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By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By J. H. Viljoen, C. H. Graan, N. B. Strydom, J. S. Greyson

M J Martinson (Fellow) There is everywhere a lamentable dearth of quantitative information on occupational factors affecting the health and safety of mineworkers, and as the authors point out in their introduction underground lighting is one of the factors which has received little attention in South Africa prior to this welcome paper. Since the authors are to some extent pioneering, it is perhaps inevitable that the paper should raise more questions than it answers, but nevertheless it provides a provisional yardstick against which the need for, and success of, remedial action may be judged. Before commenting in detail on a few aspects of the paper it may be worthwhile to summarize the statutory provisions relating to underground lighting, contained in Chapter 15 of the Regulations promulgated in terms of the Mines and Works Act 27 of 1956. Chapter 15 is entitled `Lighting, Safety Lamps and Contraband', but in the context of the present paper only four simple regulations need be noted: firstly, no person shall work or travel in an unilluminated part of a mine unless he carries a light ; secondly, adequate stationary lights shall be provided at stations and certain other localities in shafts, winzes and places used for winding; thirdly, mechanically propelled conveyances shall be provided with an effective bright light shining in the direction of travel; and fourthly, moving machinery to which personnel have access shall be illuminated so as to be clearly visible. In all four regulations the standard of lighting to be provided is wholly subjective, and under these circumstances the wide inter- and intra-mine variations in light intensity disclosed by the study are hardly unexpected. Nevertheless the data presented in the authors' Table I raise three points (1) Is there any evidence that the 19 mines visited during the survey are representative of the 45-50 large gold mines in South Africa, or that the shafts selected are representative of the respective mines? Mine managers would scarcely be human were they not to offer better lit working places for the survey; perhaps the use of a scaling factor (e.g. tonnes or transit mineworkers per shift, kilowatts, etc.) for each working place might have helped to put the figures in perspective. (2) Looking at two of the more numerous - and probably important - of the ten working places included in the survey, i.e. stations and tips, one is struck by the marked. skewness of both intensity distributions (with higher frequencies at the lower intensities) and the abrupt cut-off in both cases just short of pitch darkness. Thus, of the 45 meaned readings recorded at 26 tips no less than 19 fall in the lowest range of 0,1-0,9 1m/ft2, with but one tip in total darkness; of 46 readings on 26 stations, 7 fall in the lowest range and none is in total dark-'1 ness. Although a light with an intensity in the range 0,1-0,9 1m/ft2 may satisfy the regulations, it is certainly arguable that in some situations it may be safer to have no light at all. (3) In view of the skewness referred to above, one wonders how meaningful are the `total average light intensities for (the gold mining) industry' quoted in Table I, which the authors compare with illumina¬tion levels found in other countries. Looking at tips again, one notes that 34 out of 45 meaned intensity readings fall below the `total average' for tips, and only 10 exceed it. From this it may be concluded that a few well-lit working places included in a `total average' may conceal a plethora in Stygian gloom. In their discussion the authors make fleeting reference to the effect of underground lighting on productivity and accident rates, without however quoting any South African experience in this regard. Intuitively it seems highly likely that better lighting (in the widest sense) would improve productivity and reduce accidents, and of course it is in these areas that the mining industry might seek economic justification for providing better lighting. It is all the more regrettable therefore that these factors were not studied simultaneously with the present investigation, especially at the Psychological Division of the Human Sciences Laboratory has recently published a study on underground accidents in the gold mining industry without making any reference whatsoever to lighting as a causal factor. In the event neither of the two studies enables us to make an economic appreciation of the situation, and this seems to be a classic example of a situation where some dovetailing of research effort would have greatly increased the useful return. On the effect of lighting on accidents, it may be noted that in 1939 Mickel presented some very interesting statistics to the Mine Managers Association of the Transvaal2, on the improvement in accident rates which followed the random issue of electric cap lamps to native mineworkers in the Hercules Section of E.R.P.M. the previous year. Based on a 12 month trial period in which 250 000 shifts were worked with carbide lamps and (contemporaneously) 307 000 shifts with cap lamps, the incidence of major accidents (at least one day in hospital among men using carbide lamps was 1,15 accidents per 1000 shifts, while the incidence of minor accidents (requiring dressing only) was 11,52 per 1 000 shifts. The corresponding figures for men using cap lamps were 0,79 and 7,31 accidents per 1 000 shifts respectively, representing a reduction of over 30 per cent in both major and minor accidents. While these figures are obviously dated - only men using cap lamps were issued with hard hats, for instance - they do indicate a need for similar research today.

Jan 1, 1971

1. Book review • World mineral statistics 1974 to 1978. Production: Exports: Imports. London, H.M.S.O., Institute of Geological Sciences, 1980. (Reviewer: R. P. King) This edition is the third in a regular series prepared by the Institute of Geological Sciences. It is a useful compilation of statistics on the production, export, and import of fifty-eight different mineral commodities. Each mineral is listed by country, and a table is provided for the annual production, the annual imports, and the annual exports for each commodity included. However, some commodities are treated in considerably more detail; for example, aluminium and bauxite have tables under the following headings: Production of Bauxite, Production of Alumina, Production of Primary Aluminium, Exports of Bauxite, Alumina and Aluminium, Imports of Bauxite, Alumina and Aluminium. The information presented is the latest official information available from primary sources; the compilers have not relied on data from secondary compilations. This publication will be of considerable assistance to all who are concerned with the trading of mineral commodities and their production.

Jan 1, 1981

By C. R. Thomas

Although stainless steels have been used to a limited extent in the South African mining industry, the metallurgical development of 3CRI2 has presented materials engineers with a viable alternative for certain materials-handling applications. The various types of wear involved in these operations are described, and an explanation is given of how 3CRI2 is able to offer advantages, particularly in wet sliding applications. Certain applications result in various types of abrasive wear, and the performance of 3CRI2 in these areas is described.

Jan 1, 1981

Corosion technology: An information source book, by Judith Ann Douvile. Taylor & Francis, 1989. 188 pp. £32. Stainless steel buyers guide 1990. Southern Africa Stainless Steel Development Association (P.O. Box 4479, Rivonia, 2128), 1990. Free. Fatigue and stress of engineering materials and structures, edited by H.P. Lieurade. ITT International (40 Promenade Marx-Dormoy, 93460 Gournay-sur- Marne, France), 368 pp. US$ 109. Titanium and aluminium, edited by P.A. Coulon. ITT International (40 Promenade Marx-Dormoy, 93460 Gournay-sur-Marne, France), 200 pp. US$ 80. Engineering applications of stochastic processes. Theory, problems and solutions, by A. Zayezdny, D. Wulich, and D. Tabak. Chichester, John Wiley, 1989. 525 pp. £54.50. Metal behaviour and surface engineering, edited by S. Curioni, B. Waterhouse, and D. Kirk. ITT International (40 Promenade Marx-Dormoy, 93460 Gournaysur- Marne, France), 413 pp. US$ 109. Fuzzy control and fuzzy systems, by W. Pedrycz. Chichester, John Wiley, 1989. 272 pp. £37.50. CILO (carbon-in-leach with oxygen) cost study, by Minproc Engineers (USA). Free.

Jan 1, 1990

By Z. Khan

Iron, in the form of steel and stainless steel, is the most commonly used metal in the world. Plain steels corrode and oxidize easily, while stainless steels exhibit improved corrosion and oxidation resistance. It has been found that rare earth metal (REM) additions, such as cerium and erbium, result in the improvement of the abovementioned properties in iron-containing compounds. Gadolinium is a REM, however, there is very little information available on the influence of gadolinium on the microstructure and mechanical properties of iron-containing compounds. Thus, the purpose of this research project was to determine the influence of gadolinium additions on the microstructure and mechanical properties of mild steel and 316 stainless steel. Ten alloys were produced for the purposes of this research. Five of the alloys had a base composition of mild steel while the remaining five had base composition of 316 stainless steel. The alloys for each of the base composition contained gadolinium additions of 0.1, 0.5, 1.2, and 5 weight per cent. The as-cast and the cold-rolled alloys were analysed. The alloys responded well to the cold-rolling with the exception of the 5 weight per cent gadolinium mild steel and stainless steel alloys. These alloys were extremely brittle and underwent a significant amount of cracking during the cold rolling process. A microstructural analysis of the alloys was conducted using a light optical microscope, while the chemical analysis of the alloys was conducted using energy dispersive x-ray spectroscopy (EDS). The resulting microstructures and EDS analyses revealed that the gadolinium displayed minimal solubility in the ferrite matrix of the mild steel alloys and minimal solubility in the austenite matrix of the stainless steel alloys. Instead the gadolinium formed as an interdendritic secondary phase in both alloys. EDS analysis revealed that the secondary phase in both alloys was gadolinium-rich. Vickers microhardness tests conducted on both alloys revealed that the alloys were composite-like, with a hard, brittle gadolinium-containing compound dispersed throughout a softer, more ductile matrix. The corrosion resistance of the alloys was determined through potentiodynamic anodic polarization tests. Two solutions were used for the corrosion rate tests: a 0.5 weight per cent NaC1 solution and a 0.5 M H2SO4 solution. The results from the mild steel alloys revealed that in both the solutions, the corrosion potentials and the corrosion resistance of the alloys increased with increasing gadolinium concentration up to 1 weight per cent. The corrosion rate test results from the stainless steel alloys revealed that the passivation current density and corrosion resistance of the alloys increased with increasing gadolinium concentration in both solutions. The oxidation resistances of the mild steel and stainless steel alloys were determined through the use of a Netzstch Simultaneous Thermal Analyser. For both the mild steel and the stainless steel alloys, it was found that the oxidation resistance of the alloys increased as the concentration of gadolinium increased when compared to the as-received mild steel and stainless steel samples. This could be due to a strongly adhering gadolinium oxide scale that formed on the surface of the alloys and resulted in the protection of the mild steel and the stainless steel.

Jan 1, 2012

By M. J. H. Tonkins, C. C. Crosson, G. Paterson

The development of drilling and blasting practice at Palabora Mining Company Limited by c. C. CROSSON, Pr. Eng., A.C.S.M. (Hons), BASe. (Min. Eng.) Toronto, M.!.M.M. (Member), M. J. H. TONKING, Pr. Eng., A.C.S.M., BASe. (Min. Eng.) Toronto, M.I.M.M. (Member), and G. PATERSON, B.Se. (Min. Eng.) Glasgow, M.!.M.M. (Visitor) Open-pit drilling and blasting practice at the Palabora Mining Company Limited is described, with particular reference to the development of aluminized slurry explosives. Rotary drilling of primary drill holes, drilling patterns, and blasting techniques for use with slurry explosives are described.

Jan 2, 1976

By A. Koursaris, Y. Turan

The object of this study was to investigate the i1Jfluence of nitrogen on the structure and properties of AISI 310S steel. Experimental ingots of the steel with nitrogen contents of up to 0,525 per cent by weight were prepared, hot-rolled, and tested after various treatments. The rollability of the material was adequate. The yield strength, tensile strength, hardness, and fatigue properties of the new alloys improved with increasing nitrogen content. The impact properties improved slightly. Empirical equations were developed for the calculation of the yield and tensile strengths, as well as the difference between these two properties, with increasing nitrogen content.

Jan 1, 1995

By Colin M. Spence

If one is to discuss sensibly and beneficially the whole spectrum of education, training, and employment of engineers, it is not possible to confine oneself to Professional Engineers because the profession of engineering embraces also technologists, technicians, and those people known in South Africa as certificated engineers. It would therefore be imprudent if this seminar were to be limited to certain sectors of the profession and industry. I hope that it will review the full situation from top to bottom and from side to side. New President of FAPA Mr Douglas H. Mills took office as President of the Federation of Societies of Professional Engineers on 1st July, 1985.

Jan 1, 1985

Introduction to high temperature oxidation of metals, by N. Birks and G. H. Meier, London, Edward Arnold, 1983. 19S pp. R30,25. Reviewers: M. B. Cortie and G. G. Garrett Seam gas drainage with particular reference to the working seam, edited by A. J. Hargraves. Woollongong, The Australasian Institute of Mining and Metallurgy. 370 pp. $A30. Reviewer: C. J. Fauconnier New books Solvent extraction Part I, by G. M. Ritcey and A. Ashbrook. Amsterdam, Elsevier, 1983. Elektronishche Steuerungen und Mikroprozessoren im Bergbau. Sicherheit und Zuverlassigkeit Environmental impact control. Philosophical and procedural guidelines for the planning professions Mineral processing and extractive metallurgy. Reagents in the minerals industry.

Jan 1, 1984

The 101 st Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Gold Room, Transvaal Automobile Club, 60 5th Street, Lower Houghton, Johannesburg on Wednesday, 12th August, 1998.

Jan 1, 1985

By A. Refahi

For predicting the energy consumption during the size-reduction process, the Bond approach is often used. In this work, the PFC3D discrete element method (DEM) software was employed to model the crushing behaviour of some rocks with different mechanical properties in a laboratory jaw crusher. FLAC3D software was adopted to analyze the stress distribution in the rocks. The rocks studied were modelled as granular assemblies in the shape of a sphere and/or a cube located between two jaws, and the work done by the jaws in the crusher was determined. Nine different types of rocks were studied and the energies consumed by the crusher were compared to those of the Bond comminution energy estimated from the Bond index. There is considerable difference between Bond crushing energy and work done by the jaw crusher for rocks. It appears that the Bond approach is not a suitable method for predicting single particle fracture energy done by the crusher. To verify the results obtained from DEM models, the fracture behaviour of the crushed rocks was examined and was compared to the PFC3D results. The tensile mode of fracturing is favourably modelled by the PFC3D software while the delamination mode cannot be well modelled by PFC3D software. Keywords: jaw crusher; discrete element method; crushing energy; Bond index

Jan 1, 2009

Toxic gases, mostly carbon monoxide (CO) and nitrous oxides (NOx), are invariably generated by commercial explosives under practical conditions of usage because of oxygen unbalance and non-ideal chemical reaction. Permitted explosives are statutorily required to meet the criteria stipulated by regulatory authority for their toxic fume quality for their safe use in underground coalmines. Solid blasting using P5 explosives contribute around 60% production from Indian underground coal mines. Low pull and yield per blast in solid blasting has been identified as a reason for low production and productivity of Indian underground coal mines. In an effort to improve performance of solid blasting, it was envisaged to apply air decking between suitable P5 explosives using high density polyethylene (HDPE) spacers under a Ministry of Coal, Government of India funded project. A non-deflagrating slurry explosive composition having high air gap sensitivity was specially developed for this purpose, so that air decked cartridges get detonated sympathetically with single priming. However, statutory authority in India apprehended that the use of oxygen negative HDPE spacers can influence the generation of toxic gases. The effect of using HDPE spacers on the generation of toxic gases was studied under simulated laboratory conditions with newly developed as well as with three commercial P5 explosives. The results of studies presented in this paper revealed that the level of carbon monoxide increases linearly and there is no significant effect on the level of oxides of nitrogen due to the use of HDPE spacers with selected explosives. Studies also revealed that this newly developed slurry explosive can be used for air decking up to 15 cm using HDPE spacers of weight not more than 21 g without exceeding the permissible limits for toxic gases.

Jan 1, 2008

By K. -I. Higuchi, M. Mizutani, K. Haga, A. Shibayama, A. Batnasan

In recent years, the quality of iron ores has decreased due to the increase in the content of impurities, namely quartz, aluminum, phosphorus, and sulfur. It indicates that the removal of impurities from iron ore is an extremely challenging task. In particular, the high amount of phosphorus in iron ore could be a problem for energy consumption and CO2 emission in the steelmaking process. To reduce the impact of phosphorus, mainly two approaches: the utilisation of low-phosphorus iron ore, or dephosphorisation of high-phosphorus iron ore using mineral processing technology, have been suggested. In this paper, the removal of phosphorus from a low-grade high-phosphorus iron ore containing 0.1 mass% P and 57.5% Fe by alkaline roasting and wet grinding is discussed. The iron ore consists mainly of hematite, goethite, and quartz. Effects of sodium hydroxide concentration used as an alkaline source, roasting temperature, grinding time, and particle size on the dephosphorisation of highphosphorus iron ore were investigated. The dephosphorisation efficiency, iron loss, and mineralogical components of low-grade high-phosphorus iron ore under various experimental conditions were characterised by using XRD, SEM-EDS, and particle size distribution analysis. Results showed that the phosphorus content was lowered from 0.1 mass% to 0.034 mass%, while the iron grade reached 59.8 mass% from 57.5 mass% by alkaline roasting with 0.05 w/w NaOH at 300 °C for 2 h, followed by wet grinding in an attritor with water for 30 seconds at room temperature. Under the experimental conditions, the dephosphorisation rate was about 54.7%, and the solution obtained by wet grinding contained 22.7 mg/L of phosphorus and 21.5 mg/L of iron. The recovery rate of iron by this process reached 99.9%. Keywords: Iron ore, phosphorus, dephosphoriszation, alkaline roasting, wet grinding

Jan 1, 2020

By T. T. Chiweshe, L. S. Mokhahlane, M. Welman-Purchase

This study examined an alternative technique of extracting tungsten from wolframite ore using a fusion method with ammonium phosphate salt. Current techniques use alkali salts to decompose tungsten ores and use various purification methods to produce ammonium paratungstate, which is a key intermediate precursor in the extraction of tungsten. In this study, a two-step extraction process, which involves thermal decomposition of the ore using fusion and a separation stage, is examined. The novelty of this technique is the ability to completely decompose wolframite ore and form an unstable tungsten oxide phosphate (WO2(PO3)2) compound. The instability of WO2(PO3)2 in deionized water enables selective isolation of tungsten as insoluble precipitates of WO3 and WO2. The decomposition reaction of WO2(PO3)2 is influenced by the presence of oxygen and determined to be first order under ambient conditions. Scanning electron micrographs and X-ray diffraction analysis showed above 80% of the tungsten precipitated compared with the amount that remained in the filtrate solution.

Jul 10, 2024

By B. Strohmeier

An account is given of the use of a computer to control the performance of three ultra-high-powered electric-arc furnaces in Iscor 5 steelmaking plant at Vanderbijlpark, South Africa. Several of the reports and graphs printed by the computer are reproduced.

Jan 1, 1985

Deciding on plant-scale reagent dosage regimes and air rates is a topic of ongoing investigation and high importance. The current work explains some techniques that have proven useful in deciding on plant-scale flotation operating regimes. Specific focus has been placed on the reagents: frother and depressant, as well as some discussion around the control of air rate and froth depth. Air rate has been selected based on its effects on the froth phase. Froth velocity and froth height above the cell lip are the two variables measured and used to select the operating air rate. Pulp level is then adjusted to increase or decrease mass pull. A technique has been developed using the Anglo Platinum Bubble Sizer on an industrial flotation cell to determine the relationship between bubble size and frother concentration. This technique has been extended to measure the equivalent frother concentration or frothabilities of various streams on a rougher bank. A mass balance for frother was performed successfully, and this provided a better understanding of the way frother moved in the rougher bank. With this knowledge, more informed decisions can be made about frother addition required in subsequent flotation stages. For depressant, a new protocol for deciding on dosage rate has been developed. The depressant dosage should be based on the amount of fresh feed material reporting to a bank. Currently 400 g/t of fresh feed has been assumed a reasonable starting point with promising results. Improved froth stability and grades were observed. There is scope for more accurately defining the optimal dosage rate. Importantly, the combined effect of changing the chemistry and the hydrodynamics together has been demonstrated. A significant upward shift in the grade-recovery relationship for a cleaner bank was observed.

Jan 1, 2012

By R. P. King, L. C. Woollacott

To date developments in the simulation of carbon-in-pulp (CIP) adsorption circuits have focused primarily on the modeling of adsorption. This series of three papers describes a development in a direction that has received less attention, i.e. the need for a detailed description of the movement of carbon and slurry in continuous CIP and carbon-in-leach (CIL) plants. A new simulator has been developed based on the population-balance approach for modeling the movement of carbon and slurry. Existing adsorption and leaching models are evaluated in this paper in order to establish which are appropriate for use in the new simulator. The details of the simulator are given in Part 2 of this series.

Jan 1, 1990

By A. B. Stewart, I. J. Barker

Traditionally it has commonly been believed that the only problem with inductive reactance in a submerged-arc furnace is that it leads to difficulties with the electricity supply as a result of the Iow power factor. This paper sets out to show that inductive reactance can also give rise to the following problems in the metallurgical operation of a furnace: (i) dead and live phases (fairly well known in openarc furnaces), (ii) lack of sensitivity to electrode movement, (iii) interactions between electrodes. These problems increase with increasing inductive reactance relative to resistance, and thus they increase with furnace size. Each of these effects is discussed in detail, and suggestions are made for their alleviation.

Jan 1, 1980

By I. Bock

This presentation describes a technique under development referred to as Selective Blast Mining. The technique involves millisecond sequential blasting. It applies to mines where the gold bearing conglomerate band is clearly demarcated, and separated from the waste rock in the foot and hanging wall. The width of the conglomerate band should be less than ± 0,7 metres. A research program was initiated in August 1994 by Drs RE. Robinson and I.E. Bock. The objectives were to develop new blasting methods that can reduce: ? the losses of gold in narrow reef stoping. Losses of gold can be as much as 10-15% ? and to introduce selective mining to reduce ore dilution with waste rock.

Jan 1, 1996