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By S. Usui, Y. Shinohara, C. Tokoro, K. Horiuchi, S. Owada

Process optimization of heating and physical separation for Cobalt (Co) recycling from spent lithium ion battery (LIB) was investigated. LiCoO2 in spent LIB was transformed to LixCoO2 which was more easily decomposed than LiCoO2 by heating. Coexisting materials of aluminum and carbon, and sealed atmosphere of the LIB promoted LixCoO2 decomposition. In an atmosphere of Argon, 95 % of LixCoO2 in the spent LIB was decomposed to 76 % of Co oxide and 19 % of Co metal in 10 min at 823 K; a lower temperature than the theoretical value for LiCoO2. The Co oxide and Co metal exhibited magnetic properties and could be recovered by wet magnetic separation. Furthermore, slow heating was effective for grain growth of Co oxide and Co metal. At 2 K/min rate of heating, average grain size of Co oxide and Co metal were 239 µm and 28 µm respectively, whereas at 30 K/min they were 190 µm and 15 µm respectively. Therefore, separation efficiency for Co recovery by wet magnetic separation was increased when spent LIB was slowly heated at 2 K/min.

Jan 1, 2015

By Tao Long

Recently, the great amount of funds has been invested in the reconstruction of damaged infrastructure and house of subsidence area of coal mine and mine reclamation. This is a benevolent and popular work, which is highly praised. However, because of complicated collapse area problems in China, especially the less integrated control research in the collapse area of metal mine, and the technological weakness, how to effectively control the subsidence area, restore landscape and ecological environment, and utilize the abandoned mine land, are major issue related to the mining area of sustainable development. The research situation about the formation of metal mine collapse area at home and abroad is reviewed, and then the effect of the collapse area on the mine safety and ecological environment, the existing technical problems and development direction are analyzed. Lastly, the technical measures of the collapse area control and cooperative underground mining is put forward.

Oct 1, 2010

By Hamid-Reza Manouchehri

Coarse particles flotation is controlled by detachment (particle hydrophobicity and flotation cell turbulence) For composite particles (the bubble may attach to good hydrophobic region, but the expansion of the three phase line of contact is limited. Hence, the equilibrium contact angle, characteristic of the hydrophobic region, may never be attained, and the force of attachment is decreased relative to that possible for homogenous hydrophobic surfaces.

May 1, 2013

By H. J. White

Haynes International, a world leader in the manufacture and production of nickel, and cobalt base alloys has invented and developed a low cost high temperature material, with a unique combination of superior oxidation resistance and weldability/ fabricability. HAYNES® HR-224TM (Ni ? 27.5Fe ? 20Cr ?3.8A1 ? 0.3Si ? 0.3Ti) forms a planar/ continuous/ adherent aluminum oxide film at high temperatures which has been shown to effectively limit chromium poisoning in solid oxide fuel, cell, systems. A 20,000 pound vacuum induction melted (VIM) + electroslag remelted (ESR) heat has been melted and converted into various product forms: sheet, plate, bar, welded tubing, wire, etc. The alloy was designed for service in severely oxidizing environments recuperators, automotive catalytic converters, wire strand annealing furnace tubes, etc. and has been of great interest to solid oxide fuel, cell, manufacturers as a materials of construction in balance of plant (BOP) design. This manuscript presents the physical, properties, mechanica, properties, and oxidation resistance of the alloy compared to other materials being considered for solid oxide fuel, cell, design

Jan 1, 2010

By C. O. Aksoy

Operating the underground marble quarries effectively, it is important to evaluate the deposit blocks economically which are affected by the suitability of the topography and configuration of bedding. The joint sets within the deposit and the spacing between these discontinuties are also of great importance. In this study, the marble deposits that could be geomechanically eligible for underground excavation have been selected throughout Turkey and these selected reserves have been classified accordingly by Q-Rating System. These classified marble deposits that forms groups of 1,2, and 3 (groups were determined by evaluating the O-rating, topography, quarry situation, cracks, joints etc.) are convenient for this type of production. Nevertheless, when the auxiliary factors (topography, location, production method etc.) regarding the deposit have also been investigated, the most convenient sub-group of deposits (Afyon Tiger Skin, Burdur Beige, Diyarbakir Pink and Mugla White) have emerged. The sizing of the pillars have been performed utilising Bieniawski?s stress profile. The LAMODEL software, developed by National Institute for Occupational Safety and Health (NIOSH), USA and run under the laminated displacement discontinuity method, has been used to size the pillars. This work brings in a novel opportunity to Turkey, in which no underground marble quarry has been attempted up-to-date similar to its several examples in Italy, USA, etc. This study serves as a reference for the marble operators and for the pioneering application of laminated displacement discontinuity method in hard rocks.

Apr 1, 2005

The Beginning ! The status quo simply isn?t sustainable ! Our social license is at risk ! The bar keeps rising ? We must improve our performance, both operational and social ? We must improve stakeholder judgement of our industry by taking action collectively Implementing TSM " TSM Guiding Principles " Performance Indicators " Crisis communications " External Outreach " Tailings management " Energy management " Performance manuals, guides " Reporting " Communities of Interest Advisory Panel

May 1, 2004

By Guoxiang Chi

The Cornwallis Fold Belt in the Canadian Arctic Archipelago contains numerous Mississippi Valley-type (MVT) Zn- Pb occurrences and the world-class Polaris deposit. The occurrences are mainly hosted by the dolostone in the Thumb Mountain Formation which spreads over 25000 km2. Success in exploration requires further understanding of the genesis of these occurrences and an assessment of their parentage with the giant Polaris deposit. Syn-sulfide dolomites in regional occurrences share C-O-Sr isotopic characteristics similar with Polaris dolomites, indicating warm basinal brines enriched in 87Sr. The dolomites and sphalerites contain fluid inclusions with ice-melting temperature between ?45° and ?25°C, which is significantly lower than for most MVT districts in the world (?30° and ?10°C). These characteristics indicate that all the Cornwallis occurrences were produced by fluids of the same sources and/or aquifers. The deposit size was largely controlled by the rate and duration of the metal-carrying fluid flow, and by the availability of reduced sulfur at the site of mineralization.

May 1, 2001

By C. Sui, J. E. Nesset, M. Li, J. Y. Kim, S. L. Chryssoulis

"A plant study of zinc rougher flotation at Brunswick Mining was conducted using lime, soda ash and a combination of both as the pH modifiers in order to establish the effects on sphalerite and pyrite kinetics and mineral selectivity. The plant sampling and analysis was augmented by surface analysis using TOF-LIMS, SEM and XPS as well as fundamental precipitation and surface-charge studies in the sphalerite Ca/C03/S04 system.The results revealed the important role of carbonate ions in cleaning the sphalerite surface for effective activation by CuS04 to occur, and the beneficial role of combined soda ash and lime in increasing pyrite and galena depression.1.0 IntroductionThe studies reported in this paper were initiated as part of an investigation into the causes of a particularly pronounced seasonal deterioration in metallurgical performance at the Brunswick Mining concentrator during the summer of 1995. The concentrator treats a complex base metal ore having a typical feed composition of 9.0% Zn, 3.5% Pb, 0.4% Cu and 100g/t Ag at a current throughput of 9,000 TPD, although at the time of the problem in 1995, the average production rate was closer to 10,500 TPD. Zinc, lead, copper and bulk (zinc-lead) concentrates are produced with overall metal recoveries of 86% zinc, 63% lead, 60% copper and 60% silver; results which are typical of the lower recoveries associated with fine-grained, highly complex VMS and SEDEX type deposits. The main economic minerals of interest are an iron-containing (7% Fe) sphalerite, galena and chalcopyrite with the main diluent (about 60% wt) being pyrite.Figure 1 shows a simplified flowsheet of the Brunswick milling circuit while the seasonal decrease in summer metallurgy in 1995 is illustrated in Figure 2. Of significance is the rapid drop in copper and lead recovery in June while there is an apparent delay until late August-September before the zinc deterioration reaches its lowest point. A more typical seasonal effect within the experience of the authors is the reverse of the Brunswick situation, namely an improvement in summer performance thought to be associated with improved differential flotation kinetics during warmer weather leading to better mineral selectivity. The historical Brunswick experience was particularly severe during the summer of 1995 with estimated incremental losses of $10 Million for this period. The potential of the very significant economic benefits to be gained from understanding and hopefully improving the annual drop in performance led to an investigation involving the minesite metallurgical group, the Noranda Technology Centre (NTC) as well as researchers in Professor Jim Finch's group at McGill and the surface analytical services and interpretive skills of AMTEL."

Jan 1, 1998

By Ning Yu

There are about 1.341 trillion tons (t) of proven coal reserves in China, of which 279.58 billion t are available for mine well construction basis. Thick coal seams are 44% of the reserves. The production of thick coal seams exploitation is over 45% of the total coal production. Full-seam mining and fully-mechanized mining for large mining height is the technology development direction of thick and extra thick seam mining. It is also the important way to achieve efficient and intensive mining with the characteristics of high production, high mechanization, high efficiency and low energy consumption, etc. Complete set of technology and equipment of fully-mechanized top caving for large mining height of full-seam (7m) mining and extra thick seam ( 14-20m) has been gradually mature and for demonstration application by the joint research of government, enterprises, universities, scientific research organizations and users. It has solved some technical problems of coal face for large mining height (over 7m) such as the coal wall spalling control, stability of support, wall rock coupling, cooperation work of mining and caving, full roadway support for super large section, end support, equipment matching of coal shearers, hydraulic support and scraper conveyor. It has developed key equipments including powerful hydraulic support of fully-mechanized mining and fully-mechanized top caving for large mining height, electrically-driven coal shearer with high speed and reliability, scraper and belt conveyer with big capacity, soft-start and high reliability, automatic control system of coal face with the core of electric-hydraulic control, bolting drill boom large section coal roadway shearer, heavy auxiliary transport equipment. The operation rates of fully-mechanized top caving equipment for full-seam and large mining height are 94% and 92.1%, and recovery ratios are 93.6% and 88.9% respectively. The annual raw coal production of single work face is over 10 Mt. The automation and intelligentization level have been clearly improved. The exploitation of thick and extra thick coal seam that is safe and efficient has been achieved in China.

Aug 1, 2013

By C. H. B. Leitch

"The Bralorne-Pioneer deposit produced more gold than any other deposit in British Columbia over its 70 years of operation (130 kg or 4 million oz of Au, from 7 million tonnes of 18 glt ore). Mineralization is related to a suite of late Cretaceous albitite dykes of 85 to 90 Ma age. It thus occurred long after and is genetically unrelated to the Early Permian (275 Ma) Bralorne diorite and soda granite.The major veins strike about 110 degrees and dip north at 70 degrees, with slickensides plunging 45 degrees east that indicate last movement was reverse. Major ore shoots in the veins occupy somewhat less than 20% of the vein and plunge steeply west, roughly perpendicular to the slickensides. The structures that contain the veins probably formed at around 95 to 90 Ma during a strike-slip episode with easterly directed maximum compression.Disseminated pyrite, pyrrhotite, and minor chalcopyrite occur within envelopes up to several metres from the veins. Arsenopyrite is confined to vein selvages. Local sphalerite and galena appear to correlate with gold-rich portions of the veins. Traces of tetrahedrite and stibnite have been observed but tellurides have not. Gold is found principally as thin smeared flakes of the native metal in the black sulphidic septae of the strongly ribboned veins. Hydrothermal alteration envelopes around the veins grade outwards from intensely foliated quartz - ankerite - sercite (±fuchsite) to less sheared calcite - chlorite - albite to unsheared epidote -calcite.Open-space vein filling textures found in the deep (mesothermal) environment at Bralorne can be explained by a fault- valve model. High-angle reverse faults may have acted as fluid-pressure activated valves on geopressured reservoirs, causing large cyclic fluctuations in fluid pressure that promoted mineral deposition in an episodic fashion . The faults that were mineralized were reactivated sub-vertical former strike slip faults, oriented at a high angle to the northeast-directed stress in a compressive regime."

Jan 1, 1990

By M. P. Tibbs

An autonomous spray application system for a structural Thin Spray-on Liner (TSL) is targeting productivity and safety on underground coal continuous miners by potentially replacing steel mesh, and has broader applications as surface support and confinement in metalliferous mines and civil tunnelling. Polymer chemistry, coating formulation, geotechnical assessment and the autonomous application system are being developed as an integrated package as part of a continuous miner automation project. This polymer-based TSL system has significant benefits over conventional steel mesh skin confinement, including being more automatable by spray application, providing complete skin confinement and active skin reinforcement as a fast-curing composite with substrate, and having effective fire retardant properties for the polymer and the underlying coal. This paper presents a preliminary assessment of distance sensing systems that would enable autonomous adaptation of a nominal spray path to spray a consistent thickness of TSL (nominally 5mm) over an irregular topography. Two alternate sensors are assessed; firstly, a 2D LIDAR mounted on a linear axis is used to produce a 3D surface profile for generating an adapted spray path; and secondly, a robot end-effector-mounted ultrasonic sensor is assessed for wall following techniques to dynamically adapt a nominal spray path.

Aug 1, 2013

Gold recovery from refractory ores can be very difficult and complicated depending on the causes of the refractoriness. Typically, a fine wind and/or the oxidation of the gold-bearing sulfide minerals are required to liberate gold from the host rock matrix. Mineral separation techniques, particularly surface¬wettability based separation (i.e., flotation) and magnetic separation, can be used to pre-concentrate the gold and sulfide minerals, or to remove mineral species that are harmful either to the oxidation of the gold-bearing sulfides or to the cyanidation following the oxidation. In this paper, several processes are described, including oil-agglomeration flotation recovery of fine-grained gold and sulfide, reverse flotation of carbonate minerals prior to pressure or bio oxidation, reverse flotation of elemental sulfur after pressure or bio oxidation but prior to cyanide leaching, and magnetic concentration of gold-bearing iron oxides. The integration of these techniques with gold hydrometallurgical processes may make the economic recovery of gold from an otherwise uneconomic refractory ore possible.

Jan 1, 2011

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are in northern Saskatchewan, 11 km west-northwest of the Rabbit Lake mine. Their average grade is 1.8% UJ0 8 and they contain 6,350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende.Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest mineralizing fluids were aqueous and at temperatures of about 200°C. Ar39/ Ar40 laser age determination of illite indicates mineralization began about 1300 m.y, ago and that significant hydrothermal alteration ceased about 1170 m.y. ago though Pb/U data suggest the deposits continued to evolve into the Mesozoic.The deposits are interpreted as the result of oxidizing ground water stripping uranium and other metals from either the Athabasca sandstone, especially the heavy mineral layers, or from the regolith, and precipitating these when encountering a warm reduced fluid emanating from the basement."

Jan 1, 1984

By Yongbao Zhu

The Ag2O-mediated reactions of cycloaurated compounds with a general formula Au(L)Cl2 (L = bi-dentate C?N ligand) with thiosalicylic acid, N-acetyl cysteine or 1,2-benzenedithiol in DMF proceeds via ligand substitution of the Au?Cl bonds to afford the S-O and S?S adducts all in good yields. The reactivity of the dichloro, S-O and S-S adducts towards thiols were examined by reacting with cysteine in an aqueous medium, revealing that all of Au-Cl, Au-O and Au-N are labile for thiol displacement. The measurement of the inhibitive activities of these compounds against human cathepsins B and K showed that the dichloro and S-O adducts are effective inhibitors with IC50 values ranging from 0.1 to 2.6 -M, and that the S-S adducts are inactive.

Oct 1, 2003

By H. Hao

This paper outlines the development of a 2-D axisymmetric mathematical model to predict the evolution of temperature during the Direct Chill (DC) casting of AZ31 magnesium billets. Model predictions of temperature have been compared to measurements made on an industrial DC casting machine at Timminco Ltd, in Haley, Ontario. These measurements have been used to fine-tune the thermal boundary conditions employed in the mathematical model, The model, which is based on the commercial finite-element code ABAQUS, has been developed as part of a strategic project aimed at improving the DC casting process for light metals through a reduction in casting related defects and increased productivity.

Jan 1, 2004

"During the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests.In the current case, a composite sample of gold ore is dedicated to a Gravity Recoverable Gold (GRG) test. The properties of interest are the head grade of gold, the size distribution of the material, and the gold assay per size class. The sample is mixed and a sub-sample is taken to measure the feed properties: the size distribution and the gold assay per size class. The remaining material of the sample is subject to the first stage of concentration using the laboratory Knelson concentrator. The concentrate is analysed in its entirety, while a sample of tailings is taken for the same analysis. The remaining part of tailings is subject to grinding to feed the second and third stages of concentration. Similar sampling is performed at each stage.The concentration performances are analysed in light of these measurements. But what is the accuracy of the measurements of the properties? Pierre Gy’s theory of sampling, associated with a heterogeneity model built using the GRG test results, will answer this question. The current paper presents, through a real example, the calculation of the errors of the measurements of size distributions and gold assays performed during the GRG test. The uncertainties of the concentration performances and liberation size estimate are then calculated and their impact on the results interpretation is analysed.INTRODUCTIONDuring the development of a mining project, samples are taken for metallurgical tests. The sample can be a composite sample made of material from a selection of various drilling products or a sample from a mining test. It can be also a sample from an existing plant in order to investigate process enhancement. This sample can represent several tonnes of material which are analysed and split for use in various tests. In order to take into account the ore variability in terms of gold deportment, it is recommended to perform variability studies (Dominy, Murphy, & Gray, 2011, Dominy, 2013) using samples representing various horizons or years of production. But for a given ore type, it can be necessary to perform many tests with different operating conditions (Brochot, 2012a). In that case, the variability of the samples is not due to the heterogeneity of distribution of the deposit, but only on the heterogeneity of constitution of the primary sample. The level of confidence associated with the estimated performance parameters is directly linked to the overall error (including sampling error) of the measurements performed during the tests."

Jan 1, 2016

By Ross Gallinger

In 1997 a group of Canadian mining companies met to review the Mine Environment Neutral Drainage (MEND) program and to consider future activities. They concluded (i) that Canadian industry and NRCan should fund a small secretariat in Ottawa to support technology transfer in Canada and (ii) that it was important for industry to continue the momentum of MEND on an international scale. The need for INAP (International Network for Acid Prevention) was strongly endorsed by company, university, consultant and government experts from Australia, Canada and the U.S. who were convened in Vancouver in February 1998. The initial focus was the development of a solid knowledge base covering the collective experience of INAP's members to promote the dissemination of successful practices, the identification of knowledge gaps and the formulation of effective research proposals. The sharing of information on past successes and failures alone was viewed as sufficient justification for the formation of INAP. INAP was officially launched in October 1998, and is now an effective, industry based initiative to globally coordinate research and development in the management of sulfide mine waste. Significant improvements in the management of sulfidic mine materials through knowledge sharing, research and development of technology by INAP will reduce liability associated with acid drainage. This paper will explore the international efforts and activities of INAP.

May 1, 2002

By S. Torizuka, I. Mizushima. Kawasakitohri, A. Ohmori, K. Nagai

Strain (work)-hardening in tensile tests were examined for low carbon steels with various ferrite grain sizes ranged from 0.4µm to 16µm. The steels had microstructures composed of ferrite grains and dispersed cementite particles. They were fabricated through warm caliber rolling with an accumulative area reduction of 93%. Strain-hardening rate at a given strain increased with an increase in volume fraction of cementite particles. The balance of yield strength and uniform elongation for ultrafine-grained structures could be improved by the dispersion of cementite particles. Effects of the cementite dispersion and the ferrite grain size on the strain-hardening rate can be roughly explained by the work-hardening model with GN-dislocation density. Strain-hardening design using dispersed cementites was proved to be effective in controlling ductility of the ultrafine-grained steels.

Jan 1, 2004

By Yue hua Hu, Wei Sun, Pan Chen, Li Wang, Runqing Liu, Central South University

"The flotation separation of muscovite from quartz was investigated using mixed sodium oleate/dodecylamine (NaOL/DDA) collectors. The flotation experiments were conducted on single minerals and their collecting performances were studied by means of adsorption amounts and molecular dynamics simulation. Flotation results show that muscovite presents good floatability while quartz exhibits poor floatability in alkaline condition. Adsorption amounts show that both NaOL and DDA can absorb onto surfaces of muscovite and quartz in presence of mixed surfactants. Molecular dynamics simulation indicates that DDA plays an important role in the adsorption of mixed surfactants on these two mineral surfaces. The molecules of mixed NaOL/DDA are arranged in a rigid and well-ordered packing on muscovite (001) surface. Only a few DDA adsorb on quartz directly, and rest DDA and NaOL molecule exist near by the quartz surface, forming a hydrophilic cylinder-like structure. This study may provide guidance for the flotation mechanism and application of mixed anionic/cationic collectors.INTRODUCTIONIn the past decades, there has been an ever-increasing demand for muscovite (KAl2(Si3Al)O10(OH)2) because of its potential applications in cosmetics, construction and metallurgy industries (Barlow & Manning, 1999). Besides, muscovite is an important carrier for some rare metals, including vanadium, titanium and lithium (SsuerrN, 1979). Quartz (SiO2) occurs as the main gangue mineral in muscovite ores, which results in a low purity of muscovite and limits its wide applications. Therefore, there is an urgent need for the beneficiation of low grade muscovite ores. Many studies remove quartz by screening and gravity separation in virtue of their differences in shape, hardness and density. However, these methods undergo poor efficiency in case of small particle size (below 50µm) of muscovite and quartz (Liubakka, Sullivan, Lamphere, Corradi, & Dykhuis, 2011; Santos, Franca, & Ogasawara, 2011)."

Jan 1, 2016

By G. E. Agar, W. B. Kipkie

"This paper deals with the prediction of locked cycle flotation results from data developed from individual batch tests. A postulate is made that the distribution of material in a separation stage is determined by the chemical conditions and the flotation time and that this distribution can be characterized by split factors which are constants for a fixed set of conditions. With this premise, it is demonstrated that a steady state balance can be calculated for a circuit.Although the necessary equations can be solved algebraically, a computer program was written that uses an iterative tec1nique to arrive at the steady state balance. The program is written so that a variety of circuits can readily be simulated.A number of examples are examined to demonstrate the validity of this simulation procedure. The sensitivity of the material balance to changes in the split factors was examined. Data developed from different flowsheets is presented on sulfide ores, on copper-nickel separation and on silver flotation,"

Jan 1, 1978