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The 99th Annual General Meeting of The South African Institute of Mining and Metallurgy was held in the Gold Room, Transvaal Automobile Club, 60 5th Street, Lower Houghton, Johannesburg on Wednesday, 14th August, 1996. Obituaries The President announced the death, during the year, of the following members: Life Fellows H.L. Munro, H.S. Simpson, P.L. Ward Fellows I.M. Hossy, A.E. O'Meara Retired Fellows E.A. Arvidson, R.F. Bourne, F. Hawke, W. Lloyd, J.M. Meyer Members J. Allen, P.A. Boardman, L.M. Jacobs, G.F. Marx, G.D. Perry, R.W. Spraggs Retired Member M. Milner Associate I. Pieterse. In memory of the deceased and in sympathy with the bereaved, all rose and observed a moment of silence.

Jan 1, 1996

By K. Y. Lee, J. M. Park, C. W. Park

Laboratory-scale experiments were carried out to investigate the effect of ladle slag composition on the decreasing behaviour of aluminum content in steel, i.e., reoxidation of molten steel in contact with slag, using a vertical tube furnace. The steel composition and the slag system chosen were for ultra low carbon and CaO-Al2O3-FeO-MnO-MgO based to simulate ULC steel grades. It has been observed that the reoxidation rate shows a good relationship with (T. Fe) content in slag. In case of (T. Fe) content higher than 1.5 weight per cent, the reoxidation rate increases linearly with increasing (T. Fe) content. For a given (T. Fe) content, it decreases with the increasing (CaO)/(Al2O3) ratio of the slag. However, in the case of (T. Fe) content lower than 1.5 weight percent, no particular relationships are observed between the reoxidation rate and (T. Fe) content or the (CaO)/(Al2O3) ratio of the slag. These results were used to propose for an aim a slag composition for the ULC steel grades in a steelmaking plant. Keywords: slag deoxidation, slag killing, slag composition control, IF steel, ULC steel grade

Jan 1, 2004

By O. Bazhko, F. D. L. Uahengo, Y. R. S. Hara

Although the conventional acid-reductive leaching method effectively extracts copper (Cu) and cobalt (Co) from Cu–Co oxide ores, efforts to enhance hydrometallurgical performance are ongoing. This study evaluates the influence of sulphuric acid (H2SO4) and sodium metabisulphite (Na2S2O5) on metal extraction from Zebesha Cu–Co oxide ore using ferrous sulphate heptahydrate (FeSO4·7H2O) and ferric sulphate (Fe2(SO4)3) as lixiviants. Ore samples (<150 μm) were leached at ambient temperature for two hours, and metal concentrations were determined via X-ray fluorescence analysis. In the FeSO4·7H2O system, Co, Mn, and Ni recoveries increased w=ith Na2S2O5 concentration, reaching a maximum of approximately 80% Co at 150 kg/t, while Cu recovery remained below 5%. Conversely, with Fe2(SO4)3, Cu recovery peaked at 88% at 50 kg/t Na2S2O5, then declined to 79% at 150 kg/t. The addition of H2SO4 improved metal recoveries in both systems. Notably, 60 kg/t H2SO4 yielded 92% Cu extraction in Fe2(SO4)3, while Co, Ni, and Mn remained below 40%. However, in FeSO4·7H2O, Co recovery improved from 40% to 84%. These findings suggest Na2S2O5 is more effective for cobalt extraction with FeSO4·7H2O, whereas H2SO4 enhances copper extraction in Fe2(SO4)3.

Oct 24, 2025

[Consider the situation where we wish to estimate the value of a block of ore W from the values of n samples wt (i = 1, 2.... n). The samples can be located anywhere inside or outside W. The blocks and the samples can have any size or shape (Fig. 8.1). We define ws as the set of all the samples wi: WS = Iw1; W2; W3.. . wn and we wish to estimate the block W using the samples ws. Let xi be the value of the ith sample and µw the unknown average value of the block. We can estimate µw from the average value of all the samples. Let µw be the estimator of µw. As the samples need not be of equal size, the sample average is: µw = wi xi/~ wi. (8.1) The mean squared error made when estimating µw by µw is known as the variance of estimation of W by ws. It is the error made when giving the value of the sample set ws to the block W and is written o2E (WS to W). By definition: o2E (ws to W) = E [(µw - µw)2]. (8.2) If n = 1, this error is known as the extension variance. Since the sum of the weights given to the sample values is equal to 1,0, the estimator µw is unbiased (the question of the absence of bias is studied in more detail in Chapter 9): E [( µw - µw)1 = 0. (8.3) The error (µw - µw) has zero mean and a variance o2E = E (W8 to W). If we assume that this error is normally distributed, we can define confidence limits for µw. Let tP be the value of the standardized normal variance t such that the probability that t is less than tP is p: (t,) = .\/27T f exp (- t2/2) dt = p (8.4) The probability that µw is larger than µw + t1-P oE is p. The probability that µw is smaller than µw- t1-P oE is p. The following approximation formulae are often used to calculate 2p central confidence limits for the block value: 68% central confidence limits (p = 16%): µw - o2E, and µw + o2E. 95 % central confidence limits (p = 2,5 %): µw - 2 oE, and µw + 2 oE. Tables of the function 0 can be found in any textbook on statistics (for example, Fraser, 1958, p. 388) (see Table 7.2). [ ] The last line of Table 2.2, corresponding to f = 00, also contains the value of tP for p = 80, 90, 95 and 97,5 %.]

Jan 1, 1978

By S. Zhao, S. P. He, M. Y. Zhu, Y. Tao

"The effect of two refining slags (A: 1.0–1.8 CaO/Al2O3 ratio, 11–20 wt% SiO2; and B: 1.0–1.2 CaO/SiO2 ratio, 25–35 wt% Al2O3) on the inclusion morphology of a carbon structural steel (Q235B) was studied by controlling the balance between the steel and the refining slag at 1600ºC in a Si–Mo resistance laboratory furnace. The results showed that most of the inclusions in the molten steel balanced with slag A were formed by a lowmelting CaO–MgO–Al2O3–SiO2 system with a total oxygen content (T[O]) being fixed at 6–13 ppm. The inclusions in liquid steel balanced with the slag B were mostly formed by the CaO–MnO–Al2O3–SiO2 system, with T[O] controlled to 19–26 ppm. The overall size of the inclusions under balance conditions was higher in the steel reacted with the slag B than that reacted with slag A, with the latter showing more inclusions smaller than 3 um. In order to generate a large number of spherical CaO–MgO–Al2O3–SiO2 inclusions smaller than 3 ??m while decreasing the T[O] in the resulting steel, the composition of slag A should be used. This composition allowed improving the cleanliness of the slab, and is also advantageous for the castability of the molten steel. IntroductionThe sample used in this study was a typical carbon steel manufactured by CQ Steel. The galvanized, tinned, and plastic composite steel plates made of the original plates are used extensively for decorative panels, general dust pipes, drums, instrument cases, switchboxes, and train cars, among other uses. The target control composition is shown in Table I. The S and P contents are usually fixed during production below 0.020 and 0.025 wt%, respectively, with the aim of reducing longitudinal cracks on the slab surface."

Jan 1, 2017

Keywords: Stellenbosch, university, teaching, research The pyrometallurgical activities at Stellenbosch University are reviewed in this paper. The history of the activities, both in teaching and research, is outlined, as well as some of the perceived research opportunities that the University of Stellenbosch is currently focusing on. The course content, as well as its relationship to other courses in the curriculum, is discussed and the interfaces between the courses are explained to present a holistic picture of the education an engineering graduate receives in process pyrometallurgy.

Jan 1, 2006

By S. Zhang, Z. Hua, D. Feng, X. Tong, X. Xie

The separation and beneficiation of low grade collophanite has long been a technical challenge in phosphorous production. It requires the joint efforts of process design, reagents optimisation and operational control. In this study, the statistical response surface method was applied for determining the optimum reagent dosing in the flocculate flotation of a low grade (18.59%) collophanite ore. The dosage of three reagents, including a pH regulator (Na2CO3), depressant (Na2SiO3) and flocculant (modified starch), were input parameters of the modelling design. Two quadratic mathematical models were derived for prediction of grade and recovery based on the statistical design. Statistical analysis of the experimental results validates the reliability of the models. Through further calculation, the optimum dosage of the three reagents were found to be 3,020g/t Na2CO3, 1,990g/t Na2SiO3 and 880g/t modified starch, with which a maximum recovery of 75.81% and P2O5 grade of 30.08% was obtained from flocculate flotation test. Keywords: Process optimisation, modelling, froth flotation, collophanite ore, response surface methodology

Jan 1, 2020

By R. J. Davidson, B. Strong

The piloting and eventual large-scale operation of fixed-bed carbon columns for the recovery of gold from plant effluents is described. A fixed-bed carbon pilot plant comprising three adsorption columns was used for the recovery of gold from clarified plant effluent at the Vaal Reefs Exploration and Mining Company (West Division). The effluent ,which contained 0,1 toO,S g/t of gold and less than 10 g/t of free cyanide, was adjusted to pH 8 prior to use. Daily acid treatment of the carbon circuit with 3 per cent hydrochloric acid was shown to have a most significant effect on increasing the gold adsorption. The acid treatment involved a plant downtime of only I to 2 minutes per day. High loadings of gold (up to 30 k g/t) and copper (up to 75 k g/t) were obtained on the leading column, while the gold recoveries averaged 98 per cent over 17 weeks of continuous operation. The subsequent elution of loaded carbon in a pilot elution column indicated the use of abnormally high amounts of the pretreatment reagent (caustic soda and cyanide) used in gold elution. This was attributed to the high loading of copper on the carbon. However, the elution of both the gold and the copper at 110°C with demineralized water as the eluant was satisfactory. In a similar large-scale operation, three fixed-bed carbon columns each containing 4,5 t of carbon were used to treat 80 to 120 t/h of plant effluent with a gold concentration of about 0,15 g/t. Gold loadings of 5 to 6 k g/t were obtained regularly, while the gold recovery averaged 97 per cent over a 12-month period. The capital cost of the plant was recovered in 2 to 3 months. The evidence presented strongly suggests that copper plays a significant role in the adsorption and elution of gold under the prescribed conditions, and in the subsequent precipitation of gold following acidification of the eluates. The formation of a highly insoluble gold-copper complex produced under acid conditions appears to explain many of the observations made in the investigation.

Jan 1, 1983

By O. Celep, T. Uslu, Savas

This study investigates the enrichment of a low-grade colemanite concentrate (-3 mm) using a Knelson centrifugal gravity concentrator. Due to its low boron content, the concentrate is unsaleable and has to be stored under appropriate conditions to avoid potential environmental problems. The low-grade colemanite concentrate was comminuted to size fractions of-1 mm, -0.5 mm, and -0.15 mm before treatment in the Knelson Concentrator. The effects of particle size, fluidizing water velocity, and bowl speed on the enrichment process were examined. The B2O3content of the concentrate was increased from 33.96% to a maximum of 45.52%. B2O3recovery increased with increasing bowl speed and particle size, and decreased with increasing fluidizing water velocity. The enrichment process also rejected arsenic and iron to some extent, with a maximum reduction of arsenic from 1360 g/t to 765 g/t and iron from 0.88% to0.33%.

Jan 1, 2015

By J. D. Steenkamp, J. Muller

"Excavation of an industrial-scale submerged arc furnace, utilized in the production of silicomanganese, identified two high-wear areas in the refractory lining: the tap-hole, built with cold rammed carbon paste and SiC bricks, and the hearth, built with cold rammed carbon paste. To obtain insight into the potential causes of wear, thermodynamic calculations were conducted on eight sets of data, obtained for seven furnaces on three plants based in South Africa. FACTsage software and associated databases – FACTPS, FToxid, and FSstel – as well as the Mn-Fe-Si-C database of Tang and Olsen (2006), were applied. Theoretical indications are that chemical reaction between carbon refractory and slag, as well as dissolution of carbon and SiC refractory in metal, contributed to tap-hole refractory wear; and dissolution of carbon in metal contributed to hearth refractory wear. IntroductionDuring the excavation of a 48 MVA submerged arc furnace (SAF) used for silicomanganese (SiMn) production, it was found that the taphole and hearth were high refractory wear areas (Steenkamp, 2014). In both these highwear areas, carbon-based cold ramming paste formed the hot face refractory lining (crucible). The wear profile of this SAF is presented in Figure 1.The hot face refractory lining was formed by cold ramming of high-grade carbon ramming material. This material consisted of 50–70% anthracite, 15–25% graphite, 6–12% resin, 2–7% tar, 1–5% clay, and 1–5% alumina. The tap-hole was built using SiC bricks, consisting of 75% SiC, 23.4% Si3N4, 0.3% Fe2O3, 0.3% Al2O3, and 0.2% CaO.In the tap-hole area, the wear of the SiC refractory material was estimated at 0.4 t, and that of the high-grade carbon ramming material, at 1.9 t (Steenkamp, Pistorius, and Tangstad, 2015). The amounts of slag and metal tapped during six years of operation of the tap-hole (September 2007 to April 2013) were estimated at 33 088 t (Steenkamp et al.,2015) and 41 360 t, respectively."

Jan 1, 2016

The Annual General Meeting of the South African Institute of Mining and Metallurgy was held in Kelvin House, Johannesburg, on Wednesday, 27th August, 1975. Professor R. P. Plewman (President) was in the Chair. There were present 45 Fellows, 37 Members, 8 Graduates, 3 Associates, 4 Students, and 45 Visitors, making a total of 142. The President declared the Meeting open at 16h00. OBITUARIES The President: Ladies and gentlemen, it is my sad duty to announce the death of the following members of the Institute : M. Barcza, an Honorary Life Fellow and Past President of the Institute; J. A. Boyd, F. E. Keep, and J. H. Taylor, Life Fellows ; I. D. B. Corner, C. O&apos;G. Deane, R. E. Gilmour, A. C. Hofmeyr, M. W. Howell, T. J. Robin, and F. S. Steinhobel, Fellows; J. J. Frankel, Member; and T. J. Higgs, Associate. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I ask you to rise and observe a few moments&apos; silence. MINUTES The President: May we confirm the minutes of the General Meeting held on March 12th 1975 and published in the June issue of the Journal? Agreed. WELCOME The President: It is now my very great pleasure to welcome the many members of our Institute and all the distinguished guests who have honoured us with their presence this afternoon. In particular, I would like to welcome our Honorary President, Mr R. S. Lawrence, President of the Chamber of Mines, and also our Honorary Vice-President, Mr T. L. Gibbs, the Government Mining Engineer. Ons is ook besonder vereer dat dr. Naude, die Wetenskaplike Raad-gewer aan die Eerste Minister, en mnr. C. A. J. Borman, Direkteur van die Witwatersrandse Kollege vir Gevorderde Tegniese Onderwys, hier aanwesig is om die vergadering by to woon. We are also honoured by the presence of some 19 Presidents, Vice-Presidents, and Chairmen of our sister scientific and technical organizations. I would particularly like to welcome Mr Gericke of the South African Council for Professional Engineers, Professor Pretorius of the A.S. & T.S., and Dr Lloyd of F.S.P.E. And then, also the Presidents of the Institute of Welding, Professor Robinson; of the Electrical Engineers, Dr Troost ; of the Certificated Mechanical and Electrical Engineers, Mr Gibbs; of the Geological Society, Professor Maske; of the Land Surveyors of the Transvaal, Mr Course ; of the Assayers and Analysts, Mr Williams; of the Mine Ventilation Society, Mr Martinson; of the Chemical Institute, Mr Goodman; of the Association of Mine Managers, Mr Pretorius ; of the Institute of Foundrymen, Mr Attenborough; of the Production Engineers, Mr Duggan ; and of S.A.F.U.E.S., Mr Avalle. Then, the Chairman of the Council of the Institute of Metallurgists, Mr Snow; the Vice-President of the Town and Regional Planning, Mr Reinecke; the Vice-President of the Association of Consulting Engineers, Mr O&apos;Kell; and Mr Cronje, who is representing E.A.S.A. Finally, the Chairman of the Southern Transvaal Section of the Chemical Institute, Mr Bloom ; the Chairman of the Witbank-Middelburg Branch of our own Institute, Mr Hosking; and the Secretary-Treasurer of our O.F.S. Branch, Mr Bird. We also have with us Mr Trueman; the Deputy Manager of Kelvin House, Mr Mrost ; our Honorary Editor, Dr Glen; Mr Walford; and also some representatives of the Press. Finally, it gives me great pleasure to welcome those who will receive Honorary Life Fellowships tonight, and also the winners of our student prizes. MEMBERSHIP The President: Ladies and gentlemen, I have pleasure in announcing the names of the following candidates, which have been published in accordance with By-Law 5.2.5., and Council has elected them to membership in the following grades: Fellows: R. G. Boswell, R. W. Chadwick, D. R. Hardman, J. A. Holmes, T. J. B. Jones, and R. P. King. Members : M. A. Bridgeford, C. F. Bonney, H. E. Bartlett, L. G. Floyd, A. K. Haines, D. Hatfield, C. G. Heymann, M. J. Howes, J. B. See, E. van Greunen, and S. P. Swanepoel. Associate Members : J. Coetsee and R. P. G. Steyn. Graduates: J. J. de Villiers and J. C. King. Associates: B. J. Bucher, P. A. Combrinck, W. J. N. Gelderblom, L. S. Halasz, J. van Wyk, C. P. Visser, and A. Veress. Students: D. J. Claasens, P. C. Crous, D. H. Murchison, P. A. Rossouw, and J. P. L. Schultz. Company Affiliates: Airco Engineering (Proprietary) Limited and Deelkraal Gold Mining Company Limited. There have also been some transfers: Member to Fellow: J. B. Nangle. Graduate to Member: E. E. Eichenbergen, M. J. Hillbeck, L. A. Melis, P. J. Venter, and R. O. Wellman. Associate to Associate Member: B. M. Williams. I welcome the newly elected members to the Institute, and I congratulate those who have been transferred to a higher grade.

Jan 10, 1975

1. New books Australian Institute of International Affairs. Uranium - energy source of the future? Canberra, thelnstitute (Box E181, P.O., Canberra, A.C.T. 2600, Australia), 1979. 202 pp. A$4,95 (postage 50c). Euroeconomics. The steel industry in Western Europe.. industrial and financial indicators. Paris, Eurofinance (9 Avenue Hoche, 75008 Paris, France), 1979. 167 pp. FF4,500 (Available in English and French.) M. B. Piggott. Load-bearing composite materials. Oxford, Pergamon Press, 1979. $15,00. J. H. E. Olaf. Automation and remote monitoring and control in mines. Essen (West Germany), Verlag Gliickauf GmbH, 1979. 200 pp. DM36. (In English.) J. P. Jenkins and E. T. Brown (eds). KWIC index of rock mechanics literature. Oxford, Pergamon, 1979. 742 pp. £60. R. J. Wakeman (ed.). Progress in filtration and separation 1. Amsterdam, Elsevier, 1979. 346 pp. Dfl.llO,OO. 2. New journal As from 1980, Coal Calendar is being published as a separate monthly periodical. 3. Proceedings L. E. St Pierre and G. R. Brown (eds). Future sources of organic raw materials. Oxford, Pergamon, 1979. 612 pp. £22,50. P. Haasen, V. Gerold, and G. Kostorz (eds). Strength of metals and alloys. Oxford, Pergamon, 1979. 3 vols., 1800 pp. $200. K. J. Miller and R. F. Smith (eds). Mechanical behaviour of materials. Oxford, Pergamon, 1979. 3 vols., 1800 pp. U.S.$200. 4. Tax relief? The Publishers&apos; Association of Great Britain recently issued a circular to a number of professional bodies drawing their attention to a court decision in favour of tax allowances on the purchase of textbooks. In January Electroheat The International Union for Electroheat, which com. prises a score of highly industrialized countries, every four years organizes a congress at which experts discuss the technicalities and economics of the latest applications of electroheat in industry and other sectors. Corrigenda: March issue The following amendments should be made to Table II of the paper &apos;Commodity analysis:

Jan 1, 1980

By Y. Ren, B. Yang

The magnetic field characteristics due to electromagnetic stirring in the secondary cooling zone of an extra-thick slab during continuous casting are numerically determined using Maxwell's equations, with particular emphasis on the distribution of magnetic induction intensity and electromagnetic force, as well as the influence of process parameters on the magnetic field. The orientation of the electromagnetic force is the same when the electromagnetic stirrers at the 30° and 60° posistions of the arc-shaped slab are powered in the same direction; otherwise, the orientation is opposite. The magnetic induction at the centre of the section of the stirrer's central axis at the 30° positio, as well as the current, frequency, and fitting formulae, are as follows: B = {0.075I.(1/A)-0.3} mT and B = {-1.75f.(1/Hz)+22} mT. The electromagnetic force and current fitting formula at the central point of the B-B section is F = {0.03168I2.(1/A2)-03.762I.(1/A)+326.7} N/m3, and the fitting formula of electromagnetic force and frequency at the centre point is divided into two segments. The first takes the form of a parabola: = {-21((f-4.3).(1/Hz)2)+970} N/m3, and the second segment is negative linear: F = {-1.65f.(1/Hz)+51.5} N/m3.

Apr 16, 2024

By D. M. MacHunter, M. K. Palmer

Refinement of design parameters and features has resulted in the development and commercialization of spiral separator models that offer enhanced performance for a number of application areas. Examples of recently developed spiral separator models include the enhanced performance (EP)spiral and the HC (high capacity) series. Comparative performance data for appropriate applications are presented for each of these new model spiral separators. The utilization of spiral separators providing improved performance offers significant cost and operational benefits for process plants. Examples of process flowsheet changes that have resulted from the incorporation of recently developed spiral separators include the reduction of the number of process stages and the achievement of high density tailings by the utilization of a dewatering arrangement in the spiral tailings splitter system.

Jan 1, 2003

By M. L. Bakker

Keywords: Pyrometallurgy, top submerged lance (TSL), nickel, PGM, calcium ferrite, lime ferrite The ISASMELT? top submerged lance (TSL) bath smelting process was developed in Mount Isa, Australia by Mount Isa Mines Limited (now a subsidiary of Xstrata plc) during the 1980s. By the end of 2011, the total installed capacity of the ISASMELT? technology will exceed 9 000 000 metric tons per year of feed materials in copper and lead smelters around the world. Commercial plants, operating in Belgium and Germany, are also batch converting copper materials in ISASMELT? furnaces. This TSL technology is equally effective for continuous converting processes, whereupon it is called ISACONVERT?. This paper presents the recently patented ISACONVERT? process for the continuous converting of nickel and Platinum Group Metal (PGM) containing mattes using the calcium ferrite slag system. The paper focuses on the potential application of the ISACONVERT? technology to existing nickel and PGM smelting complexes.

Jan 1, 2011

By C. Nexhip, S. Sun

Critical to understanding and controlling phase mixing and separation in metallurgical processes, is the development of reliable experimental techniques to measure interfacial properties of melt systems. A series of experiments has been carried out to determine the effect of oxygen potential on the surface tension of liquid copper. Using an electromagnetic levitation method, a surface tension-oxygen chemical potential adsorption isotherm was produced for the Cu-O system at T 1400 K. The surface tension results show good agreement with the literature values e.g. within 3 per cent for pure copper. The Belton `ideal&apos; adsorption isotherm was applied, and the following equation derived to best fit the experimental data ? =1251-77.5 1n41+ (2.79x105 . pO1/2)](mN.m Using this equation, the surface tension of copper was calculated/predicted as a function of oxygen potential at 1400 K, and showed excellent agreement with the experimental values. This confirmed that the adsorption behaviour of oxygen in liquid copper is ideal. The saturation coverage of oxygen on the surface of liquid copper was determined to be T0 = 6.65 µmoles.m,-2 corresponding to an area per adsorbed oxygen atom of ao ? 25 Å2. These values agree well with those cited in the literature, and our experimental data cover a very wide range of oxygen potential (10-5 to 10-17 atm). Keywords: levitation melting, surface tension, Cu-O alloys, oxygen potential, adsorption isotherm, surface coverage.

Jan 1, 2004

In this study, the effects of slag compositions, slag amount, temperature, and carbon content of steel on the manganese and phosphorus distribution ratios during converter steelmaking were analysed using the classical regular solution theory, and industrial tests were performed using two 80 t top-and-bottom combined blown converters (duplex melting process). The results indicate that the slag amount, temperature, and carbon content in steel are the main factors affecting the manganese yield when converter slag compositions remain constant. The FeO content of the slag has a strong impact on the manganese distribution ratio, while the slag basicity and MgO content have no obvious effect. The calculations and experimental results show that the phosphorus distribution ratio increases sharply with increasing slag basicity R, but then decreases with the increase of MgO and MnO contents in the slag. The final slag in converter steelmaking should have the following characteristics: 3.5 < R < 4.5, 15% < (FeO) < 20%, and 6% < (MgO) < 8%. The slag amount should be controlled appropriately at the same time. The results of this investigation would be useful in deciding on the application of manganese ore in alloying and identifying the slagging regime in converter steelmaking.

Jan 1, 2014

Mixtures of MnO and graphite were reacted under argon at temperatures ranging from 1200 to 1425°C, and the loss in mass of the mixture was recorded continuously. The results showed that the rate of reduction of MnO increased as the temperature increased and the ratio of MnO to C decreased. The effect of the particle size of MnO and of graphite on the rate of reduction at I350°C was very small in the range 63 to 250 µm for MnO and 45 to 355 µm for graphite. The rate of reduction at I350°C was increased markedly by the addition of Na2CO2 and K2CO3, was slightly increased by the addition of Fe2O3, was unaffected by the addition of CaO, MgO, and AI2O., and was decreased by the addition of SiO2. Some CO2 was always present in the effluent gas, and this was taken as evidence that the reduction of MnO occurred by way of CO2 as an intermediate product. The activation energy of the ratecontrolling step was 57,5 kcal, and this was similar to the measured activation energy for the gasification of graphite by CO., namely, 61,S kcal per mole of graphite. A simple kinetic model was derived on the assumption that the gasification of graphite was the ratecontrolling step, and the results over the temperature range 1200 to I425°C, when plotted in the appropriate form, yielded straight lines as predicted by the model.

Jan 1, 1980

By B. M. Wainstein

An extension of lognormal theory and its application to risk analysis models for new mining ventures by B. M. WAINSTEIN*, B.Sc., M.B.A. (Witwatersrand) (Visitor) The lognormal distribution, which remains the most popular distribution model for ore values, is investigated. The T-distribution, an integral part of this theory, is dependent on the sample size, n, and the unknown population parameter, o2, which cannot be integrated out. Hence, o2constitutes a nuisance parameter. In this study, the robustness of the T-distribution to changes in o2 is examined. It is found that the T-distribution is robust for 0,1 <= o2 >= 2,5, a domain covering most practical applications of the lognormal theory. By the use of o2 = 0,7, multiplier factors, which facilitate the computation of the confidence limits, are derived for a comprehensive set of confidence levels.

Jan 4, 1975

By R. Shen

This paper presents results of a feasibility study of recycling manganese furnace dust generated in production of ferromanganese and silicomanganese at Tasmanian Electrometallurgical Company, Australia. Dried manganese furnace dust contains about 20 wt% of carbon, in average 33.4 wt% of manganese and 1.3 wt% of zinc. Manganese in the dust is in the form of MnO, Mn3O4 and MnCO3; zinc is mainly in the form of ZnO andZnSO4. Analysis of the zinc balance with dust recycling showed that to keep zinc intake at the acceptable level, it should be partly removed from the dust. In the reduction laboratory experiments, zinc oxide was reduced to zinc vapour by tar of the dust. Reduction of zinc oxide started at 800°C and zinc removal rate increased with increasing temperature; removal of zinc was close to completion at 1100oC. Optimal conditions for removing zinc from the dust include temperature in the range 1000-1150°C, inert gas atmosphere and furnace dust fraction in the furnace dust-manganese ore mixture above 60%. In the sintering of manganese ore with addition of manganese dust in the sintering pot, zinc was reoxidised and deposited in the sinter bed. Removal of zinc in the sintering pot tests was in the range 4-17%. Up to 30% zinc removal was achieved from the bottom layer of the sinter bed. It can be concluded that zinc removal will be low during the processing of manganese furnace dust in the sinter plant. The zinc removal rate will be the highest when pelletised manganese furnace dust is added to the bottom layer of the sintering bed.

Jan 1, 2007