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By K. Rubow, Z. Zhlqun, V. Marple

A theoretical technique has been developed and verified experimentally for determining the aerodynamic diameter of irregular shaped particles. The aerodynamic diameter of a particle is a very important property in determining where that particle deposits in the respiratory tract. Many instruments, such as impactors and cyclones, will determine the aerodynamic size distributions of aerosol particles but few analyze the particles individually. The theoretical approach of our technique is to solve, by use of high speed computers, the three dimensional Navier-Stokes equations to obtain the flow field around an irregular shaped particle of any contour. The computer program will then determine the drag on the particle, and thus the aerodynamic diameter of the particle can be calculated. The experimental approach has been to pass the particles through a centrifuge and collect the particles upon a collection foil. The position of a particle on the foil is an indication of its aerodynamic diameter. These particles were then shadowed in two orthogonal directions and inspected under an SEM. The top view of the particle in the SEM plus the views of the two orthogonal shadows allows one to determine the three dimensional shape of the particle. Studies have been performed on silica, coal and talc particles with aerodynamic diameters in the 1 to 4 um size range. The three dimensional shape, as is determined from SEM analysis was used in the theoretical computer program and the results compared. It was found that in most 'cases the agreement between the experimentally and theoretically determined aerodynamic diameters was within 5%.

Jan 1, 1988

By Peter N. Gabby

A mineral survey of 8,300 acres of the 24,980-acre Burnt Creek Wilderness Study Area (ID 45-12), was conducted by the U.S. Bureau of Mines in 1985 at the request of the Bureau of Land Management. The study area is located in Custer County, ID, 90 miles northwest of Idaho Falls. No mines, claims, or prospects are in the study area. The northern half of the study area and adjacent lands to the north, northeast, and east are or were recently under oil and gas lease, Basalt and latite-andesite of the Challis Volcanics predominate in the study area. Several hundred feet east of the study area is a quarry in talus of Mississippian-age limestone that was used for sized 100-pound rock fill in the Old Dry Creek Reservoir dam. Two samples, one taken at the quarry and the other at a limestone outcrop on East Fork Burnt Creek, have CaC03 content in the range of 90 to 95 percent, and is suitable as the limestone component of Portland cement, However, limestone outside the study area could supply foreseeable demand. Lead- silver mineralization has been observed in Paleozoic carbonate rocks elsewhere in the Lost River Range, but these rocks do not occur in the study area.

Jan 1, 1986

By Phyllip Worley, Frank E. Chase, Christopher Mark

The Harris No. 1 Mine, located in Boone County, WV, has been longwalling the Eagle Coalbed for over 30 years. Harris has experienced numerous interactions associated with the extensive room-and-pillar and longwall mining operations which have been conducted in the overlying No. 2 Gas Coalbed. The problems have included roof falls, excessive rib sloughage, and gateroad and bleeder entry closure. A detailed evaluation of the multiple seam experiences at Harris No. 1 Mine was conducted as part of the National Institute for Occupational Safety and Health (NIOSH) nation-wide multiple seam mining case history data base. One observation from the Harris gateroad case histories was that smaller, critically loaded, upper seam pillars seemed to cause more severe ground conditions than did wider pillars. The LaModel program was used to investigate this supposition, and the results confirmed that “critical” sized pillars do transmit the highest amounts of stress to adjacent seams. In addition, the data suggest that the probability of a major multiple seam mining interaction increases when the depth of cover is 1,000 ft or greater and when the Eagle seam pillars have a Analysis of Longwall Pillar stability factor less than 1.50.

By James E. Mills

Coal, in the process of mining, transportation, and handling and on exposure to the weather, is subject to more or less disintegration. This disintegrated coal is usually called "slack" and amounts often to a considerable percentage of the lump coal produced in the mines. If this slack coal is wasted the loss so occasioned ranges from 5 to 50 per cent, or even more, of the total coal mined. It is therefore clear that the utilization of this waste slack coal becomes a serious economic consideration. When the coal is suitable for the production of coke, the utilization of the slack presents no difficulty, as it is in demand for that purpose. If the coal does not produce good coke, but cakes rather readily, the slack can be used for boiler purposes, as it fuses together more or less quickly, and burns on the furnace grate without great loss. Coal that cakes less readily can be burned on grates of special construc- tion. When so used it is more troublesome to handle, and the waste is greater than when lump coal is used. Consequently the price of much of the slack coal for fuel purposes ranges considerably lower than that of the lump coal from the same mine. The full value of this slack coal as fuel can be realized by first form- ing the coal into a coherent mass or briquet, such briquets, when of good quality, being equal to or of greater value than the original

Jan 1, 1911

By W. H. Ode, F. H. Gibson, W. A. Selvig

The great expansion of production of aluminum for war purposes has aroused some concern regarding the available supply of carbon suitable for making carbon electrodes required in the electrolytic aluminum process. Approximately three-quarters of a pound of carbon electrode is consumed for each pound of aluminum produced. 5 Because of its small amount of impurities and its suitable physical characteristics, calcined petroleum coke is the standard material used by the aluminum industry for making electrodes As it may be necessary to use some substitute materials, the possibility of using coke made from coal has been considered. Besides this possible use, information concerning the source of low-ash coals is of general interest. Specifications of the aluminum industry for calcined petroleum coke suitable for the manufacture of electrodes are very stringent in regard to allowable impurities. In one such specification the maximum allowable ash is 1.0 percent; the maximum allowable content of iron (as Fe) is 0.06 percent and that of silicon (as Si) is 0.08 percent; the maximum for cal- cium (as Ca) and for sodium (as Na) is 0.12 percent for each, but the two combined may not exceed 0.12 percent; maximum allowable sulfur is 2.0 per- cent. The presence of barium, nickel, chromium, manganese, cobalt, or vanadium is objectionable, and only extremely small amounts are allowed. In regard to physical properties, the coke is required to be so thoroughly calcined that it has a real density of at least 2.02.

Nov 1, 1943

By L. C. IlsLey

Cooperation between the United States Bureau of Mines and the Safety in Mines Research Board of Great Britain, continuous since 1924, has made possible this and other papers on safety subjects. Grateful acknowledgment is made to representatives of the Safety in Mines Research Board of the Mines Department for their assistance in arranging visits to several mine safety stations, and to F. R. Wynne, Deputy Chief Inspector of Mines, Great Britain, for arranging visits to mines in Great Britain, Belgium, Germany, and France. During the summer of 1927 the writer had the privilege of visiting the mine safety testing stations in Great Britain, Belgium, Germany, and France, in the order named. All of these countries have large coal mines, many of which are rated as gassy. Therefore, when installation of electrical equipment is contemplated, each of these countries is confronted with the same safety problem as is the United States - the development of electrical equipment that will not ignite gassy mine atmospheres which might, through neglect or accident surround the equipment. The means used by these countries in safeguarding gassy mines should therefore be of general interest to safety engineers of American coal mines, and it is proposed to give a brief survey for each of the four countries mentioned. This paper presents the second of these surveys, which covers conditions in Belgium.

Jan 1, 1929

By Hillary W. Clair

An equation is derived for the rate of reaction of a sphere of metal oxide in a restricted enclosure through which a reducing gas is flowing . The equation takes into consideration the reaction rate coefficient , transport through the gas and through the porous shell of reduced oxide , the rate of gas flow , and the volume of the enclosure . The equation serves as a model for predicting the course of reduction of a particle of metal oxide in a shaft furnace .

Jan 1, 1964

By J. J. Forbes

The rapid increase in the quantity of coal being mined by stripping methods is one reason for the increased interest evinced by safety and other agencies in the hazards that are inherent in this Method of mining. The coal-mining laws of some States contain general provisions governing the mining of coal by open-cut methods, but none contains a complete list of specific safety regulations or laws for-the safe operation of such mines. The cool-mining laws of one State empower the head of the coal-mining inspection organization to proscribe regulations for coal-stripping operations and gave him the authority and power to enforce the rules and regulations promulgated by him.

Jan 1, 1944

By D. L. Nussear, W. E. Wallace, N. N. Clark, M. Gautam, G. Hong-Guang

"Results from a study directed towards identifying and measuring the mutagenicity of diesel exhaust particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented in this paper. Particulate matter emissions from a diesel engine, representative of the ones found in underground mines, were sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust was diluted in a multi-tube mini-dilution tunnel and the particulate matter was collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8"" x 10"" hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the mutagenicity potential.Protocols developed for using a primary component of pulmonary surfactant as a medium for collecting and applying respirable particulate material to cells for mutagenicity testing offer a true representation of in-vivo delivery of such respired aerosols to pulmonary cells and the genetic material within . The surfactant dispersion technique is discussed in this paper. Methods have been developed to sample and assay the diesel soot and diesel soot/mineral dust complexes which would not compromise the surface and physical properties of the particulate material."

Nov 1, 1995

By Paul J. Barrett

The Bureau of Mines evaluated a sulfurous acid-sulfuric acid process for recovering alumina from clay, in which clay is leached. successively with sulfurous acid and sulfuric acid. The resulting aluminum sulfite and aluminum sulfate solutions are combined and heated to produce a basic aluminum sulfate and sulfur dioxide. Alumina is extracted from the basic aluminum sulfate as sodium aluminate by leaching with dilute sodium hydroxide. After desilication, sulfuric acid is used to precipitate alumina as alumina trihydrate, which is then calcined to alpha-alumina. The estimated fixed capital cost for a plant producing 1,000 tons per day of alumina is about $74 million on a 1971 basis. For comparison with previous alumina-from-clay evaluations, the estimated fixed capital cost for the plant is about $67 million on an M and S Chemical Equipment Index basis of 24.0.0, which is equivalent to a 1960 cost level. Because the operating cost is highly dependent on fuel and electric power costs, graphs are included to show the effect of these items on the operating cost. On a 1971 basis, with natural gas costing 35 cents per million Btu and operating labor costing $4 per hour, the estimated operating cost is about $100 per ton of alumina. On a 1960 basis, with labor costing $2.30 per hour and natural gas costing 25 cents per million Btu, the estimated operating cost is about $86 per ton of alumina.

Jan 1, 1973

Federal lands often contain extensive mineral resources and decisions affecting access to those lands are made with knowledge of the possible minerals-related consequences. Information is provided to the Bureau of Land Management (BLM) in this report for use in preparing environmental impact statements on the Western Mojave Management Area (WMMA) and the Desert Tortoise Priority Habitat (DTPH). To augment U.S. Bureau of Mines (USBM) efforts such as the Mineral Assessment of the Planned Foil Irwin Expansion, Modified Silurian Valley Alternative, San Bernardino County, California which is in progress, and the Economic Analysis of the Minerals Potential of the East Mojave National Scenic Area; California, the USBM studied mineral deposits and estimated the potential impacts of mining in a segment of the California desert; the 8.7-million-acre WMMA, an area which includes the 1.2-million-acre Desert Tortoise Priority Habitat (DTPH). In addition, this information is intended to assist administrators, legislators, and the concerned public in understanding the economic importance of mineral resources in the California desert, especially that portion designated as the WMMA. See figure 1.

Jan 1, 1993

By Robert J. Timko, Edward D. Thimons

Sulfur hexafluoride (SF6) is an odorless, colorless, nontoxic gas that has found acceptance as a tracer gas in research on ventilation pat- terns, measurement of air leak rates, respirable dust reductions due to bagging hood modifications, and the study of airflows relating to gob boreholes. Following a short review of the SF6 sampling technique, this report describes recent Bureau of Mines projects in which SF6 was used successfully as a tracer gas, enabling researchers to acquire representative data quickly and inexpensively.

Jan 1, 1982

By J. B. Littlefield

The term "konimeter" is used generally to designate a type of dust-sampling instrument that collects the dust from a small volume of air by impingement on a glass plate prepared aced with an adhesive film. The konimeter was first developed by Sir R. N. Kotze about 20 years ago and was followed a few years later by the circular-type konimeter, by which a number of samples may be collected on a glass disk. The present discussion will be confined to the circular type, as it is used most. Various techniques have been developed for using the konimeter, and many materials, such as petrolatum, mineral oil, and glycerine jelly, have been used in preparing the adhesive film. In South Africa, Australia, and Canada, where the konimeter has been employed most widely, dust samples are treated by ignition and washing before being counted. In Canada the dust samples are collected on a disk of special heat-resistant glass prepared with a film of mineral oil; the disk is then heated to a dull cherry-red in a muffle-furnace to remove the film and organic matter, cooled, and washed with a few drops of 50-percent hydrochloric acid followed by distilled water and alcohol, and then heated again to remove residue left by evaporation of the alcohol. After this treatment, the dust samples are counted under a magnification of 150 diameters with dark field illumination.

Jan 1, 1938

By Doris M. Hyde

To a greater or lesser extent, the economies of the smaller Caribbean Island countries continued to have common problems. These included unemployment, inflation, foreign exchange shortages, trade deficits, and unstable world prices for their exports. Declining prices for petroleum provided some relief from scarce foreign exchange. Overall, the mineral sector remained stable. The Amerada Hess Corp. crude oil transshipment terminal on St. Lucia was completed during 1981. However, there were no shipments during the year. No official reason was offered for the delay in opening the terminal, but it may have been related to the world surplus of crude oil that occurred in 1981. There has been no further action on the refinery, which was to complete the island's petroleum complex. During the first half of 1981, an announcement was made that a second oil transshipment terminal would be built on St. Lucia. The report indicated that the terminal was to be financed by Saudi Arabia and include underground storage. After the original announcement, no further information was made available. This terminal, like the Hess petroleum complex, may have been temporarily postponed because of the crude oil surplus.

Jan 1, 1983

By J. A. Gutierrez-Rodriguez, R. J. Purcell, F. F. ApIan

"Based on contact-angle measurements and the work of adhesion equation, the hydrophobicity of a wide variety of coals was found to decrease with decreasing rank, fixed carbon and total carbon content and with increasing oxygen and hydroxyl content. The estimated hydrophobicity, based on the water-sessile-drop contact angle, is '\.. 20% for lignite, increases with increasing rank up to a maximum of 'V70% for low (LV) and medium (MV) volatile bituminous coals and then decreases somewhat for anthracite. Using the captive-bubble technique, the calculated hydrophobicity ranges from '\.. 0% (below HV A bituminous rank) to a maximum of 55% for L V-MV coal. The former estimation is believed to be the more accurate. While the water-sessile-drop contact angle as measured on a polished-coal surface is usually larger than that shown by the captive-bubble method, the two values were found to converge at""' 95% relative humidity. It is proposed that the surface of coal consists of three kinds of sites: strongly hydrophobic, weakly hydrophobic and hydrophilic. The sessile-drop technique measures the total hydrophobic sites whereas the captive-bubble method measures only the more strongly hydrophobic sites. A water film covers the weakly hydrophobic sites preventing their detection by the captive-bubble technique.INTRODUCTIONCoal is a mixture of the degradation products of plants and of mineral matter. The appearance and properties of a specific coal is determined by the nature of the original vegetation and the extent of the physical and chemical changes which have occurred after deposition. The coalification process may be considered to have started with peat formation followed by a transition to lignite due to burial under sediments and metamorphic processes. Further metamorphic transformation to bituminous coals and, finally, under intense metamorphic action, to anthracite causes the carbon content and rank of the coal to increase. With such a wide variation in their genesis and composition, equally wide variations in the degree of hydrophobicity of different coals may be expected. It is the purpose of this paper to provide a means of estimating the hydrophobicity of a given coal sample based on rank parameters."

Jan 1, 1989

By Harold L. Rhodes

The Bureau of Mines has developed a quantitative method to determine water vapor in helium in the range of 0.1 to 15 ppm by volume. This method uses the quantitative chemical reaction of H20 with CaH2, which produces 1 mole of hydrogen for each mole of H20 in the sample. A gas chromatograph is then used to determine the concentration of hydrogen in the product. The precision of the H20 analysis is ±0.05 ppm at a concentration of 1 ppm. This method is used to calibrate a commercial platinum-phosphorus pentoxide (Pt-P205) electrolytic water vapor analyzer that has an improved inlet system and digital voltmeter readout.

Jan 1, 1981

By Rogers F. Davis

This publication has been prepared to supply manufacturers and industrial users a listing of mobile diesel-powered equipment and subassemblies approved and certified by the Bureau of Mines for use in noncoal mines. Testing of diesel-powered equipment is one phase of the Bureau's program of health and safety that concerns approval of electrical and diesel equipment designed to prevent explosions, fires, shocks, or toxic hazards in underground mines, when such equipment is used and maintained properly. Manufacturers submit machinery and component parts to the Bureau for study of their design, safety features, and use. Equipment must pass exacting tests and must meet strict requirements established through research and experience and listed in the Bureau's permissible schedules before the Bureau approves it as permissible for safe use in mines.

Jan 1, 1963

By E. G. King

This report contains experimentally determined heat-content values for cerium dioxide and Columbium (niobium) dioxide in the temperature range from 298° to 1,800° K. There are no previous similar data for Columbium dioxide, and those for cerium dioxide have an upper limit of 373° K. The heat-content and corresponding entropy-increment data are presented in tabular form. Equations were derived to represent the heat contents and heat capacities. The data for cerium dioxide are entirely regular, but those for columbium dioxide show two previously unreported anomalies at 1,090° and 1,200° K.

Jan 1, 1961

By Sarkis G. Ampian

The Bureau of Mines has developed a method for identifying fine particles of beryl in mineral samples by preferentially staining the beryl grains. The sample is first subjected to a heated sodium hydroxide solution to etch the beryl particles, which are subsequently stained an intense blue color in a boiling alkaline solution of quinalizarin. Positive identification of beryl grains permits quantitative analyses by microscopic techniques. INTRODUCTION Beryl, a beryllium aluminum Silicate, is the principal ore mineral of beryllium. The only known commercial concentrations of this mineral are found in pegmatite dikes of granitic composition. Normally beryl is associated with muscovite mica, quartz, and the sodium-and potassium-bearing feldspars (orthoclase, microcline, and albite). Other beryllium-bearing minerals which are found occasionally in minor amounts with beryl are phenacite, a beryllium silicate, and chrysoberyl, a beryllium aluminate.

Jan 1, 1962

By R. J. Shanley

This report presents a computer code that has been developed by the Bureau of Mines for isolating naturally occurring clusters of data plotted on the unit hemisphere and testing these clusters against a probability distribution which admits elliptical symmetry about its mean. A listing of the computer code is provided along with an example output illustrating the delineation and analysis of clusters in fracture orientations measured in a porphyry copper deposit.

Jan 1, 1975