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By Gopalan Ramadorai

This paper presents a review of halogen solvents used in the processing of precious metals. Reagents of widely varying chemical structures, such as chlorine gas, calcium and sodium hypochlorite, chlorine dioxide, iodine and bromine have been used for precious metal extraction. None of these chemicals are a replacement for cyanide: however, each of these chemicals present an opportunity for use in processing a specific type of ore. The ore and chemical must be matched to each other for success. Recovery of metal from the leach solutions also offers challenges.

Jan 1, 1994

By I. J. Jansen, C. L. Hooks

Successful soil construction involves prepa¬ration of an adequate base, selection of high quality soil ma¬terials, and placement of those materials by means which will establish a continuous macropore network and modest to low soil strength. Where such has been accomplished, experi¬ments reveal row crop productivity on reclaimed land which is very competitive with that on undisturbed land. Inferior productivity and sensitivity to drought stress are experienced where the soils are excessively compacted during construc¬tion. Some deep tillage practices have been quite successful in improving the compacted soils, but it is preferable to avoid compaction as the soil materials are handled.

Jan 1, 1987

Exploration for SX-EW copper deposits and plant operation depend largely on the copper and gangue mineralogy inasmuch as? they govern the feasibility of leaching. Mineralogical parameters are pivotal in identifying if an ore is suitable to dump, heap, thin layer, vat or agitated leaching and/or if the ore requires curing, bioleaching or alternate lixiviants. Problems in metallurgical testing, production leaching and recovery forecasting are very often related to lack of mineralogical data. This presentation will illustrate the use of quantitative mineralogical analysis for exploration, acquisition assessment and optimization of copper leach operations.

Jan 1, 1996

By J. C. Cawley

Improvements in today's maintenance practices are mandatory as more complex and productive machines evolve in the mining industry. By keeping machine reliability high through improved maintenance procedures, overall mining costs can be reduced. The Bureau of Mines is investigating diagnostic maintenance systems for underground mining machinery. A hydraulic expert diagnostic system and an electric motor predictive diagnostic system have been designed and installed on a Joy 16CM continuous miner. An electrical diagnostic system has been designed and installed on a Joy 14CM continuous miner. Each system is functionally described and the relative merits of expert diagnostic systems versus algorithmic diagnostic systems are discussed.

Jan 1, 1992

By Malcolm Reeves

The heavy oil reservoirs of Alberta and Saskatchewan include sequences of unconeolidated silts and fine sands which respond in an unusual manner when subjected to the high temperature and pore-fluid-pressure associated with steam injection and other thermal enhanced recovery techniques. Apparent transient connections are suddenly established between producers and injectore and there is an associated enhancement in oil (and sand) production. These phenomena have been attributed to local fluidization and piping processes which are known to occur in situations where high pore-fluid-pressures prevent the mobilization of intergranular friction. These breakdown processes may be associated with the penetration of tongues of the heated reservoir fluids with suspended sand into the creep sensitive intact reservoir since the viscosity ratios are sufficiently high for viscous fingering instability of the fluid-fluid interface. A program of laboratory tests has been carried out to measure the strength characteristic of saturated oil sands at a variety of temperatures and fluid pressures. These tests suggest, that in common with the coarser Athabasca sands, the Waseca sands have very little cohesive strength and show the characteristic dilational failure response of dense sands. Some special tests, devised to determine the relative ease with which samples can be fluidized, confirm the expected susceptibility of the fine- sand silts. Both piping and fluidization can be readily induced at in-situ reservoir temperatures and pressures. Analysis of stresses around wellbores suggests that fluid-pressure gradients may be sufficient to initiate piping and that backward erosion along streamlines may link producers and injectors. Such pipes may act as well “adits” gathering oil from the heated reservoir and contributing to enhanced production rates. Mechanical breakdown of the reservoir by drilling, injection and production processes provides a consistent possible explanation for the sand-cut response of production wells.

Jan 1, 1986

By J. F. T. Agapito, J. B. Page

This paper describes part of a geotechnical study based on stress determinations and convergence measurements conducted to assess the long-term stability of an experimental room-and-pillar oil shale mine. A rock mechanics program was initiated in 1971 at the Colony Mine as part of a large study conducted for the design of a commercial operation. The Colony Development Operation is a joint venture currently consisting of four active members; Ashland Oil Inc., Atlantic Richfield Company (Operator of the project), Shell Oil Company, and The Oil Shale Corporation. Although oil shale commercialization plans are presently suspended, rock mechanics instrumentation has been continued as part of Colony's policy in maintaining readiness to proceed with a commercial shale oil plant when national energy policies became better defined. The property is located in the southern edge of the Piceance Creek Basin in northwestern Colorado, approximately 200 miles west of Denver. Experimental mining operations were conducted from 1965 to 1972 with one of the major objectives of the pilot mine being the assessment of opening and pillar sizes for the determination of extraction ratio and life of the property. Mining was conducted in a 60 foot thick portion of the Mahogany Zone in the Parachute Creek Member of the Green River Formation, at depths of 600 to 850 feet by a one-bench system. Pillar dimensions were 58 feet by 58 feet and rooms were 55 feet wide.

Jan 1, 1977

By S. Bhattacharya, M. M. Singh

The Surface Mining Control and Reclamation Act of 1977 (SMCRA) requires under-ground coal mine operations to prevent "material damage" to renewable resource lands caused by subsidence. However, what constitutes material damage is not defined. This paper discusses the applicable criteria for agricultural lands, forests and grazing lands, surface water bodies, and ground water aquifers. Although data on the subject are limited, an attempt is made to present quantitative guidelines to distinguish between moderate and severe damage due to subsidence.

Jan 1, 1988

By P. K. Berger, G. T. Lineberry, H. P. Cole, J. V. Haley

Sixty-five simulation exercises were developed for teaching and testing problem solving and decision making skills to miners and mining engineers. The exercises focused on judgment and decision making for preventing and controlling mine emergencies. The structure and field testing of the exercises are described, and sample frames of individual exercises are presented. Empirical data are summarized about the effectiveness of these simulations based on the performance scores of a national sample of miners and mining engineers.

Jan 1, 1994

By D. Akers, R. Dospoy

Introduction The geological processes that form coal can also concentrate trace elements in the coal. For example, the average concentration of arsenic in bituminous coal (20 ppm) is ten times the average concentration found in all the other rocks that make up the earth's crust (2 ppm). Similarly, other elements, such as antimony, cadmium, mercury and selenium, are more concentrated in coal than in the earth's crust. When coal is burned, trace elements can be further concentrated. Although no new constraints on trace clement emissions were placed on the power generation industry under the 1990 Clean Air Act Amendments, the act does mandate a three-year study of air toxics. Any new regulations aimed at electric utilities as a result of this Federally-mandated study will almost assuredly be very costly-an estimated $1 billion per year. Many trace elements in coal are associated with mineral matter. For example, arsenic is commonly associated with pyrite, cadmium with sphalerite, chromium with clay minerals, mercury with pyrite and cinnabar, nickel with millerite, pyrite and other sulfides, and selenium with lead selenide, pyrite and other sulfides (Finkelman, 1980). There are also cases in which some of these elements are organically bound. Just as both organic and pyritic sulfur can be found in the same coal, the same trace element may be both organically bound and present as part of a mineral in the sane coal. Physical coal cleaning techniques are effective in removing mineral matter from coal and can potentially remove at least some of the trace elements associated with specific minerals, thereby reducing the release of these elements into the atmosphere. Conventional coal cleaning to remove trace elements As part of a project funded by the Electric Power Research Institute, CQ Inc., a wholly-owned EPRI subsidiary located in western Pennsylvania, has demonstrated that large reductions in the concentration of many trace elements are possible if conventional coal cleaning techniques are properly applied. Four examples are given in Tables 1 to 4. In each example, the results shown were generated by cleaning the coal at CQ Inc.'s commercial-scale cleaning test facility. Cleaning results for Upper Freeport Seam coal from Northern Appalachia are provided in Table 1. Data are presented in the table in two ways: as a weight-based concentration (parts per million) and as a concentration per heat unit (grams per billion Btu). Grams per billion Btu is analogous to pounds per million Btu, but avoids the use of numbers with many decimal places. The heat-based concentration provides a better measure of boiler impacts, because the increased heating value obtained through coal cleaning reduces the number of tons that must be burned to produce a given thermal output. Reducing the quantity of coal burned reduces the quantity of trace elements entering the boiler. This raw coal is relatively high in several trace elements of environmental concern, including arsenic, cadmium and chromium. Cleaning provided large reductions in the quantity of arsenic, barium, cadmium, chromium, fluorine, lead, mercury, nickel, silver and zinc. The results for tests with a Powder River Basin coal, Rosebud/McKay, are presented in Table 2. Large reductions in arsenic, barium, cadmium, fluorine, mercury, nickel, selenium and zinc were observed with cleaning. The concentration of chromium increased with cleaning, while lead concentration increased in one test and decreased in another. Table 3 presents test results for Croweburg Seam coal from Oklahoma. Large reductions in arsenic, barium, cadmium, chromium and zinc were obtained with cleaning. Smaller reductions were obtained with lead and nickel, while chromium, fluorine and mercury increased in at least one of the tests. Table 4 presents cleaning test data for Kentucky No.11 Seam coal. In this case, large reductions were obtained with all elements measured. In general, these data indicate that physical coal cleaning is effective in reducing the concentration of many trace elements, especially if they are present in the coal at relatively high concentrations. The degree of reduction achieved is coal-specific, relating in part to the degree of mineral association of the specific trace element and the degree of liberation of the trace element-bearing mineral. The extent of trace element removal also depends on the method of cleaning the coal. Figure 1 is a washability plot, by size fraction, of arsenic vs. ash content for Upper Freeport

Jan 1, 1994

By M. C. Roberts

The material composition of product is defined as the quantity of metal used per unit of product manufactured during a year. The material composition of product has shown steady and persistent declines over time for most metals and materials. This tendency demonstrates the continued improvements in manufacturing technology resulting from substitutions of other materials and increases in production efficiency. The purpose of this paper is to use the material composition of product to show the impact of advanced materials on the use of traditional metals.

Jan 1, 1992

By Kal V. S. Sastry, Stephen N. Little

Computer simulation of comminution systems is found to provide significant cost savings by enabling efficient circuit design and development of control systems. These simulation systems are based on sound mathematical models and numerical methods. Nevertheless, they are found to be hard-to-use and hard-to-modify to carry out more elaborate process analysis. This paper discusses the fundamental principles and practical aspects of an advanced, highly functional, and user-friendly SIMulator for COMminution, SIMCOM, that is being developed at Berkeley by incorporating state-of-the-art software engineering principles.

Jan 1, 1992

By G. Belardi, G. Marruzzo, P. Plescia

This paper presents the results of grinding tests performed on magnetite from Kiruna (Sweden) and on chromite from Skoumtza (Macedonia. Greece). Stresses were measured by XRD, which determined the variations in the characteristic structural spacings of the minerals both before and after, grinding in a HSM/250 Herzog laboratory ring mill. Anal Isis of the magnetite and c hromite crystallinstallin was performed hi measuring the broadening of the strongest diffraction peak (311). .Also, structural analysis on chromite was carried out using the Mikheev model. Ultrafine-grinding tests on the magnetite and chomite demonstrated that this type of treatment can induce profound variations m the surface-stress state. These included plastic variations of the cell followed by "chemical" stress with oxidation front the stricture to form hydroxide or carbonate, films. This can have a great influence on the mineral reactivity to flotation reagents

Jan 1, 1996

By S. P. Lucido, I. Iwasaki

The potential of controlling heavy metal ions in effluents from discontinued mining operations and waste rock piles has been investigated. A fresh water green alga, Cyanidium caldarium, was found to have the potential to remove Cut' from solutions while exhibiting high tolerance to acid conditions which are commonly encountered in copper-nickel mine drainage. The process has the potential for application as a low maintenance metal decontamination system. The growth requirements and copper removal characteristics of this microorganism are described.

Jan 1, 1991

By R. A. Pindred, M. P. Lam

Cyanide is a conventional lixiviant for gold extraction but its' toxicity is a major concern for the environmentalist. There are many alternative non-cyanide lixiviants, such as thiourea, thiosulphate, chlorine and hypochlorite etc., which may reduce environmental sensitivity. This paper will discuss the leaching characteristics of gold in hypochlorite leaching solutions. The dissolution of gold in a hypochlorite solution not only depends on the concentration of the hypochlorite but also on other variables, such as hydrochloric acid, sodium chloride and temperature. The dissolution rate of gold in hypochlorite solution is much faster than other lixiviants. Due to the interference of impurities, gold extraction from an ore under ambient conditions requires large quantities of reagents. However, refractory gold ores may be successfully pressure oxidized in an autoclave at reasonably low reagent levels. Gold extraction to the pressure oxidation leach solution is rapid and complete in one stage, thus eliminating the need for further cyanidation.

Jan 1, 1990

By L. M. Chan, D. H. Carlson, J. H. Johnson

This paper discusses laboratory evaluation of a tailpipe emissions measurement apparatus (EMA) developed by Michigan Technological University (MTU) under contract to the Bureau of Mines. The apparatus dilutes diesel exhaust and measures the concentrations of diesel particulate matter (DPM), CO, C02, NO and NO2 at known dilution ratios. The EMA was evaluated by side-by-side comparison of its measurements with those by laboratory grade instruments. During the preliminary laboratory evaluation concentrations of DPM, CO and CO2 were measured. The concentrations of CO and CO2 measured by the EMA were usually within ±14 pct of laboratory-measured values for CO and ±20 pct for CO2. EMA DPM concentrations correlated well (r = 0.96) with the laboratory values, but were 29 pct lower on average. The CO and C02 differences were observed to be related to the method of calculating the EMAs' dilution ratio and the difference in DPM concentrations is attributed to thermophoretic and/or condensation losses related to the EMA's unheated sample probe. Preliminery analysis of data obtained with a heated sampling probe and modifications in the sampling procedures have indicated reduced variability in DPM and in the calculated dilution ratios.

Jan 1, 1991

By Andrzej Luszczkiewicz, Kazimierz S. Sztaba

Flotation tailing of Polish copper sulfide ores represents more than 90% of the mass of run-of-mine ore. The tailing contains mainly quartz, dolomite, clay minerals, traces of sulfides, and some accessory minerals. Almost all minerals of the tailing are well liberated and, therefore, any further beneficiation process applied to the tailing is expected to be inexpensive. In this work, results of investigations on utilization of flotation tailing using classification and gravity concentration are presented. It is shown that due to classification of flotation tailing in hydrocyclones, the coarse fraction becomes suitable material for gravity separation providing backfill material for underground mines as well as heavy minerals, a source of valuable rare elements. It was also found that heavy minerals separated by gravity methods contain a significant amount of rare elements such as zirconium, titanium, silver, rare earth metals, and uranium. The light fraction of the gravity separation contains well deslimed quartz particles and meets strict requirements for hydraulic filling material ked for structural support in underground mines. Evaluation of the cost of the proposed technology indicated that investment to implement the method would provide a return within 2-4 years.

Jan 1, 1995

By J. S. Long

A finite-difference model using a digital computer was constructed to assist in the water management of a proposed oil-shale mining operation in the Piceance Basin in Colorado. The presence of ground water is both a detriment and a benefit for development of the resource. On one hand, dewatering is required because permeable zones are present in and above the oil-shale sequence, and rich oil shale at the proposed mine is as much as 457 m (1500 ft) below the water table. On the other hand, ground water is the most feasible source of water for processing the oil shale. A ground- water model was constructed to simulate the development of an environmentally acceptable water-management system that will satisfy both the mine-dewatering requirements and the water-supply requirements for processing. The ground-water model discussed in this chapter was constructed for the Rio Blanco Oil Shale Co. (RBOSC) by International Engineering Co., Inc., a subsidiary of Morrison-Knudsen Co. The model was applied to evaluate dewatering and water control systems for several open-pit mining plans initially investigated to develop Federal Lease Tract C-a. A collateral application of the model analyses was to project effects of the proposed dewatering operation on the regional ground-water regime in connection with a permit acquisition program by RBOSC. Subsequently, RBOSC has completely changed its mine development plan and has adopted modeling and related techniques more suitable for study of that plan and dewatering operation. The authors of this chapter are solely responsible for the contents and conclusions.

Jan 1, 1979

By Richard A. Brown, Robert D. Norris

By-product metals can be a significant source of revenue for a mining operation if their recovery can be accomplished without negatively impacting primary metal recovery. The main problem encountered in separating primary and secondary metals is to selectively control the solubility of the individually important metals with¬out affecting their ultimate recoverability As a class of hydrometallurgical chemicals, peroxygens have a versatility which permits the selective recovery of individual metal species. Peroxygens function as more than simple oxidants. They are effective solubility control agents and have proven utility in complexation, precipitation, dissolution, extraction, oxidation and reductive processes Peroxygens have been used commercially to recover by-products vanadium, uranium, molybdenum, and cobalt and have proven experimentally to recover rhenium, gold, silver, manganese and zinc

Jan 1, 1983

By P. J. Brown, R. W. Nice

The Thalanga Copper-Lead-Zinc Concentrator in Northern Queensland was commissioned in early 1990. The design of a flotation process for the sequential production of separate copper, lead, and zinc concentrates has always been a most formidable mineral processing challenge. In 1988-1989 during the process design phase, sized fractions of various samples were subjected to quantitative and qualitative mineral analyses. These analytical techniques are collectively known as modal analysis. Modal analysis aided in the selection of key process treatment parameters for the initial laboratory testwork on the Thalanga ore. The work also guided the flowsheet development and quantified the mineralogically imposed limitations on the separation process. This paper describes in general terms how these modal techniques were used to guide the program of laboratory flotation testwork which constituted the flowsheet design phase of this project. During these design studies, the primary grind and regrind requirements were deduced and the basic flowsheet configuration selected. Recent operating plant performance data are to illustrate the value of modal methods in addressing complex metallurgical separation problems.

Jan 1, 1995

By John Keay, Douglas R. Shaw, Gregory J. Olso

Rhodes Mining NL, Perth, Australia, is developing the Lahoca Gold Project which is located in Hungary, about 30 km from the town of Eger. The preliminary resource is estimated to contain approximately 1.5 million ounces of gold. The project is being evaluated for an annual process capacity of 2 million tonnes. The test samples contain just over 2 g Ault and 6% sulfur as sulfide. Copper and arsenic levels are approximately 0.2 and 0.1 %, respectively. The ore is refractory due to submicroscopic gold occurrences and structural associations with pyrite. A small amount of the gold is finely encapsulated in quartz. Approximately 30% of the gold in the crushed ore is soluble in cyanide and up to about 55% is cyanide-recoverable with ultra­fine grinding. The ore has little preg-robbing ability. Metallurgical test work done by Colorado Minerals Research Institute (CMRI) and other investigators has shown that as much as 85 to over 90% of the gold was recovered by the relatively severe conditions of pressure oxidation or roasting of the whole ore or a flotation concentrate. The Lahoca ore responds to flotation with gold recoveries of 87% into a low grade concentrate. Subsequently, with a view toward defining a process route with potentially more attractive economics, Rhodes Mining and CMRI conducted an extensive review of biooxidation technologies and concluded that, in particular, heap biooxidation methods promised lower process costs which normally are associated with heap leaching. Based on the study, which included the analysis of the closely related practices of copper dump/heap bioleaching now well established in that industry, CMRI conducted simulated heap biooxidation experiments which evaluated factors such as ultra fine ore crushing, agglomeration techniques, heap design, forced aeration oxygen supply, and whether or not the heap is irrigated. Separate flask biooxidation tests at Little Bear Laboratories showed that the finely crushed ore is biooxidized readily, with a near linear relationship between sulfide oxidation and gold cyanide solubility. Gold recoveries of as high as 66% have resulted after biooxidation of crushed ore. This paper highlights the metallurgical developments of the Lahoca project, and focuses on recent biooxidation laboratory test work aimed at enhancing the treatment of crushed ore.

Jan 1, 1997