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By X. Zhou

"Hydrogen induced failure and degradation in structural metals, namely hydrogen embrittlement, has been a long-standing industrial problem for more than one century and remains unsolved. Despite the proposal of numerous models, no consensus has been reached, and considerable discrepancies in experimental observations and theoretical calculations exist. One aspect that is central to the understanding of hydrogen embrittlement is the interaction between hydrogen and grain boundaries. In this study, we investigated the influence of several solute elements (i.e., Cr, Mo and Nb) on hydrogen segregation at the representative 9 grain boundary using first-principles calculations. Our results showed that the presence of Mo and Nb can reduce the tendency of hydrogen segregation at grain boundaries, while meanwhile enhance the grain boundary strength. This indicates that Mo and Nb are salutary elements that can be used to increase the material’s resistance to hydrogen embrittlement, providing new insights in designing hydrogen embrittlement resistant Ni alloys. INTRODUCTION Hydrogen embrittlement (HE), a phenomenon of hydrogen triggering premature failures in structural metals, has been a headache for industries ever since its first discovery one century ago (Johnson, 1874; Zhou, Marchand, McDowell, Zhu, & Song, 2016; Zhou, Ouyang, Curtin, & Song, 2016). It is well accepted that the segregation of hydrogen at microstructures such as grain boundaries (GBs) plays a key role in determining the occurrence and severity of HE. GBs are two-dimensional defects where significant local lattice distortion exist, which leads to large free volume and thus locations for hydrogen trapping and segregation. Numerous works have clarified GBs as the energetically preferable places for hydrogen segregation. For instance, Geng et al. demonstrated the preferential segregation of hydrogen at the S5(120) GB in several metals, and suggested a decohesion-type of HE in light of Rice-Wang thermodynamic theory (Geng, Freeman, & Olson, 2001). Birnbaum et al. illustrated that complete intergranular crack of Ni GBs can be induced by hydrogen segregation when the hydrogen concentration is sufficiently high, evidencing the significant role of hydrogen accumulation on GB weakening (Lassila & Birnbaum, 1987). Yamaguchi et al. demonstrated strong segregation hydrogen also occurs at S3 GBs in alpha-iron, showing that local hydrogen clustering (i.e., multiple hydrogen atoms, up to six, per unit cell) can be trapped at the S3 GB (Yamaguchi, Kameda, Ebihara, Itakura, & Kaburaki, 2012)."

Jan 1, 2017

By H. Rafiei Renani, C. D. Martin

"The Cohesion Weakening Friction Strengthening (CWFS) is adopted in numerical analysis to capture the observed progressive failure of hard rock pillars. As a case study, pillars at the Elliot Lake mines with width to height ratios of 0.5 to 3 were analyzed in FLAC3D. Pillars with width to height ratios of 0.5 and 1 show a very similar strain softening behavior while with width to height ratios of 2 and especially 3 indicated prolonged strain hardening. The CWFS model successfully captured the mechanism of progressive failure observed in hard rock pillars including initiation of spalling at the corners, progress of spalling towards the centre and formation of hour-glass shaped pillar, and eventually shearing through the width of pillar. Both the CWFS model and site specific empirical formula successfully separated the stable and failed cases in the Elliot Lake mines. While both models are in reasonable agreement for width to height ratios of less than 2, the empirical formula gives increasingly lower strength values for wider pillars which may result in excessively conservative and uneconomical design.INTRODUCTIONPillars are the portion of in situ rock left between the adjacent openings to maintain the stability of excavations. Conditions of equilibrium require that the loads previously carried by the excavated rocks be transferred to the pillars resulting in elevated stresses within the pillar. Hence, prediction of the behavior of pillars under these loads is important for underground design. Determination of the strength of pillars is a classic subject in underground mining. In conventional mining methods such as room and pillar operations, economic incentives point towards higher excavation ratios i.e., leaving smaller pillars between the mined excavations, while safety and stability requirements favor wider stronger pillars. In some mining methods such as caving operations, the problem is even more challenging. On one hand, the whole operation is directly dependent on the proper continuous flow of caved ore between the drawpoints which requires optimizing the spacing between drawpoints and thereby often leaving narrower pillars. On the other hand, the pillars should be wide enough to ensure the safety of mining operation. Both the blockage of drawpoints as a result of wide pillars and uncontrolled failure of narrow pillars can jeopardize the investments and mining operation.Therefore, design of pillar poses a somewhat unique challenge to rock engineers where simple conservative approaches frequently used in other design methods are no longer acceptable. The behavior of pillar under elevated loads should be predicted accurately."

Jan 1, 2015

By A. L. Mular

"On behalf of Bob Bruce and myself I would like to begin by stressing some key points.First, most of us know that the Canadian Mineral Processors was formed in 1969 and is an offshoot of the Canadian Gold Metallurgists. I attended that first meeting in 1969, and I haven't missed a meeting since! Pretty obvious that CMP serves the best booze! At any rate, we know that our meetings are supported by CANMET. Camsell Hall is always at our disposal; Bob Bruce acts as permanent secretary pretty much free of charge; we receive a financial grant from CANMET. This brings me to a second point.Second the Canadian Mineral Processors do not enjoy a free ride in this relationship. CMP provides a genuine service to the mining industry, to government, and to universities. For the industry, CMP serves as a forum for the rapid dissemination of new ideas and new technology developed at remote locations throughout Canada. New developments outside Canada are introduced by invited speakers at our meetings. The effect is to help reduce operating costs and increase efficiency.For government, problem areas and research priorities can be isolated through mutual discussions. Direct communication at our meetings can help CANMET to temper its goals and modify its national priorities.For universities, CMP provides a wealth of operating experience and practical know how. The yearly proceedings are a major current reference source fo1· those of us who teach mineral processing. Admittedly, the proceedings are publ-shed from CMP coffers. However, I note that our fees are up this year, which brings me to a third point.Third, we face some potential problems of a financial and political nature. From a financial view, we may lose our CANMET grant and other financial good will simply because of spending constraints. Our fees are expected to climb each year thereafter.From a political view, we know that the metallurgical society of CIM is anxious to incorporate CMP as a section. The pros and cons of such a merger have been described in a recent mailing. In th2 final analysis, the political and financial problems are interrelated. There are several alternative solutions to both problems, which brings me to a fourth point"

Jan 1, 1979

By N. Lecuyer

"During early 1980, pre-production work commenced at the ""Les Mines Gallen"" project, north of Noranda, Quebec. As a result of the acid mine water associated with this property, a major pre-production phase included the installation of a water treatment plant to render the water environmentally suitable.This paper emphasizes the planning, installation and operational factors of the treatment plant necessary to the success of the mining operations and the maintaining of a clean environment.Introduction,T he Gallen Project is a zinc, gold and silver open-pit mining operation approximately 10 kilometres north of Noranda, Quebec. This property has a long history, with initial diamond drilling done in the early 1930s and underground mining taking place between 1953 and 1962. This property was reactivated in 1980, with production scheduled a t a rate of 45,000 ton s per month.Included in the reactivation plans for the property was the installation of a water treatment plant to treat the acidic mine water.Plant DesignThe requirements for the Gallen water treatment plant were two-fold. Firstly, it was necessary to neutralize the acid water and secondly to produce a sludge containing metal hydroxides and sulphates which would be stable when stored, and a clarified overflow meeting governmental regulations to be discharged to the environment.The flow sheet (Fig. I) will explain the process in treatment of the acid water.Acid mine drainage is treated with lime to increase the pH to 9.50. Metals in solution are precipitated as metal hydroxides and the 504 as calcium sulphate. The precipitate slurry is then aerated to convert ferrous iron to ferric iron, which is more stable for storage and disposal.The precipitate is next flocculated with a polymer flocculant and settled in the thickener to produce a sulphate/Hydroxide sludge and a final effluent discharged to the environment."

Jan 1, 1983

By A. Malfliet, A. Van den Bulck, D. Willems, M. Guo

The feed stock of copper fire refining processes consists of two major constituents: blister copper and high-Cu secondary scrap. A large fraction of this secondary scrap, originating from urban mining, is quite high in impurities such as Fe, Ni, Pb and Sn. Problems arise in electro-refining when these elements exceed certain limits. As a consequence, transformation of the secondary copper raw materials into high grade copper has become troublesome. However, the behavior of impurities relevant to fire refining conditions, essential for anode refineries, has not been studied in detail. Furthermore, limited research has been performed on the distribution of Ni between copper metal and slag. In this study, equilibration at 1300°C of liquid Cu-1wt.% Ni alloy and CaO-CuOx- FeOy-SiO2 slag in vacuum sealed quartz ampoules was performed for 12 hours, followed by water quenching. Electron Probe X-ray Microanalysis was employed to investigate the composition of the equilibrated alloy and slag. The distribution coefficients of Ni between slag and alloy were determined as a function of oxygen partial pressure and CaO concentration. INTRODUCTION Europe’s initiatives for a circular economy, pushing for resource-efficient ways for a sustainable future, puts Europe at the forefront of the globe. In Europe, 50% of the copper originates from recycling, being an excellent example of Europe’s circular economy (Juncker, 2018; Lacasse, 2018). High-grade copper recyclates are made available which regularly contain impurities like Fe, Ni, Sn and Pb. Aurubis Belgium is responsible for recycling these types of recyclates to anodes, cathodes and copper products. However, after fire refining of copper, the aforementioned impurities remain in the anode copper, leading to problems in electrorefining. During the fire refining of copper, a CaO-“Cu2O”-“Fe2O3”-SiO2 slag is used. Fundamental information of the distribution of impurities between the copper and this slag system is therefore essential to understand and improve the copper fire refining process at Aurubis Belgium.

Jan 1, 2019

By M. J. Michaud, M. J. Lavigne

"Abstract - North American Palladium Ltd. operates its Lac des Iles open pit palladium mine 85 km north of the city of Thunder Bay, Ontario. The Roby Zone deposit occurs within the mafic/ultramafic Lac des Iles Intrusive Complex (LDI-IC), which was created by multiple pulses of magma of varying composition within several closely spaced chambers. Chaotic lithological distribution, the presence of magmatic breccias, and the rarity of rhythmic layering suggest a dynamic intrusive environment with disruptive magma pulses. As of December 31, 2001, measured and indicated resources for the 950 m long by 815 m wide Roby Zone deposit totalled 159 Mt grading 1.55 g/t Pd, 0.17 g/t Pt, 0.12 g/t Au, 0.05% Cu, and 0.05% Ni at a palladium cut-off grade of 0.7 g/t. The Roby Zone contains an additional 73 Mt of inferred resources at similar grades.The Roby Zone is dominated by varitextured gabbro containing pipes and pods of breccia, and large blocks (~60 m across) of varying lithology. Mineralization at Lac des Iles occurs as: (1) a PGEand base metal-rich magmatic matrix of breccia (breccia ore); (2) mineralized dikes or sills (gabbronorite in North Roby ore); (3) lower-grade mineralization in varitextured units that are host to the distinctive breccia ore and envelope the North Roby ore; and (4) high-grade mineralization associated with strong silicate alteration exemplified by high-grade ore.The close spatial association of the mineralized breccias with both varitextured units and silicate alteration leads to an interpretation that the energetic magma that created breccia was charged with a dissolved fluid, and that this deuteric fluid exsolved at high temperatures to migrate through crystal mush, enhancing crystallization along its pathways, resulting in variable grain size. This transformation occurred at high temperature and produced sulfide-poor, varitextured gabbro-hosted mineralization exemplified by some of the mineralization in the North Roby Zone, and also found throughout the Roby Zone. The association of hydrous silicate alteration with mineralization can be explained by continuing fluid migration during cooling and continued metal transport. Résumé - North American Palladium Ltd. opère la mine à ciel ouvert de Lac des Iles située à 85 km au nord de Thunder Bay, Ontario. Le gisement Roby Zone est encaissé dans le complexe mafique/ultramafique de Lac des Iles (LDI-IC), lequel représente une intrusion polyphasée créée par plusieurs pulses magmatiques de différente composition à l’intérieur de chambres magmatiques fermés. La distribution chaotique des lithologies, la présence de brèches magmatiques, et la quasi-absence de litage rythmique suggèrent un environnement magmatique dynamique perturbé par l’introduction de nouveau magma. Au 31 décembre 2001, les ressources mesurées et indiquées s’élevaient à 159 millions de tonnes titrant 1,55 g/t Pd, 0,17 g/t Pt, 0,12 g/t Au, 0,05% Cu, et 0,05% Ni, pour une teneur de coupure de 0,7 g/t Pd. De plus, la Roby Zone contient 73 millions de tonnes de ressources inférées à une teneur similaire.La Roby Zone est principalement encaissée dans un gabbro de texture hétérogène (varitextured) caractérisé par des cheminées et des lentilles de brèches et des énormes blocs (environ 60 m de diamètre) de plusieurs lithologies. Au Lac des Iles, la minéralisation en EGP et en métaux de base se retrouve dans la matrice magmatique de brèches (breccia ore), dans des dykes ou des sills minéralisés (gabbronorite dans la zone North Roby ore), comme minerai de basse teneur encaissant le minerai de brèche (breccia ore) et enveloppant la zone North Roby. Du minerai de haute teneur est également associé avec une forte altération en silicates dans la zone high-grade ore.L’étroite association spatiale entre les brèches minéralisées et les unités de texture variée (varitextured) et l’altération en silicate suggère que le magma énergique qui a causé la bréchification était chargé de fluides. Ces fluides deutérique"

Jan 1, 2001

By Douglas W. Reeve, Hoc Nghia Tran, David Barham

"In kraft pulp mills, the spent pulping liquor is concentrated and used as fuel in the recovery boiler. Extensive deposits are formed in the upper section of the boiler due to the very high ash content of the fuel and the volatite nature of the ash. Deposits are composed of Na2S04, Na2C03 NaCI, some potassium salts and reduced sulphur compounds. Chloride and potassium salts are enriched in the deposits compared to the smelt due to their greater volatility.Severe corrosion of the superheater tubes in a recovery boiler has been traced to three factors: a non-uniform temperature profile in the flue gas, relatively high operating steam temperatures and high chIoride and potassium concentrations in the fireside deposits.The role of chIoride and potassium in superheater corrosion has been explained by increased Iiquid phase in deposits. Together with corrosion studies, this information has shown that kraft recovery boiler superheater corrosion due to the chloride and potassium enriched deposits can be avoided by proper boiler operation and by judicious superheater and furnace design.IntroductionThis investigation of recovery boiler superheater corrosion was initiated by the discovery of severe corrosion of the final stage superheater in a Canadian closed cycle kraft pulp mill(1,2). Metal wastage leading to tube failure was believed to be due to three major causes : the relatively high operating steam temperatures, the uneven distribution of flue gas temperature across the boiler which created a "" hot spot"" and the high chloride and potassium concentrations in the superheater fire side deposit. The mill responded to the problem by i) lowering the superheater steam temperature from 475°C to 380°C, ii) minimizing the chloride content in the spent pulping liquor, by controlling the NaCI input with recovered bleach plant effluent, and iii) changing metallurgy of a portion of the bottom section of the final stage superheater platens from ferritic steel T-22 (2.25% Cr, 1% Mo) to austenitic steel Incoloy 800H (21% Cr, 32% Ni, 46% Fe, 1.5% Mn, 1% Si, 0.6% Al) (Fig. 1). Details of the superheater corrosion experienced in the closed cycle mil! have been reported in previous papers(l ·2,) ."

Jan 1, 1984

By R. V. Fox, L. K. Sinclair, D. L. Baek

"In this study, rare earth elements were recovered from bastnasite concentrate and waste fluorescent lamp phosphors using supercritical carbon dioxide extraction with a nitric acid/tributyl phosphate adduct. Several pretreatment methods were used to alter the crystal structure of the source materials, and thus improve rare earth element recovery. Pretreatment methods included 1) dry roasting of the source material at 730oC, 2) decomposition with 50% sodium hydroxide solution at 150oC for 4 hours, and 3) decomposition with 12 M sulfuric acid at 300oC for 4 hours. Treated and untreated samples underwent supercritical extraction at 24 MPa and 65oC for 1 hour. Untreated bastnasite and phosphor samples showed <10% rare earth element recovery, but sodium hydroxide digestion resulted in >60% recovery for most rare earth elements. Dry roasting of the bastnasite concentrate was also effective, resulting in >60% recovery for cerium.INTRODUCTIONRare earth elements (REEs) consist of the 15 lanthanides, scandium, and yttrium. Scandium and yttrium are included because they are in the same group as lanthanum, appear in many of the same ore deposits as the rest of the lanthanides, and exhibit many similar chemical properties. REEs are used in a wide array of applications including electronics, magnets, catalysts, glass, and solid-state lighting (Xie, Zhang, Dreisinger, & Doyle, 2014). Because of China’s continued dominance of worldwide REE production, the United States Department of Energy has sought to diversify domestic supplies of REEs (United States Department of Energy, 2011). A key part of this strategy is the development of improved extraction methods for both ores and recycled sources.Supercritical fluid extraction (SFE) is a promising technology for extraction and separation of rare earth elements. Contact with an acid adduct dissolved in supercritical carbon dioxide allows for the rapid extraction of REEs from solid matrices. Supercritical CO2 has several potentially useful properties as a solvent, including high diffusivity and the ability to tune solvation properties by adjusting pressure. Such tunability may have applications in separating the REEs once they have been extracted from the solid phase. Tributyl phosphate/nitric acid adducts (TBP:HNO3) are a particularly promising class of adducts for SFE extraction of rare earth elements. Using TBP:HNO3 adducts in supercritical CO2, several researchers have successfully extracted REEs from their oxides (Wuhua, Pijia, & Yongjun, 2010; Zhu, Duan, Xu, & Zhu, 2009). However, there is a complication in applying this technique to many types of ores and recycled sources: REEs are often locked in refractory minerals which are resistant to acid attack, resulting in limited recovery in supercritical extraction."

Jan 1, 2016

By W. A. Plachner, Schiller E. A., S. P. Santiago

"The Monkman Coal Property is located in the Northeast Coal Block of British Columbia. It is divided into the Duke Mountain Block on the north east and the Dip Slope on the west. Together, these areas cover 39,503 ha of coal licences.The property is underlain by Jurassic and Lower Cretaceous marine and continental sedimentary rocks. Economic coal measures are contained within the Gates Formation. Exploration of the property began in the early I970s, with drilling commencing in 1975. To date, 255 holes have been drilled and nine adits have been driven to recover unoxidized coal samples.The property has a geological resource potential of 2.8 billion tonnes of medium and high-volatile bituminous coal. Medium-volatile bituminous reserves, totalling 68.9 million ROM tonnes at an over-all strip ratio of 6.3:1, have been identified in three pit areas in the Duke Mountain Block.Construction start-up will commence when sales contracts are arranged. The clean coal will be exported via the Ridley Island Terminal at Prince Rupert.IntroductionThe Monkman Coal Property is located in the Northeast Coal Block of British Columbia in the southern port ion of the Peace River Coalfield. The coal field encompasses a strike length of 250 km of Lower Cretaceous coal-bearing strata in which 13 companies have identified several billion tonnes of resources and several hundred million tonnes of reserves. Currently, two companies with contracts are in the construction phase, and are scheduled to produce coal by early 1984. Quintette Coal Ltd. has a contract with Japanese steel mills to supply annually 5.0 million tonnes of metallurgical and 1.5 million tonnes of thermal coal. Teck Corporation (Bullmoose property) has a contract to supply 1.7 million tonnes of metallurgical coal annually."

Jan 1, 1983

By Oliver B. Hopkins

"WE HAVE patterned our lives on the things we take from under the earth's surface. Our civilization is built upon the ore from which we obtain our metals and the fuels which power the world as we know it.Today I should like to discuss with you a newcomer to the ancient mining industry. This lusty infant of which I speak is just a century old - the oil industry.While one doesn't commonly think of oil men as delvers in the earth, It was by sinking a shaft that the first oil was obtained commercially in Canada. Men sank a shaft in a ‘gum bed' in southwestern Ontario's Lambton county, not far from Petroilia, and distilled from the gum a burning oil That was just a hundred years ago. The gum was originally liquid petroleum which had seeped to the surface and lost most of its volatile components.Later, the miners dug down to •bed-rock and soon after they were not digging but were drilling wells, as they have been ever since. From the wells they obtained erode oil.What is crude oil? It is not an element like gold, silver or lead, •but a complex mixture of compounds. These compounds are made basically from two elements, carbon and hydrogen, and are called hydrocarbons (Figure 1).The remarkable ability of these. Two elements to combine in different ways gives crude oil its physical and chemical character. The lighter hydrocarbon compounds in it are gases, at normal temperature and pressure, and these are dissolved in the other, heavier compounds."

Jan 1, 1952

By S. Nikolic, O. O. Kehinde-Philllps, O. T. Djamgouz, D. H. Rousell

"A bulk mining method is employed at the Lockerby mine resulting in the formation of large muck-piles. If these muckpiles remain in the stopes for some time they may agglomerate to the extent that the muck cannot be removed by a scooptram. A laboratory investigation was undertaken with sulphide material from the mine in order to detemine the time that oxidation begins and the flowability of the material as a f unction of several factors. The laboratory results are applied to the conditions in the muck-piles.The time of the beginning of oxidation of the material decreases as the sulphide composition, water content and availability of air increases. Oxidation is retarded by the addition of a copper sulphate solution instead of water. The unconfined yield force (strength} of the material increases with an increase in the sulphide composition, water content and time. The material ceases to be free-flowing before there is visible evidence of oxidation and this suggests that oxidation actually begins earlier and that agglomeration is also due to the capillary action of water.Broken ore should be removed from the stope prior to the time a muck-pile ceases to be free -flowing-perhaps as early as two days f or high-grade ore and 5 days f or low-grade ore. In order to control dust, 1.4 weight per cent of a 5 per cent solution of copper sulphate should be added 10 the muck-pile rather than water. This inhibits oxidation and increases the time that a muck-pile remains free-flowing."

Jan 1, 1984

By Bruce K. McKnight

"The new H-W orebody was evaluated by considering its production at three technically feasible rates. Capital and operating costs were estimated f or each rate and production sequences were established using mining cutoff limits generated by an ore value algorithm. The viability of the project was then examined by conducting economic and financial analyses of each of the three production cases under various world economic scenarios. These analyses employing standard profitability measures demonstrated all three cases would be economically viable; the production case which maximized the Net Present Value of the project was the one selected for development and production.IntroductionWestmin Resources Limited and its predecessor company, Western Mines Ltd., has been continuously carrying out mining operations near Myra Falls in Central Vancouver Island since December 1966. The mining operation, whose current production rate is approximately 830 tonnes / day (t/d), based on ore derived from the Myra and Lynx Mines, produces copper, lead and zinc concentrates which contain significant quantities of gold and silver in addition to the base metals.In the late 1970s, with Lynx and Myra ore reserves slipping to unacceptably low levels, a major increase in mine-site exploration was initiated, with outside geological staff brought in to complement the efforts of the mine&apos;s geological staff. By the end of 1979, this program had resulted in the discovery of a significant new orebody on a deeper horizon some 300 metres below the one which hosts the Lynx and Myra deposits. Throughout the period 1980-1982, major drilling was carried out to evaluate the new H-W deposit and by the end of 1982, drill-indicated mineral inventory for the deposit compared with Myra, Lynx and Price ore reserves was as shown in Table I. During this same three-year period, a major development and evaluation program was underway comprising environmental monitoring and control programs, shaft sinking test mining, bulk sampling and mill testing, rock mechanics studies and preparation of the Stage I and II reports for the multidisciplinary Environmental Land Use Committee (ELUC).As a result of the preliminary engineering work and exploration drilling, it became rapidly apparent that the H-W deposit could support a considerably higher production rate than the current one. Accordingly, engineering studies including scheduling of development and production as well as capital and operating cost estimates, were focused on three possible production rates: 1350, 1800 and 2700 t/d. Our task was to select the optimum one of these three rates."

Jan 1, 1987

By A. Flemming

"As the next century draws near, new mine properties must be brought into production to replace existing operations that are approaching their economic life. This paper presents some of the critical technical issues being addressed by Manalta Coal Ltd. as they strive to bring the Telkwa Coal Project near Smithers, BC into production during the year 2000. The mine is planned to produce between 1.0 to 1.5 million tonnes per year of medium volatile coal for export to overseas thermal and PCI markets. IntroductionManalta Coal Ltd. (Manalta) is proposing the development and operation of a surface coal mine and associated infrastructure approximately six kilometres southwest of the village of Telkwa, British Columbia (Fig. 1). The infrastructure consists of a coal washing facility, tailings disposal area, clean coal haul road, access road and rail loadout facility. Over a 25-year period, the mine is expected to produce between 25 and 37 million clean tonnes of coal primarily for the export market.To achieve public and governmental approval for the development, the project will be reviewed under British Columbia’s Environmental Assessment Act. Manalta entered the formal Assessment process in February 1, 1997 with the submission of an Application for a Project Approval Certificate for the Telkwa Coal Project."

Jan 1, 1997

By David Estrella, Hector M. Lizama, Jhonny Carrión

"Microcel™ sparging systems were installed on one column of the molybdenum cleaner circuit and one column of the copper first cleaner circuit at Antamina. The Microcel™ system is known to generate finer bubbles than jetting-type spargers, and smaller bubbles have been associated with higher recoveries in flotation. Alternating tests were carried out on the molybdenum column, using either jetting-type spargers or the Microcel™ system. Experimental conditions of gas flow rate, wash water rate, and froth depth were tested. Use of Microcel™ decreased the bubble sizes from 2.6-2.9 mm to 1.5-2.0 mm. In addition, Microcel™ improved both unit molybdenum recovery and unit molybdenum concentrate grade. In the copper first cleaner circuit, side by side tests were carried out that compared the Microcel™ column with a parallel columns fitted with jetting-type spargers. Best results were obtained at manifold pressures of 260-290 kPa, where bubble sizes of 1.6-2.6 mm were observed. In either copper or molybdenum flotation, the Microcel™ system required only 50-60% of the gas flow used by jetting-type spargers.INTRODUCTIONAntamina is a copper-zinc mine located in the Peruvian Andes. Compañía Minera Antamina is owned by BHP Billiton (33.75%), Xstrata (33.75%), Teck Cominco (22.5%), and Mitsubishi (10%). The mine was commissioned in 2001 with a capital investment of US$2.3 billion, and has a nominal 100,000 t/d mill capacity. Mining, milling, flotation, and tailings impoundment take place at the mine site, which sits at an altitude of 4,300 m above sea level. The deposit is a polymetallic skarn ore body with intrusive phases of quartz-monzonite porphyry into Cretaceous aged limestone [Evans et al, 2005]. Ore body thickness is 100 to 150 m and has the shape of a flat-lying crescent. Copper is present mainly as chalcopyrite with a minor bornite component. Zinc is present as sphalerite. Molybdenum is present as molybdenite. Some lead, bismuth, and silver are associated with the sulphides. The deposit is currently classified into six main ore types [Dechert, 2006], grouped into two categories: copper and copper-zinc. The mill produces four concentrate types: copper, molybdenum, zinc, and lead-bismuth. Copper, zinc, and lead-bismuth concentrates are transported by pipeline down to the port of Huarmey. Molybdenum concentrates are bagged and trucked to port."

Jan 1, 2008

By Kenneth L. Norris

Stonegate Agricom Ltd. is currently conducting exploration and development drilling of the Paris Hills Phosphate Project (Paris Hills Project) located in Bear Lake County, southeastern Idaho, 3.2 km west of the towns of Paris and Bloomington, Idaho. The project is located adjacent to a highway and 19 km by paved highway to Montpelier, Idaho where the Union Pacific Railroad system is located. Power and water are available locally. The nearest metropolitan centre is Salt Lake City, Utah approximately 225 km by road to the south-west of the property. The Paris Hills Project encompasses an area of approximately 856 hectares. Property holdings consist of three (3) patented lode mining claims and 16 contiguous fee parcels (some with federal phosphate leases). Active open pit phosphate mining operations are located in surrounding counties in south-east Idaho and are owned and operated by Agrium Inc., Monsanto Company and J.R. Simplot Company. The Paris Hills Project is located near the centre of the Western Phosphate Field which constitutes the most extensive phosphorite beds in the United States. Phosphate beds of the Western Phosphate Field occur within the Phosphoria Formation of Permian age and extend over an area of more than 350,000 km2 including extensive areas of Idaho, Utah, Wyoming and Montana. At Paris Hills the phosphate mineralized beds occur in the overturned limb and the horizontal limb of the Paris Syncline. Grades and thicknesses in both the western overturned limb and the eastern horizontal limb of the anticline are similar. The vast majority of potential mineralization occurs in the horizontal limb which underlies most of the property holdings. Mineralization in the overturned limb has a strike length of over three (3) kilometres and extends from the surface to a depth exceeding 300 m depending on location along the north-trending strike of outcrops. Depths of the horizontal limb range from surface along the north side of Bloomington Canyon to estimated depths of 915 to 1,035 m at Paris Canyon. The property contains an Inferred resource of 109.6 million tonnes at 23.6% P2O5 over two mineralized horizons. The phosphate zones have a strike length of over 3 km and extend from surface to a depth of at least 900 m. Drilling commenced late in the 3rd quarter of 2010 and is planned to continue through 2011. The drilling was planned to target an area of potentially higher grade phosphate mineralization and better define and upgrade the current resources.

May 1, 2011

By D. J. Robertson

"THE copper smelting operation of the Hudson Bay Mining and Smelting Company, Limited, at Flin Flon, Manitoba, generates a gas flow of 350,000 c.f.m. at n.t.p. This gas stream passes to atmosphere through a 20-foot diameter by 250-foot brick stack, carrying with it an appreciable dust burden in the form of metallic oxide fumes. The flow constituents during the period 1952 and 1953 and •before gas filtration was included in the treatment scheme are shown in Table I. This paper describes the gas filtration treatment which was installed in 1957, using glass cloth media to recover this dust burden, and discusses the associated problem as its treatment for recovery of zinc and cadmium.The metallurgical details associated with the problem are illustrated by a description of the material flow sequence of the Company's hydrometallurgical zinc plant and copper smelter. In this ore processing complex, the zinc plant and copper smelter form an integrated unit within which intermediate zincrich products of each operation enter the treatment circuit of the other."

Jan 1, 1960

By Yvon Trudeau, Deni Raymond

"The Orion gold mine, located 7 Ian northeast of the town of Malartic, Quebec, was discovered in mid-1985. Underground exploration was undertaken in 1986 leading to commercial production in 1988. The upper part of the orebody was exploited above the 125 m level and a total of 131 090 t at an average grade of 5.31 g/t gold were extracted.This paper describes the authors&apos; current knowledge and interpretation of the geology, gold distribution, and structure of the Orion No.8 ore zone deposit. The deposit is an epigenetic lode gold occurrence somewhat unique in that both quartz-vein type and pyritic type of gold ore occur side-by-side. It is located within the Marban-Noriartic Deformation Corridor (MNDC) formed during a first deformation stage (D1) The MNDC is a well-defined regional structural feature in the Val d&apos;Or - Malartic mining camp. Primary gold mineralization is associated with the D1 event and is represented by pyritized, silicified and brecciated basaltic lavas enclosed by ultramafic flow units. The ore zone is concordant with the MNDC. Felsic intrusions are spatially related with the ore zone, but their role in the genesis of the ore has yet to be dermed.A second deformation event (D2) resulted in local folding, a second schistosity (S2) and reverse faulting. Gold remobilization, the formation of the gold-bearing quartz breccia and the emplacement of the main quartz vein at the No. 8 zone deposit were associated with this event."

Jan 1, 1992

By Denis Raymond, Yvon Trudeau

"Abstract-The Orion gold mine, located 7 km northeast of the town of Malartic, Quebec, was discovered in mid-1985. Underground exploration was undertaken in 1986Ieading to commercial production in 1988. The upper part of the orebody was exploited above the 125 m level and a total of 131 090 t at an average grade of 5.31 g/t gold were extracted.This paper describes the authors&apos; current knowledge and interpretation of the geology, gold distribution, and structure of the Orion No. 8 ore zone deposit. The deposit is an epigenetic lode gold occurrence somewhat unique in that both quartz-vein type and pyritic type of gold ore occur side-by-side. It is located within the Marban-Norlartic Deformation Corridor (MNDC) formed during a first deformation stage (D1). The MNDC is a well-defined regional structural feature in the Val d&apos;Or- Malartic mining camp. Primary gold mineralization is associated with the D1 event and is represented by pyritized , silicified and brecciated basaltic lavas enclosed by ultramafic flow units. The ore zone is concordant with the MNDC. Felsic intrusions are spatially related with the ore zone, but their role in the genesis of the ore has yet to be defined.A second deformation event (D2) resulted in local folding, a second schistosity (S2) and reverse faulting. Gold remobilization, the formation of the gold-bearing quartz breccia and the emplacement of the main quartz vein at the No . 8 zone deposit were associated with this event."

Jan 1, 1992

By T. Grammatikopoulos, K. Gibbs, H. De Souza, C. Gunning

The mineralogy of any ore body is a key factor in defining ore zones and predicting minerals/metals behaviour during processing. The determination of forms of gold, defined as the different chemical states in which gold is encountered in ore deposits, is critical. The most commonly known form is that of gold minerals and alloys, while other forms of gold have been collectively described in the literature as submicroscopic gold (i.e., less than 1 µm in diameter). Gold mining operations generally deal with very low-grade ores, in the order of a few g/t, in which gold displays complex mineralogy. These difficulties complicate the mineralogical studies and pose challenges for processing and recovering the gold. A comprehensive understanding of the chemical forms of gold is necessary to define gold mineralization and optimize gold metallurgy. SGS Canada Inc. has been using QEMSCANTM and a Tescan automated SEM that are automated mineralogical techniques that provide vast amounts of data for microscopic Au. The data in conjunction with other physical and chemical methods provide a comprehensive delineation of the ore composition and behaviour.

Jan 1, 2011

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013