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By M. N. Pons, E. Benizri, B. Laubie, A. Bani, Université de Lorraine LRGP, P. Kidd, A. J. M. Baker

"Serpentine (i.e. ultramafic) outcrops in Europe cover more than 10,000 km2 and have a low-fertility and low-productivity, making them unattractive for traditional agriculture. In general, these areas are slowly abandoned by local farmers, affected by strong rural exodus and landscapes undergo a process of closure. However, ultramafic landscapes have the potential to provide multiple ecosystem services that can contribute to Europe’s goals towards insuring food security, production of renewable raw materials and renewable energy. Phytomining (agromining) aims at cultivating metal hyperaccumulator plants that are able to accumulate Ni and other strategic elements from metal-rich soils and transport them to the shoots (>1%), which can then be harvested as a bio-ore. Such metal-rich biomass can be used to recover highly valuable metals, e.g. nickel (Ni) and also to produce energy (heat, electricity). Nickel agromining can thus offer an eco-efficient alternative to classical pyro- or hydrometallurgical processes without disturbing the soil cover and the geology from soils and rocks that would be considered as low grade ores or sterile material for conventional mining methods.Phytomining agroecosystems can lead to better soil resource efficiency and can offer a fully integrated, new agromining agriculture that could cover thousands of km2 in Europe, benefit local communities with a sustainable rural development and provide a wide array of ecosystem services which will need to be optimised under a life cycle assessment methodology:1. Production of bio-sourced metal products2. Production of energy biomass3. Restoration of soil fertility for conventional agriculture (Ni stress)4. Limiting Ni intake by local populations and farmers5. Use and conservation of local biodiversity (plant and soil fauna and microflora) as cultivated ecosystems6. Store carbon in cultivated soils7. Enhance pollination activity at landscape level.Nickel agromining could therefore change the economical balance in historically-disadvantaged ultramaficregions of Europe"

Jan 1, 2016

By T. R. C. Aston, C. M. K. Yuen, J. L. Gilby

"The access tunnels for the Donkin-Morien Mine in Cape Breton, Nova Scotia, comprise two parallel tunnels driven through a sedimentary sequence of sandstone, siltstone and mudstone to intersect the Harbour Coal Seam under the Atlantic Ocean, approximately 3.5 km offshore (Fig. 1). The No. 2 tunnel was driven a total distance of 3579 m using a 7.6 m diameter Loyat full-face tunnel boring machine (TBM) and was supported by steel sets. The No. 3 tunnel was initially driven a distance of 1027 m using drill and blast methods (dimensions 7.6 m wide by 5.3 m high) supported by rock bolts and shotcrete. This tunnel was then completed (front March 1986 to February 1987) using the tunnel boring machine to a distance of 3573 m.During the period May 1983 to December 1984, a major geotechnical research program was undertaken in the Donkin-Morien tunnels by Golder Associates in conjunction w,ith CANMET and the Cape Breton Development Corporation (Yuen et al., 1985). The research program included the monitoring of the performance of the TBM and drill and blast drivages, and the study of the thrusting characteristics and rock-interaction of the TBM excavation. The main emphasis of the research program was on the collection of field data which was to be made available in the form of a comprehensive report for the future use of others who might wish to carry out a detailed interpretation and analysis. The information gained from the program was also used during the tunnel"

Jan 1, 1988

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

By A. L. MacAllister

"Keymet Mine lies on the Elmtree River 4 miles west of Petit Rocher and about 18 miles northwest of Bathurst, Gloucester County, New Brunswick. A good gravel road runs through the property.The deposit was discovered in 1880 when a vein 7 to 8 feet wide was re-ported. In 1883 the first shaft was sunk as part of an exploration program which was carried out sporadically until 1897, when the company dissolved. Activity on the property was intermittent until 1946 when the property was again staked and during the next year diamond drilling intersected the vein in several places. In December 1949 Coulee Lead and Zinc Mining Company optioned the property and held it until its sale to Keymet Mines Limited in June 1952. By July of the same year work had begun on a three-compartment shaft.Early development work was concentrated on the 150, 300 and 450 foot levels but the shaft has since been sunk to I,228 feet to allow for eight levels at intervals of 150 feet. Little lateral work has been done to date below the 600-foot level.The first mill constructed to treat the ore was to go into production in the spring of 1954, but was destroyed by fire. A second mill, having a capacity of 200 to 300 tons a day, was officially opened October 25th, 1954. Present shipments are zinc and copper-lead-silver concentrates.The rocks of the area are shale, conglomerate, limestone, and quartzite with minor interbedded volcanic rocks, all probably of Silurian age. Small plugs of Devonian acidic intrusions occur 3 miles east and about 5 miles northwest of the mine. Minor dykes of both acidic and basic rocks occur on the mine property. In many of the fine-grained sedimentary rocks the more brittle laminre have been brecciated and give the rock the appearance of an argillaceous conglomerate."

Jan 1, 1949

By John D. Galloway

Mining is one of the important primary industries of Canada, with a gross production in 1927 estimated at $241,773,000- the highest in the history of the country-and an impressive dividend record. It is quite apparent, therefore, that mining is a business worthy of the careful attention of the people of Canada. Furthermore, with a vast undeveloped territory more or less mineralized, it is highly probable that our mining industry will continue to expand indefinitely, with a consequent increase in production and in the amounts of the yearly profits distributed. In recent years, the public has taken a larger interest than formerly in mining-an interest, moreover, that is not academic, but primarily from the viewpoint of profits. It is quite evident that mining is a profitable business, at least to some, and the average man on the street, hearing of these profits, is attracted thereto. I have no doubt that many of you have .read in promotion prospectuses, with figures to prove it, that mining is the most conservative, the safest, and the highest-yielding business in the world. Now, a lot of this information is best judged by the old saying that "While figures don't lie, liars figure". At the same time, mining, properly conducted, is a profitable business, even though speculative, and undoubtedly much profit will come from Canadian mines in the future. In this paper my conclusions regarding mining investments are based largely on British Columbia experience, together with some slight knowledge of mining conditions in the other Provinces. It is considered, however, that the inferences drawn are applicable to mining throughout Canada.

Jan 1, 1928

By H. L. Cameron

General Statement In July, 1948, experimental aerial photography o shallow water zones on Northumberland strait was carried out by the Nova Scotia Research Foundation. This work was designed to test the feasibility of aerial photography for coastal surveys o various types, including seaweed and bottom detail surveys. In the course of the work at Lismore, undersea faulting was noted visually and was later clearly apparent in the photographs. In order to prove beyond doubt that the lineations photographed are actually faults, a ground check was made, and terrestrial stereoscopic photographs were obtained of these features where they intersect the shore line. There can be no doubt of their nature, and the type of faulting is probably thrusting due to compressive forces. This is indicated by the successive right- and left-hand displacements on intersecting faults. The age of the fracturing is post Lower-Pennsylvanian (Lismore) and is correlated with similar compression faulting in western Cape Breton. As far as can be ascertained, this is the first time that subsea faulting has been photographed, though it is quite possible that similar structures have been observed elsewhere. Location and Area Lismore is on Northumberland strait, approximately thirty-five miles east of Pictou (see index map, Figure 1). The area mapped from aerial photographs (Figure 2) is a strip approximately two miles long by a quarter of a mile wide. Figure 3 shows a stereo-pair of the aerial photographs used to construct this map. The terrestrial stereoscopic photographs (Figure 4) show one of the faults.

Jan 1, 1949

By A. Lemay, G. Morin, C. Desmeules

"Incorporated in 1976, Sidbec Normines was mandated to exploit a deposit of specular hematite at Fire Lake. A combined effort of three companies, Sidbec, which holds 50. 1 % of the actions, British Steel Corporation another 41.67 % and finally Quebec Cartier Mining, a subsiduary of U.S. Steel Corporation, with still another 8.23 %.The deposit is located 60 miles north of the town of Gagnon. The extracted ore is crushed, in a giratory crusher, to-8 11 chunks, and from there, it is transported, by rail, to a concentrator at Lac Jeannine.A concentrate containing 65.5 % Fe and 5.5 % Sio2 is produced, using conventional methods like autogeneous mil ls and spirals. The concentrate is then transported by rail to the Port Cartier installations.The installations in Port Cartier include a secondary concentrator, a pellet plant, and stockpiling facilities for pellets and concentrate. The pellet plant has two product lines in paralel, producing a total designed tonnage of 6 millions tons of iron ore pellets, of which 3mi11ions tons are used in direct reduction furnaces.The secondary concentrator is designed to remove a portion of the silica contained in the ore, usually less than 2 % Si02 should remain from the original 5.5 % Si02 in order to produce iron ore pellets which are well suited for use in direct reduction and electric furnaces."

Jan 1, 1981

By Kousuke Takahata, Hirofumi Yoshimura, Jun Nakahigashi

Studies of a protium treatment for grain refinement of a + ß type titanium alloy are reviewed and recent experimental results are introduced. Protium treatment consists of the following three processes: (1) protium absorption, (2) martensitic transformation and hot working, and (3) final treatment for protium desorption and recrystallization. A combination of these processes results in the ultra-fine grains of 0.3 to 0.5 µm in diameter with high angle boundaries. The ultra-fine-grained material exhibits superplastic elongation of over 9000%. Superplastic forming was successfully used to fabricate a denture base. These materials may be widely applicable as biomaterials in various medical industries.

Jan 1, 2004

By D. Yuan, L. Yan, M. J. Collins, P. Kalanchey, I. M. Masters

ABSTRACT Pressure oxidation tests have been conducted by Sherritt for a refractory gold-silver project in China. The feed contained 39 g/t Au and 970 g/t Ag; the major gold-bearing minerals were pyrite and arsenopyrite. Because the feed contained a significant amount of silver, which can be refractory to cyanide leaching after pressure oxidation due to the formation of argentojarosite, the test program included investigation of methods to enhance silver recovery. The “lime boil” process proved successful and was incorporated into the flowsheet. Gold extraction from the lime boil product solids was 95–98%; silver extraction was up to 94%.

Jan 1, 2013

By Y. Wang

Phosphates and fluorides are used as regulators for the removal of silicates from diasporic-bauxite both in direct and reverse flotation. While using dodecylamine chloride as a collector, micro-flotation studies showed that sodium hexametaphosphate has stronger depressing power on diaspore than on silicate minerals with increasing sodium hexametaphosphate concentration at pH 6.5, but sodium fluorosilicate shows poor depression on diaspore with increasing sodium fluorosilicate concentration at the same pH. Zeta potentials of diaspore and silicate minerals become more negative both in the presence of sodium hexametaphosphate and sodium fluorosilicate. Adsorption density studies indicated that the adsorption density of sodium hexametaphosphate on diaspore is much higher than that on silicate minerals at the concentration of 75 mg/L. FTIR spectroscopy studies show that sodium hexametaphosphate interacted with the Al atoms exposed on the diaspore and silicate minerals surfaces to form P?O?Al bonds through the P02 groups. It is possible that sodium fluorosilicate interacted through F- or [SiF6]2- with silicate minerals surfaces based on the analysis by AES.

Jan 1, 2006

By Peter N. Calder, Garston Blackwell

"The history and analysis of a structurally complex open-pit rock slope displacement are described. The failure involved part of the only haulage access to a major ore zone. The ongoing movement was monitored using an electronic distance measuring device and a continuous electronic system specifically designed for the problem. A major fault, infilled with a thick clay gouge, and intersected by other structural features, resulted in the transfer of weight to a rock mass acting as a buttress in the lower regions. Movements were affected by blasting vibrations and ground-water conditions. Remedial measures included limiting blasting levels and lowering the water table, following which mining was successfully resumed in the area.IntroductionBrenda Mines is situated in a mountainous region of the southern interior of British Columbia; the location is indicated on Figure 1 . The elevation is approximately 5000 ft , giving a climate typical of more northern areas. Temperatures vary from -30°C to + 30°C. A snowfall level of 400-800 cm is experienced from November to April. During the spring, a heavy runoff period occurs, increasing the pumping rate in the pit from a nominal 50* gal/min to 2000 gal/min.The orebody occurs in a fractured Jurassic rock mass referred to as the Brenda Stock; it is approximately 3000 ft in diameter and 1000 ft deep. The Brenda Stock was intruded into the Upper Triassic Nicola Group tuffs, breccias and argillites. Mineralization occurred in several stages in a relatively homogeneous quartz diorite host rock. Shearing, faulting and jointing occured later in many stages, producing mineralized clay gouge zones up to several feet in thickness'> , These gouge zones have a major effect on the stability of the pit walls.The structural geology of the pit walls is otherwise relatively simple. Figure 2 is a conventional pole diagram indicating the orientation of the rock structural systems which are present. The major system has an average dip of approximately 70 degrees to the south and strikes approximately east /west , it is not undercu t by the pit slope. Figure 3 is a photograph of part of the North wall on which this system is indicated.The basic pit design consists of a working bench height of 50 ft, with a final wall height of 100 ft between berm s and a 100-ft-wide berm every second lift. Combined with a local face slope of 50-70 degrees, the resulting wall slope, not including haulage roads, is 45 degrees. Figures 4 and 5 are generalized plans and sectional views of the pit."

Jan 1, 1980

By Galen Bauer

"Up until the mid 1960's, the only available methods for making continuous weight measurements were through the use of mechanical and electro-mechanical weigh scales. It was during this time period that a new concept in weighing was introduced. It was known and is still known as the nuclear belt weigh scale.During the early days of its appearance in the market place, many things were learned about its advantages and disadvantages for weighing various materials. As with many new devices, it had to go through a ""wringing out stage"" before it became accepted by the weighing industry. Even today, even though it is a proven device, there are skeptics who believe the nuclear belt weigh scale will not survive. Let me assure you, it is here to stay.. 'PRINCIPLE OF MEASUREMENTThe nuclear belt weigh scale consists of a ""C"" Frame assembly which houses the radioactive source (Cesiwn 137) and the radiation detector (Ionization chamber). The ""C"" Frame assembly is put in place around the conveyor belt as shown in Figure 1. The radiation source emits a fan shaped beam of radiation which covers the full width of the material being conveyed on the belt. Radiation which has passed through the material on the belt is detected by the ionization chamber which is located in the lower arm of the ""C"" Frame assembly. The ionization chamber changes the radiation energy into an electrical signal which is related to pounds per foot belt loading. This signal is transmitted to a highly stable amplifier which combines the pounds per foot signal with a belt travel signal from a digital tachometer which allowed the scale user to be able to monitor total mass being conveyed. Many so-called conventional type scales use belt speed rather than travel to obtain mass per unit time, and then integrate the signal to obtain their weight signal. This unnecessary step tends to erode the overall accuracy of the weighing system."

Jan 1, 1975

By C. G. Harris, R. Sluyter

The purpose of an undercut is to undermine a block of ore which will then proceed to cave into draw holes just below the undercut. Undercut-ting is the final and most vital phase in the development of an ore block. Since its purpose is to undermine and induce caving into a block of ore, great care must be exercised to avoid premature caving by removing only enough rock to permit undercut development to proceed. Several undercutting methods, used over a twenty-year period, are re-viewed and their suitability is com-pared with ideal requirements.

Jan 1, 1960

By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By Makarinskym F. M.

"This paper describes mechanical and operating modifications that were and are being made to current on-line flotation cells at Falconbridge Nickel Mines concentrators. Improved metallurgical performance and metal recoveries of some 3·4% over the past ten years are the end result of the modifications made. The paper acknowledges the contribution of operating, technical and maintenance personnel and the Company ""suggestion plan"" program. 1. INTRODUCTIONFalconbrirdge Nickel Mines Limited, incorporated in 1928 is a major product of nickel, copper,coba1t and other metals and minerals. The Canadian Nickel Division operating facilities in the Sudbury Area currently includes seven mines, two concentrators, and a smelter.For many years at all concentrators, improv0mcnts in metal recoveries have been continually under investigation. One area was to improve the flotation cell performance. This paper will deal with mechanical and operating modifications to the cells at the Strathcona and Falconhridge Ni-Cu sulphide concentrators, at the Sudbury Operations.One of the prime means to mineral beneficiation processing has been, and will continue to be, the basic froth flotation cell. The efficient operation of a flotation cell is the key to satisfactory metal selectivity and recovery. The essence of good design is simplicity. Changes to cell design can contribute to a significant improvement in metal recovery.Over the past 10 years, modifications to the flotation cells have contributed to an improvement of some 3-4” in mineral recovery. Providi11g tl1c initiative for improvements include operating, maintenance and technical personnel, as well as the employee suggestions submitted th1·ough the Suggestion Plan Program."

Jan 1, 1982

By Robert B. Parsons

"The new Ontario Liberal government introduced its first budget in October. The changes to The Mining Tax Act proposed in the budget are mean t 10 simplify the current system without any loss of revenue to the government. It goes without saying that some operators will benefit from the changes while others will pay more taxes after 1985.With regard to ongoing matters at the federal level, the proposed carve-out legislation and the issue of northern allowances are being discussed with government officials, and a small victory has recently been scored with regard 10 the laxation of certain share transactions of prospectors and grubstakers. A report on these issues is provided herein.Ontario BudgetOn October 24, 1985, Ontario Finance Minister Robert F. Nixon tabled a budget proposing several significant changes to both the Ontario Mining Tax Act and the province’s income tax legislation.Mining Tax ActA flat rate of tax and reduced processing allowances highlight proposed changes to The Mining Tax Act. The proposed changes, with a comparison to the existing system, are set out in Table I.The most significant change is the replacement of the graduated tax rate schedule with a flat 20010 tax rate. This is a welcome change for most mine operators who viewed the high rate of 30% on profit over $20 million as counter-productive.However, the flat rate of ta x may not be welcome to all operators. Generally speaking, operators with less than $ 10 million annual profit are better off under the graduated rate system, while operators with annual profit exceeding $10 million will benefit from the 20010 tax rate."

Jan 1, 1986

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012

By R. Roufail

Mineral liberation is accomplished by comminution and is the first step towards achieving successful downstream processes such as flotation or leaching. In metal mining, one of the most effective comminution methods that is used to grind particles below 10 microns is stirred milling. In this paper the study of particle breakage mode vs. mill operating parameters is addressed. Stirred mills' grinding action is mainly attrition, but operation can be manipulated to include breakage by compression or impact loading. Macro and micro analysis of particle breakage and grinding mechanisms are correlated. Macro analyses convey information that relates grinding mechanism to particle size and shape. It is speculated that the breakage mechanism in the horizontal stirred mills is massive fracture for the coarsest particles and attrition (abrasion) close to the grinding limit where the size reduction ratio approaches 1.0. For micro analysis, the particle breakage mode has a direct impact on fracture type either transgranular or intergranular. Intergranular particle breakage leads to higher mineral liberation compared to transgranular breakage. Similar minerals would have more homogeneous properties that convey a stronger bond compared to dissimilar, heterogeneous mineral bonds. Transgranular fracture requires higher energy than inter granular fracture; trans granular fracture toughness of pure single phase mineral is about 10-14 % higher than the intergranular fracture toughness. This communication presents the results of an investigation to assess how operating conditions can affect trans- vs. inter-granular breakage.

Jan 1, 2009

By M. B. Myers

The subject matter of this paper will be discussed under three main headings. 1.-Fire-Resistant Fluids: (a) the need for such materials, based on historical events; (b) a definition of fire -resistant fluids; (c) general description, characteristics, operational parameters, advantages and disadvantages of oil-in-water emulsions (HFB), water-polymer fluids (HFC) and anhydrous or synthetic fluids (HFD). 2.-A review of equipment associated with the use of fire-resistant hydraulic fluids; (a) performance testing of hydraulic equipment, i.e. gear pumps, vane pumps, axial and radial piston pumps, hydraulic motors, etc., pressure, speed, filtration limitations, etc., and effects on valves, elastomers, paints, etc.; (b) hydraulic system design features and selection of suitable units; (c) types of mining applications currently employing fire-resistant fluids. 3.-Test methods used to evaluate fire-resistant fluids: (a) fire testing methods, i.e. wick tests, spray ignition testing, hot manifold tests, factory mutual tests, all to establish fire-resistancy parameters and acceptance; (b) new developments in fire-resistancy evaluation; (c) the examination of other performance tests, e.g., effects of evaporation, sliding wear, life of rolling element bearings, etc.

Jan 1, 1979

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020