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By G. I. Voiloshnikov, V. E. Dementyev

"One of the most important advances in the world gold metallurgy is the introduction of adsorption technologies for processing of ores and concentrates. «Adsorbent-In-Pulp» process allows to eliminate pulp filtration that is especially important during processing of clay and slime bearing ores. “Adsorbent-In-Leach” process is one of the ways for processing of preg-robbing (carbonaceous) products. High efficiency, increased metals recovery, decrease in capital and operational costs, possibility of easy control and adjustment are the advantages of adsorption processes. Anion-exchange resins and activated carbons are used as adsorbents. This paper presents Irgiredmet experience on gold adsorption technology using both adsorbents (RIP, RIL, CIP, CIL processes). It includes results of long-term studies of different theoretical and practical issues of adsorption processes. Irgiredmet started development of ion exchange technology (RIP, RIL) in 1964. Laboratory and pilot plant tests were conducted to develop process design criteria for 15 RIP plants of the former USSR. During this test work a great number of newly synthesized resins including strong- and medium-base resins was studied, different types of adsorption feed (ores and concentrates) were tested; some theoretical regularities of adsorption process were investigated; the technology of two stage adsorption for silver gold ore, improved flowsheet for gold elution and resin regeneration, designs of technological equipment for adsorption, elution, electrowinning processes including pulsation columns, electrowinning cells etc. were developed. Irgiredmet took part in commissioning of practically all RIP plants in the former USSR. Due to its efforts RIP process became to be the standard technology. Last Irgiredmet RIP projects include the development of adsorption technology using medium-base resin for the three mines owned by GC Petropavlovsk (Amur region, Russia). The complex of the testworks on activated carbon gold adsorption technology including the search of prospective activated carbons; study on gold adsorption mechanism; development, testing and introduction of process flowsheets and the equipment for their realization was conducted. The original gold elution process was developed. The developed CIP technology was firstly introduced at Lebedinsky gold plant (Yakutia). Now carbon adsorption technology is widely used at Russian gold mines as CIP, CIL, CIC processes. The most relevant example of CIP introduction is Svetlinsky gold plant (Ural, Russia) with capacity 8 Mt of ore/ year."

Jan 1, 2018

By Leming Ou, Hongqiang Li, Li Zeng, Qiming Feng, Yiping Lu, Guofan Zhang

"The entrainment of sericite, especially in the presence of hydrophobic microcrystalline graphite, leads to the poor flotation selectivity of microcrystalline graphite ore. In this paper, it was attempted to reduce entrainment of sericite, selective flocculation of microcrystalline graphite using polyethylene oxide (PEO) was studied. For the sake of flocculate microcrystalline graphiteselectively, flocculation tests of microcrystalline graphite and sericite single mineral were conducted.To investigate the effect of selectiveflocculation of graphite on entrainment of sericite in microcrystalline graphite flotation, batch flotation tests of graphite single mineral and artificial mixtures were conducted; theflocculationselectivity of PEO of different molecular weight (M.W.) was alsocompared inartificial mixture flotation. Inthe end, the structure of flocs in different particle size was studied by sieve analysis and microscopic observation. The resultsindicated that PEO of molecular weightone million andtwo million could selectivelyflocculate the microcrystalline graphite and reduce the entrainment of sericite at a lower dosage; further increasingof the dosage of PEO(M.W. ?two million) led to hetero-flocculation between graphite and sericiteandmadethe ash content of concentrate increase again."

Jan 1, 2014

By Masakazu Niinae, Kenji Aoki

"Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble substances. At a higher pH, the soil particles sorb more heavy metals than at a lower pH and the precipitation of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering cleanup more difficult and electrokinetic extraction inefficient.In this study, the effectiveness of introducing a complexing agent to enhance the removal of cadmium from kaolinite in the region of neutral pH by ionic migration is examined. The complexing agent selected was ethylenediaminetetraacetic acid (EDTA). The investigation was carried out in a laboratory-scale column containing kaolinite contaminated with cadmium. As the results of the study, cadmium migrates toward the anode without accumulation of cadmium and is successfully removed at the anode reservoir."

Jan 1, 2003

By Chiharu Tokoro

Acid Mine Drainage (AMD), high acid water containing heavy metals discharged from mines, has been recognized as major cause of mine pollution. In Japan, the government spends billions of yen every year to prevent pollution caused by AMD in about 80 abandoned mines. It is widely recognized that the treatment could continue for long decades or an even century. However, costs and environmental loads are uncertain during the treatment because a predictive model for the quality of AMD, the dosage of neutralizer, and the amount of sludge that is applicable for abandoned mines with limited data has not yet been established. In this study, a two-steps predictive model for solution composition and neutralization chemical requirements of AMD in future was constructed based on the geochemical modeling. Requisite input data of the model was the past historical water quality data from AMD monitoring, such as metal concentration and pH in the solution, instead of the sample rocks as other conventional prediction methods. In the first step, solution composition of AMD in the future was extrapolated from the available historical data using geochemical simulation considering the first order kinetics for the mineral dissolution. In the second step, neutralizer dosage and sludge generation in the future was predicted based on the geochemical simulation supposing the chemical equilibrium and oxidation state for all of elements in the solution. Based on case studies of two abandoned mines in Japan, solution composition, neutralizer dosage and sludge generation were estimated. The results of this study demonstrate the effectiveness of our model for the prediction of AMD quality and chemical requirements of neutralization treatment after mine closing. The model is useful for the estimation of the neutralizer dosage and the sludge volume in abandoned mines with limited data. Keywords: acid mine drainage, predictive model, geochemical modeling, first order kinetics, water monitoring

Sep 1, 2012

By V. A. Masloboev, A. V. Svetlov, D. V. Makarov

"The methods of heap leaching are considered to be the most promising for the low-grade copper-nickel raw materials. The article presents intensification capabilities of the process. Objects of research: the low-grade copper-nickel ores of Moncheplutone deposits (Moroshkovoye Lake, Nyud Terrasa, Nittis-Kumuzh’ya-Travyanaya (NKT), as well as the copper-nickel ore dressing tailings of the “Kola MMC” JSC. The following directions for the intensification of the low-grade copper-nickel raw materials heap leaching have been considered: preliminary electric pulse destruction (EPD) of ore; ore crushing and further sulfuric acid agglomeration. The impact of sulfuric acid concentration (1-3%) on the extraction of non-ferrous metals kinetics from the copper-nickel ore dressing tailings under various conditions of the percolation leaching has been studied. INTRODUCTION The low-grade grade sulfide ores at the abandoned and producing deposits, overburden rocks, mill tailings and non-ferrous slag are thought to be one of the large-scale sources for non-ferrous metals, on the one hand. On the other hand, they are known to be the subjects of emergency environmental danger. For this reason, the use of mine dumps and tailings, as well as the remained ores left in the ground as raw products, and at the same time decreasing the load on environment, are considered to be the pressing ecological and economic issue (Chanturia et al., 2012). Methods of heap hydrometallurgical and bacterial leaching are sure to be potentially productive for processing such low-grade and technogenic raw materials (Petersen, 2016). The early studies of hydrometallurgical method possibility to process copper-nickel ores of the Murmansk region deposits were launched in the seventies of the previous century (Golovko et al., 1978). For referencing purposes, the main types of impregnated ores from the deposits Zhdanovskoye, Kaula, Sopchinsky Plast and Lovnoozerskoye were selected. The metal content varied, as %: 0.46-1.49 of nickel, 0.01-0.62 of copper. In the first experiments, the solution containing 150g/l of H2SO4 and 135g/l of NaCl, was used in the capacity of leaching reagent. The possibility of underground metals leaching from the ores of the Lovnoozerskoye deposit was justified due to the performed laboratory and further large-sized tests."

Jan 1, 2018

By Paolo Bevilacqua, Paolo Antonini, Lorenzo De Lorenzi

"Ceramic production requires large quantities of K-feldspar, which is commonly sourced from granites, alkali-granites, and feldspathic sands. These rocks contain other minerals, such as quartz and plagioclase, which are undesirable for ceramic production. Due to the coarse mineral grains that constitute these rocks, a reasonable liberation is achieved at a relatively coarse particle size.The feasibility of feldspar-quartz separation using a dynamic dense medium separation system has been investigated as an alternative to flotation techniques. The use of a two stages cylindrical vessel (Tri-Flo) was preferred to a conical vessel, due to the improved separation efficiency.In a full-scale processing plant, a dense medium separation process can be used as a K-feldspar preconcentration step. This reduces the amount of material to be treated in the more expensive processes, such as finer comminution, flotation or magnetic separation.A comparison between commercial raw materials for the ceramic industry and the “rich in feldspar” products of the Tri-Flo process is reported, and the validity of the process is demonstrated."

Jan 1, 2003

By M. Naymanbayev

The characteristics of the mineral composition of ores and valuable set of components: the technology of processing depending on the type of mineralization, the nature of the impregnation of ore minerals and their composition have been considered. There have been given technological schemes for processing concrete objects. The analysis of fitness fields for industrial development (degree of scrutiny, the effectiveness of developed enrichment and hydrometallurgy technology) has been provided.

Sep 1, 2012

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um, Joobeom Seo

In the present work, we report a novel microstructure of synthesized scalenohedral PCC (precipitated calcium carbonate) without any additives by a simple and ecofriendly carbonation process carried out in a liquid-gas system on the crystal growth of the scalenohedral calcite phase. Especially, the process parameters of Ca(OH)2 concentration and CO2 flow rates were investigated to enhance the sensitivity of the process. The highest average length of the scalenohedral calcite was obtained at pH 6.0, temperature 450C, Ca(OH)2 concentration 0.2M, CO2 flow rate 80mL/min, and total volume 1L. The utilization of flue gas-derived CO2 from coal fired power plants could be a form of carbon capture and storage using carbonation reaction with scalenohedral PCC. Finally, the synthesized scalenohedral PCC was used as a filer for ONP recycling. We demonstrated all these experiemnts at semi pilot plant scale.

Jan 1, 2014

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:- flotation tailings of crystalline graphite minerals- outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers.The most important variables affecting the leaching process, such as grain size, mineralogical species, reagent consumption, and so on, were previously studied. (Weiss, L.1985)On the basis of the present study results, the possible definition of an economically viable mineralization will be analyzed to define an auriferous district."

Jan 1, 2003

By Tamara Matveyeva, Tatiana Ivanova, Nadezhda Gromova

"The paper presents the results of study of the sorption and flotation properties of the reagents of plant origin - tannin and natural extracts of the oak bark and stems of plants, with a view to their application as a low-cost environmentally friendly modifiers of iron sulfide flotation for the recovery of minerals containing precious metals. The technique of preparation of plant extracts with a fixed content of extractable tannins has been developed.The mechanism of flotation reaction of tannin extracts has been identified as based on their adsorption on the surface of pyrrhotite and arsenopyrite to form strong complexes with iron (III) at concentrations below micelle concentration. It has been found that adsorption of plant extracts occurs without displacement of primarily adsorbed xanthate, and preliminary adsorption of xanthate did not preclude fixation of tannin on the mineral surface.It has been shown that plant extracts having hydrophilizing properties at low concentrations could be applied as selective depressants for pyrite, pyrrhotite and arsenopyrite in a weakly acidic, neutral or weakly alkaline medium. The use of plant modifiers could help to increase the quality of gold- and platinumcontaining concentrates and reduce the ecological impact on the environment."

Jan 1, 2014

By Arkady Senchenko, Yuri G. Seredkin, Alexander Aksenov

"This paper describes the development of efficient technology for the treatment of complex ores containing gold and copper as major valuable components, where silver is present as well. Copper is mostly represented by oxidized minerals in these ores; however, copper sulfides are also present. Gold is present in its free form and in associations with oxidized and sulfide minerals; silver usually accompanies gold. Complex composition of the ore requires complex solutions for their treatment. The results of searching for the techniques to recover valuable components are described in this paper. Gravity methods allow for free gold recovery, flotation methods allow one to recover major part of copper and precious metals in associations; and in the result of leaching process additional amount of copper, gold and silver is reported to solution. Combining all these methods help achieving high levels of valuable components recovery. When implementing a combined technological flowsheet about 80 % of copper goes to concentrates from gravity and flotation of sulfide and oxidized copper minerals; and sulfuric acid leaching allows increasing total copper recovery up to 90 % and higher. Major part of precious metals (up to 90 % of gold and 80 % of silver) is recovered to these concentrates, and after hydrometallurgical treatment it is possible to increase gold recovery up to 96 %, silver recovery - up to 90 %. The suggested technology helps solving the problem of precious metals recovery from complex gold-copper ores, and allows treatment of the ore with different proportion of sulfide and oxidized minerals, and at different valuable components grade."

Jan 1, 2014

By S. J. Neethling

"This paper examines the impact of several key variables on the performance of flotation cells. The study makes use of a simulator for the froth phase of the flotation vessel, as the main purpose of this study is to separate the impact of different variables from one another. In experiments it is very difficult to separate the effect of variables from one another as a change in a singe input parameter, such as air rate, invariably also affects many of the other key variables, such as bubble size and bubble bursting rates.In order to achieve this a base case simulation that is typical of many of the rougher cells found in sulphide flotation circuits was carried out. Four key variables, air rate, incoming bubble size, surface bubble size and the fraction of the bubbles flowing out of the cell unburst, were varied in order to obtain the system.s response.The most significant results were obtained when the bubble size was varied. An increase in the incoming bubble size has the effect of reducing the pulp zone recovery, but increases the froth zone recovery. If it were possible to vary the incoming bubble size without influencing the overflowing bubble size, the impact of the change would be unclear because of these two competing effects. The effect of a change in the overflowing bubble size has an opposite effect on the froth recovery, with larger bubbles resulting in lower froth recoveries.A final interesting result is that all the effects examined affect the process to a similar degree, which implies that none of these variables can be disregarded, either in industry or in further research."

Jan 1, 2003

By G. P. Karmakar, K. K. Chandan

"The drilling mud is an essential part of the drilling process, which plays a major role in keeping safe and efficient oil and gas well drilling. In the oil industry, bentonite clay dissolved in water produces the simplest type of drilling muds. Bentonite clay contains montmorillonite particles. These particles are dispersed uniformly in water and such dispersions are used in various industrial products like paints, ceramics, pesticides and drilling muds. The bentonite clay easily dissolves in water and increases the viscosity of the water, which is one of the most important properties of a drilling mud. Bentonite has the highest swelling capacity, which is responsible for building up of the viscosity of the clay-water system. The flocculation behavior of bentonite is one of the major concerns for the performance of the water-based drilling mud in the oil and gas well drilling process. The behavior of drilling mud greatly depends upon the quality and quantity of bentonite clay, as well as the additives that are used in their formulations. In this work, a comprehensive study has been carried out to find out the effect of added polyacrylamide (PAM) polymer, surfactant, pH and salt concentrations on the dispersion/ flocculation characteristics of bentonite clay-water system. It has been observed that the increase in PAM dosage reduces the residual turbidity and improves the settling rate of the bentonite particles. The flocculation rate has also been found to be better under higher pH conditions. The combined effect of salt concentration and PAM dosage improved the overall flocculation efficiency of the system.INTRODUCTIONIn the oil industry, bentonite clay dissolved in water produces simplest type of drilling muds. Bentonite clay containes montmorillonite particles. These particles are dispersed uniformly in water. Such dispersions are used in various industrial products like paints, ceramics, pesticides and drilling muds (Akther et al., 2007). The bentonite clay easily hydrates in water and increases the viscosity of the mud system (Razi et al., 2013; Meng et al., 2012). Bentonite clay in the drilling mud increases the viscosity which is one of the most important prop erties of a drilling mud. Bentonite has the highest swelling capacity, which is responsible for the building up viscosity of the clay-water system (Sonmez et al., 2013). The drilling mud is an essential part of the drilling process, which plays a major role in keeping a safe and efficient oil or gas well drilling (ASME, S. S. C., 2005). The flocculation behavior of bentonite is one of the major concerns for the performance of the water-based drilling mud in the oil or gas well drilling process. This behavior of drilling muds greatly depend upon the quality and quantity of bentonite clay, as well as the additives that are used in their formulations (Yu and Amanullah, 2005; Akther et al., 2007). Bentonite particles form aggregate under certain conditions including high temperature, and high concentration (Luckham and Rossi, 1999). If the quality of bentonite is not sufficient to accomplish intended viscosity of the muds, it is essential to add certain additives to increase the viscosity and prevent aggregation of the system (Razi et al., 2013). The anionic polymer bearing sample can build up inter-particle bonds between the polymer and clay particles. The addition of various additives like, polymers control the dispersion and enhance the viscosity of the mud by controlling the flocculation of montmorillonite particles in bentonite dispersion (Heller and Keren, 2002; Mahto and Sharma, 2004)."

Jan 1, 2018

By Cristian Melipichun, Leopoldo Gutierrez

The effect of the presence of fine particles of kaolinite and montmorillonite on the induction time for attachment of bubbles to particles of a copper concentrate rich in chalcopyrite was evaluated in this study. The results obtained from induction time measurements were correlated with data of concentrate recovery achieved from micro-flotation experiments. The effect of the presence of fine clays on the stability of air-water foams was also studied through measurements of the foam volume generated in a glass column under different conditions of air flowrate and MIBC concentrations. The experimental results showed that induction time values increased under the presence of fine clays. These data agreed with results obtained from micro-flotation experiments that showed that copper concentrate recovery decreased when clay particles were added. Although a complete explanation for these results is not available, the fact that experimental observations indicated that fine clay particles tend to adsorb on gas bubbles, suggests that the interactions between fine phyllosilicate particles and air bubbles have to be taken into account when studying the effect of clays on froth flotation. Foamability tests showed that the presence of fine clay particles increased the foam volumes only at high additions of clays and low dosages of MIBC. The results obtained at higher dosages of MIBC showed that the foam volumes decreased with the addition of clays under all the experimental conditions tested.

Jan 1, 2014

By J. Bouchard, Ali Vazirizadeh, R. del Villar

"The amount of water reporting to the concentrate correlates well with the solid entrainment. It is well known that the frother and collector dosage as well as the froth depth and gas rate influence the amount of water reporting to the concentrate. This is also true for gas dispersion properties such as gas holdup and bubble surface area flux. On the other hand, a positive bias rate, required to reduce hydraulic entrainment, also affects water recovery and thus the particle recovered by entrainment (depending on the their size). Up until now, the effect of the gas rate on the water recovery has been studied, but no comprehensive investigation on the gas holdup, bubble size and bubble surface area flux has yet been reported. This research precisely aims at addressing this issue. The experimental work was carried out under a constant gas flow rate to eliminate the gas volume effect, while other gas dispersion properties have been varied by modifying the frother concentration and the shearing water introduced to the frit-and-sleeve sparger. A constant froth depth and no wash water were used, in order to be able to evaluate the exclusive correlation between the water recovery and the bubble surface area flux and/or the bubble size. It is worth mentioning, that the particle size of the hydrophobic particles did not show a significant effect on the amount of water going to the concentrate. Not surprisingly, experimental results demonstrate that water recovery increases with the bubble surface area flux and with the gas hold-up."

Jan 1, 2014

By Thomas Mütze, Anja Hirte, Ursx Peuker, Thomas Kuhn

"The comminution behavior of two ferromanganese nodules samples of the equatorial northeast Pacific has been examined as a basis for the separation of two kinds of metal-rich layers. Those layers were finely grown together during nodule formation and are one reason that the exploration of deep-sea minerals calls for the development of new mineral processing concepts. Therefore fundamental analyses of the fracture behavior have been made under compressive and impact stress. Further experiments took focus on the crushing behavior in a jaw crusher and a small scale impact crusher as well as the milling behavior in a dry vibrating mill, a wet planetary ball mill, and a wet agitated ball mill. The comminuted products were characterized by PSD, particle shape, particle density, and porosity. The experiments show a low stress resistance of the ferromanganese nodules. Compared to compressive stress, impact stress turned out to be the more effective for crushing. Both samples showed no significant difference in the comminution behaviour which makes differing mechanical treatments unnecessary. In both cases particle sizes below 1 µm were achieved by wet grinding. This particle size is necessary to separate the two kinds of metal-rich layers which is part of continuative studies."

Jan 1, 2014

By Rainer M. Lotzien, Michael J. G. Battersby, Jan Kleefeld, Julian V. Brown, Rainer M. Imhof

"The standard method of separation using flotation is compromised in terms of kinetics and efficiency, because of the generally slow separating differentials of fine bubbles and fine particle suspensions. A new flotation system has been developed that addresses these issues and imparts other benefits. The new technology is based on established pneumatic flotation designs called Imhoflot which use intensive in-line pre-aeration to aerate the flotation pulp prior to its introduction to the separating cell. Consequently the cell is designed only for the separation of the phases and not for bubble-particle contact. In the new system this separation is speeded up dramatically by the introduction of centrifugal motivation in the separating vessel, without the use of internal moving parts. The design focuses on providing increased differential forces on buoyant mineralised bubbles and hydrophilic fines. The observed result of these differential forces is the improvement of concentrate qualities by the reduction of the amount of misplaced material found in the froth. The commercial benefit to industry is much reduced residence time, less than 30 seconds, which offers considerable cost savings in equipment and infrastructure.Prototypes of 0.65m, 1.7m and 2.2m cell diameter size have been constructed for hydrodynamic and industrial scale tests to assess the previously established computational methods for scale up of the process. The 1.7m cell has been installed and operated for cleaning of potash concentrates in Germany, at throughputs of 150 m3/hr, with extremely encouraging results. A 2.2m cell has been installed and operated in plant trials for superfine coal in South Africa. Results are presented that illustrate the effects of differential separations by comparison with conventional pneumatic and mechanical flotation techniques. Predictions of performance are provided in the contexts of the applications tested."

Jan 1, 2003

By Shuji Owada, Yang Geng, Natsuko Kuroki

Micro-bubble flotation is considered to be an ideal method for the separation of fine or ultra-fine particles, which are difficult to be separated with conventional flotation and other solid separation technologies. Micro-bubble flotation can increase the probability of bubble-particle collision more than conventional milli-bubble flotation. However, there are also some problems. For example, it is known that the rising velocity of micro-bubble is quite low; therefore, the flotation rate reduces. And also, the bubble-particle adhesion probability becomes lower than that of milli-bubble flotation, which is proved in our prior research. In this paper, we applied ultrasonic irradiation to the micro-bubble flotation system in order to solve the above problems and focused on the bubble-bubble and bubble-particle interactions. For clarifying the behavior of bubble-bubble interaction, bubbles behavior was recorded by high-speed camera under irradiation of various ultrasonic frequencies. As a result, in the case of bubble-bubble interaction, it is proved that bubbles are highly coalesced by ultrasonic irradiation especially in the lower frequency and it can enhance more precise separation. In the case of bubble-particle behavior, it is found that the floatability become higher with the ultrasonic irradiation of higher frequency, and it is indicated that ultrasonic irradiation might improve the bubble-particle adhesion probability. Additionally, it is also found that the apparent CMC of the micro-bubble flotation under the ultrasonic field become much lower with higher frequency than with lower frequency, and it is suggested that the dramatic improvement of hydrophobization is achieved.

Jan 1, 2014

By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014

By M. Minagawa, G. Granata, C. Tokoro, T. Kato

"In this work, we studied the mechanochemical activation of chalcopyrite by vertically stirred ball milling (VSBM) to enhance the dissolution of copper. By using x-ray diffraction (XRD) and laser diffraction particle size analysis, we investigated the effect of milling and milling conditions on particle size and phase composition of the chalcopyrite concentrate. To elucidate the efficiency of VSBM towards the mechanochemical activation of chalcopyrite, we also conducted leaching experiments in sulfuric acid-ferric sulfate media. Under all investigated milling conditions, the VSBM determined a dramatic decrease of particle size from over 100 µm of P80% up to about 13 µm. Furthermore, the XRD of the ground chalcopyrite specimens highlighted a partial oxidation of the mineral. In leaching, upon grinding by VSBM, the increase of copper extraction ranged from a minimum of +10% to a maximum of +40%, depending on the grinding conditions. In order to elucidate whether the dissolution enhancement was a consequence of the decreased particle size or of an induced mechanochemical reaction, we performed leaching experiments on activated and non-activated chalcopyrite sample having the same particle size. In addition, we determined the activation energy of leaching before and after vertically stirred ball milling. The leaching results on samples with the same particle size highlighted a greater copper extraction and higher dissolution rates upon mechanochemical activation. Whether performing grinding by VSBM or not, the leaching kinetics was found to be controlled by the chemical reaction on the surface of the chalcopyrite particle. By grinding the chalcopyrite concentrate by VSBM, the activation energy of leaching slightly decreased from 66 to 58 kJ/mol. INTRODUCTION Due to the increasing demand of copper, low grade ores and refractory minerals like chalcopyrite are expected to become the main copper source in the next years (Klauber, 2008). As a low-grade sulfide, chalcopyrite shall be processed hydrometallurgically. However, due to the formation of a protective layer of elemental sulfur during the oxidizing leaching, the dissolution of copper is slow and/or incomplete (De Bernardi and Carlesi, 2013). Therefore, the development of new technologies to enhance the extraction of copper from chalcopyrite is highly required."

Jan 1, 2018