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Viscosity measurements were carried out on slags in the CaO-Cu2O-CuO-MgO-SiO2systemcontaining ~ 63 wt% SiO2in air. The experimental work was carried out over a range of temperatures where the slags were completely liquid. Initial measurements were on a binary CaO-SiO2slag to which incremental additions of CuxO-MgO-SiO2slag with the same silica mole fraction were made. The viscosity-temperature relationship was measured for slags with‘Cu2O’contents of 0.02, 0.19, 0.38, 0.79, 1.69, 2.47, 3.01, 5.31 and 10.0 wt%. The proportions of Cu+and Cu2+in the slags were determined. The oxidation state of Cushifted from predominantly Cu+to Cu2+, with the Cu+/Cu2+ratio of approximately 0.3 for slag with a Cu content above 2 wt%. This is equivalent to Cu1.13O. The trends observed for changes of Cu2+/Cu+redox ratio with slag chemistry were consistent with the literature. Decreasing the CaO content by substituting copper oxide resulted in a decrease in the Cu+/Cu2+redox ratio. The change in ratio corresponded to a shift of the value of x in CuxO from an initial value of 1.8 to 1.1,when the slags contained 10% ‘Cu2O’. In this study, the SiO2content of the slags varied between 64 and 60 wt% as the Cu content increased. The viscosity of the slag containing 10 wt% CuxO was nearly 4.5 times lower than the binary CaO-SiO2slag. As the silica mole fraction (xSiO2) actually stayed constant (0.61±0.009),the results show that CuxO acted as a network breaker. Comparison with other ternary slags with similar silica mole fractions suggest that that addition of CuxO to silicate slags has a stronger effect on lowering the viscosity than FeO or MnO has on a molar basis. Keywords: viscosity, copper, silicate, slags

Jan 1, 2004

By E. Matinde, S. L. Msibi

"The robust nature of alumina refractory materials presents opportunities for their in-process reclaiming and re-use in non-critical applications. Virgin refractories can be substituted with different quantities of reclaimed materials without compromising the quality of the refractory products. In this study, the effect of reclaimed bauxite on andalusite-containing refractory castables for tundish applications was investigated. The recycled bauxite was formulated in different proportions to replace virgin andalusite in the castables. Standard tests were conducted to evaluate the physical, physicochemical, and thermochemical properties of the formulated products. Static corrosion tests were conducted using tundish slag in order to simulate the actual operating conditions. The results show that the standard flow behaviour, open porosity, and bulk density of samples containing up to 22 mass% reclaimed bauxite were comparable to those of the reference castable. However, high-temperature properties such as static corrosion at 1400°C and hot modulus of rupture at 1500°C indicated that there is an upper constraint to the amount of substitution. The study demonstrated direct potential savings of up to 10% when the reclaimed alumina replacement ratio was increased to 22 mass%. IntroductionAlumina-based refractories can be classified into low-alumina, containing less than 50% Al2O3, and high-alumina or bauxite, containing between 50 and 90% Al2O3. High-alumina refractories have widespread applications in high-temperature metal extraction processes due to their outstanding thermochemical and thermomechanical properties and stability (Rebouillat and Rigaud, 2002; Frulli, 2016). The typical chemical composition of refractory-grade bauxite consists of 85–90 wt.% Al2O3, 5–10 wt.% SiO2, 1–2wt.% Fe2O3, 3–4 wt.% TiO2, 0.4–0.8 wt.% CaO + MgO, and 0.20–0.8 wt.% K2O + Na2O (Nyoka et al., 2013). The thermochemical and thermomechanical properties of bauxite-based refractories rely principally on the conversion of the contained silica and alumina to the highly stable corundum (?-Al2O3) and mullite (3Al2O3· 2SiO2) phases (Rebouillat and Rigaud, 2002; Hill and Sehnke, 2006; Garbers-Craig, 2008; Frulli, 2016)."

Jun 1, 2019

By J. L. Taylor, E. B. Viljoen, W. M. Craig, A. M. McIntosh

The Chemwes uranium plant treats old gold-plant residues from the Sttifontein and Buffelsfontein Gold Mines by acid leaching, belt filtration, countercurrent ion exchange (ClX), and Bufflex solvent extraction (SX). The uranium is recovered by precipitation as ammonium diuranate. Absorption and elution in the CIX section are achieved in four NIMCIX columns operating as two parallel streams. Each loading column is 4,85 m in diameter and contains 12 absorption stages. The elution columns are 3 m in diameter and contain 8 stages. The eluant used is 10 per cent sulphuric acid at ambient temperature. During the commissioning and initial operating periods reported here, the plant yielded an average barren solution of 1,6 p.p.m. of U3O8 from a feed with a mean U3O8 concentration of 132 p.p.m. The U3O8 concentrations in the barren solution were better than 2 p.p.m. some 85 per cent of the time, and better than I p.p.m.73 per cent of the time. Investigations are underway to institute an automatic control system that will result in the U3O8 values on the resin and in the barren solution being maintained at or near the target values in spite of changes in the concentration of uranium in the feed solution.

Jan 1, 1982

By L. Capponi

At Tapira Mine (Tapira/MG/ Brazil), the largest phosphate concentrate producer in Brazil, the mining is fully mechanized and carried out using open pit mining. This work presents a review of the sampling protocol used for short term mine planning at different stages. Sampling is carried out in two steps. Firstly, diamond drill cores are sampled at 50 x50 x5 metre pattern. Fosfertil analyses grades of P2O5, Fe2O3, CaO, MgO, SiO2 and TiO2 plus geological logging. This information feeds the long term block model. Secondly, drill cuttings are collected at the mining faces released for blasting. The drilling pattern is staggered and when blasting is not necessary, a drill hole is made centered in the block area (25 x 25 x 5 m). The primary samples have mass approximately 60 kg and the same chemical parameters are analysed. Metallurgical and mass recovery tests are performed as well. These samples are used to build the short term block model. At the final stage, the short term mine planning model is used to build a stockpile blending model which is simulated using a spreadsheet to match the goals established by the process plant.

Jan 1, 2009

By Z. Yang, X. Bian

"The synthesis of 3-hydroxy-2-naphthyl hydroxamic acid (H2O5) as a collector for bastnaesite is described. The flotation performance of H2O5 with respect to bastnaesite was investigated by flotation tests, measurements of the surface adsorption capacity, and polarizing microscopy. The results indicated that H2O5 exhibits superior collecting performance compared with direct flotation recovery of bastnaesite, with recoveries above 90% at pH 8–9. The adsorption mechanism of H2O5 on bastnaesite was studied by solution chemistry analysis and ?-potential tests. The results showed that the adsorption of H2O5 is associated with the types and concentrations of hydrolysis products of rare earth cations on the bastnaesite surface. At pH 8–9, the hydrolysis-dominant components RE(OH)2+ and RE(OH)2 + of the rare earth cations were adsorbed onto the bastnaesite surfaces, which were considered to be the major positive active points and were beneficial to chemical adsorption of the reagents. The pH range of 7–10 was optimum for bastnaesite floatability, and the adsorption of H205 on bastnaesite was by means of chemical adsorption through formation of a five-membered ring chelate. IntroductionThe rare earth elements (REEs) have long been known as ‘industrial gold’ and are widely used in the petroleum, chemical, ceramic, metallurgical, and permanent magnet material industries because of their special physicochemical properties (Chen, 2011; Krishnamurthy and Guptac, 2002; Esquivel, Bohe, and Pasquevich, 2002; Abrahami, Xiao, and Yang, 2015). Demand for REEs is growing in response to continuous advances in science and technology. Currently, most REEs are extracted from bastnaesite ((Ce,La)CO3F) (Chelgani et al., 2015; Yosry, 1990), which is recovered from rare earth ores by flotation. Typically, hydroxamic acids are used as bastnaesite collectors (Xu, 2015; Ren, 1997; Mousumi and Venugopal, 2016). Research into the mechanism of interaction between hydroxamic acids and bastnaesite is important for improving the recoveries of bastnaesite. However, there have been few studies that examine this mechanism."

Jan 1, 2017

1. Book reviews Tungsten: 1982. London, Mining Journal Books Ltd, 1982. 179 pp. Reviewer: G.A. Brown The geology of industrial minerals in Canada, edited by G.R. Guillet and Wendy Martin. Canadian Institute of Mining and Metallurgy, special volume 29. Reviewer: R.W.O. Kersten Foam flotation - theory and applications, by Ann N. Clarke and David J. Wilson. New York, Marcel Dekker, 1984. 418 pp. Reviewer: B.K. Loveday Industrial and financial indicators of the steel industry, by Patrick Genevaz. Paris, La Chambre des Cartes, 1982. 2 vols. Vol I: Analysis and conclusions, FF3500. Vol. 11: Tables, FF4000. Reviewer: R.J. Dippenaar An encyclopaedia of metallurgy and materials, by C.R. Tottle. Plymouth, Macdonald and Evans and The Metals Society, 1984. 481 pp. RI44,50. Reviewer: P. T. Wedepohl The role of crack growth in metal fatigue, by LP. Pook. London, The Metals Society. Reviewer: C.A. Boothroyd Hydraulic coalmining - new technology and its geological and industrial significance, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 33 pp. Hydraulic coalmining - hydromining update: potential impact on coal deposits and coal mining industry, by H.C. Siebert. Hamm, Zentraldruckerei BAG, 1984. 130 pp. Victoria's brown coal. A huge fortune in chancery, edited by J .T. Woodcock. The Australasian Institute of Mining and Metallurgy, 1984. 204 pp. Reviewer: J.J. Versluis 2. Canadian publications The following reviews of the activity and developments during 1982 in respect to the chief minerals produced or consumed in Canada are now available. Zirconium. An important mineral commodity. Mineral Policy Sector, Mineral Bulletin MR 202, $6.60. Canadian minerals yearbook 1982. Mineral Policy Sector, Mineral Report 32, $40.75. Canadian reserves of copper, nickel lead, zinc, molybdenum, silver and gold as of January 1, 1983, by W.H. Laughin. $4.20. Mineral Policy Sector, Mineral Bulletin MR 201. Sulphur market profile, by B.W. Boyd. Mineral Policy Sector, MRI 84/5. 3. Mintek publications Report M123 The use of of activated charcoal in a NIMCIX column for the recovery of gold from cyanide solutions. Report M150 Energy transfer in the hearths of submerged-arc furnaces. Report M151 A preliminary investigation of the initiation of pitting corrosion in austenitic stainless steels and nickel-based alloys. Report M154 The reduction of Winterveld chrome spinel at 1300°C under an argon atmosphere in the presence of carbon. Report M165 The development of an improved on-line gold analyser. Report MI67 three nebulizers for use with an inductively coupled plasma spectrometer. 4. New publications Mineral Industry Consultants Association (as at 31st March, 1984). Parkville (Australia), The Australasian Institute of Mining and Metallurgy, 1984. 112 pp. Philosophical and procedural guidelines for the planning professions. Johannesburg, the Environmental Planning Professions Interdisciplinary Committee (EPPIC, P.O. Box 61019, Marshalltown 2107), R2.50. Directiona//y solidified materials for high temperature service, by M. McLean. London, the Metals Society, 1983. 337 pp. Tin and its uses no. 142. Greenford (England), International Tin Research Institute, 1984. Metals engineering International Symposia & Exhibitions Ltd - a subsidiary of Industrial Newspapers PLC - are pleased to announce that they will be organizing a mammoth engineering event, entitled Metals Engineering 86, comprising five important exhibitions in 1986:. Agglomeration A major symposium on agglomeration is being organized in Toronto for the 2nd to 5th of June, 1985. Speakers from around the world (Canada, U.S.A., Brazil, Australia, Japan, West Germany, Italy, India, China, Switzerland, Poland, Yugoslavia, and France) will address delegates on various aspects of agglomeration relative to iron ore, coal, coke, and fuels. Plenary theme papers will also be presented by speakers from Japan, the U.K., and the Netherlands.

Jan 1, 1985

By S. Fuchida, Y. O. Zubair, C. Tokoro

Mining of As-bearing minerals had resulted in the release of arsenic species predominantly As(III), which is known to be more toxic, and undue exposure to it is detrimental to human organ systems. Many materials have been examined for As(III) removal, but it is still challenging to advance sustainable materials for effective removal of As(III). In this paper, a more eco-friendly and superparamagnetic Fe0-Fe3O4 composite was synthesised and evaluated for heterogeneous catalytic oxidation and removal of As(III) with peroxymonosulfate (PMS, KHSO5). The kinetic removal studies showed that removal of As(III) was probably through a chemical process and the Elovich model best represented the experimental data. The removal capacity for As(III) on Fe0-Fe3O4 with PMS (1.76 mmol/g) is superior to that without PMS (0.83 mmol/g). Combined results from XPS and ESR showed that As(III) was fully transformed to As(V) through catalytic oxidation by Fe0-Fe3O4/PMS and afterwards enhanced its removal. The removal mechanism of arsenic was ascribed to the formation of outer-sphere (electrostatic attraction) and inner-sphere complexes. The adsorbent can be separated easily from water due to its excellent magnetisation (64.5 emu/g) and also has good reusability potential as more than 85% of the initial concentration of As(III) was immobilised after five consecutive cycles. Keywords: Arsenite, Fe0-Fe3O4 composite, catalytic oxidation, removal mechanism

Jan 1, 2020

By Merete Tangstad, Kai Tang

The primary aim of the present investigation is to develop a model which permits to calculate/predict the viscosities of ferromanganese slags, typically focus on the MnO-SiO2-Al2O3-CaO-MgO-FeO multicomponent system. The present viscosity model emphasizes the ability of prediction, i.e. using the binary parameters to extrapolate the viscosities in ternary and higher order systems. To this end, a physical sound model is essential. Temperature dependence of viscosity is described by the Eyring?s formalism. The well-known cell model is used to define the SiO44- tetrahedra in the silicate melts. Composition dependence is expressed in term of viscous activation energy, which is characterized by the binary structural units. The viscosities in ternary and higher order systems are hence predicted using the binary activation parameters. The model has been used to calculate the viscosities in the whole liquid composition range of ferromanganese slag.

Jan 1, 2007

Council Members 1988/1989, left to right: Row 1 (seated): H.E. James, P.W.J. van Rensburg, Dr H. Wagner, B.C. Alberts, C.E. Flvaz (President), H.G. Mosenthal, R.D. Beck, Professor A.N. Brown, Dr P.R. Jochens Row 2 (standing): P.C. van Aswegen, J.P. Hoftman, D. Wllson, P.M.T. White, K.A. van Gessel, Dr LA. Cramer, J.S. Freer, V.J. Moore, G.A. Brown, R.A. Snodgrass, J.D. Austin Row 3 (standing): Dr G.A. Fourle, Dr J. Lurle, A.M.P. Henderson, R.P. Mohring, J.A. Cruise, J.L. Nel, H. Scott Russell, J.P. Deetlefs, D.A.J. Ross-Watt Inserts, top row: K.R. Beard, N.J. De~ine, R.J. Dlppenaar, G.T.G. Emere, Dr J-P. Franzidls, Professor R.P. King, J.G. McCallum. Bottom row: G.Y. Nisblt, Professor R.P. Plewman, Dr R.E. Roblnson, Dr O.K.H. Steften, P.A. van Wlelllgh

Jan 1, 1989

By R. J. Davidson, W. D. Douglas, J. A. Tumilty

SYNOPSIS Two pilot plants operating on different types of carbon were used to generate steady-state adsorption data in the treatment of gold-plant solutions of high and low tenor. A pilot plant comprising three 4 m long columns and using 3 mm extruded activated carbon was used to treat pregnant solutions with a gold concentration of 5 to 8 g/t at pH 10 to 11,5. Column influent was pumped at a super¬ficial flow velocity of 0,5 m/min while the carbon was moved daily so as to effect gold loadings on the carbon of 5 to 10 k /t. With a carbon-bed depth of 12 m, an adsorption efficiency of 99,9 per cent was obtained in a bed depth of 9 m, which was subsequently reduced to 8 m when the depth of the carbon bed was reduced to 8 m. This improvement in efficiency was attributed to the reduced residence time of the carbon from 12 to 8 days. A corresponding decrease in adsorbed silica indicated that some silica fouling of the carbon had occurred. A second pilot plant, comprising a single column 6 m in length and using coconut-shell carbon of 1,0 to 2,4 mm, treated a solution with a gold concentration of 0,7 g/t at pH 8,0. Feed solution was pumped at a superficial flow velocity of 1,0 m/min while carbon was moved every 8 hours to give gold loadings of more than 5 kg/t. An adsorp¬tion efficiency of 99,5 per cent was indicated at steady state. Intermittent washing of the column with dilute hydrochloric acid was shown to have a beneficial effect on the gold adsorption and to reduce the pressure drop across the column. Intermittent washing with dilute sulphuric acid indicated that there had been some passivation of the car¬bon during the treatment of a solution with a gold concentration of only 0,2 g/t. Compared with other adsorption systems, the countercurrent moving bed appears to offer significant advantages in terms of metallurgical efficiency and capital investment. The inability normally associated with moving-bed systems to treat solutions containing suspended solids may be overcome to a degree by the use of relatively coarse extrud¬ed carbon.

Jan 1, 1985

By M. Tang, X. Tong

"SynopsisSlime coating is one of the most common ways for serpentines to contaminate metallic mineral concentrates during traditional flotation of coarse sulphide particles. This could pose quite a complicated and challenging problem in the case of some types of low-grade and finely disseminated Cu-Ni ores bearing high serpentine contents. This is the case for the copper and nickel sulphides from the Yunnan Mine, China. Previous batch flotation tests of this ore resulted in satisfactory recoveries of 86.92% Cu, 54.92% Ni, and 74.73% Pt+Pd, and concentrate grades of 4.02% Cu, 3.24% Ni, and 76.61 g/t Pt+Pd. However, the MgO content in these concentrates was more than 19%. In the current study, microflotation tests and settling rate tests were introduced to investigate the effects of a combination of strong collectors (a 2:1 weight ratio of butyl xanthate and butyl ammonium dithophosphate) on entrainment of serpentines in metallic mineral concentrate, as well as visual observations of the concentrates in suspension using still photography. All test results indicated the presence of serpentines entrapped in the hydrophobic flocs that resulted from these collectors, even with the use of effective gangue depressants. These strong collectors are used to flocculate the ultra-fine sulphides by forming loose and ‘fluffy’ hydrophobic flocs. However, these hydrophobic flocs may also be able to load or entrap some serpentine slimes into the concentrate, and this entrained serpentine could be harder to remove by using depressants or intensified conditioning than serpentine slime coating on the particle surfaces.IntroductionSerpentine minerals, which have the generalized composition (Mg,Fe)3Si2O5(OH)4, can be easy to crush and grind due to their convoluted and bent layered structures. These serpentines can hinder the enrichment of some metallic minerals and dilute their concentrates by entrainment during flotation. The resulting high pulp viscosities, slime coatings, and high content of dissolved ions adversely affect the flotation recoveries of copper and nickel sulphides, and high levels of MgO entrained in the concentrates lead to heavy penalties from smelters. Since the quality of nickel flotation concentrate depends heavily on its MgO content (generally less than 6–7% for No.1 or 2 grade nickel concentrate according to the standard requirement from National Nonferrous Industry), reducing the entrainment of serpentine during flotation is becoming more and more pressing. Previous research has focused on the collectors and depressants that are commonly used in copper-nickel flotation, as well as their interaction mechanisms."

Jan 1, 2015

The January General Meeting of the Institute was held in Kelvin House, Johannesburg, on 15th January, 1969 at 4.30 p.m. Mr R. C. J. Goode (President) was in the Chair. There were also present eighteen Members, including Messrs F. P. Bath, H. Britten, J. K. E. Douglas, P. Lambooy, V. C. Robinson, W. T. Stobart and P. W. J. van Rensburg (Council Members), Messrs J. C. Hall, P. C. Pirow, Dr D. I. Legge, Messrs E. R. Rudolph, H. R. Reid, Dr N. Stutterheim, Messrs B. F. van der Merwe, L. W. P. van den Bosch, D. T. Watt, M. Youngworth and T. Zadkin. Two Associate Members, Dr P. R. Jochens and Mr D. A. Viljoen. Two Students, Messrs R. P. W. Henrard and D. Ossin. Sixteen Visitors, including Messrs I. Barnes, B. F. Bath, S. Botha, P. A. du Plessis, K. Edwards, Dr F. S. Fulton, Messrs H. Grant, B. Havenga, L. Kok, Dr D. Lasar, R. Sandler, C. W. Wolhuter and J. D. Young. Secretary, Mr D. C. Visser. Total present: Forty. MINUTES The President: "May we confirm the minutes of the meeting held on the 20th November, 1968, as published in the December, 1968, issue of the Journal?" Agreed. MEMBERSHIP The President: "I have much pleasure in announcing that the names of the under-mentioned candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership of the Institute in the following grades: Members: Basil James Jackson and James Petrie Archibald. Associate Members: Ronald Creasy, Hugh Angus McCallum and John Barton Cunliff. Graduate: Hermanus Isak Johannes van der Merwe. Affiliate: Edgar Ramsay. Student: Petrus Daniel Wolmarans. MEMBERS TRANSFERRED TO A HIGHER GRADE From Affiliate to Associate Member: Neil Bradfield and Mervyn Bayard Allman. "I welcome the newly elected members to the Institute and congratulate those members who have been transferred to a higher grade." (Applause). GENERAL BUSINESS The President: "Are there any matters to raise under this heading? If not, we will proceed to the next item on the agenda which is the presentation of today's paper."

By J. Krzyzanowska

Paper written on project work carried out in partial fulfilment of Bachelor of Engineering-Mining Venetia Mine, an open-pit diamond mining operation in the Limpopo Province of South Africa, currently has a mixed haul truck fleet consisting of Caterpillar 785B and C; 789C; modified 793D and 793D. Even in an ideal situation these trucks have different cycle times, which causes queuing at the loading area and their different speeds cause bunching on the ramps, leading to higher overall cycle times and lower productivity. This problem was identified but the root causes of the problem were not investigated and quantified. A time and motion study on the haul trucks was thus undertaken to measure actual cycle times and compare them to ideal cycle times as well as to observe any reasons for deviations. Ideal cycle times are partly evaluated on the basis of simulation and partly from production optimization expert input. Several areas that affect production were identified and these include: haul road conditions, the control room, dispatching programme and dispatching data management, as well as truck-shovel matching. The investigation was important in establishing control parameters for haul fleet operation since time spent queuing is production time lost, which defers waste tonnes to later in the life of mine, thus decreasing the tempo at which kimberlite is exposed.

Jan 1, 2007

By P. Muthaphuli

Kumba Iron Ore?s Zandrivierspoort (ZRP) magnetite-haematite project aims to mine and beneficiate a magnetite resource with low contaminant levels to produce from 1 Mt/a to 2.5 Mt/a product, which will be either a concentrate, micro-pellets for direct reduction, or blast furnace pellets. Anglo American Technical Solutions Research conducted a number of piloting campaigns to validate the process design flow sheet, demonstrate process performance, and to generate data for use as a design basis. Secondary to this, the pilot plant was to produce approximately 7 t of magnetite-haematite concentrate with low enough SiO2 to be used as feedstock for pelletizing studies. The pilot plant achieved 34.2% mass yield, at 69.0% Fe, 2.2% SiO2, from an IsaMill grind of 80% -45 µm. This product quality will compare favourably to other leading direct reduction (DR) pelletizing concentrates. However, two-stage comminution to 80% -75 µm and beneficiation of ZRP ore will produce a blast furnace (BF) quality pelletizing concentrate, indicative quality being 67.6% Fe and 4% SiO2, at higher mass yields. An economic evaluation between producing a DR and a BF pelletizing concentrate will have to be conducted prior to finalizing the concentrate production flow sheet..

Jan 1, 2014

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House on Wednesday, 23rd August, 1978. Mr P. A. von Wielligh (President) was in the chair and declared the meeting open at 16h00. Obituaries The President: It is my sad duty to announce the death of the following members of the Institute : T. K. Prentice and W. E. Gooday, Honorary Life Fellows and Past Presidents; B. S. Allen, J. A. Becking, L. H. Mellor, C. A. Pratt and W. T. Stobart, Life Fellows; J. P. Burls, E. Cameron, M. L. Fitzgerald, C. G. Hinds, A. J. Patrick, H. O. Reisener, N. D. Shuttleworth, N. Soldan and J. Whitehouse, Fellows; T. Gemmell, J. S. A. Oelofse, W. D. Rowe, R. L. J. Shearman and G. M. Thain, Associates. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments' silence. Welcome The President: It is now my very pleasant duty to welcome our distinguished guests and visitors. We are pleased to have with us Mr D. A. Etheredge, Vice¬President of the Chamber of Mines of South Africa, and Mrs Etheredge. Mr Etheredge this afternoon represents the mining industry at our meeting. The importance of the close link that over the years has been maintained between the industry and our Institute speaks for itself. We are, therefore, grateful that he and Mrs Etheredge have managed to find the time to be with us this after¬noon.

Jan 1, 1979

By C. Righi, R. Carli

In modern steel continuous casting technologies mould fluxes are well-known to assure lubrication required by tribological system of mould-solidifying strand shell, and to provide crystalline phase solid film, contributing to control heat extraction between strand and mould wall. Actual cooling rates during normal continuous casting mould operations are far higher than critical cooling rate of the liquid slag. Indeed, DTA measurements point out that even relatively small cooling rates of 30?50 K/min are high enough to give exiguous formation of crystals. In this paper, contribution of devitrification in defining crystalline phase formation of industrial basic mould slag, used in continuous casting of crack-sensitive steel grades, has been investigated by means of non-isothermal experiments study. Devitrification has proved to play a major role in mould flux crystallization in a working environment explaining the higher amount of crystalline phase formed in plant sample in comparison with lab sample from DTA analysis with typical cooling rate of 5?20 K/min. The amount of crystalline phases formed ranks as follow: Cuspidine > Combeite > Gehlenite. Kinetic analysis of DTA non-isothermal experiments has provided kinetic parameters through Kissinger and Ozawa methods, as Avrami constant resulting to be n ?2 and activation energy of Cuspidine crystallization resulting to be EC= 315 kJ/mole. The effect of addition to the parent material of oxides as MnO, TiO2, ZrO2, Al2O3 and Fe2O3near to saturation point has proved to affect, in certain cases, crystallization behaviour of mold flux. In particular, MnO, TiO2, ZrO2oxides produce a relevant dump of crystallization of Combeite and Gehlenite phases, while Al2O3and Fe2O3do not appreciably affect crystallization. Key words: Mould flux, crystallization, devetrification, DTA non-isothermal analysis, Kissinger and Ozawa methods.

Jan 1, 2004

By G. Coetzer

"Prior to operating a non-recovery coke pilot plant oven, it was essential to ascertain coal cake stability during the loading of a 1 m3 (1 m × 1 m × 1 m) coal cake into the cold pilot-plant oven by a pusher mechanism. Previously established laboratory-scale compaction parameters, to obtain coal cakes with sufficient stability, were employed during the loading tests of the coal cakes. Two different coals were evaluated, namely Waterberg semi-soft coking coal (sscc) and Oaky North hard coking coal.It was demonstrated that lower applied compaction forces (14%) can be utilized during 1 m3 compaction, in comparison to laboratory-scale tests, to obtain similar wet cake densities, owing to differences in the effect of frictional forces. Wet cake densities for Waterberg sscc improved slightly (3%) to 1.13 t/m3 when utilizing 79 t/m2 applied force for a 1 m3 coal cake, in comparison to laboratory-scale tests. Similar results were obtained for Oaky North hard coking coal, with a 6% density increase to 1.27 t/m3 at a similar applied force. Porosities decreased by 13% and 32% for Waterberg sscc and Oaky North coal, respectively, when 1 m3 compaction was compared to laboratory-scale tests. An opportunity exists to further decrease the porosities of Waterberg sscc during compaction, whereas acceptable compaction parameters were achieved for Oaky North hard coking coal. Most major vertical cracks and the partial collapse of coal cakes were mitigated, and high-stability coal cakes were obtained that could be successfully loaded into the pilot-plant coke oven by a pusher mechanism.Factors contributing to the instability of the coal cake during loading into the oven, such as vertical cracks, are (i) the cubic geometry (1 m3) of the coal cake, (ii) friction exerted by the oven floor, and (iii) mechanical problems, such as a misalignment between the pusher machine feeder plate and the oven floor. IntroductionOperation of the stamp-charging horizontal 1 t electrically heated coke pilot-plant oven at Exxaro Resources requires coal cake stability during the loading of a 1 m3 compacted coal cake into the oven. In this case, a pusher plate is utilized to push the coal cake into the oven over the oven floor. This is in contrast to a ‘spoon’ or bottom plate feeding mechanism as found in industrial horizontal coke ovens. The pusher plate loading mechanism dictates that the coal cake should possess high stability and inherent strength owing to frictional forces exerted by the oven floor. In order to obtain a coal cake of acceptable stability for the 1 t coke oven, various compaction parameters need to be verified and established."

Apr 1, 2019

By H. A. D. Kirsten

Written contribution by L.J. Besaanst I am a Mechanical Engineering Technician (T3), and wish to further my education to at least NHD (T4) level. I read your paper in the Journal of The South African Institute of Mining and Metallurgy with great interest, and must compliment you on its brilliance. However, there are some questions I should like to ask, and certain points I should like to highlight. I should appreciate your comments. Written contribution by J.F. Curtis The comprehensive and finely detailed survey of, and proposals for, engineering education in South Africa reflects the author's wide experience in the needs for, and the provision of, such education. This paper wil make a major contribution to the enhancement of the profession of engineering and the improvement in quality of engineering activities in South Africa. Contribution by G.W. Annandalet I have studied your paper in some detail, and am of the opinion that it makes an important contribution to the topic of the development of technological manpower, which is currently being debated in South Africa at al levels. Debate on this topic has risen above the level of academic discussion; it has been discussed by the Economic Advisory Council of the President, and is being considered at Ministerial level. Author's reply to L.J. Besaans Thank you for your contribution and complimentary remarks. As you have pointed out, there are certainly many aspects that will have to be addressed in the resolution of the crisis in engineering education. I trust that the following comments satisfactorily answer the queries you have raised. Author's General Comments Since publication of the paper, attention has become focused on the provision of employment opportunities an aspect not dealt with specifically in the paper. The following comments serve to indicate some of the directions in which job opportunities will have to be developed in the numbers that will be required.

Jan 1, 1991

By E. T. Boome, A. C. Schmidt

P .E.R. T. and how P .E.R. T. techniques can be used in modern mine management by E. T. Boome and A. C. Schmidt Published in the Journal, December 1972 DISCUSSION A. E.W. FLETCHER A.c.S.A.* In making this contribution to the authors paper, I should first like to congratulate them on the clear and yet detailed way in which they have illustrated their subject. I should also like this contribution to be linked with Mr Hazell's paper "Mine Management by Objectives".

By A. V. Pavlov, V. A. Grygorian, Kossyrev, A. E. Semin, A. Korostylev

A new way of producing low-silicon ferrosilicon from iron-ore materials in a new type of aggregate-oxygen reactor is presented. The oxygen reactor process is based on using the calorific combustibility and reducibility of carbon materials inside the aggregate. The key to the process is successful post-combustion of carbon monoxide above a layer of a solid coke bed. Initially the possibility of production of grades of ferrosilicon containing 20 to 25% Si (FeSi20-FeSi25) was studied on a laboratory model of the oxygen reactor. Quartz sand and iron ore concentrates (from Russia and India) were used in the laboratory tests. This test work demonstrated that a ferrosilicon grade FeSi15 could be obtained directly from raw iron ore (containing 75.9 % Fe2O3 and a maximum of 23.8 % SiO2) without using rich iron-ore concentrates. The process was successfully tested on a pilot furnace at Serovsky metallurgical plant. Very promising results and efficiency parameters were achieved. The consumption of materials for 1t of ferrosilicon (15 % Si) production was as follows: 1567 kg raw iron ore, 591 kg of coal (in a composition of ore-coal briquettes), 299 kg of coke (for coke bed formation), and 815 m3 of oxygen.

Jan 1, 2004