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By Olli Haavisto, Juha Timperi

"Accurate on-line assays of mineral slurries are the basis for effective operation of flotation circuits. Typically the elemental content measurements are obtained by an X-ray fluorescence (XRF) analyzer, which samples the process lines and performs the analysis concurrently line-by-line. For a more frequent measurement of each slurry line the XRF measurements can be complemented with reflectance spectrum information. In reflectance spectroscopy the absorbance properties of the slurry in the visible and near-infrared wavelength range are analyzed. The advantage of reflectance spectroscopy is that measurements can be obtained quickly and simultaneously from several slurry lines. However, since the shape of the spectrum is only indirectly affected by the slurry elemental contents, frequent calibration of the measurement against the XRF analyzer is necessary. This study elaborates the combination of reflectance spectrum analysis with XRF. Results of laboratory tests for different slurries are presented and the operation of the system in a copper-zinc flotation plant is demonstrated.IntroductionElemental analysis of mineral flotation slurries is the most important factor in evaluating the performance of concentration processes. Timely on-line assays are also used as the basis for controlling the circuits and ensuring that the grade and recovery targets are reached. X-ray fluorescence (XRF) is the dominant technology in on-line elemental slurry analysis, and typically centralized XRF analyzers are used. The advantage of a centralized analyzer is that one measurement probe can be used to acquire the data from several slurry lines. This reduces the overall operating cost of the system when compared to distributed analyzer system design with several measurement probes requiring maintenance and spare parts. Slurry samplers are installed in the interesting process flows and representative sample flows are brought to the analyzer, where the slurry is further sampled and measured consecutively by the XRF analyzer. Due to the centralized structure of the analyzers and consecutively measurement of the sampling lines the sampling interval per slurry line can be relatively long. In larger concentration plants with several sampling lines a typical assay interval is in the range of 10-20 minutes."

Jan 1, 2016

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

By John A. Herbst, Alexander Potapov, Xiangjun Qiu

"High Fidelity Simulation is a name applied to the use of first principles modeling tools including Discrete Element Modeling (DEM), Computational Fluid Dynamics (CFD) and Discrete Grain Breakage (DGB) to mathematically describe and study processing systems. Over the past few years, significant advances have been made in High Fidelity Simulation applications, particularly as many mineral processors have been drawn to the study and use of DEM of grinding mills for optimization purposes. This presentation provides an introduction to High Fidelity Simulation, with an emphasis on DEM. It will include insights into current applications of these tools including the optimal design (wear and throughput) of mill lining systems and media selection, the analysis and design (flow and efficiency) of the back-end of grate discharge mills. Advantages of full mill simulations versus individual sub-process simulations will be demonstrated for a SAG mill with different discharge system designs.INTRODUCTIONHigh Fidelity Simulation is providing mineral processors with the opportunity to analyze the behavior of mineral processing equipment from a fundamental or microscale point of view. In the past complex phenomena such as tumbling mill grinding had to be analyzed using black box tools such as residence time distributions for transport and classification functions for passage of particles through grates; while breakage had to be analyzed using PBM models who derived their form from theory but required direct measurement of kinetics. Today with the help of DEM, CFD and DGB these can be analyzed at a very fundamental level.The key element of DEM simulation is the application of Newton’s laws of motion to individual objects or discrete elements. Using this simulation method one can describe the position, velocity (both translational and rotational) of all objects and the transfer of momentum to other objects (Mishra and Rajamani, 1992; Cleary, 1998; Nordell et al, 2001)."

Jan 1, 2003

By J. Moyes

The Intec Process is a generic process for the production of pure base metals and precious metals from sulphides concentrates derived from copper, nickel, zinc and lead ores. The development program for the Intec Process initially focussed on the treatment of copper concentrates, (the ?Intec Copper Process?), and more recently of zinc concentrates, (?the Intec Zinc Process?). Developed and proven in Sydney, Australia at a cost of US$15m over the last ten years, the Intec Copper Process is now ready for commercial application. The knowledge gained during the development of the Intec Copper Process has been applied to the Intec Zinc Process, which utilises the same basic chemistry to produce high purity zinc ingot from metallurgically complex zinc sulphide concentrates containing lead, copper, iron, silver and gold. The demonstrated ability of the Intec Zinc Process to treat low grade mixed zinc/lead/copper concentrates, including those with high iron and manganese levels, holds out the real prospect of overcoming major metallurgical hurdles that have long affected the zinc industry. The Intec Zinc Process consists of the three consecutive circuits of leaching, purification and electrowinning. The leach circuit is of single stage configuration with a series of reactors to which concentrate and lixiviant are fed. Purification consists of cementation and precipitation by pH adjustment. Electrowinning employs an electrolytic cell very similar in design to that of the Intec Copper Process, but differs in that a conventional plate cathode is produced. During electrowinning, the same mixed halide species (BrCl2 -, HalexTM) that is integral to the Intec Copper Process is generated in solution at the anode and exhibits powerful leaching characteristics capable of directly leaching the sulphide concentrate feed. The need to roast the concentrate prior to leaching, as is practised in the conventional Roast/Leach/Electrowin (RLE) process, is thus eliminated whilst a range of by-products (notably lead, copper and precious metals) can be extracted in the simple, single-stage leach. This paper describes the Intec Zinc Process; the technology, predicted economics and its environmental aspects.

May 1, 2002

By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

By Alessandro Navarra, Amir Arash Rafiei, Kristian Waters

Mathematical programming (MP) is fundamental to systems engineering and operations management, but has not been widely adopted by mineral processors. The current paper presents an interdisciplinary approach, using MP to incorporate basic notions of mass balancing into an optimization framework. The optimization is typically related to economic profitability. Two- and three-product formulas are extended to give formal descriptions of alternate modes of operation, and a global representation of the concentrator. At this global level, the framework may assist plant managers to make tactical decisions based on incoming feed data. The MP framework is demonstrated through sample calculations describing a lead-zinc concentrator.

Jan 1, 2015

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By W. Mueller, M. Rocheleau, E. Dimroth

The paleogeographic evolution of the Abitibi Belt is subdivided into three phases, namely: 1) a phase of the growth of a submarine volcanic chain, 2) a phase of the emergence and growth of volcanic islands and 3) a phase of uplif t and erosion of volcanic islands. Isostatic calculations suggest that the volcanic sequence in the south of the Abitibi Belt rests on oceanic basement or on the mantle; the volcanic sequence in the north of the belt rests on about 13-14 km of tonalitic basement. 10-15 km of plutonic material accreted to the volcanic islands during paleogeographic phases 1 and 2, and caused the uplif t during paleogeographic phase 3.

Jan 1, 1984

By Benoit Bissonnette, David Gelderland

"The Campbell Mine Constructed Wetlands has been in full operation, processing effluent from the water treatment plant of the mill circuit for the last two years.The overall results are extremely positive with dramatic improvements for the originally targeted parameters – Ammonia, Copper and toxicity.• Ammonia concentrations were reduced from an average of 5 mg/L to an average of 0.43 mg/L which translates to an average reduction of 91%.• Copper concentrations were reduced from an average concentration of 0.054 mg/L to an average of 0.019 mg/L, which translates to an average reduction of 65%.• LC50 Acute toxicity testing revealed no impact.• IC25 Chronic toxicity tests revealed no impairment to growth or reproduction.As a result of the improvements in discharge water quality from the wetland, 100 percent compliance with respect to all Certificate of Approval, MISA and MMER regulations for effluent will be consistently achieved.The system has proven to be very easy to operate and maintain, with a minimum of care. Given some basic rules are followed, the construction of the wetlands was straightforward and relatively inexpensive compared to other treatment methods.The ecological benefits of the operation of the wetland are also quite substantial, as is the positive image of the corporation in environmental stewardship.INTRODUCTIONOver the last four years, Campbell Mine has adopted an aggressive schedule for the development of wetlands for use as the final stage of effluent treatment within the tailings management facility. The focus of this work has been to utilize natural biological systems to provide Campbell Mine with a 100 percent compliant water quality with respect to all MISA, MMER and COA discharge criteria at all times throughout the effluent discharge period."

Jan 1, 2003

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. IntroductionGeographic information systems (GIS) are a relatively new tool in the mining industry. Although they have existed for a number of years, the potential of GIS for mine management and planning is only beginning to be investigated and exploited. The unique spatial capabilities of GIS make them particularly wellsuited for use in mining, where spatial information is fundamental to the processes of mineral exploration, mine development, and environmental reclamation. A number of potential applications for GIS in the mining industry have been identified, and they are widely used for exploration and reclamation. The use of a GIS as a platform for the development of mine planning routines and software remains an interesting, but as of yet unexplored, application of this technology."

Jan 1, 2003

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Grégoire

Abstract -A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (2:3 cm thick), which seems to have been developed over the entire sedimentary basin of >80 km2, consists of pyrite, vaesite (NiSi), and sphalerite. The average grade of the mineralization is about 5.3% Ni, 0.73% Zn, ?770 ppb (PGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE +Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrient­ rich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic­ matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained S04 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich 1arninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesite­ pyrite assemblage crystallized at approximately 138°C. The ?34:S values range from -14.7 o/oo to-10.0 o/oo and are up to 34 o/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The ?13:C values of calcite in the footwall of the mineralized unit ( -12 o/00 to -6 o/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By Linda C. M. Elliot, Liangxue Liu

"The deposition of tailings under water is considered to be one of the most environmentally promising and potentially cost effective methods to reduce or eliminate acid mine drainage from tailings. One of the concerns of subaqueous deposition has been that metals may leach into the cover waters, thereby increasing aqueous metal concentrations to higher than acceptable limits. This potential was seen to have an even greater possibility for impact when the tailings are deposited under acidic lake water.The following paper summarizes the results of subaqueous tailings pilot column test work conducted to determine the effects of subaqueously deposited tailings on lake water and tailings pore water. Two types of tailings were tested: high sulphide tailings (pyrrhotite concentrate), and low sulphide tailings (end of pipe slime tailings).Data was collected from five columns over a 13 month test period. The results indicated that a stagnant I 000 mm water cover was capable of maintaining the underlying tailings in a reducing condition. The upwards diffusion of pore water resulted in a pH increase in the waters overlying the thickened pyrrhotite tailings and the pyrrhotite tailings with a shallow cover of substrate. A conductivity gradient between the tailings and the water cover caused a diffusion of salts upwards into the overlying water column. Precipitation noted at the tailings water interface may be related to the precipitation of ferric oxyhydroxides, which resulted in a decrease in Fe concentrations noted in the water cover. Other metal concentrations did not exhibit significant increases in the water cover. A sulphate concentration gradient between the tailings and the water cover may have caused the diffusion of SQ4 from the tailings into the water cover."

Jan 1, 1997

By P. G. Semple

"In January 1985, Equity Silver Mines Limited began operation of a cyanidation circuit to scavenge precious metals from the flotation tailings. At present, this process is treating 270,000 tonnes of tailings per month and is recovering in excess of 0.20 grams of gold per tonne. To obtain these results Equity is operating a carbon-in-leach circuit that utilizes pressure stripping, zinc precipitation acid washing and thermal reactivation. A cyanide destruction circuit is also required to minimize the deleterious effects on reclaim water in the flotation stage. This paper describes the existing scavenger plant, and details the start-up problems encountered and the modifications made to correct these problems.INTRODUCTIONEquity Silver Mines Limited , a 68% owned subsidiary of Placer Development Limited , is located 38 km southeast of Houston in north central British Columbia. The geographic location of Equity Silver Mines is shown in figure #1. In September 1980, production first began with the ore being supplied from the Southern Tail open pit. In March 1984, the Southern Tail deposit had reached its economic pit depth, and since then ore has been supplied by the Main Zone pit the gold mineralization in the Main Zone is less refractory than the Southern Tail and cyanidation of the flotation tailing appeared to be a viable alternative.An extensive test program was undertaken and the results confirmed that considerable gold and silver values were amenable to cyanide leaching. A feasibility study showed that these values could be economically recovered and the detailed engineering work began."

Jan 1, 1987

By R. S. Bowman, G. S. Austin, J. M. Barker, P. S. Freeman

The physical, chemical and mineralogic characteristics of zeolites allow commercially important applications. While adoption of zeolite technology is slow in the United States compared to other regions of the world, continued testing and research has shown a wide range of uses for these minerals. They are important catalysts in petroleum refining, molecular sieves able to separate gases, and chemically inert carriers of reactants. The zeolite clinoptilolite produced by St. Cloud Mining Company (clino) (SC) is used in animal hygiene and animal feed, especially concentrated animal feeding operations (CAFOs), horticulture, water treatment, floor dry, aquariums, air and other filters, and odour control. Clino can remove cations from solution, and surface-modified zeolite (SMZ) is a sorbent for the removal of anions and neutral organics from water. Specific clino applications are: control of chemical pollution in groundwater, removal of organic compounds from oil field waters, and elimination of pathogens from sewage effluent. Combining the sorption capabilities of SMZ with chemical or biological transformations can yield complete removal of toxic materials from contaminated water. Continued development and marketing of zeolite products will be a growth market far into the future. The CAFO market for zeolites is the most significant growth area in the United States over the next few years. SMZ, currently less than 1% of St. Cloud sales, will continue to gain market penetration for many years.

Jan 1, 2004

By E. I. Robinsky

"This paper describes a new, proven approach for tailing disposal. Not only is the disclosed system less damaging to the environment, it is also less costly to operate, to close down and maintain in perpetuity. The basic concept is to discharge thickened tailing from one permanent location.This creates a conical or hill-like deposit which:(1) requires lower perimeter dykes for equivalent storage capacity;(2) eliminates decant towers and decant lines;(3) requires no steep dams built of tailing;(4) is stable:(5) requires only a small pond outside the deposit;(6) decreases pollution of the surrounding environment by water seepage and deflation; and(7) simplifies abandonment and ""closing-down"" operations.The approach is made possible by the fact that, at a sufficiently high ratio of solids to water, tailing material can be made to accumulate at slopes of 5 or 6 per cent -- considerably steeper than possible by traditional methods using low solids-to-water ratios. To achieve the necessary solids-water ratio (35 to 60 per cent), it may be necessary to install a thickener. It is expected, however, that at many concentrators it may be possible to discharqe relatively clear plant water through a line separate from the tailing line, thus reducing the load on the thickener."

Jan 1, 1976

By S. Kursunoglu

The aim of this study was to investigate the effectiveness of Ascorbic (C6H8O6) Acid (AA), Activated Carbon (AC) and Guar Meal (C6H12O6) (GM) as a reductant for the simultaneous complete dissolution of zinc (Zn) and manganese (Mn) from a spent and mixed Zinc-Carbon (Zn-C) and alkaline battery powders in sulphuric acid (H2SO4) leaching. AA was tested previously as a reductant by other researchers while AC and GM were tested as a reductant for the first time in battery recycling. The effects of H2SO4 concentration, AA/AC/GM dosages, reaction temperature and leaching time on the Zn and Mn dissolutions were investigated according to 2k full factorial experimental design and Central Composite Design (CCD) technique; then, a simple optimization study was carried out for comparing the reductants. The optimum reductive acid leaching conditions for AA were determined at 3 hours leaching time, 70°C leaching temperature, 0.5M H2SO4 concentration, 13 g/L AA dosage, 1/20 g/mL solid/liquid (S/L) ratio and 200 rpm stirring speed. Under these conditions, the dissolution efficiencies were 99.9% for Zn and 99.3% for Mn. The best reductive acid leaching conditions for AC were determined at 3h leaching time, 80oC leaching temperature, 1M H2SO4 concentration, 3 g/L AC dosage and 400 rpm mixing speed. Under above conditions, Zn and Mn dissolutions were not complete. At 2M H2SO4 concentration, 10 g GM dosage, 700C leaching temperature, 200 rpm stirring speed, 1/20 g/mL solid/liquid (S/L) ratio and 3 hours leaching time, full dissolution of both Zn and Mn was achieved. As a result, three different reductants were evaluated in this study for complete simultaneous Zn and Mn dissolutions. This paper also compared present test results with previous spent battery recycling studies for Zn and Mn dissolutions. Full valuable metals dissolutions from spent batteries were achieved at low H2SO4 concentrations with AA and high concentrations with GM. Selective precipitations of Zn and Mn from acid solutions were carried out using NaOH and KOH. Using 3M NaOH as precipitating agent at room temperature and at pH 8; 95.4% of Zn and at pH 10; 93.7% of Mn were precipitated from the leach solution. Under the same conditions, using 3 M KOH at pH 8; 91.6% of Zn and at pH 10, 96.4% of Mn were precipitated. Based on the experimental results obtained, an appropriate flow sheet was proposed to recover both Zn and Mn.

Aug 1, 2013

By Niklas Frank

Ore and waste transports form an integral part of any mining operation and represents a substantial portion of the mine´s total operating cost. Mine layout, truck fleet and size, production rates, haulage distances, shift schedules, maintenance strategies etc. are all important and not at all static variables. They all change during the life of a mine and interact in a dynamic way. It is therefore essential for the successful mine management to constantly analyse and optimise the mine's transport systems. Önnerlöv has recently conducted a life-of-mine haulage simulation project for Zinkgruvan Mining, a medium sized, underground zinc producer, located approximately 60 kilometers south of Örebro, Sweden. The main objective of the project was to analyse and optimise the investments required to provide ore and waste haulage under changing conditions over an +10- years period: Deepening of the mine, increased production rates, changed mine layout, changed truck fleet etc. A large number of scenarios has been tested in the simulation model in order to identify the "lowest cost per ton" solution. This paper comprises an introduction of Zinkgruvan Mining and a brief background to the actual project, a description of the simulation model, project conclusions and some useful hands-on tips for mining engineers and project managers how to run a successful simulation project.

May 1, 2003

By K. M. Wild, C. D. Martin, F. Amann

"Argillaceous rock formations, in particular clay shales, are notorious for creating challenges in rock engineering. Due to their generally low hydraulic conductivity and their complete saturation in their natural state at depth, the behavior of clay shales is usually characterized by a strong hydro-mechanical coupling.This paper presents typical pore pressure responses monitored in different underground rock laboratories and explores alternative ways for their interpretation. The underpinning processes and their relevance are identified based on analytical and conceptual numerical models. Pore pressure monitoring data from Opalinus clay at the Mont Terri Underground laboratory, the Boom Clay at the Mol facility and the Callovo-Oxfordian clay in the Meuse/Haute–Marne URL show a similar pore-pressure response associated with stress changes accompanying tunnel construction although the tunnels were built in different rock types, at different locations, and under different in-situ conditions.The numerical analyses in this study shows that the pore pressure response around an excavation in low permeable clay shales may have different explanations. Pore pressure drops observed in the tunnel near field can theoretically be explained by both, a pure elastic response in an isotropic or anisotropic rock mass with an anisotropic stress state, or a inelastic response and related dilatancy. However, a comparison between the numerical models and the in-situ measurements revealed that the latter is more likely. This conclusion is justified by the observation that pore pressure drops occur significantly ahead of the tunnel face which is not the case in elastic numerical simulations. Pore pressure measurements in the far field, where failure processes are unlikely to occur, can only partly be explained by a linear poroelastic models. The introduction of an anisotropic material plays a key role in reproducing the responses, conceptually."

Jan 1, 2015

By John Ramsay, Frederick A. Edwards, J. Eric Belford, Clarence V. Amyotte

"DEVELOPMENT of the underground mine is carried out from a main ramp driven from surface to the 800 and 1200 levels and from a shaft sunk to 3050 ft. Sub-levels at approximately 100-ft vertical intervals, starting 300 ft above the 800 level, were collared from the ramp as it advanced and a considerable amount of development work was pursued. The lateral and ramp work provided an opportunity to train drift crews, test equipment and methods, assess ground conditions and advance the initial stope development. The development of an exhaust ventilation raise system closely followed the extension of the level development to the south end of the orebody (Fig. 26) . On completion of the shaft, temporary lip pockets were installed at the shaft stations on the 800, 12.00, 1600, 2000 and 2400 levels. The permanent loading pocket had been installed on the 2860 level as part of the shaft-sinking contract and the level had been connected to the 2800-level station by a small muck transfer raise. Development of the 2800-level area was given top priority at this stage. This included a 1000-ft cross-cut to the crusher location, the crusher excavation, storage bins, conveyor ways and a ramp to connect the 2800 level to the loading pocket, the rope changing station and the shaft sump. The development and installation of the rock handling system between the 2400 level and the shaft bottom was contracted to Macisaac Mining and Tunnelling Company, of Sudbury, Ontario."

Jan 1, 1974