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By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

SOME months ago a Committee on Deep-level Mining was appointed [by the Government of the Union of South Africa] to consider the possibility of gold mining being carried on at a depth below 8,500 feet. The Committee consisted of Sir Robert Kotze (Chairman) , Mr. H. S. H. Donald (Government Mining Engineer), and Mr. H. R. Hill. The Committee has now made a report which was tabled in the House of Assembly on March 1st. The Committee reported that the tonnage of ore locked up in the deep level areas of the Central Witwatersrand is enormous, and in the 30 miles between Roodepoort and the East Rand Proprietory Mines has a value of about £200,000,000. The Committee says that, with good ventilation, the present system of wet mining, possibly with some modification and with the aid of refrigeration, may be carried to 10,000 feet, but that greater depths will require the adoption of dry mining. "A vigorous campaign of practical experiment into the possibility of dry mining should be initiated, and the Committee recommends to the Government the appointment of a committee of experts, consisting of representatives of the mining industry, the Mines Department, and the medical profession, with the Government Mining Engineer as chairman. The Committee suggests the provision of £30,000 for the first year for the investigations and experiments contemplated, which could best be carried out by an organization which might be styled 'The Rand Mining Research Institute' and constituted somewhat on the Jines of the South African Institute for Medical Research" . The Committee suggests that this committee of experts should arrange for experiments to be made with dry mining in one of the deepest mines, and investigate ventilation, refrigeration, support of workings, and the physiological problems connected with mining. "We emphasize the necessity of treating this whole question as one of importance and urgency. The investigations should be prosecuted with the utmost vigour and should not be delayed at any time for want of funds or for any other reason. If they are not done thoroughly and quickly, the whole scheme might just as well be left severely alone.

Jan 1, 1945

By J. B. Evans

"THE OPPORTUNITY to participate in a CIM seminarconcerning the direction of mining engineer trainingis perhaps fortuitous as it comes at a time when theengineering schools which have invited inspection byCanadian Accreditation Board of the Canadian Councilof Professional Engineers are examining theirrespective curricula.Currently there exists considerable soul-searching in various engineering schools across Canada where questions such as the following are being posed.- Have we achieved the correct balance between subjects related to technical methodology and subjects devoted to conceptual planning and design?- Should we include ""applied humanities"" in our program? (Whatever ""applied humanities"" might mean!)- Should courses covering pollution control, ecology, economics, technical writing, professional conduct and ethics be offered as compulsory subjects, as electives, or not at all?- Is it a better scheme to have students complete an Arts or Science degree before entering engineering?- Do we place too much emphasis on pure mathematics and sciences with the result that insufficient time is available for instruction in the engineering applications of these subjects?- Should English expression and/ or literature be included in the engineering programs and, if so, should these subjects be presented by the English department or by English lecturers captive to the engineering school? - Is the present program directed primarily at research activities rather than preparing engineers for their future roles in industry? - Should we teach our own versions of mathematics and physics? - Do we have sufficient engineers on the faculty strength or are we overloaded with Ph.D.'s from the pure sciences? - How flexible should the program be, what should the compulsory vs elective course content be, and what freedom of choice, if any, should be given with respect to elective courses? - To what extent should students contribute to faculty decisions?- How far should we pursue computer science subjects and do we need to make our students proficient in computer programming? - How far should operations research and mathematical models be carried in the undergraduate program when the students have limited experience in the real engineering world? - Realizing that an engineer never completes his education, should the undergraduate program cover ""bare bones"" engineering and should instruction in particular disciplines be left to graduate schools and / or industry?"

Jan 1, 1972

By C. Pawlik, R. T. Jones

Cobalt occurs together with copper in the southern African copper belt, and a large portion of this cobalt ends up in copper smelting slags, mostly dissolved in oxide form. It is possible to achieve high recoveries of cobalt by reductive smelting of the copper slags, using some form of carbon as a reducing agent in an electric furnace. For example, a 40 MW DC arc furnace was operated at Chambishi Metals in Zambia from 2001 to 2008, and demonstrated cobalt recoveries of around 80% from slag to an iron-rich alloy containing copper and cobalt. The alloy was atomized prior to leaching. With the recent increase in demand for cobalt (and the resulting high metal prices), there has been increasing interest in this process route. There is also an alternative hydrometallurgical process for recovering the valuable metals from the slag. The choice between these process options requires a trade-off between capital and operating cost and environmental acceptability. This paper examines the potential for cobalt recovery from slags, and outlines various process options. INTRODUCTION Cobalt has had a number of important uses in society since antiquity, and its principal use has changed dramatically over time. Since at least 2250 BC, cobalt-based pigments (cobalt blue) have been widely used to colour manufactured goods such as glass and pottery. Later, cobalt became known for its magnetic and wear-resistant properties and high-strength alloys, and most of the cobalt produced was consumed in the production of cobalt-based superalloys. The greatest recent growth in cobalt demand is due to it being essential to the rechargeable lithium-ion batteries used in consumer electronic devices and increasingly to drive electric vehicles. Cobalt is usually produced as a by-product of copper or nickel. The copper belt in the Democratic Republic of the Congo (DRC) and Zambia supplies most of the world's cobalt production. In 2018, the DRC was expected to produce 90 000 tons of the world total of 140 000 tons of cobalt (Shedd, 2019). This paper focuses on the southern African copper industry, and specifically the cobalt that is able to be produced as a co-product from this. A BRIEF HISTORY OF SOUTHERN AFRICAN COPPER SMELTING Copper deposits in South Africa have been documented since at least 1685, when the Cape governor, Simon van der Stel, ‘discovered’ the 'Copper Mountain' at Springbok. South Africa's first public commercial mining company (imaginatively called the 'South African Mining Company') was established in Cape Town in 1846, to exploit the rich copper resources that were believed to exist in Namaqualand.

Jan 1, 2019

By Christopher W. N. Anderson

Induced hyperaccumulation of gold by plants was first reported in 1998 by researchers from Massey University in New Zealand who proposed the idea of mining gold using plants (phytomining). Since that time research has been conducted to understand the conditions under which plants can be made to take up economic amounts of the metal. One key focus has been on the geochemistry of gold-rich soils, leading to a diagnostic test that can predict how suitable a particular soil might be to gold phytomining. Field trials have been conducted at several locations around the world in collaboration with industry partners. A Decision Support System has been developed to assist in the design and management of phytomining operations, and economic modeling has been carried out to set targets levels for phytomining technology. Novel studies are now examining the form of gold in plants. Research suggests that plants may store gold as discrete metallic nanoparticles in leaf and stem tissues, an observation that may lead to new ways to recover the metal from harvested biomass.

Oct 1, 2003

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By M. Cimenti

Fuel cells have tremendous potential as power sources but much fundamental research is still required. One key component of the research is the experimental set-up used. In particular, the placement of the reference electrode is extremely significant in measuring the half-cell overpotential of solid oxide fuel cells, since differences in area, misalignments, and also differences in the kinetics of the working and counter electrodes can cause both scaling errors and frequency distortions of the measured impedance. The impedance of thin solid electrolyte cells of different electrode geometries has been calculated using the finite element method and the results compared to experimental values obtained for the oxygen reduction reaction on platinum.

Jan 1, 2005

By J. C. Ingles

"A survey of possible methods for controlling cyanide concentration indicated that the simplest method would involve the use of a potentiometric technique. Such a method was suggested by a paper from the laboratory of Mines Safety Appliances, which described a method for determining hydrogen cyanide in air. In this application, the cyanide was absorbed in caustic and a silver electrode immersed in the caustic solution provided a measure of the cyanide concentration. However, our attempts to use the silver electrode in this simple manner to measure the cyanide concentration of solutions were not very successful. A study of the mechanism by which a silver electrode responds to cyanide concentration made it evident why this simple procedure is not satisfactory.Basically, the silver electrode provides an indication of the free silver ion concentration of a solution, and generally speaking, ignores the other ions' present. It can be used to measure an anion if this anion complexes silver. This technique has been used in complexing studies to determine the activities of such anions as acetate, citrate, oxalate and chloride. To do this, the electrode has to be placed in a solution which initially contains a known concentration of free silver ions. Addition of the complexing anion causes a drop in the free silver ion concentration and hence a change in the potential of the silver electrode. The change in potential can be expressed in terms of the concentration of the complexing anion, and used to indicate its concentration in the solution being analysed. The determination of chloride-ion by a silver-silver chloride electrode is an example of an application of this technique. The solubility of the silver chloride with which the electrode is coated provides the initial free silver-ion concentration. Depression of this free silver-ion concentration by the presence of the excess chloride ion of the sample solution results in a change in the potential of the electrode which is proportional to the chloride-ion concentration."

Jan 1, 1965

By Peter Lighthall

What is an engineering firm?s role? ? The ideal situation is a life of mine service alliance with the owner ? Engineering firms are long term custodians of information ? Maintain consistency with established closure objectives, adjust closure plans to meet changing situations and technologies ? Develop range of solutions and present owners with risk profile The mine closure planning process ?new mines ? For metal mining, geochemistry is the issue ? The planning process: ?Sampling ?Waste characterization ?ARD prediction ?ARD control strategies ?Life of mine waste management planning ?Assessment of residual impacts ?Development of strategies for dealing with residual impacts ?Estimate closure costs ?One time decommissioning and reclamation costs ?Ongoing treatment/maintenance costs

May 1, 2006

By Jeff Stufsky

Debt Financing ?Broad Market Overview ? Recovering due to factors including: ? Increased trust in the system ? Enhanced capitalization of financial institutions ? The need to deploy capital for profit ? Competition: ? Investment-grade bond volumes increasing dramatically, and starting to pressure banks to compete with new capital ? Term Loan B financing from insurance companies and related institutions is returning, also pressuring banks to lend ? Local country financial institution capacity in Latin America has materially increased ? Results: ? Loan capacity increasing generally across instruments, regions, and sectors ? Financial institutions/banks starting again to seek yield as pricing competition heats up ? Tenors increasing with pricing coming down more slowly Underwriting is back in play

May 1, 2010

By Weimin Fu

Chondrite-normalized rare earth elements (REEs) profiles and high field strength elements (HFSEs) in rocks and minerals represent important tracers of geological processes. Of these the birdwing-shaped profile with negatively-sloped light REE ((La/Sm)N >1), positively-sloped heavy REE ((Tb/Yb)N <1), and strong negative Eu anomalies is commonly associated with large-scale hydrothermal systems or granitic intrusions. In a different way, severe deviation of Nb/Ta, Hf/Sm ratios from those of chondrite may also indicate hydrothermal signatures in the rocks involved as these ratios are generally stable and chondritic in normal magmatism as a result of their nearly identical ionic radii and charge. In this study, we present a typical setting where birdwing-shaped REE profiles together with Nb/Ta, Hf/Sm ratios unusually higher than those of chondrite, are systematically developed in a series of garnetite, quartzofeldspathic gneiss, Fe- or Mg-rich aluminous gneiss, and sulfides and magnetite. These units and associated Cu-Au mineralization form a VHMS-style hydrothermal system in the granulite-facies 1.4 Ga -1.35 Ga volcano-plutonic, arc-related Bondy gneiss complex (BGC), western Grenville Province, Canada. Outside the recognized hydrothermal system of the BGC, such REE profiles are not observed. Instead the surrounding felsic and mafic gneisses display primary trace element characteristics of island-arc magmas, suggesting that granulitefacies metamorphism did not modify significantly the trace element signatures of the protoliths. Although magmatic fractionation of accessory minerals can produce birdwing-shaped profiles, it cannot explain the extreme fractionation of isovalent trace elements (Nb-Ta) and the high Zr content of the hydrothermal rocks. Neither is it compatible with the lack of significant Nd depletion that would normally incur during this process. Following our study, we demonstrate that F-rich fluid and mineral phases enriched in LREEs and HREEs respectively must have been involved in the main hydrothermal alteration and REE fractionation process in the BGC. Preferential removal of REEs from the interstitial glass of the volcanic protoliths together with dissolution of plagioclase and subsequent external influx of HREEs and HFSEs can produce birdwing-shaped REE profiles. In turn, such profiles and/or unusual Nb/Ta, Hf/Sm ratios can be used as a sensitive marker of hydrothermally altered rocks in targeting mineral exploration.

May 1, 2003

By Pieter van Nierop

Outline ? What is gasification? ? Gasification Technologies ? Gasification ?The early years ? Gasification ? The last decade ? The Alberta Situation ? The Importance of Gasification in Alberta ? Polygeneration ? Development ? Conclusion

May 1, 2004

By Don Ritz

Smart leaders focus on safety even in tough times. Businesses that retreat into survival mode and ignore safety do so at their peril, risking loss of employee and stakeholder confidence and exposing themselves to financial and reputational loss they can ill afford. It?s a moment of truth when employees and stakeholders learn whether safety is truly your priority or just a convenient cliché for good times. Visionary leaders who build safety culture even in a downturn maintain people?s trust, prevent loss, and position the organization for enhanced success as times improve. Safety is the right business focus in good times and bad.

May 1, 2009

By J. Paraszczak

Application of teleoperated and automated (or ?autonomous?) mobile equipment in underground metal mines represents a promising avenue for overcoming some of the challenges facing the industry. This paper addresses the overall effectiveness of autonomous loading and haulage equipment compared with conventional human-operated machines. Factors affecting availability, utilization, and production rate are explored, and an emphasis is placed on some problems and risks not present in conventional human-operated systems, as well as on the character and criticality of autonomous equipment. The need for a more in-depth analysis of factors affecting overall autonomous equipment effectiveness is stressed; these factors should be taken into consideration at the stage of feasibility studies. The paper concludes with recommendations and directions for future research.

Aug 1, 2010

By Y. Konishi

This paper reviews the mechanism and kinetics of bioleaching of chalcopyrite by the thermophilic archae Acidianus brierleyi in batch and continuous-flow reactors. Rate data for the batch bioleaching of chalcopyrite concentrate were collected to clarify mechanism of the chalcopyrite bioleaching with A. brierleyi. The chalcopyrite leaching was markedly accelerated in the presence of A. brierleyi, and greater than 90% copper leaching was achieved within 10 days. Chalcopyrite leaching took place predominantly as a result of direct attack by adsorbed bacteria on the sulfide surface, the chemical leaching with ferric iron being insignificant. Batch rate data collected under a variety of operating variables were analyzed with our batch bioleaching model, in order to estimate microbial kinetic and stoichiometric parameters for the microbial growth on chalcopyrite. The batch model and the estimated parameter values were used to find optimum operating conditions. Moreover, the batch model was extended to describe the bioleaching in continuous-flow stirred tank reactors. Simulations based on the continuous reactor model and the estimated parameter values were used to predict the leaching fraction as a function of the number of reactors connected in series.

Jan 1, 2007

By J. A. Hurd

Towards the goal of a better understanding of the structure-proton conductivity relationship in PEM materials, this project concerns the design of ordered polymeric solids containing well-defined sulfonate aggregates. The approach employed involves the templation of sulfonated monomers using core principles of crystal engineering. In addition to sulfonate groups, the monomeric units contain crosslinkable functionalities to enable formation of a covalently linked network. The templation strongly directs the construction of well-defined sulfonate clusters and aggregates. Structural, sorption and conductivity data for the networks will be shown.

Jan 1, 2005

By O. Moselhi

The purpose of this research is to evaluate the impact of Building Information Modeling (BIM) on Just-In-Time (JIT) material delivery, with a focus on how the use of BIM can help improve efficient implementation of JIT and reduce the cost of material management. Previous research and a number of case studies have addressed the positive impact of BIM on construction at large but none focused on JIT in construction. This paper presents a methodology for selecting reliable material vendors. It also utilises the integration of BIM and scheduling software to generate quantities of material and its required delivery time to improve the flow process and improve its reliability to minimise related delays and productivity losses arising from idle and non-productive time of equipment and labour on jobsites. 4D visualization is utilized to support coordination and timing of JIT material deliveries in an effort to minimize congestion on job sites. Case studies on JIT material deliveries are presented and the impact of BIM implementation on reducing the cost of material management is evaluated. The joint effect of BIM and JIT on quality control, elimination of waste, reduction of inventory buffers, and on relationships with material vendors are evaluated by analysing and comparing data from case studies. The paper also presents a methodology based on multi-attribute decision criteria for modelling the selection criteria for material vendors. The model can assist in ranking vendors not only based on cost and quality but also on their reliability in delivering material on time.

Aug 1, 2013

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

By V. I. Birss

Planar solid oxide fuel cells (SOFCs) offer great promise as stationary power generation devices, primarily due to their flexibility in terms of fuels, high energy conversion efficiency (when both electricity and heat are captured), and their relatively low fabrication costs. However, the anode performance can be compromised by such factors as exposure to certain sulfur-containing fuels and the deposition of coke when using hydrocarbon fuels. In terms of the cathode, its performance is limited primarily by the slow kinetics of the oxygen reduction reaction, while its lifetime can be negatively affected by factors related to the corrosion of currently used stainless steel interconnect materials. This talk will present an overview of these challenges and some possible solutions to these problems. The presentation will also focus on how electrochemical methods can be used to evaluate and improve the performance of SOFC anodes, cathodes, and interconnect materials. In addition, recent promising research efforts directed towards performance enhancement of SOFCs through the use of nanoscale electrocatalysts will be discussed.

Jan 1, 2005

By Richard Morland

The Ekati Safety Guarantee is a conversation that has been taking place at Ekati for the last two years. It is a challenging, confronting, inspiring conversation which encourages people to see and pursue the possibility of guaranteeing that nobody who works at Ekati will be seriously injured or killed at work. The conversation takes us out of the normal, incremental approach to safety improvement; it takes us out of the world of striving, of seeking, of trying, and allows us to stand in, and be a stand for the future possibility of Zero Harm. It requires an unreasonable stand for, and commitment to, our own safety and the safety of our colleagues. A Powerful Conversation The safety guarantee began with conversations between executive team members and has been propagated regularly through the line through management meetings, pre-shift meetings, during workplace inspections, job safety observations, job and project planning, orientation and induction sessions, and when opportunities present themselves. This is a conversation that continues outside of Ekati with family, with government, with community members. It is a stand for safety as a value. The conversation about the safety guarantee is now pervasive at Ekati and forms part of a framework of initiatives that have led to sustained improvement in safety performance. During the last two years, the recordable injury frequency at Ekati has dropped to its lowest level in Ekati?s history. At the same time, job safety observations have increased from 500 per month to 4000 per month, whilst the overall number of people at Ekati has reduced by 30%. It has led to new ways of thinking about the conduct of operations. It influenced the 2008 upgrade of the Ekati process plant, resulting in the development and implementation of a crane lift protocol that eliminated injuries during over 100 lifts in two weeks, in an area of difficult geometry and with multiple entrances. It created space to successfully conduct a challenging commissioning period for the process plant crusher, during which time the machine was disassembled and reassembled several times, without incident or injury. No production pressure was permitted to interfere with this work, in line with our stated aim that we wanted everyone involved to guarantee that they would not be seriously injured or killed?our people had the space to do the work at a pace, and in a way, that guaranteed this outcome.

May 1, 2010