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By Z. F. Lodhi, J. H. W. De Wit, H. A. Terry

Zinc and its alloys have been extensively used as replacements for Cadmium coatings in aeronautical and automobile industries. Zn alloys with low Co or Fe have been highly investigated but coatings with higher amount of Co are very difficult to achieve due to anomalism associated with these coatings. Anomalous Zn-Co-Fe alloy is a relatively recent addition to the family of Zn alloys. It is found that the addition of Fe in the electrolyte assist in overcoming the anomalism. In this research Zn-Co-Fe alloys especially with higher amount of Co (>15%) and Fe (~1%) are investigated, after overcoming the anomalism associated with its deposition, and the corrosion resistance is compared with pure Zn and Cd. It is found that an increase in Co to higher than 25 % accounts for a shift in the OCP to a level near Cd yet keeps it electronegative to steel. The coating shows superior corrosion resistance, in terms of its sacrificial and barrier properties in 3.5% NaC1 as compared to Zn and Cd.

Jan 1, 2006

IN 1932, the No. 4 shaft at Wright-Hargreaves mine was completed to a depth of 4,000 feet, and the lowest operating level at that time was at 3,900 feet. It was realized that the existing pumping system, using triplex plunger pumps at somewhat irregular depths in the mine, would be in-adequate to take care of the increasing volume of water that would have to be handled as mining operations expanded. Accordingly, in February, 1932, after a thorough study of the whole matter, it was decided to instal an entirely new, automatically controlled, system of pumping, employing centrifugal pumps, with their characteristically trouble-free performance, operated by off-peak power.

Jan 1, 1939

By O. Hall

STOPING at Noranda" is a sequel to "Mining at Noranda". "Mining at Noranda", presented in 1937 (1), sketches Noranda's history, metallurgical problems, exploration, mining methods, mining details, pillar extraction, and costs. "Stoping at Noranda" deals in greater detail with our stoping, the use of sub-level drifts instead of benches, and the drilling out of the stopes with jointed rock drill steel and diamond drills. Sun-LEVEL DRIFT STOPING: Sub-level drift stoping is almost universal throughout the mine and is the standard sroping method in both sulphide ore and rhyolite flux ore. The features that have led to the adoption of this standard are: (1) Continuous symmetrical drilling in sub-level drifts with no delay for blasting. (2) Large-tonnage blasts Saturday night after the drillers have left. (3) Comparative freedom from gas and smoke during the working days. ( 4) The daily safety achieved by having all stope drilling done in drifts. (5) The safety and security achieved by drilling out stopes, floors, and pillars before there is any weighting or cracking.

Jan 1, 1939

Vast quantities of cosmic material, ranging in size from fine dust to large meteorites and planetoids, have been colliding with and accumulating on the earth since its origin 4.5 billion years ago. There are less than twenty well preserved meteorite craters and Jess than thirty fossil craters or astroblemes on the present face of the earth. On the moon, there are approximately 200,000 craters on the visible face alone -the largest crater being 132 miles in diameter and attaining a depth of 16,000 feet. Making allowances for the different physical conditions on the moon and assuming that these lunar features are of impact origin, the indifference is that, since primeval time, large numbers of celestial objects have also encountered the earth, but that both the topographic expression of the impact and the objects themselves have been destroyed by weathering and erosion. It may be reasonable to suggest that additions of cos-mic bodies have materially altered the chemistry of the earth's crust from place to place and that the impact of large meteorites and asteroids has created zones of weak-ness in the crust that could be the center of magmatic intrusion and mineralization.

Jan 1, 1965

By A. W. Jolliffe

AEROPROSPECTING may be defined as the application of the air view to the search for mineral deposits. The term is suggested as a preferable alternative to either aerial prospecting (which may be confused with areal prospecting) or air prospecting. The air view may be obtained by visual observation from an aircraft or by examination of air photographs; each has its particular advantages and disadvantages. Aeroprospecting should be regarded only as an aid to, and not as a substitute for, accepted prospecting methods ( l ). The Precambrian region north of Great Slave lake consists of two well defined physiographic units, a feature first noted by J. T. Wilson (2). The boundary between these lies close to the north shore of the east arm of the lake and extends northwesterly near Spencer, Beniah, Carp, and Ghost lakes (Figure 1). South and west of this line, exposed bed-rock makes up the greater part of the land area; eskers are very rare, and overburden is largely limited to rock-walled valleys and depressions. North and east of the line, outcrops are rare or absent, eskers are abundant, and most of the surface consists of drumlin-like drift hills, elongated parallel to the direction of ice movement (Figure 2). Where this boundary passes through the area shown in Figure 1, it lies near the 1,200-foot contour and may mark the maximum extent of the lake or sea arm present in this vicinity toward the end of the Pleistocene period. For convenience, the first area may be called the 'bed-rock belt' and the other the 'drift belt'.

Jan 1, 1945

By J. Aydt, W. McCombe, H. McLaughlin, L. Nightingale-Mercer

The McClean Lake mill is located approximately 850 kilometers north of Saskatoon, Saskatchewan, Canada and is operated by Orano Canada Inc. (Orano). The mill was designed to process high grade uranium ores, and in 2014 completed a multiyear expansion to increase its production capacity to 24 Mlbs U3O8 per annum. This expansion included significant changes to the mill’s secondary leach circuit in support of safely processing high grade ore directly from the Cigar Lake mine. In particular, inter-stage pumps were introduced for slurry transfer between the secondary leach tanks, replacing the original pressure feed forward operation. The design and selection process for these pumps was strongly influenced by the uncertainty related to actual radiation dose exposure when processing undiluted high grade ore (up to 30%U), and consequently the desire to maintain minimal occupancy in the vault enclosure containing the secondary leach tanks. These constraints resulted in the decision to install positive displacement pumps above the leach tanks in a suction-lift configuration. Operating experience with this design has shown that the pump capacity is significantly de-rated due to process solution gas-entrainment and pipe scale build-up, particularly in the front end of the secondary leach circuit where reagent dosage is high. Experience processing high grade ore also provided accurate radiation dose data to demonstrate that the level of occupancy in the leaching vault enclosure could be re-evaluated to accommodate alternate pump configurations. This paper reviews the lessons learned and improvements made to safely increase the capacity and reliability of the leach inter-stage pump system.

Jan 1, 2020

By J. H. Sokolowski, R. I. MacKay

The level of Si and Cu in the 3xx series of alloys affects the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase. The volume fraction of these phases in turn affects the feeding conditions during solidification and ultimately the Area Fraction Porosity and Mean Pore Diameter measured in the as-cast structure. This work sets out to establish the relationship between the volume fraction of the a-Al dendritic phase and the Al-Si eutectic phase and the resulting porosity that forms on the Monotonic and High Cycle Fatigue properties. The alloys in question are the Al-9%Si-l %Cu and a Al-7%Si-4%Cu alloys which were cast into V8 performance engine block castings and then heat treated to achieve desired mechanical properties. The engine block castings provided the mechanical and metallographic test samples analyzed for this work.

Jan 1, 2006

By W. Kunda, J P. Warner

SHERRITT GORDON Mines Limited annually produce 300,-000 pounds of pure cobalt by processing a nickel-cobalt-copper-iron sulphide ore which is mined at Lynn Lake, Manitoba. The ore (containing 0.04 per cent Co) is •concentrated to give a concentrate containing l 1-12 per cent nickel, about 2.0 per cent .copper, and 0.25-0.35 per cent cobalt, which is treated at the Refinery in Fort Saskatchewan, Alberta. The concentrate is leached in an ammoniacal solution of ammonium sulphate using compressed air as the oxidant. After filtration the leach solution contains, besides nickel and cobalt, copper ammines, sulpharnates and salts of various thionic acids. The copper is removed by precipitation as sulphide and the sulphur compounds converted to ammonium sulphate by a combined oxidation and hydrolysis treatment. The purified solution •Containing about 45 gpl of nickel and 1 gpl of cobalt is treated with gaseous hydrogen under pressure at 350°F to precipitate metallic nickel powder, the precipitation 'being terminated when the nickel content of the solution is about 0.8-1 gpl. Only about

Jan 1, 1962

By R. Pelton, Z. Dai, S. Yang

ABSTRACT Hydrophobic polystyrene nanoparticles were evaluated as potential flotation collectors for pentlandite. The flotation of hydrophilic glass beads demonstrated the nanoparticles’ ability to induce flotation. Deposition of nanoparticles on glass surfaces increased the contact angle and enhanced adhesion of the beads to air bubbles. High flotation recoveries were achieved when 5–10% of the bead surfaces were covered with nanoparticles. Surface functionalization—the addition of vinylimidazole to polystyrene nanoparticle surfaces—caused the nanoparticles to selectively deposit onto pentlandite surfaces in the presence of Mg-Si slimes. Ongoing work includes attempts to identify specific applications where nanoparticle collectors might be cost effective. _ KEYWORDS Flotation, Nanoparticle collector, Coverage

Jan 1, 2014

By Frédéric Flament

The aim of this paper is to present the development of a data validation software as component of a commercial mass balance package. Data reconciliation through mass balance is basically an optimization problem constrained by the law of mass conservation. As any optimization problem solved with a modern and robust software application, erroneous information or starting point will always lead to a solution, whether it is realistic or not. Moreover, good information wrongly weighted by an incorrect error model will lead to the same bad ending. In an industrial context where competition requires accurate information, data reconciliation without validation can be disastrous and calls for data validation before and after reconciliation. The challenge in automated data validation resides in the development of general theoretical solutions. Until now, none has been presented and only partial solutions are available. The development presented in this paper incorporates some of these partial solutions. The integration of human knowledge into the application paved the way to a more general solution. The combination ?theoretical validation ? human expertise? proved to be flexible and reliable enough to be integrated in a commercial data validation package. Numerous examples though industrial applications are presented. These applications demonstrate the validation of raw measurements, user support in the development of error models and validation of reconciled measurements.

May 1, 2001

By Gui Hua Wang, Xin Chang, Zhong Ying Han, Yuan Fang Cheng

"According to the geometrical characteristics of triangular meshes, Triangular Mesh Split Model (TMSM) based on a finite element method is proposed to simulate cracks propagation of fractured rock. With TMSM, stress intensity factors at the tip of cracks are obtained by far-field contour integral. Meanwhile, vector cross multiplication is adopted to fix the cracking unit, and maximum circumferential stress criterion is used to determine the crack propagation angle. Then crack dynamic propagation simulation is realized through local mesh split or node movement at crack tip. With this method, the crack can split apart a unit or extend along the mesh boundary, so the crack could extend along an arbitrary path and is not restricted by the initial mesh. The applicability of the mesh split algorithm is verified by the crack propagation examples of wing crack and multi-fractured rock mass with holes. The results show that this method not only has higher accuracy of fracture parameters calculation, but also can accurately simulate the crack initiation and propagation of rock under complex stress state such as tension, compression and shear. In addition, the far contour integral is introduced to determine the crack tip stress intensity factor and there is no need to reconstruct a singular element at the crack tip or to intensify the meshes. Compared with the existing mesh reconstruction algorithm, this method significantly improves the computational efficiency.INTRODUCTIONGenerally, rock is neither the full continuum, nor entirely discrete body, but rich in geological defects, such as joints and cracks. A large amount of geotechnical engineering practice shows that most fracture of rock is closely related to the internal joints, cracks and crack expansion (Horii et al., 1985; Wong et al., 1998). Although the classical theory of fracture mechanics established the theoretical foundation of crack initiation, propagation, so far it is still extremely difficult to characterize the propagation of airfoil-typed crack and the interference problem of multiple cracks. Up to now, the micromechanics mechanism research of crack propagation of fractured rocks has still been a hot research topic of rock fracture mechanics."

Jan 1, 2015

By Rodney Trevor Jones, Arthur Robert Barnes

Anglovaal Minerals acquired the Nkana slag dump from Zambia Consolidated Copper mines (ZCCM) in 1998 and embarked on an ambitious project to pioneer the recovery of cobalt from slag using DC smelting technology. Anglovaal Research Laboratories performed initial pioneering smelting tests in a 250 kW DC furnace over a 3-year period before engaging Mintek for three piloting campaigns at the 1.5 MW level. Mintek had previously developed a reductive smelting process, patented in 1995, using a DC arc furnace for the recovery of cobalt from slags. The results of the pilot-plant test campaigns were used as the basis for engineering the commercial 40 MW operation installed at Chambishi Metals plc in Zambia in 2001. This paper traces the development of understanding of the metallurgical fundamentals ultimately used to predict furnace performance, reviews some of the extreme technical challenges faced, how solutions were identified and highlights some of the critical issues identified during piloting and how these impacted both positively and negatively on the final commercial operation.

Jan 1, 2011

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By L. Vu, V. Popov, J. Beland, R. Darling

"The Ferderber gold deposit is of Archean age. It consists of a series of gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz dioritic Bourlamaque batholith. On average, this zone strikes N70E and dips 65SE. The Ferderber shear zone, which hosts the ore lenses, has been affected by a succession of tectonic events. A possible early period of brittle shear, accompanied by the formation of quartz lenses, resulted from strike slip movement along the zone. These early quartz veins were subsequently folded and boudinaged during reverse movement that accompanied a prolonged period of ductile shear. More quartz veins were emplaced in the shear zone at this time; these were also deformed by the thrusting. The latest tectonic event to affect the shear zone was a period of brittle fracture.Early dextral strike-slip movement on the shear zone is suggested by the local occurrence of Riedel shears, the preferred association of ore with east-northeast oriented segments of the zone, and by the apparent en echelon arrangement of some ore lenses. The most important event, a reverse movement, is indicatedby the attitudesoffoliation, folds, boudins, COS tectonites and slip planes. The late brittle fracturing formed narrow gouge filled faults, locally flanked by brecciazones, whichrun generally within and parallel to the shear zone, and also conjugate fractures that crosscut the zone.The Ferderber and six other adjacent gold deposits were formed in a structural regime dominated by a generally horizontal north-south regional compression. The Y axis of the strain ellipsoid is east-west and varies from horizontal to a plunge of 25 0 w."

Jan 1, 1987

By M. E. D. Raymont

"During the history of the sulphur industry there have been three distinct phases of production. Factors controlling supplies during these periods have shifted from demand for sulphur to demand for energy and a cleaner environment. The pattern of brimstone production is t raced through these phases and includes estimates of future supply; these indicate an involuntary excess production of some 20 million plus tons per year by 1980 unless some large-scale new uses are found. Traditional uses for sulphur, including fertilizer, chemicals, fibers, etc., are generally expanding slowly; how• ever, supply in ""by-product"" form alone will soon outstrip demand. The predicted oversupply situation can be corrected by the development of novel potential markets. Promising areas include construction materials, insulation and plastics, among others."

Jan 1, 1972

By J A. Gilliand

Mineralogical cross sections of orebodies on the 300-,600- and 900-foot levels of the Coronation mine have been interpreted in terms of centers of mineralization. The maximum concentration of chalcopyrite occurs closest to these centers, with pyrite and pyrrhotite concentrated some distance away. The magnetite concentrations are farthest removed from the centers. A hydrous halide fluid model is established. Attempts to explain the observed mineralogy by the action of temperature gradients on the fluid model were unsuccessful. Likewise, the action of diffusion alone on the fluid model cannot explain the observed mineral distribution. The concept of attenuation is introduced-i.e., the rate of diffusion of a particle species is related to the product r2 I/ M, the attenuation coefficient, where r is the particle radius and M its molecular weight. Attenuation, acting on the fluid model alone, will not produce the observed mineral distribution, but, when considered together with the action of temperature gradients, the observed mineralogy can be well explained by the combined effects of these two processes on the assumed fluid model.

Jan 1, 1965

By Maciej Wrobel, Joerg Hammerschmidt, Dana Nurgaliyeva, Alexandros Charitos, Jochen Guentner

"Smelting of copper concentrates in the flash smelter generates a flue dust stream that contains a substantial amount of copper and accumulates more than half of the arsenic input to the smelter. In view of its high copper content flue dust recirculation to the flash smelter is common practice. Globally traded copper concentrates are affected by ever increasing arsenic contents and cause an increasing circulating arsenic load in flash smelter operation. Control of the arsenic level in the smelter slag becomes a challenge. This interaction of arsenic loaded copper feedstock, need for flue dust recirculation and slag quality control call for possibilities to reduce the arsenic load of the recirculated flue dust stream.The technology of partial roasting is known from pre-treatment of copper concentrates before smelting, and gold concentrates before cyanide leaching, to remove the harmful element arsenic. The partial roasting technology can be adapted for use in the purification of the flue dust. A major challenge for flue dust treatment is its extremely fine particle size compared to usual concentrates. For this reason Outotec developed a new process, which allows handling of such fine flue dust. This process solution provides an efficient possibility to reduce the arsenic burden in copper smelter operations.The suggested process aims at reducing the arsenic load to the smelter by treating the flue dust prior to recirculation to the smelter. The presented results are based on test work in the Outotec R&D-centre in Frankfurt. It is possible to remove 80-85% of the contained arsenic and to collect it in an arsenic trioxide residue with a concentration above 90%. The final off gas contains SO2 from decomposition of sulphates that are contained in the flue dust. The off gas stream is relatively small. We assume that it is possible to combine the off gas stream with other smelter process gas streams and to treat it in an existing sulphuric acid plant. Coal is used as fuel and as reductant to reduce pentavalent arsenate to trivalent arsenite. Arsenite can be kept in gas form at temperatures above 450°C. This permits separation of a calcine stream with arsenic levels of 0.2 – 0.3%, which is recirculated to the furnace.Outotec has a wide range of roasting testing facilities from lab-scale to pilot-scale. Outotec has both capability to modify and adapt technology to specific ore or concentrate requirements, but also the necessary infrastructure in its research centers in Frankfurt and Pori to do appropriate validation tests in lab and pilot scale size plants."

Jan 1, 2016

By William B. Coker, Vladimir J. Sopuck, J. S. Fox

"Preliminary investigations indicate that organic lake sediments offer some potential for gold exploration within the Canadian Shield of northwestern Saskatchewan. It is also apparent that certain precautions must be taken.Gold is primarily related to the organic fraction of the lake sediments, which, although giving consistant Au contents to those sediments, may restrict the dispersion of Au within the lake itself. It may be necessary to carry out selective extractions on the lake sediments to differentiate between Au related to organic sequestration, indicative of hydromorphic and/ or chemical dispersion, and Au related to inorganics, indicative of mechanical dispersion.Lake sediments are probably only of use for very detailed exploration (i.e. every lake). One to three samples per lake should be appropriate, although a single centre-lake organic-rich sediment sample may be adequate in very small lakes. Each lake sediment sample should be analyzed at least twice and the analytical data carefully monitored and evaluated.The use of As in lake sediments as a pathfinder element for gold is applicable in the search for certain types of gold occurrences.Following detailed lake sediment sampling, basal till sampling can possibly be used to localize areas of potential gold with or without base metal mineralization."

Jan 1, 1982

By L. Heber Cole

In making this plea for a better and more sympathetic understanding of the non-metallic industry, I do not for one minute wish to give the impression that I in any way belittle the wonderful strides that have been made in the exploitation of our metallics. We in Canada can be justly proud of our Sudburys, Norandas, Flin Fions, and of the remarkable growth of the Consolidated in British Columbia, and at the same time, without in the !east detracting from these worthy undertakings, be equally as proud of our asbestos, gypsum, salt, and coal deposits, as well as of our building-stone and limestone industries. If, in my remarks, I have occasion to compare the metallic with the non-metallic industry, I do so, not with any idea of dimming the glory which the metallics of Canada have gained- not only in our own country, but in the world at large-but for the purpose? of bringing to your attention the fact, perhaps not very well recognized, that Canada contains deposits of non-metallics well worth y of your serious consideration. In the past 33 years, namely, since 1895, the value of non-metallics produced in Canada has exceeded the value of metallics in 19 of the years, and for the last three years has been increasing rapidly. The war years (1915-1918 inclusive) naturally saw an intensive metallic production, but since that time, with the exception of 1925, when there was a general depression throughout the whole country, the non-metallics have been in the ascendency.

Jan 1, 1929

By J. W. Craig

THERE are, broadly speaking, three classes of refractories: acid, basic, and neutral. Fireclay, diaspore, silica, and the sillimanite group of minerals are included in the acid class, which for the most part are not very resistant to basic slags. The neutra! class includes chrome, graphite, and silicon carbide, while most important in the basic class are magnesite and dolomite. Although chrome is a neutral refractory, it has no sharp distinction from magnesitic refractoriness. The two are mineralogically (1) and chemically related, and there is available on the market a complete range of brick from straight chrome to straight magnesite. In many indus trial applications, one. type may be replaced by another. The present paper is confined entirely to such refractories. The following types of basic and neutra! brick, each sold under sorne special trade name, are available for use in Canada: (1) Burned chrome from crude ores (2) Burned chrome from treated ores (3) Chemically bonded (unburned) chrome-magnesite ( 4) Burned chrome-magnesite (5) Chemically bonded ( unburned) magnesite-chrome (6) Chemically bonded (unburned) high-iron magnesite (7) Burned high-iron magnesite (Regular) (8) Burned low-iron magnesite (9) Burned olivine-magnesite (10) Burned magnesitic dolomite-chrome (Magnecon) (11) Chemically bonded magnesitic dolomite-chrome (Magmecom) (12) Dolomitic brick

Jan 1, 1936