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By G. Kill

Although other energy commodities have developed successful futures contracts, long-term contracts still dominate the coal market. To establish whether coal markets will develop in the same way, coal price and volume data are tested against a set of criteria considered to represent some of the factors contributing to the development of a successful futures contract. Coal meets only some of the criteria: market players are subject to little risk in quite a stable market, have strong preferences for the specific nature of long-term contracts and profit from product uniqueness, each trade being individually negotiated. Potential structural changes in the western European market are not felt to be sufficient to create demand for a coal futures contract, but an empirical model has been developed that could form the basis of a further study to predict the potential for success

Aug 1, 1994

By J. S. Duval

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). The compilation of the National Uranium Resource Evaluation aerial gamma-ray data to produce maps of the apparent surface concentrations of potassium, uranium and thorium for the conterminous USA has resulted in a reasonably accurate representation of the distribution of these elements in the surface rocks and soils. This claim is supported by the general agreement between the mapped geology and the patterns seen in the data

Jul 1, 1991

By G. Zhan, P. Mousset-Jones, G. Danko, J. J. K. Daemen, C. Mezei

Paper presented at the conference Risk assessment in the extractive industries, held in Exeter, 23-24 March 1994, and first published London: IMM, 1994, preprint volume. 18pp., 12 refs. (Originally entitled: Tunnel roof diagnosis using a robotic sensor test bed.) An integral roof diagnosis method is proposed to assist in assessment of risk regarding the stability of an excavation. A Robotic Sensor Test Bed (RSTB) is being developed for the characterisation of roof stability. The sensor test bed consists of a sonic/ultrasonic wave response sensor, a laser surface profiler and a surface temperature sensor. These sensors are mounted on an articulated robot manipulator for performing remote-controlled or fully automated diagnoses. A number of laboratory and field sonic/ultrasonic tests were conducted. A high-energy ultrasonic transducer and an impact device were used to resonate rock slabs. The fracture depths of the slabs were found to be inversely related to the measured resonance frequencies. The agreement between identified and actual dimensions was acceptable. Field tests also showed that loose rock on the surface can be clearly distinguished from solid formation by comparing their wave responses. The robotic laser profiler part of the RSTB was used to measure surface geometry. Different scanning methods are being developed to achieve the fastest and most precise measurements and to provide pertinent information about rock joints and major fractures

Dec 1, 1994

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By D Macdougall, J Otto

The financing of large mining projects in developing countries is often achieved, at least in part, by limited-recourse financing methods. Financing agreements are affected by the basic accord that is struck between the host government and the sponsors of the project. It is concluded that governments and project sponsors should take into account the requirements of lenders when structuring such mineral development agreements to maximise the potential for attracting project financing. Lenders are likely to be most interested in aspects such as fiscal arrangements, calculation of taxable income and general accounting rules, royalties, transferability of payments/dividends overseas, corporate structure and control, staged development, financing, loan support and state guarantees/approvals, political risk, provisions for default, product marketing, settlement of disputes and environmental issues

Aug 1, 1994

By A. G. Pasamehmetoglu, N. Celebi, K. Erarslan

A deposit evaluation system has been developed for a proposed new mine in the basin around Collolar in Turkey. It includes compositing, gridding and reserve estimation facilities and takes account of the economic value of the pit and the pit bottom elevation

Sep 1, 1991

By T Grenne, R. B. Larsen

Paper presented at the conference on Economic geology in Europe and beyond II, models for mineral deposits in sedimentary basins, held in Keyworth, UK, 13-14 April 1994. Paper originally entitled: Processes in a newly discovered sulphide-PGE mineralisation in Norway. The Stormyrplutten mineralisation is hosted by a minor tholeiitic metagabbro of low-Ti composition intruded at a high level in the volcanic lithology. It is thought to be the subvolcanic counterpart of submarine basalts generated during an extensional episode of ensimatic arc evolution. The sulphide-PGE mineralisation occurs as stratabound pyrite, pyrrhotite and chalcopyrite disseminations with average grades of 376 ppb Pd, 313 ppb Pt, 40 ppb Au, 0.5% Cu and 0.08% Ni in a deposit 15-25 m thick. Locally the PGE content peaks at 2 ppm over 1 m. Microprobe analysis isolated 14 different platinum-group minerals, dominated by sperrylite, temagamite and borovskite and occurring as 1-20 micron compounds embedded in the main sulphide minerals or along the sulphide/silicate grain boundaries. Mantle-normalised plots reveal strong depletion in Os, Ir and Ru and enrichment in Pt, Pd, Cu and Au. The general decrease in Pd and Pt and increase in S up through the stratigraphy is similar to PGE distribution in the Darwendale subchamber of the Great Dyke in Zimbabwe, and may reflect strong fractionation of Pd and Pt in favour of the first droplets of sulphide melt; two reversals of the trend at the 4 and 12 metre levels represent replenishment with fresh magma and repetition of the cycle. In contrast to the Darwendale system, Cu and Ni also show peak concentrations in the first-formed liquids and Pt appears to have fractionated more strongly into the sulphide melt than Pd

Aug 1, 1995

By H. Y. Sohn, Hang Goo Kim

Computer simulations were carried out using calcium ferrite slags containing 25 wt% CaO, and the results compared with those obtained using fayalite slags. There was little difference in overall elimination of Pb and Bi, but elimination of Sb and As was much lower with calcium ferrite slag. When calcium ferrite slag is used only in the converting stage and fayalite slag in the smelting stage, as in the Mitsubishi process, the contents of Sb and As in the blister copper can be kept to reasonable levels. This allows advantage to be taken of the considerably higher iron oxide-holding capacity of calcium ferrite slag than of fayalite slag at the high oxygen potential under converting conditions, thus preventing precipitation of magnetite. Satisfactory agreement was obtained between predicted values and observed data from a Mitsubishi converter

Jun 18, 1905

By F. T. Da Silva

Concentrates of titaniferous minerals containing around 30 wt% Ta2O5 are processed hydrometallurgically by hydrofluoric acid leaching and solvent extraction, followed by the precipitation of hydrated potassium heptafluorotantalate. A fundamental study of the thermodynamics of this precipitation and recrystallisation was undertaken to increase understanding of the conditions most conducive to the production of pure, well-crystallised K2TaF7. Activity-pH diagrams for the Ta-K-F-H2O system explained the dissolution of Ta2O5 in fluoride solutions quite well and also the precipitation-recrystallisation of K2TaF7.H2O. X-ray diffraction and scanning electron microscopy confirmed the thermodynamic observations. It was concluded that the best precipitating agent for K2TaF7 from fluoride solutions is KF but a recrystallisation step in a HF environment produces purer, well-crystallised K2TaF7.H2O, eliminating oxy-salts and other impurities

Jun 21, 1905

By Xuejing Xie, Tianxiang Ren

Paper presented at the 28th International Geological Congress held in Washington DC, July 1989 (International geochemical mapping sessions). Standardised stream-sediment sampling procedures have been used in mountainous and hilly terrains. Special sampling procedures were developed for application in remote environments, such as high mountains, desert, semi-desert, karst and loess-covered regions. The diversified analytical methods used in more than 20 analytical laboratories participating in the project have been unified into two multi-element, multi-method analytical systems. A unified data monitoring procedure was developed based on primary and secondary standard samples. To date the project has covered about 4 000 000 km2 and the aim is to complete the coverage within the present decade

May 1, 1991

By W. E. Stephens, A. J. Boyce, D. Lowry

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. An integration of S isotopic, fluid and mineralogical data for granitoid-related mineralisation showed that the porphyry systems had a predominantly subcrustal magma source, but the inner magma pulse of two-mica granite in the Fleet pluton was derived mainly from reduced sediments. The porphyry-style mineralisation formed from boiling fluids at high crustal levels, with a moderately saline fluid percolating down to the upper veins as they cooled but not penetrating the deeper Talnotry deposit. Veins in peripheral greywackes have a significant magmatic component but also incorporated CO2-rich components and metals released by dewatering of host sediments in response to granitoid intrusion. The low grade of regional metamorphism resulted in the significant fluid input from country rocks which led to the more exotic mineral compositions, especially where argillaceous sediments were involved

Jun 19, 1905

By R. Allington, G. Walton

The approach has been applied with success to the restoration of chalk workings in southern England, and research and trials relating to restoration blasting and the replication of limestone dale landforms have been undertaken. An essential prerequisite for application of the technique is rigorous geomorphological analysis of the locality to ensure that final quarry landforms are consistent with the local geomorphological and landscape setting. It is always important to ensure compatibility of the final landform with the intended after-use, and to achieve this it is also essential that such restoration schemes have a sound geotechnical basis. A disadvantage of the approach is that final slopes tend to be flatter, especially in weaker strata where natural slopes are not steep; the implications for reserves may be unacceptable, particularly in quarry extensions

Aug 1, 1994

By R. A. Ixer, R. A. Lord, H. M. Prichard, A. J. Boyce, P. McConville, C. T. Pillinger, I. P. Wright, J. Maynard

Analysis of 62 samples show that the sulphides throughout the igneous stratigraphy have a magmatic signature, with the exception of the uppermost gabbros and the lowermost basal thrust talc-carbonate lithologies. Mean delta-34S values for whole-rock samples from harzburgites, dunite pods in harzburgite, crustal dunites and wehrlites, the main and high-level pyroxenites and gabbros suggest that the primary sulphides derived their sulphur from a magmatic source enriched in 34S. This finding is compatible with the proposed origin of the ophiolite above a subduction zone. Values for pyrite mineralisation in the uppermost part of the gabbros are thought to result from precipitation from a seawater-derived fluid, while isotopically light sulphur in the basal thrust could have been introduced from underlying metasediments. The replacement of pentlandite by heazlewoodite has not led to sulphur fractionation

Jun 19, 1905

By V. Distler, E. F. Stumpfl

Paper presented at the IAGOD international symposium on mineralisation related to mafic and ultramafic rocks held in Orleans, France, 1-3 September 1993. The massif contains large chromite bodies of "Alpine-type", ophiolitic affinity. Orebodies reach thicknesses of 150 m and sizes of more than 150 000 000 t chromite ore with average grades of 55-60 wt% Cr2O3. Chromites in the Main ore field are low-Al, high-Cr spinels which exhibit some variation in their Mg-Fe distribution. This differs markedly from high-Al spinels in peridotite host rocks and in narrow chromite pods which occur in the western and northern parts of the massif. Chromites carry silicate inclusions, often hydrous silicates such as amphibole. Chromites in massive chromitites contain micron size inclusions of platinum group minerals (PGM). Composite grains containing two PGM and, occasionally, a hydrous silicate are common. Os-Ir alloys rimmed by PGM sulpharsenides occur in narrow serpentine veinlets that cut chromite and are evidence for the reconcentration of PGE concomitant with introduction of As, probably during serpentinisation. Whole-rock PGE contents are highest in massive chromitites of Diamond Pearl mine (totals of 500 ppb). Chondrite-normalised PGE patterns of chromitites show negative slopes which are typical for ophiolitic, podiform chromitites in mantle sequences. The PGE patterns of host rocks are flat and rather depleted compared with those of chondrites and chromitites. Petrological data from unaltered host peridotites suggest a high temperature overprint leading to sub-solidus re-equilibration of olivine and spinel and to the growth of pargasitic and edenitic amphiboles

Jun 16, 1905

By A. Sutton-Pratt

The African continent has been the most prolific producer of gold since mining began. Although most of this gold has come from South Africa, other countries have also been important contributors in the past. There is currently little production outside South Africa, Ghana and Zimbabwe, but the gradual globalisation of the industry over the past decade has resulted in growing interest in the region which bodes well for its future development. An outline is given of prospects and activity (or lack of it) in South Africa, Lesotho, Swaziland, Zimbabwe, Mozambique, Madagascar, Botswana, Namibia, Zaire, Tanzania, Kenya, Uganda, Rwanda, Burundi, Zambia, Malawi, Angola, Congo, Central African Republic, Gabon, Equatorial Guinea, Ethiopia, Eritrea, Djibouti, Somalia, Sudan, Chad, Libya, Tunisia, Egypt, Algeria, Morocco, Ghana, Ivory Coast, Liberia, Sierra Leone, Guinea, Senegal, Guinea-Bissau, Gambia, Mauritania, Mali, Burkina Faso, Togo, Benin, Niger, Nigeria and Cameroun

Apr 1, 1996

By S. C. Tennant, G. M. Steed

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. Immobile-element lithogeochemistry is providing a detailed chemostratigraphy of the submarine Ordo-Silurian volcano-sedimentary sequence. Primary lithologies and magmatic affinities of the sericitised and silicified volcanics are determined from binary plots of Nb, Zr, Y, TiO2 and Al2O3, while mass-change calculations using immobile-element anchors can identify and quantify zones of significant hydrothermal alteration. Stratiform polymetallic mineralisation at the western margin of Parys Mountain, around the Penymynydd fault zone, has been shown to have a distinct hanging-wall and footwall stratigraphy. These ore zones are probably part of a homoclinal, north-younging volcano-sedimentary sequence. The apparent stratigraphic complexity results from primary lithofacies variations and pervasive alteration, with the modifying role of the Caledonian orogeny much less than previously suggested

Jun 19, 1905

By M. Lombardero, J. Garcia-Guinea, J. Taboada, B. W. Roberts

The structural, textural and mineralogical properties of the slate formations of NW Spain make it the most important district in the world for quarrying roofing slates. Over the past 10 years the introduction of new methods has increased yields from 2 to 13%. The main factors affecting quality are quartz grain size less than 75 micrometres, homogeneity of slaty cleavage and S0-S1 intersection angle, very low metamorphic grade, absence of secondary foliation, beds 10-12 m thick and low content of oxidisable Fe sulphides. The two main controls on fissility are lithology and deformation accompanied by metamorphism. The minimum natural block size should be 0.6 m3 but this volume can be reduced for modern cutting tools such as diamond wire, chain and circular saws. Structural analysis is crucial in exploration and quarrying, as shown by the prospecting methodology applied at Dominio de Truchas in central Spain and the computer analysis of rock mass discontinuities at Casaio quarry

Jun 19, 1905

By S. L. R. Lenharo, H. Kahn, H. Born

Different ore types result from the irregular spatial distribution of the associated alkaline/carbonatite rocks and the zoned alteration profile within which apatite may have undergone reprecipitation. Different flotation responses are caused by their mineralogy, iron oxide impregnation and grain-size characteristics. Samples from seven deposits were crushed, screened and separated before being studied by chemical analysis, optical microscopy, X-ray diffraction, FTIR spectroscopy, cathodoluminescence and scanning electron microscopy. Two main apatite varieties with peculiar crystal morphology were identified: hydroxy-fluorapatite as the primary phase and carbonate-fluorapatite as the reprecipitated phase. The former occurs as prismatic or ovoid grains and the latter as polycrystalline aggregates or crusts on the primary grains; both are associated with iron oxide coatings (primary) or intergrowths (secondary). Microflotation tests showed variations in flotability for particular apatite associations as well as intensity of iron oxide coatings. The differences in flotation behaviour can be related to morphological properties and chemical substitution in the apatite structure

Aug 1, 1996

By R. A. D. Pattrick, R. A. F. Ixer

Paper presented at Mineralisation in the Caledonides, the Mike Gallagher memorial meeting held in Edinburgh, 27-28 June 1996. At Calliachar Burn, 14 steeply dipping quartz-sulphide veins, with and without gold, infill master joints that crosscut gently dipping metasediments and metabasics of the Pitlochry Schist Formation. The wallrock is extremely bleached and enriched in sericite, chlorite and carbonate. Gold grades vary from high with quartz-galena-pyrite to low with galena-chalcopyrite; the gold forms electrum inclusions smaller than 20 micrometres in pyrite or, rarely, arsenopyrite. At Urlar Burn, gold is present in small amounts in 4 quartz-galena-chalcopyrite veins. Although much of the mineralogy is similar to that at Calliachar, there are significant differences in Sb-, Te-, Bi- and Hg-bearing phases. Fluid inclusion data suggest mineralisation occurred over the range 320-140 degrees C, from fluids with significant CO2 and 2-13 wt% equiv. NaCl. Mantle-derived fluids appear to have been generated during the late Caledonian and focused by the Urlar Burn fault

Jun 19, 1905

By T. T. Chen, J. E. Dutrizac, C. Canoo

The calcine consists principally of ZnO and ZnFe2O4, which occur as banded and porous grains, together with lesser amounts of Zn2SiO4, Zn-Fe-Pb silicate, sphalerite, quartz, PbSO4 and Fe2O3. Al is present in solid solution in most of the Fe-bearing phases and also as residual aluminosilicate minerals from the original concentrate. Si occurs mostly as Zn2SiO4, Zn-Fe-Pb silicate and as residual silicate minerals. As is commonly found in the ZnFe2O4, Fe2O3 and Zn-Fe-Pb silicate phases. The major As carrier may be calcium arsenate particles less than 1 micrometre in size which are dispersed throughout the calcine. The neutral leach residue consists mainly of ZnFe2O4 and precipitated masses of iron gel-silica gel. Lesser amounts of ZnO, Zn2SiO4, Zn-Fe-Pb silicate, PbSO4, sphalerite, Pb-K-jarosite and basic zinc sulphate are also present. Al occurs in minor concentrations in most of the Fe-bearing phases and in the Zn-Fe-Pb silicate. The residual aluminosilicates are also an important Al carrier. The major As carrier is the precipitated iron gel-silica gel phase, but some As is also present in the Zn-Fe-Pb silicate, ZnFe2O4 and Fe2O3 phases. Silicon is divided about equally between the iron gel-silica gel, Zn2SiO4, Zn-Fe-Pb silicate and residual silicate minerals. The weak acid leach residue is generally similar to the neutral leach residue except for its reduced content of ZnO and basic zinc sulphate.

Jan 4, 1993