Search Documents

By F. F. Netzeband

This report relates to the sulfur industry of seven States--Arkansas, Kansas, Louisiana, Mississippi, Missouri, Oklahoma, and Texas--and is part of a national study of the sulfur industry by the Bureau of Mines. Markets as used in this report are divided into two components for individual analysis-- (1) supplier markets which include regional Frasch and byproduct sulfur producers and (2) consumer markets which include processors and manufacturers requiring sulfur in their operations The term sulfur as used in this report includes brimstone, native sulfur, elemental sulfur, or sulfur equivalents.

Jan 1, 1964

By M. E. Volin

The tungsten potentialities of the Combination mine were examined by a mining engineer of the Bureau of Mines in 1947. A report based upon his personal knowledge of the mine and the results of the examination contained recommendations for further investigation. This report presents factual data from Bureau of Mines field investigations begun in August 1947 and continued until December 1948, except for a 5-month recess during the first winter. The Combinat.ion mining property of 52 patented claims and 15 patented mill sites is in the Black Pine mining district, Granite County, Mont., 11 miles northwest of Philipsburg. The altitude in the mine vicinity is approximately 6,500 feet.

Jan 1, 1952

By Louis C. Brichta

The Rush Creek district of Marion County, Ark., has had a more or less continuous record of zinc production over the past 40 years. The ore has come from many small mines working on oxidized and semi-oxidized deposits found in the Everton formation where that formation forms the present surface rock. Prospecting has been restricted to the hillsides above the creek levels, the actual ore outcrops being the guides. Little attention has been paid the possible sulfide zones. In August 1942, the United States Geological Survey and the Bureau of Mines recommended exploration of the Powell and Cotter formations, which underlie the Everton, for which purpose the Survey had previously located 18 proposed drill-hole sites in geological structures that seemed favorable to are deposition.

Jan 1, 1949

By E. P. Youngman

This paper is one of a series of digests of foreign minim legislation and court decisions that is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of the minim lams of Ceylon has been prey tired from the best available information in Washington and is released subject to amplification and correction, if necessary, by United States foreign-service officers. INTRODUCTION Ceylon has no basic mining law; the general rules governing the granting of mineral concessions and affecting legal titles of concessionaires are laid down in Ceylon Government ordinances or are found in the authorized forms for licenses and leases. The material available in the preparation of this digest is as follows:

Jan 1, 1933

By George L. Gates

The Bureau of Mines studied pressure-buildup data from a number of California gas wells to determine if the reservoir properties calculated from these data correlated with field-observed reservoir properties. Pressure-buildup curves from 24 wells showed distinct changes in slope, indicating changes in permeability of the reservoir rock. Calculated distances from the wells to indicated permeability changes were in fair agreement with distances deter-mined in the field. Pressure-buildup curves from three wells had more than one distinct change in slope, indicating multiple permeability changes. Thus field data supported the theoretical relations used to calculate reservoir properties from pressure-time relations measured in gas wells.

Jan 1, 1967

By Thomas A. Phillips

This publication is an economic evaluation of the Bureau of Mines electrolytic process for recovering lead from scrap lead-acid batteries. In this process, scrap batteries are crushed and separated into metal and sludge fractions. The metal fraction is cast as anodes and electro- refined. Lead in the sludge fraction is converted to lead carbonate by reaction with an ammonium carbonate-ammonium bisulfite solution. The lead carbonate is then dissolved in a fluosilicic acid electrolyte from which pure lead metal is electrowon. A cost estimate is presented for a plant capable of processing 10,000 scrap batteries per day. The fixed capital cost for this plant is estimated to he $14 million on a fourth quarter 1984 basis. Operating costs are estimated to be $0.15/lb Pb recovered. Assuming a lead selling price of $0.17/lb, the interest rate of return on investment after taxes is 11 pct. A lead selling price of about $0.21/lb is needed to obtain a 20-pct-interest rate of return.

Jan 1, 1986

By K. E. Tame

A resume of the history and state of the art of physical beneficiation of uranium ores is presented along with a detailed description of research on concentration of uranium ores by attrition grinding. The information on flotation, gravity concentration, electronic sorting, and selective grinding was gathered to complement the study of attrition grinding methods. Both dry and wet grinding procedures were investigated as potential methods of upgrading a variety of ore types, ranging in grade from 0.02 to 0.42 percent U308. A Mardun4 disintegrator that employs high-speed rotating paddles in a cylindrical shell lined with interrupter bars was used in most of the dry grinding studies. Attrition scrubbing devices, which impart a violent mixing or attritioning action to ore pulps, and cylindrical mills, employing rods or punchings as grinding media, were used in the wet grinding tests.

Jan 1, 1961

By John W. Walkiewicz

The U.S. Bureau of Mines has conducted studies to utilize rapid microwave heating to stress fracture ore samples. Iron ores containing hematite, magnetite, and goethite were subjected to microwave energy in batch operations at 3 kW and heated to average maximum temperatures between 840 and 940 °C. Standard Bond grindability tests showed that microwave heating reduced the work index of iron ores by 10 to 24 pct. In a microwave chamber designed to simulate a continuous throughput operation at 3 kW, the grindability of a taconite ore was improved by 13 pct at a bulk temperature of 197 °C. Because stress cracking occurred at a lower temperature, less energy was consumed. To further improve the economics of microwave fracturing, higher powers up to 16 kW were used to rapidly heat samples to relatively low temperatures in a continuous, belt-fed applicator. A significant improvement of grindability was obtained with a larger rod mill feed size in comparison to a minus 6-mesh Bond feed.

Jan 1, 2010

By R. F. Selden

The material in this paper is intended simply, to be an inquiry into some of the theoretical aspects of the occurrence of methane and carbon dioxide in coal, with a brief resume of the more recent literature. Several discussions on various phases of the subject have been published, a few of which (4, 20, 25, 88, 90)4/ have more or less extensive bibliographies of tie earlier literature. In large measure the pertinent literature deals with the unusual aspects of the subject, and in consequence it might appear that the normal aspects have not been given due consideration here. The latter information is largely a matter of practical field experience, and since that which is normal to one locality is often abnormal to another no sharp differentiation appears to be necessary or, in fact, possible. No attempt will be made to present a critical discussion of the relations between the presence of gases in coal and pertinent geologic features or mining practice. Although the presence of foreign gases in the ventilating air of many mines is not particularly noticeable, in many others the evolution of methane and perhaps small amounts of carbon dioxide (or sometimes the reverse - large amounts of carbon. dioxide with perhaps sore methane) is quite apparent.

Jan 1, 1934

By R. F. Selder

The material in this paper is intended simply to be an inquiry into some of the theoretical aspects of the occurrence of methane and carbon dioxide in coal, with a brief resume of the more recent literature. Several discussions of various phases of the subject have been published a few of which (4, 20, 25, 88, 90) have more or less extensive bibliographies of the earlier literature. In large measure the pertinent literature deals with the unusual aspects of the subject, and in consequence it might appear that the normal aspects have not been given due consideration here. The latter information is largely a matter of practical field experience, and since that which is normal to one locality is often abnormal to another no sharp differentiation appears to be necessary or, in fact, possible. No attempt will be made to present a critical discussion of the relations between the presence of gases in coal and pertinent geologic features or mining practice. Although the presence of foreign gases in the ventilating air of many mines is not particularly noticeable, in many others the evolution of methane and perhaps small amounts of carbon dioxide (or sometimes the reverse - large amounts of carbon dioxide with perhaps sore methane) is quite apparent. The presence of small quantities of carbon dioxide can be attributed to oxidation of the carbonaceous matter exposed to the air. In the few cases in which this explanation is not sufficient, obviously the carbon dioxide must escape as such from the coal and neighboring strata.

Jan 1, 1934

By G. L. Humphrey

Although silicon carbide has been an important manufacture refractory for many years, knowledge of its thermodynamic values has been seriously lacking. In fact, some of the very properties that make it a useful substance, particularly chemical inertness, obstruct determination of its heats of formation and reaction. This paper reports the results of new measurements of the heats of combustion and formation, low-temperature heat capacity, entropy at 298.16°K., and heat-content and entropy increments between 298° and l,800°K. Two varieties of silicon carbide were studied -the common, hexagonal (type II) and cubic. The data are combined to obtain heat and free-energy-of-formation functions, which are given in tabular form. It is shown that the cubic variety is the more stable at temperatures to at least 1,800°K but, because of the inherent difficulties and errors in the heat-of-formation determinations at 298°K, it was not found possible to specify the free-energy difference accurately. The mechanism of silicon carbide formation from silica and carbon is not known and is not ascertainable from thermodynamic data. It appears improbable, however, that it can be a single-step reaction. Some reactions involving silicon monoxide gas and metallic Silicon, as possible intermediates in silicon carbide formation, are considered and shown to be thermodynamically feasible.

Jan 1, 1952

By T. H. Davis

Twelve laboratories from the Western United States and Canada participated in radon progeny intercomparison measurements at the U.S. Bureau of Mines radon calibration facility in March 1987. The participants intercom pared grab-sampling and automated equipment methods at high and low concentrations of radon progeny and condensation nuclei (CN). The objective of this intercomparison was to determine if the measurement procedures and equipment of the North American facilities are equivalent. The sampling results showed good agreement among all participants. The standard deviation for the working level measurements was less than 3.5% for 1.70 working level (WL) and less than 8.8% for 0.21 WL. This relatively good agreement was achieved by using alpha standards calibrated by National Bureau of Standards (NBS) and by closely checking and monitoring airflows.

Jan 1, 1989

By Alla D. Mah

The energies of combustion of zirconium carbide and hafnium carbide were measured by combustion calorimetry and the heats of combustion and formation. of zirconium carbide and hafnium carbide were derived . The results are-- ZrC AH298.15 ( combustion) = -308.60 ± 0.55 kcal /mole , AH298.15 ( formation) -47.0 ± 0.6 kcal /mole , AH298.15 = HfC (combustion ) = -306.08 ± 0.20 kcal/mole , AH298.15 ( formation) -52.3 ± 0.4 kcal /mole . = INTRODUCTION This report contains the results of calorimetric measurements to obtain the heats of formation of zirconium carbide ( ZrC) and hafnium carbide ( HfC) . The work was conducted as part of a Bureau of Mines program for determining the heats of formation of oxides , carbides , and nitrides by combustion calorimetry . Combustion calorimetry is one of the most precise calorimetric techniques . The chief obstacle to obtaining accurate heat of formation values for carbides , and the chief reason for the variation in the results of different investigators , is the lack of purity of the carbide samples . Corrections for impurities always involve assumptions which lead to uncertainties . In general , a large impurity correction is accompanied by a large uncertainty in the final result .

Jan 1, 1964

By K. L. Paciorek

The aim of this program was to develop a reliable and meaning-ful basis for assessing certain safety aspects, namely fire and, in particular, toxicity hazards of articles employed in underground coal mining operations. The present investigation was concentrated on the thermal oxidative degradation of representative hydraulic fluids. To achieve this goal all products formed on thermal oxidative degradation of the fluids studied were analyzed, identified I and the amount of each individual species present was determined quantitatively on a weight of product per weight of material basis. The weight/weight data thus obtained can then be factorized to reflect the relative toxicity of each individual species present, using for example the Threshold Limit Values adopted by the American Conference of Governmental and Industrial Hygienists, whereby an overall "toxicity index" can be arrived at which makes it possible to compare the different fluids and/or classes of fluids in a quantitative manner insofar as their toxicity is concerned.

Jan 1, 1976

By Will H. Coghill, C. O. Anderson

In July 1921 , we were assigned by the U. S. Bureau of Mines to an investigation of milling methods in the Tri - State zinc district ( Missouri -Kaneas- Oklahoma district ) . The work has progressed without interruption , and about onehalf of the funds allotted for it has been expended . This preliminary statement abcut the nature of the work and the results so far obtained , has been prepared for the information of the operators , and through their assistance to insure the greatest possible progress during the remainder of the work . A general survey of the district was made , and many of the mining companies cordially offered the facilities of their plants for the investigation . The work was finally centralized at the plant of the 0. M. Bilharz Mining Co. Its manager , F. H. Gartung, and his successor , O. W. Bilharz , have been especially helpful , also the millmen at this plant and elsewhere have rendered assistance without which the work could not have advanced . The Missouri School of Mines and Metallurgy , Rolla, Mo. , and the Miami School of Mines , Miami , Okla . , have given hearty cooperation . The Webb City Iron Works and the Joplin Supply Co. donated some necessary apparatus .

Jan 1, 1922

By R. W. Watson

In January 1980, the Bureau of Mines initiated an experimental program to examine the fire and explosion hazards of one-hour self-contained self rescuers (SSRs). This action was prompted by a growing concern on the part of government and industrial safety officials over the potential hazards of these devices when deployed on a large scale in underground coal mines. Prior evaluation of the safety of these devices had been at best sporadic and usually limited to experimental models. The recent availability of preproduction models of a l-hour SSR fabricated by the Mine Safety Appliance Company* and a production model manufactured by Dragerwerk Ag Lubeck of the Federal Republic of Germany allowed for a more comprehensive and meaningful evaluation of their safety in underground coal mines. This report summarizes the results of a 5-month study of the potential hazards of these two items. During the course of the work, periodic progress reports were presented to officials of the Mine Safety and Health Administration and various mining organizations including the American Mining Congress, Bituminous Coal Operators of America. National Independent Coal Operators Association, and the United Mine Workers of America. The free exchange of ideas that occurred during these meetings had a significant impact on the direction of this study and a serious attempt was made to address all of the issues that were raised at these meetings. The authors are extremely grateful to the individuals that participated in defining the specific problems that could arise as a result of deploying the self-contained self rescuers in an underground coal mine environment.

Jan 1, 1980

By Michael A. Anuta

This report describes the potential for utilization of satellite observations for remote sensing of mine waste disposal areas. Four study sites consisting of metal and nonmetal mining areas in different climatic and physiographic regions of contigous United States were used in this investigation. The mine waste disposal sites consisted of mining of phosphates in Florida, copper in Arizona, silver in Idaho, and coal in West Virginia. Landsat satellite multispectral scanner observations were used together with aerial photographs, ground surveys, U.S. Geological Survey maps, and other ancillary information. Landsat digital data were categorized using automated supervised classification algorithms and an image analysis system. Detailed description of automated classification techniques employed and the accuracy attained is provided together with the results of manual interpretations. The inventory of areas distrubed for phosphate mining and a change detection investigation for-Polk County Florida were also undertaken during this study.

Jan 1, 1982

By A. Visnapuu

The Bureau of Mines has upgraded high-iron domestic chromite concentrates by a carbonyl process. The upgraded chromite concentrates show as much as 10 wt pct higher Cr203 content and up to a threefold in-crease in the Cr:Fe ratio, compared with the starting concentrates. The high-iron chromites were first reduced to convert the iron oxides to the metal, and then treated with CO at elevated pressures and low temperatures to convert part of the metallic iron fraction to iron pentacarbonyl. Carbonylation was accelerated by the addition of H2S in small quantities. The iron pentacarbonyl was extricated from the con-centrate in the pressure reactor during carbonylation by a CO sweep through a pressure-reducing valve and passed through a decomposer at atmospheric pressure to convert it back to iron metal and CO. CO pres-sure, temperature, promoter trends, and other factors enhancing iron pentacarbonyl formation are presented.

Jan 1, 1985

By J. E. Hipp

Three electrostatic field sensing proximity warning devices were tested using full-scale cranes and power line systems, a scaled model facility, environmental testing facilities, and theoretical/numerical analysis. The design objective of each device is to assist in safe crane operation near overhead power lines. Several design deficiencies (varying from device to device) were observed, including inadequate overlap in sensitivity ranges, utilization of vacuum tubes and electro-mechanical parts, temperature sensitivity and inaudible alarms. In addition, the testing showed major device limitations including sensitivity to boom orientations and length, polarization dependent responses, and unreliable operation in the presence of multiple power line circuits. The multiple power line circuit problem is intrinsic to electrostatic sensing devices. The remaining deficiencies and limitations are correctable within a state-of-the-art design. This investigation is not intended to evaluate the safety aspects or policy of utilizing proximity warning devices. Rather, the purpose is to determine the performance characteristics of such devices in relation to the criteria specified in proposed MSHA regulation 77.805-4 (i. e., the devices must alarm at a distance of 10 feet from the power line).

Jan 1, 1980

By J. K. Whyatt

Researchers at the U.S. Bureau of Mines collected and analyzed overcore measurements and other indicators of in situ stress characteristics at the Lucky Friday Mine, Mullan, ID. An analysis of these data revealed that significant local variations in in situ stress are present in this mine and that these variations existed prior to mining. High stresses were found to be associated with the most competent strata and a locked section of a fault. An estimate of the predominant stress field was developed for mine-wide modeling. The estimate shows that the greatest principal stress was oriented north of northwest. This information should provide a basis for mine-wide structural modeling of the Lucky Friday Mine and should generate important insights into localized stress conditions, which may significantly affect both local and mine-to-mine variations in seismicity induced by excavation.

Jan 1, 2010