than 0.45 kg per ton of raw feed at a feed rate of 454 tph.

Jan 1, 1988

By S. Helgen, C. Byrns, A. Davis

The 4000 acre historic Robinson Mining District outside Ely, Nevada hosts a continuum of oxidelsulfide waste rock dumps of different ages. In an effort to develop a paradigm to explain past, existing, and future conditions at the site profiles of oxygen, pH, temperature, and specific conductivity were collected from various waste rock dumps using a hand-driven soil gas probe and a down-hole sampling device. The resulting data are useful in interpreting the fate and manner of pyrite oxidation within the dumps and in identifying waste rock dumps that may require remedial measures compared to those that require only minimal action prior to closure.

Jan 1, 2000

By Z. T. Bieniawski, Christopher Mark

A new method for the design of long- wall chain pillars, called Analysis of Longwall Pillar Stability (ALPS), is described. The method provides estimates of the relative stability of different longwall pillar designs during all stages of their service life. The key issue addressed by ALPS is the magnitude and time-of-arrival of the longwall abutment loads applied to chain pillars. A field study was conducted and other available field data were analyzed in order to develop an approach for estimating the abutment loads. An example based on longwall experience in the Pittsburgh seam is used to illustrate how ALPS can be used in mine design.

Jan 1, 1986

By J. L. Kohler

The knowledge-based expert systems (KBES) is a potentially powerful technique to the mining engineer in traditional areas of mine design and operations, as well as in the emerging areas of mining automation and robotics. Since KBES is still experimental in many respects, caution must be exercised as this "high tech" tool is developed and applied to mining. The objective of this paper is to demystify expert systems by introducing the elements of KBES, discussing the strengths and weaknesses, and identifying some areas of application in mining, based on the authors' experiences.

Jan 1, 1986

By Vincent R. Bovino

Introduction Only a person fresh from an information vacuum could not know the status of this nation's economy. The inability of the US to compete in the world marketplace is manifested in many industries, from shoes to computer chips, from cars to copper. What industry will next fall prey to world competition? Perhaps the question should be, what insustry will next fall prey to declining productivity? American industry is being forced into an era where the focus must be on productivity, quality, cost control, and competition in the world marketplace. It is approaching a change that could rival the American Industrial Revolution. The future of the US is bright only if it can increase productivity by trying different and new ways to manage its businesses and people. Unlike the easy successes during the 60s and 70s, success in the decades ahead will depend on an ability to compete in the world market. Any operation can achieve unlimited productivity by developing the resources within its employees. As an industry, mining has harvested the earth's resources. As an industry in trouble, it now has to learn to tap human resources to release the energy and creativity in each person. Recently, I worked with a mining operation to reopen a mine and implement a different management approach. The extensive changes resulted in a 50% reduction in cash cost of producing silver (from $0.40 to $0.19/g or from $12.50 to $6 per oz). Thus, an unprofitable mine became an attractive business venture without technological changes or significant capital infusion. The operation is union-free, in spite of being in a highly unionized area. The mine implemented a real productivity improvement process called "gain-sharing." Employees now recognize their individual success is tied to the success of the business. They recognize the day of the free lunch is over for mining employees. This paper will explore three areas related to productivity: • some of the unspoken "whys" of the mining industry's paralysis and how management has caused unproductiveness in mining operations; • major components of a productivity improvement process; and • characteristics common to companies with successful productivity plans. Unspoken whys When things go wrong, everyone tends to point a finger at someone, anyone. This industry has blamed every conceivable person, corporate group, government agency, foreign government, and private group for its failures. The fault finger will not work anymore. Nobody is listening. It is a characteristic of winners in management to assume responsibility for less than acceptable performance. Excellent people tend to blame others less for problems. Everyone involved in mining should shoulder part of the blame for the industry's illness. Is the problem low prices or our high operating costs? To regain our status in the world marketplace and increase our productivity, we need to painfully and honestly talk about our mistakes.

Jan 3, 1986

By R. W. Henn

Introduction Shotcrete, by the American Concrete Institute definition, is mortar or concrete pneumatically projected at high velocity onto a surface. The term gunite is still common in literature. It is a trade name established by Cement Gun Co. of Allentown, PA, around 1911 for a dry mix of fine aggregate material, hydrated at the nozzle, and pneumatically projected at high velocity onto a surface. This article will discuss shotcrete applications, ingredients, mix proportioning, batching and mixing, admixtures, testing, and steel fiber vs. conventional shotcrete. Applications Shotcrete is used primarily by the mining and underground construction industries to temporarily stabilize an excavated rock surface until a permanent cover can be installed. It may also be used as the permanent covering material. Other uses include refractory material, architectural finishes, slope stability, wearing surfaces, repairing existing concrete structures, fireproofing, and corrosion protection of steel. Wet Versus Dry Process In the wet process, all ingredients, including water but not accelerator, are mixed the same way as normal concrete before its placement by pneumatic projection. The accelerator is added in a liquid state through the nozzle at the point of placement. In the dry process, all ingredients, including acceleration in dry form but not water, are mixed just before placement by pneumatic projection. Water is added through the nozzle at the point of placement. Liquid accelerator may be added at the nozzle in the dry process. Ingredients Shotcrete consists basically of the same ingredients as concrete with some limitations. Type I, II, and III cements are used. However, Type II seems to be used most in underground applications. This can be attributed to ground water at most sites having slight to moderate concentrations of sulfates. Air-entraining cement or air-entraining admixtures are generally not used in dry mix shotcrete. It is generally agreed that it is impossible to entrain air due to the absence of the usual concrete mixing action, and the high velocity of impingement of the material on the application surface. Air-entraining cement or air-entraining admixtures are used in wet mix shotcrete. Their use, however, is not widespread due to the placement method and the fact that high velocity air drives off most of the entrained air. Test results are not conclusive in showing any durability increase of shotcrete to freezing and thawing by using entrained air. In spite of current practice, the trend is toward additional research, with more agencies and owners requiring the use of entrained air. The philosophy behind this is that some entrained air is better than no entrained air to increase durability to freezing and thawing. The aggregates used in shotcrete are the same as those used in concrete. However, the largest coarse aggregate presently used is 19 mm (0.75 in.). A typical gradation requirement is shown in Table 1. The water quality requirement for shotcrete is the same as that for concrete. Accelerators are by far the most important admixture in shotcrete.

Jan 6, 1984

By R. D. Schmidt, S. E. Follin

Introduction Mineral recovery from an in situ leaching operation is determined by the often complex interaction of hydrology, mass transport, and chemical kinetics. The operating conditions of many pilot and production scale uranium leaching operations involve heterogeneities in aquifer permeability. Differences in permeability may be naturally occurring, the result of differences in main size or cementation, or they may be induced by leaching activity. Variations in permeability directly affect the fluid flow streamline pattern, fluid flux, and so also leaching geochemistry and uranium recovery. An in situ leaching hydrology model (ISL) and a mass transport-oxidation rate model (ISLGC) have been developed for use in making site specific predictions of the leachability and productive potential of heterogeneous ore deposits, and for the optimal design of leachant injection and recovery operations. The two models are linked by output and input requirements. The ISL hydrology model generates a leachant flow streamline pattern between injection and recovery points in a flow domain incorporating regions of arbitrary permeability. The ISLGC transport model describes the changing solution concentrations of uranium and oxygen and the changing mineral concentrations of uranium and pyrite resulting from convection, longitudinal dispersion, and oxidation reactions. ISL hydrology model Basic equations The differential equation for steady-state two- dimensional flow in an isotropic porous medium is

Jan 1, 1988

By P. J. Suardini, S. K. Kawatra

A number of on-stream coal slurry analyzers are presently being developed and commercialized for measuring ash and solids in coal process streams, particularly around flotation circuits. The eventual goal of these efforts is to develop on-line quality control systems for flotation circuits and other fine-coal cleaning operations. As part of this on-line monitoring and control effort, it is important to gain a better understanding of the response of industrial flotation circuits to changing operating conditions. This paper summarizes the results from a detailed sampling program performed at an industrial coal flotation circuit in western Pennsylvania. The testing focused on evaluating the response of the circuit to changes in reagent dosages, operating conditions and feed compositions. The testing indicated that it is desirable to maintain high collector-to-frother ratios to enhance coarse particle flotation. The recovery of fine impurity particles was also proportional to water recovery, due to hydraulic entrainment. Key words: Industrial, Coal, Flotation, Circuit, Reagent, Response.

Jan 1, 1995

By Marietta Canty

Results are presented that were gathered during field-scale testing of an innovative technology, sulfate-reducing bacteria (SRB), designed to treat and control acid mine drainage (AMD). The project was performed under the Mine Waste Technology Program (MWTP), which is funded by the U.S. Environmental Protection Agency (EPA) and jointly administered by the EPA and the U.S. Department of Energy through an Interagency Agreement. The MWTP is implemented by MSE Technology Applications, Inc., located in Butte, Montana. A field-scale test is described in which the subsurface workings of an abandoned mine were used as an "in situ biological reactor."

Jan 1, 2000

By John C. Morrisey, Harold M. Ray

With full production from the Casteel Mine in 1987 The Doe Run Company, a wholly owned subsidiary of the Fluor Corporation, encountered a significant increase of copper and iron to the Viburnum Mill. This major change of the lead, zinc, and copper metal ratios in the ore created circuit problems which adversely affected concentrate quality. Recognizing the problem, the company embarked on a metallurgical research program to include laboratory, pilot plant, and plant testing. The program developed an innovative copper prefloat process which both increased copper recovery and significantly improved concentrate quality. The process was tested and first operated at Doe Run's Brushy Creek Mill then installed at the Viburnum Mill in 1992. A brief history of development, plant operating data, and other potential applications for the patented processes will be described in the paper.

Jan 1, 1993

By Scott K. Palm

The initial intent of the Hazard Communication Standard (HCS) was to improve worker health by providing more information about the hazards of chemicals used in the workplace. However, the impact of the HCS goes well beyond worker right-to-know. There are direct costs associated with compliance. In addition, labelling and hazard communications can provide a competitive advantage to producers of minerals that have not been identified as hazardous. Often, the lack of hazardous information about a substance is due to the lack of scientific study, rather than an indication of product safety. Currently, industry and regulators sometimes give known hazards greater weight than unknown risks.

Jan 1, 1991

By Andrew Neale, Ari Supomo, Mike Mular, Rob Perry

A method is presented to measure and correct the performance of regulatory control loops. Freeport Indonesia treats over 220,000 dmtpd of copper-gold ore in a complex of four concentrators. More than 400 regulatory control loops are implemented throughout the operation. The performance of each loop is quantified by an index based on its time in automatic, the deviation of the measurement from the setpoint and a metallurgical assessment of its impact on overall plant operation. Index values are recorded in a plant-wide data acquisition system and analyzed to produce a report of loops requiring attention. Loop statistics are analyzed to show if the problems can be corrected with tuning. The practical application, benefits, management and staffing requirements of this method are discussed.

Jan 1, 2000

By G. R. Rao, K. A. Natarajan, P. Devasia

The role of growth conditions and adhesion of Thiobacillus ferrooxidans on the leaching of chalcopyrite was investigated. Thiobacillus ferrooxidans grown on sulfur, thiosulfate and ferrous ion substrates was used in this comparative study. Growth on sulfur, a solid substrate, requires bacterial adhesion unlike that required in the presence of soluble thiosulfate and ferrous ion in a mineral-salts medium. Solid substrate-grown cells showed higher rates of leaching than those grown in liquid media. An initial lag period noticed during leaching by solution-grown cells was absent when solid substrate-grown cells were used. Such a behavior is attributed to the presence of an inducible proteinaceous cell-surface appendage on the sulfur-grown cells. This appendage aids in bacterial adhesion onto the mineral surfaces. Such an appendage is absent in solution-grown cells, as substantiated by electrophoretic measurements. The importance of bacterial adhesion and the direct mechanism in leaching by Thiobacillus ferrooxidans are demonstrated.

Jan 1, 1997

By William H. Schiffbauer

Research is being conducted toward making underground mining equipment autonomous. This will facilitate improvements in safety by relieving workers of dangerous tasks and will increase production by providing more accurate control with less down time.. A Bureau of Mines developed microcomputer network has enhanced this research by permitting a group of diverse computers to interact with a mining machine as well as with each other over a common data link. The network is composed of specially integrated off-the-shelf hardware and industry-standard operating system and programming languages. Using the network, researchers can conduct various experiments with the mining machine using a diverse group of intelligent sensors, computers, and microcontrollers. Descriptions of the mining machine, the mining machine control computer, control algorithms, -the microcomputer network architecture, and communication protocols are discussed.

Jan 1, 1989

By Alec G. Richardson, S. H. Chiang, Ralph W. Lai, McMahan L. Gray

The potential of coal cleaning by selective agglomeration was examined for a Pittsburgh seam bituminous coal using isooctane as an agglomerating liquid. The effects of particle size, pH, degree of mixing, and dosage of isooctane on the pyrite and mineral matter removal from finely ground coals were investigated. The role of shear-enhanced-hydrophobic-association in the flocculation of fine particles was examined. The degree of liberation of pyrite from coal at different grinds was examined using an automated petrographic image analyzer. The effect of dispersant on slurry rheology during grinding was studied. The results indicate that over 95 percent of the pyritic sulfur can be removed from the coal. Final products containing less than 0.9 percent ash at a combustible recovery in excess of 90 percent have been obtained with multiple stages of cleaning.

Jan 1, 1989

By W. Douglas Gould, Mei-Lin K. Stichbury, Jeffrey G. Bain, Blowes David W.

The mechanisms of release of arsenic in gold mine tailings were investigated. The highest concentration of dissolved As (75 mg/L) was observed near the base of the tailings impoundment, in close association with a peat layer. Elevated concentrations of reduced iron and hydrogen sulfide were also measured at the base of the impoundment. High numbers of iron-reducing and sulfate-reducing bacteria were detected at depths within the impoundment which correlated with dissolved As, Fe and H2S. The data presented in this paper suggest that arsenic is released from the tailings by bacterially-mediated reductive dissolution of As-bearing iron minerals.

Jan 1, 2000

By J. S. Walker

Public Law 95-87 enacted by Congress in 1977 and subsequent regulations require coal mine operators to predict the effects of mining on the environment prior to the start of mining. Prediction of the effects of mining on the local groundwater system is a difficult task due to its complex nature and the lack of detailed published information. An investigation of water level fluctuations in five we1 1s positioned over three consecutively mined longwall panels was initiated in conjunction with an intensive subsidence monitoring program. The purpose of this work was to provide detailed information which could be used to predict certain hydrologic effects of longwall mining in the Northern Appalachian Coal Region. The results of this case study indicate that water level fluct- uations in the local ground-water system above longwall panels is associated with subsidence and that the static water level will generally re- establish at or near the pre-mining elevation after mining is completed.

Jan 1, 1986