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While there is reasonable agreement on the basic chemistry of the slag fuming process, there has been an on-going debate for nearly 50 years as to the nature of the rate controlling factors in its industrial application. There have been advocates in the technical literature for thermodynamic limitations on the one hand or kinetic limitations on the other. The different viewpoints result in very different predictions as to the technical and commercial potential of the process. A resolution of the debate becomes of importance as pyrometallurgical processes are advocated as a means of extracting environmentally deleterious elements from metallurgical wastes. The present paper reviews the arguments in favour of both equilibrium and kinetic control and puts forward the view that much of the evidence for limitation of the process by kinetic factors under all conditions is unconvincing. It is maintained that the process can approach thermodynamic equilibrium under industrial conditions and that this determines the ultimate limitation on its technical performance. It is acknowledged, however, that kinetic considerations may cause the batch process to fall well short of performance predicted on thermodynamic grounds. The strong process limitation arising from the influence of chemical thermodynamics on the likely outcome of a hypothetical continuous fuming process is contrasted with optimistic forecasts resulting from the extrapolation of process models based only on kinetic considerations.

Jan 1, 2000

By D Laurence

Significant developments in future mining systems, technology and best practices are emerging that are driven by issues relating to human resources, competitiveness, environmental and social responsibility, within the dynamics of globalisation. It is proposed that the definition of the role and attributes of the mining engineer in the mine life cycle needs to be viewed more holistically in the face of increasingly more diverse and complex responsibilities. These developments are motivating the need to consider a fresh approach to mining education and training at all levels for industry. A growing diversity and complexity of professional responsibilities is extending the mining engineerÆs broadly based skill set and reinforcing the need to play a central role within increasingly interdisciplinary teams. On the other hand, the imminent new technologies that will transform the mining process are prompting the assumption that more focused and specialised skill sets will be needed. A way forward is suggested that would first define a blueprint for the future mine, as an attempt to characterise the systems architecture, processes and organisation of the next generation mine. This can be the basis for assessing the nature of the workforce and distribution of responsibilities, from which can be inferred the skills and training requirements. In the context of the mining engineer, the paper explores how understanding such future requirements will enable more proactive development of a strategy for educational development. The paper then concludes by considering issues and lessons learned from some recent mining educational development initiatives underway in Australia and Canada that are shaping significant change.

Jan 1, 2008

By F A. Roddick, C Swaminathan

As remaining gold deposits tend to become more refractory, some form of oxidative pre-treatment involving hydro or pyrometallurgy is necessary to maintain high metal recoveries. These pre-treatments include pressure oxidation, bio-leaching or roasting. In the past, the primary criterion for selection of oxidative pre-treatment relied mainly on the extent of gold recovery and relative economics. In this study, a different approach has been adopted, ie the quantitative determination of environmental performance of the oxidative pre-treatment processes bio-leaching, roasting and pressure oxidation to assess which had the least impact on the environment. By establishing the environmental performance of processes, waste minimisation can be addressed early in process selection. Using mass balances, the environmental theme method was applied to determine the performance, on the basis of gold treated, of the oxidative pre-treatment processes of selected plants. No clear trend was observed in the overall impacts of each of seven plants, with all but one of the environmental evaluation indices being of the same order of magnitude; this was probably due to masking effects arising from the large variations in feed composition, tonnage, and gold levels. Within each type of pre-oxidation plant however, certain trends were detectable. For instance, irrespective of plant size, ore composition or mineralogy, for the bio-leaching and pressure oxidation units, the general order of environmental impact from greatest to least was sequentially toxicity, acidification potential, depletion of resources, solid waste generation and greenhouse enhancement. For the roasters the acidification potential was the most significant. Determination of the environmental performance of the oxidative pre-treatment of a hypothetical ore in a plant of fixed tonnage was undertaken to remove the possible masking effects of variables associated with feeds of different mineralogy, gold tenor and tonnage. The bio-leaching process gave a marginally better performance than pressure oxidation, the roasting process the worst, although there was not a great difference between them. The decreasing order of contribution to the environmental index was acidification potential, toxicity, resource depletion, solid waste generation and greenhouse enhancement for bio-leaching and pressure oxidation; whereas it was acidification potential, solid waste generation, toxicity, resource depletion and greenhouse enhancement for roasting. Since the major contributor to the environmental index was the acidification potential, the environmental performance of treatment processes for the acidic effluents was calculated. After neutralisation of the net acid resulting from bio-oxidation and pressure oxidation, and the application of various scrubbing and product formation processes for the sulphur dioxide from the roasting process, it was shown that pressure oxidation gave a marginally better performance than bio-leaching, ahead of roasting. This study demonstrated the potential for the development of a predictive tool which could be used in determining the environmental performance, and thus the selection, optimisation, and improvement of pre-oxidation processes for least impact on the environment. These would allow operation of these processes within defined environmental performance limits and decisions regarding the desirability of processing various parts of a heterogeneous orebody to be made on environmental grounds.

Jan 1, 2000

This paper is a tribute to the late Dr Donald Martin Hausen as a father of applied mineralogy. His dedication to promoting the field through technical societies and through his professional work was outstanding, and his activities as a humanitarian are noteworthy. Dr HausenÆs involvement in technical societies included organising and conducting the only ICAM congress that was held in the USA, co-founding and nurturing the Process Mineralogy Committee within the American Institute of Mining, Metallurgy and Petroleum Engineers, and participating in CAM, the International Mineral Processing Congress, as well as other technical societies. The Process Mineralogy Committee that he co-founded has continuously organised annual meetings in the USA by conducting a series of sessions, and 17 books on the proceedings from those sessions have been published. As an applied mineralogist Dr Hausen solved many problems in exploitation and processing of minerals, metals and materials, especially gold. He helped to find many Carlin-type gold orebodies by outlining targets using alteration halos as determined by X-ray diffractometry, and he defined mineral characteristics that affected gold metallurgy and cyanidation. It is also noteworthy that Dr Hausen and his wife, Mary, opened their arms and home to many foster children and were instrumental in their placement in many homes. They also sponsored refugees from south-east Asia, taught them English, housed them, and provided constant support until the refugees became responsible and independent US citizens.

Jan 1, 2008

By Barns K. E, Munro P. D, Brindley S. K

Ernest Henry Mining Pty Ltd started production in August 1997. The Ernest Henry orebody consists of two distinct parts, a complex supergene ore zone overlying a primary ore zone. The economic copper minerals in the supergene ore are chalcocite

Jan 1, 1998

By Pinghui J

The paper describes the detailed hydrogeological studies carried out prior to the sinking of twin shafts at British Coal's new mine at Asfordby, Leicestershire, UK. The test methods for assessing potential groundwater inflows to the shafts are discussed and details are given of the ground freezing scheme employed through the major aquifer zone in the Sherwood Sandstone at a depth of 375 metres. During shaft sinking pressure recovery tests were carried out to further assess potential inflows and the results are compared with those from the surface tests prior to sinking.

Jan 1, 1988

By M Simpson, K Brodie, J L. Mauk

Subaqueous water-rock reactions that occur at the pit wall/lake water interface can affect the pH of pit lakes. Many pit lake water chemistry models neglect subaqueous reactions, which may create inaccurate predictions over time. A mineral quantification method is presented that defines the wall rock mineralogy of active open pit mines, using samples collected from the Martha Mine, a low-sulfidation epithermal Au-Ag deposit in Waihi, New Zealand. The mineral quantification method has five components: field observations and sampling, X-ray diffraction analyses, selection of representative samples, geochemical analyses, and mineral accounting. Predicted mineral concentrations closely match observed mineral concentrations visually estimated using petrographic techniques. Results of the method can be incorporated into a geochemical model of long-range pit lake water quality resulting from subaqueous water-rock reactions.

Jan 1, 2003

Increasing attention is being focussed worldwide on the strategic environmental assessment of mining projects, including consideration of cumulative environmental effects. In New Zealand there is now an end in sight for inappropriate delays in resource consent approval of responsible mining projects. This paper investigates six case examples of recently consented mining and quarrying projects, whose applications were notified. It also explores the nature of delays that occurred, the factors that contributed to the delays, and whether the consent process delivered fair and effective public participation and desirable environmental outcomes.

Jan 1, 2005

Over the last decade mineral exploration in New South Wales has increased markedly. This is due to various factors including the influx of overseas companies an. capital, increase and stabilization of metal prices and improvements in exploration techniques. The initiation of full-scale petroleum exploration and recent discoveries of large mineral deposits in the west, north-west and north of Australia has increased overseas capital, and brought scientists and technicians into the country. Naturally there has been an overflow into New South Wales, which is less attractive as an area for new and large-scale discoveries. In some fields, rise in metal prices and price stabilization has largely contributed to the intensif- ication of exploration. Increased tin production in New South Wales since 1963 is a direct result of price rise and stabilization, and rise in the price of silver has revived an interest in silver prospecting in recent Years,

Jan 1, 1969

The Manto Verde copper mine (Atacama Region, Chile) is due to go into production in 1996. It will produce 40 000 tonne/year of copper cathode by heap leaching/SX-EW. Mineralogical studies were undertaken in conjunction with the metallurgical testwork program to characterise the ore and its response to leaching by dilute sulphuric acid. The leachable copper mineralogy is dominated by the oxide copper minerals: brochantite and malachite with minor chrysocolla and atacamite. The gangue minerals include abundant orthoclase, specularite, quartz and chlorite with minor muscovite and trace smectite clay, calcite and limonite. The study showed that complete or partial decomposition of calcite, chlorite, smectite and wad consumed acid and generated solution impurities (Ca2+, Fe2+, Mg2+, A13+, K+, Si4+ and Mn4+2+ ). Although these were manageable at Manto Verde, their uncontrolled build-up could have affected the operation in several ways: the degradation of heap penneability and fonnation of crud in the SX plant from the precipitation of gypsum, goethite, colloidal silica and jarosite; and the entrainment of contaminated pregnant leach solution in the SX organic resulting in the transfer of impurities to the electrolyte and subsequent effects on cathode quality and electrowinning efficiency. In conclusion, process mineralogy played an important role in understanding and managing potential mineral-related problems in the heap leaching and SX-EW recovery of Manto Verde ore.

Jan 1, 1994

The "Industrial Minerals" sector of the Australian minerals industry over the past decade or so can be seen to be moving away from a somewhat ad hoc grouping of producers to a more highly integrated and sophisticated industry in which products are being more stringently specified and greater amounts of capital are being spent.

Jan 1, 1983

Mount Isa Mines Limited has been mining silver-lead-zinc ore at Isa Mine for 60 years. Mining methods have evolved continuously, and current production rates of 4.7 Mt/yr are obtained from a combination of sublevel open stopping, cut and fill, and benching methods. In the near future, orebodies mineable by open stoping will be gradually depleted, and the relatively new benching method will be further refmed to replace cut and fill methods wherever possible.

Jan 1, 1993

By Baynes F. J, Bermingham A. G

The 6000m long King Headrace Tunnel will be driven through hard Owen Conglomerate in the Eastern third and feldspar porphyry in the Western two thirds, with the anticipated hardness up to 350MPa unconfined compressive strength. Since the Commission had not driven a long, large diameter tunnel for some twenty years, major research was undertaken to assess the current tunnelling trends. Tunnel boring machines were compared with drill and fire equipment. Rail equipment was compared with rubber tyred equipment. Tenders were called with tenderers invited to submit alternatives if desired. Commissioning and production excavation using the equipment is discussed with the final conclusion being that the individual items of equipment purchased combined to make an efficient hard rock drill and blast system capable of progressing through all rock conditions likely to be encountered on the King and Anthony Schemes.

Jan 1, 1987

By Anylmore M, Walker A, Fletcher A

Roasting of sulphide and sulph-arsenide gold ores produces unwanted emission of sulphur and arsenic oxides, and a less than complete recovery of gold. Pyrite loses sulphur and arsenopyrite loses arsenic at a useful rate at temperatures of 600¦C and above in an inert atmosphere. Sulphur and arsenic driven off can be condensed before entering the atmosphere. During the process, solid-solution gold redistributes itself on internal surfaces of the resulting iron sulphide. Two subsequent processing options may be used; direct cyanidation of the porous sulphide resulting from the anoxic pyrolysis, or a second-stage roast to oxidise the remaining iron sulphide. The first option may be viable under certain conditions of pyrolysis. The two-stage option has an environmental advantage over the traditional roast because it reduces oxide vapour emissions by 50 per cent. The second stage may provide nearly enough energy to sustain the entire process.

Jan 1, 1992

An analysis of pumping figures suggests that there are two distinct styles of water inflow patterns in Zambia's mines. Carbonate hosted orebodies (Kabwe and Nampundwe) display a characteristic seasonal variation in water inflow with peak pumping showing a short time lag with respect to the rainfall pattern. Aquifer characteristics are controlled by secondary, weathering enhanced, near surface phenomena. Non-carbonate hosted orebodies such as those of the Copperbelt (Konkola and Nkana) occur in successions of highly variable lithology and consequently there are stacked aquifers of variable character. Inflow of water does not display seasonal variation. The major factors affecting the amount of inflow are the structural setting, the geometry of the orebody and the local lithostratigraphy. Thus the Konkola orebodies which occur in a saddle shaped open ended basin result in what is probably the wettest mine in the world, pumping some 376,000 cubic metres of water a day.

Jan 1, 1988

By Peverett N. F

The purpose of filtration in a gold reco- very plant is to separate the gold bearing liquid from the solids in the slurry. Some of the gold is inevitably lost due to incomplete separation. An investigation recently completed by the authors has brought to light a method of reducing such losses. In this investigation, the filtration pro- cess was represented by a steady-state mathema- tical model which took account of 14 indepen- dent variables and three parameters. One of the filters in the plant at West Driefontein Gold Mine in South Africa was isolated from the rest and fully instrumented. A computerized data acquisition system was installed close to the filter, and the data obtained from it served to test the model. Using the model together with an optimizing program, the optimum operating point for the filter as a function of throughput was found, and a control strategy developed to minimize the total gold losses in the filter plant.

Jan 1, 1977

Politicians and economists talk glibly about the so-called knowledge revolution. The reality is that knowledge is fundamental to economic progress. Consequently there have been many technological revolutions. The global impacts of the invention of the steam engine and the development of the frozen meat industry are well known. Another less publicised technological advance occurred in Central Otago late in the nineteenth century. This was the adaptation of the bucketladder dredge to the mining of placer deposits. A product of over 30 years experimentation and innovation, New Zealand dredging technology was taken to the Risdon Iron and Locomotive Works, San Francisco by R H Postlethwaite, a Dunedin based mining engineer. New Zealand-style dredges built by Risdon operated successfully in California, Alaska and the Yukon. Californian engineers assimilated the best features of the New Zealand dredges with American (Bucyrus) designs to produce a standard for the worldwide placer mining industry.

Jan 1, 2003

By A D. Farmer

Power ultrasound may be used in a number of ways to enhance the processing of minerals. It is both technically and commercially feasible to apply ultrasound to leaching processes in order to enhance the removal of contaminating minerals, or the rate and ultimate recovery of valuable mineral. When applied to the production of synthetic rutile from reduced ilmenite produced by the Becher process, its use proved beneficial to both the aeration and the final acid leach process. The enhanced performance is achieved through the very localised high energy release at the mineral surface from the collapse of cavitation bubbles produced by power ultrasound. This gives rise to two effects: initially, the rapid cleaning of mineral surfaces û of oxidation products and coatings of fine adhering gangue minerals û and the attenuation of the boundary layer at the mineral surface during leaching, which allows fresh leachant to contact the surface more readily.

Jan 1, 2000

The capacity of chlorine based solutions to rapidly and effectively dissolve coarse gold in oxide ores is well established. The inherent advantages of chlorine are high dissolution rates (10 - 100 times those of cyanide), and low cost. The high dissolution rates mean that coarse or poorly liberated gold may be dissolved over relatively short periods and hence ore particle size may cease to be such a critical factor. The cost of size reduction to allow adequate gold liberation in order to achieve an adequate gold recovery is less of a consideration when using chlorine than in traditional plant or heap leaching cyanide-based treatment systems.Because chlorine based solutions capable of dissolving gold evolve an unpleasant vapour phase with the potential for significant chlorine losses into the atmosphere, traditional heap leaching with active solutions being sprayed onto prepared heaps is not possible. The ore must be covered and the solution may be introduced beneath that cover through prepared injection `wells' and recovered through production 'wells'. The pit is flooded with active solution beneath an overburden or cover with the solution migrating from the injection 'wells' to the production 'wells' over a period of around five - ten days.

Jan 1, 1992

By M D. Urbani

HiTec Energy Ltd has been conducting research since 1996 into novel process routes for the treatment of low-grade and waste manganese sources for the production of high value and high quality electrolytic manganese dioxide (EMD) for the alkaline battery market. HiTecÆs approach is to treat previously unsaleable manganese deposits and mine site tailings using a novel sulfur dioxide leach route, followed by purification and electrowinning to generate the sought-after EMD product by an environmentally superior processing route to those presently practiced throughout the world today.HiTec Energy Ltd expects to be in commercial production with its Stage 1 facility in Kalgoorlie in the last quarter of 2004 for the production of 12 500 tpa EMD. With this production facility being adjacent to a laterite nickel producer with available waste manganese units, the opportunity arose for HiTec to combine its existing technologies with processes (that will be discussed in this paper) to turn two waste by-products into products that are used for high-tech purposes.HiTec Energy Ltd and the Parker Centre have had a collaborative research relationship for a number of years in areas involving EMD and battery related technologies. Meanwhile the solvent extraction (SX) group of the Parker Centre (CSIRO Minerals) has developed SX processes to separate manganese from nickel and cobalt. A project was initiated by HiTec Energy to recover manganese from waste laterite leach solutions using SX technology. Batch tests were conducted to select a suitable organic system for the extraction of manganese in terms of selectivity and extraction and stripping kinetics.A total of eight organic systems were tested by determining pH isotherms of metals using a laterite nickel process waste stream. Two organic systems, the Versatic 10 and Versatic 10/synergist systems, were chosen for further test work with Shellsol D70 chosen as the diluent for both systems.The Versatic 10/synergist system would be advantageous over the pure Versatic 10 system because fewer SX stages are required, resulting in a smaller organic inventory and lower capital costs. The risk of gypsum formation is also significantly lower with the synergistic system.

Jan 1, 2004