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By Willis G. M

Preliminary experiments have shown that, when used in a fusedchloride electrolyte, titanium carbide anodes dissolve yielding lower titanium chlorides which nlay be electrolysed in situ to produce a cathode deposit of pure titanium metal. The anode residues are easily withdrawn from the cell. Further experiments have established the operating conditions for maximum efficiency in the process.The process is essentially two-stage, viz.: (1) titanium carbide production, (2) electrolysis producing metal. Power requirements appear to be moderate and this fact, combine·d with the simplicity of the process make it attractive as a possible method for the production of titanium.INTRODUCTIONDue to the high reactivity of titanium and its, affinity for oxygen and nitrogen, the extraction of this metal generally involves the use of halide. compounds as intermediates. For instance, magnesium reduction of titanium tetrachloride is the basis of the well established Kroll process and electrolysis of the lower chlorides in a molten salt bath has been proposed by Cordner and Worner (1951, p. 358) and others (Brenner and Senderoff, 1952, 223C; The TitaI Company (Inc.), 1952) as means of production of the metal. Thedifficulty of preparation of these compounds prompted a search for an alternative extraction process. The fact that aluminium, an equally reactive metal, has been prepared by electrolysis using aluminium alloy anodes suggested the possibility of a similar process for titanium production.The Titan Company (Inc.) (1952) has patented the use of crude titanium metal anode, but it was thought possible that a metallic compound, such as the carbide, could be used for this purpose. Although Lorenz and Kaufler (1909) suggested the use of carbide anodes for metal production, no...

Jan 1, 1956

By Recepoglu O, Tolun R, Yavasoglu N, Bulutcu AN

Scheelite was floated from a low-grade (0.28 per cent W03) calcitic (96.30 per cent CaCO3) scheelite ore using oleoyl sarcosine as collector and alkylated 8-hydroxyquinoline as modifier. Compared to oleoyl sarcosine alone, the grade and the recovery of scheelite concentrate were increased from 8.07 per cent to 33.54 per cent and from 55.1 per cent to 73.4 per cent, respectively. Infrared studies with pure calcite and scheelite minerals showed that while alkyl oxine is adsorbed on the scheelite surface, it is not adsorbed on the calcite.

Jan 1, 1993

By Field R. V, Graieg O, George T. J

The design, construction and operation ofa laboratory scale rotary pot kiln are outlined. Charges ofup to 3 kg can be heated to temperatures up to 1200°C in a controlled atmosphere. Some examples of pyrometallurgical investigations carried out using the kiln are briefly described, including thermal reactivation ofcarbon using steam at 550-850°C, high temperature testing ofkiln liners for corrosion resistance to fluoride, and calcination oflimestone. Results obtained from these trials allow either direct scale-up to the Engineering Chemistry Laboratory's pilot-scale (50-100 kg/hr) rotary kiln or modifications to be made to commercial scale processes and/or equipment.

Jan 1, 1986

Queensland hosts vast deposits of brown and black coal, significant accumulations ranging in age from Permian to early Tertiary. The great diversity of coal resources in the State to some extent reflects the proximity of Queensland to plate-marginal tectonic processes through much of the Phanerozoic eon. Coal is contained within sedimentary basin fills of four fundamental types; 1. extensional, 2. foreland, 3. strike-slip, and 4. intracratonic. Thick (10 m+) though laterally restricted coal bodies are characteristic of extensional and strike-slip basins, whereas coals of more modest thickness but much greater lateral extent are typical of foreland and intracratonic basins.

Jan 1, 1991

By Weimin F

In the last decade, great strides have been made in the raise boring technique in China. Extensively, the drilling and blasting method has been replaced by the mechanized raising method since 1980. There are now over 3C raise drills operating in more than 20 mines. The diameters for shaft boring varies from 500mm to 2000mm, and to depths up to 90m. Tlis paper mainly describes the performance, mtLin technical achievments and applications of all four kinds of raise drills, and auxiliary equipment. Finally, some recommend- ations for future improvement in the raise boring technique are presented also.

Jan 1, 1987

By Mack JF

A metallurgical evaluation of the Argyle Kimberlite No. 1 (AKl) orebody has been carried out using a 40 tonnes per hour pilot plant. Pilot plant results, together with laboratory investigations provided a basis for the determination of process design criteria for a major treatment plant. Various sampling programmes were carried out to determine specific aspects in the evaluation of diamond liberation. Treatment parameters such as the top crush size, recrush size and the bottom cut-off size were investigated. A description of the pilot plant is given together with the design criteria for a 3 million tonne per annum treatment plant

Jan 1, 1984

The thick coal seams of the South Maitland field are the only ones in New South Wales which have been worked extensively to heights beyond 3.8 m (nominal "thin" seam height). Under shallow cover only minor difficulties were experienced in developing first workings but later the widespread occurrence of incidents of spontaneous combustion and the growth of "creeps" extending over large areas gave the field its own peculiar problems. As the mines have driven under deeper cover extreme difficulties in forming development roadways have been experi- enced. Various methods have been adopted in an attempt to overcome the problems of the field.

Jan 1, 1976

By Madgwick J

A novel method for determining viable cells of the mineral leaching bacterium Thiobacillus ferrooxidans has been developed. The cells were collected on 0.45/Lm cellulose acetate filters, washed with artificial minewater, and incubated in the presence of ferrous ion at pH3 in an atmosphere containing radioactive (14C) carbon dioxide. Colonies of bacterial growth were detected by the image formed on X-ray photographic paper (autoradiography). The method was compared with three conventional techniques and shown to detect three orders of magnitude more cells in cultures of Thiobacillus ferrooxidans in the late exponential phase of growth.

Jan 1, 1987

By Ushakov S

New geological and geophysical in vestigation including our detailed field observation in different regions of the Koryak upland testify that Nor- theastern Eurasia margin eastward of the Ochotsk-Chukotka belt is composed of a collage of allochtonous terranes arcs and sedimentary filling of back- arc basins, which bordered North East Siberia and Chukotka (1)1). Ancient island are assemblages are the most tipical for this region (2-4; shown by heavy line). They are marked by long (500-1000 km) volcanic belts which become younger towards the Pacific up the Latest Jurassic-Neocomi- an (2) to Late Cretaceous (3) and Pale- Gene (4).

Jan 1, 1987

Under South Africanncoalmining conditions, in the majority of instances coal is won using the bord and pillar system without pillar extraction. Examples demonstrate that strata control policy has an effect on practically all aspects of mining: (1) the choice of mining method; ((2) degree of coal recovery; (3) effect on productivity; (L}.) integration of'-support techniques with other operations. This is confirmed by use of modern research results and computer simulation. Although the examples are drawn from South African experience, the conclusion is generally valid. Strata control problems cannot be solved in isolation but as an. integral part of overall mining policy.

Jan 1, 1971

In any open pit mine some slope instability may be expected. This can range from small scale sliding on individual benches to large scale overall slope failure. This paper presents two case histories which illustrate how mining has successfully continued despite major pit instability. The common threads in each of these are listed below. 1. The recognition of the type and nature of movement (either regressive or progressive). 2. The successful application of simple monitoring techniques to minimise the potential impact on the mining operation, and 3. The management of the waste and ore excavation to avoid potentially damaging and costly situations.

Jan 1, 1986

By Khosrowshahi

A scientific approach to analysing grade control has been applied at a number of mining operations. By dividing the grade control process into the various stages of data collection and interpretation, errors can be identified using reconciliations of production against predictions. The merits of different mining styles in large and small open pit mines are examined.One factor in successful grade control is estimation of the expected ore loss and dilution. Empirical methods developed in two dimensions have been refined to enable 3D modelling of the effects on mineable grade and tonnage of varying the bench height, sampling orientation, and sampling Resolution.

Jan 1, 1992

By A R. Cruden, M S. Egglseder

The formation of banded iron formation (BIF)-hosted high-grade iron ore deposits in the Hamersley Province, Australia has been debated for decades. Although a structural control on their formation is widely accepted, only the roles of large-scale structures (ie faults and folds) formed by brittle and ductile deformation have been considered to date. However, the deformation of multilayered sequences in the Hamersley Province (ie the Mount Bruce Supergroup), with their contrasting rheological behaviours, creates challenges for understanding the complex structural framework at regional to deposit scales, including the significance for mineralisation and orebody location.Our approach to understanding these complex relationships is based on an established principle of structural geology, which is to extrapolate microscale structures to deposit-scale structures and vice versa, supported by state-of-the-art 3D modelling techniques. Complexly deformed hand samples associated with the Mount Tom Price iron ore deposit (Hamersley Province, operated by Rio Tinto Ltd) have been analysed and visualised with 3D explicit (Move™, Midland Valley Ltd) and implicit modelling software packages (Leapfrog™, AranzGeo Ltd) and supported by microstructural investigations (optical and X-ray microscopy) and fieldwork.Our study shows that the deformation of BIFs in the central Hamersley Province is controlled by microscale chemical processes (ie dissolution precipitation creep) due to rheological differences between iron oxide and chert layers, contrasting fluid flow properties and layer thickness variations. These processes account for the removal of vast amounts of silica, its transportation by diffusion in the presence of a fluid and reprecipitation at low-pressure sites. Consequently, this structural framework was used by different upgrading fluids to form iron orebodies.CITATION:Egglseder, M S and Cruden, A R, 2015. Evolution of a structural framework for high-grade iron ore deposits, in Proceedings Iron Ore 2015, pp 255–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Moxon N. T, Berndt J. R

BHP-Utah Coal Limited's Peak Downs Mine is located in Cen- tral Queensland, approximately 200 km south west of Mackay. The annual raw coal production of the mine is over 8 million tpa, requiring the removal of about 40 million cubic metres of prime overburden. This is achieved through the use of five large draglines. The large depths of overburden (up to 55 metres) encountered over half the strike length of the mine enables cast blasting to be carried out in conjunction with draglines employ- ing the chopping method of digging. The objective of cast blast- ing is to use explosive energy to move as much material directly into spoil as possible. The additional costs of drilling and blast- ing are offset by reducing dragline rehandle. Two factors which are of primary importance to the design of cast blasts are initiation control and material velocity. High speed motion picture photography is a powerful diagnostic tool to quantify these aspects of blasting (Winzer, Montenyohl and Ritter, 1979; Chiappetta et al., 1983; Anon., 1983). The objec- tives of such analysis are to: 1. Determine the burden velocity, 2. Determine the time to initial movement (that is, the inter- val between a face hole firing and the initial movement of the burden), 3. Check the accuracy of the initiation sequence. BHP Central Research Laboratories (CRL) and Peak Downs Mine monitored a cast blast in the mine's Winchester Pit on 18 August, 1988. The objectives of this exercise were to: 1. Quantify current cast blast performance, providing a base case for comparison with modified blast design. 2. Compare two orientations of angled holes within the blast. 3. Assess the effectiveness of cast blasting utilising an air-deck. 4. Check blast timing with respect to burden movement times.

Jan 1, 1989

By E Donskoi

In order to develop downstream processing routines for iron ore and to understand the behaviour of the ore during such processing, extensive mineralogical characterisation is required. To determine mineral associations, mineral liberation and grain size distribution, imaging techniques have to be used. There are two main imaging techniques used for the characterisation of iron ore, ie, Optical Image Analysis (OIA) and Scanning Electron Microscopy (SEM). In this article a QEMSCANTM system is used as an example of SEM methodology and results obtained from it are compared against results obtained by the CSIRO ‘Recognition3/Mineral3’ OIA system.Both OIA and QEMSCANTM systems have advantages and drawbacks. Even though the latest QEMSCANTM systems can distinguish between major iron oxides and oxyhydroxides, it is still problematic for QEMSCANTM to distinguish between iron ore minerals very close in oxygen content, eg haematite and hydroheamatite, or between different types of vitreous goethite.QEMSCANTM also can misidentify minerals with close chemical composition, ie haematite as magnetite and vitreous goethite as haematite. In OIA, iron minerals with slight differences in their oxidation or hydration state are more easily and directly recognisable by correlation with their reflectivity. In both methods, the presence of microporosity can result in some misidentification, but in SEM methods misidentifi cations due to microporosity can be critical. Low resolution during QEMSCANTM analysis can significantly affect the textural classifi cation of particle sections.The main conclusion of this study is that, for low iron content ores or tailings, QEMSCANTM can provide much more detailed information on the gangue minerals than OIA. However, for routine characterisation of iron ores with high iron content and containing a variety of iron oxides and oxyhydroxides, OIA is a faster, more cost-effective and more reliable method of iron ore characterisation. A combined approach using both techniques will provide the most detailed understanding of iron ore samples being characterised.

Jul 11, 2011

By R W. Henley, L Knuefing, M Turner, Y Zhang, M Saadatfar, A Limaye, R Cruikshank, M A. Knackstedt, A Kingston, L Beeching, N Francois

A better understanding of ore fragmentation and the textural features of ore is a key to the energy efficient extraction of targeted minerals from low-grade ore deposits. In this study, X-ray microcomputed tomography (micro-CT) is employed to study mineral liberation during the tensile failure and onset of fragmentation of a copper ore. Our results show that X-ray micro-CT could inform new studies of ore micromechanics and fragmentation at the laboratory scale and may offer new avenues to address current challenges in the design of efficient comminution processes. We present the results of experiments based on a high-pressure apparatus enabling micromechanical studies to be carried out in situ (inside a micro-CT scanner). This platform produces high-quality 3D images of the evolution of a sample of porphyry copper ore during an in situ fragmentation test. A sequence of tomographic images enables mapping in 3D of both the deformation of mineral phases and the fragmentation process. The fragmentation occurs quasistatically through multiple stages starting with an initial tensile fracture splitting the ore diametrically, followed by tensile-activated nucleation and growth of multiple fractures producing a complex fracture network. Coupling breakage with microstructural information enables quantitative determination of the impact of ore texture heterogeneity on fracture patterns and mineral liberation. This microstructural information can be compared to key measurements of the ore mechanical behaviour such as the global deformation energy, strain deformation field and the stress relaxation response. The latter allows one to identify interesting precursor signals of the tensile failure. The copper liberation, fragment size distribution and breakage patterns are statistically characterised and related to comminution mechanisms which are clearly identified in the sequence of tomographic images. The two dominant mechanisms are rock-rock friction/compression induced by fracture closing and compression-driven fragmentation at rock-crusher contact points.

Aug 24, 2022

By A Purchase, C Stacey

The procedure for operation of deluge systems installed in road tunnels is still a subject of debate. The work undertaken in this paper assists in the understanding of the effects of deluge in road tunnels, and thus aims to help inform the development of operational policy. Analysis was undertaken using computational fluid dynamics (CFD) simulations to help explore the deluge interaction with the tunnel ventilation (including smoke exhaust) and combustion products. It was found, for the scenarios considered, that: Deluge activation can decrease the required critical velocity for smoke backlayering, and this in turn can improve the effectiveness of a smoke exhaust system.The dominant parameter for deluge effectiveness is the vehicle configuration, with shielded scenarios (such as a fire in the passenger compartment) showing almost no water reaching the fire. The water delivery rate (5 mm/min versus 10 mm/min) has only a minor effect on the smoke duct damper inlet temperatures and downstream smoke temperatures for small fires (5 MW). For large fires (50 MW) the higher water delivery rate gives slightly improved performance (lower damper inlet temperatures and lower downstream smoke temperatures). A one-dimensional transient tunnel model incorporating different operational and deluge response policies (ie deluge activation times) was developed. It was used to examine the influence of different operational parameters on life safety risk and tunnel damage risk. It was found, for the scenarios considered, that: The life safety risk for different scenarios has a sensitivity to deluge activation policy with the case of delaying the deluge activation for a long time giving the worst outcomes. However, the most critical parameters for life safety risk are operator response time (for all response activities, not just deluge) and the type of fire (configuration, size and growth rate).There is a reduction in risk of tunnel damage when the deluge is activated earlier, although the fire configuration (ie whether or not the seat of the fire can be reached) has the greatest influence on the outcome. It is concluded that the deluge activation policy should be case-dependent. It will depend on the tunnel, the safety systems provided, and most particularly the vehicles involved. The current policy in Australian tunnels is for manual activation of the deluge by the tunnel operator as soon as practical after the fire is confirmed (see also PIARC, 2007). This is a good policy. However, future work may be helpful to improve the skills of operators to make the best judgement as to when deluge should be activated, balancing all risks. This work could include research to further the understanding of deluge and fire in road tunnels, training programs and consideration of historical fire events.

Jan 1, 2008

By K Barbosa, G Wilkie, F Reyes, V Jokovic, C Evans

The idea behind Grade Engineering is to exploit the natural heterogeneity of an orebody (spatial, temporal) in order to divert low-value waste out of the mining value chain. Essentially, this involves rejecting material at relatively coarse particle sizes (10 mm to 200 mm). However, lack of knowledge about the inherent particle grade distributions in these coarse particle size ranges limits the opportunities for optimisation. Particle grade distributions are essential for quantifying and modelling gangue liberation and yield curves. These curves can then be used to predict the mass and value flows that will go towards the accept and the reject streams. Particle grade distribution information for particles coarser than 10 mm can be collected based on chemical assays of sufficient number of individual particles. However, for smaller particles (1 mm to 9 mm), a significantly larger number of particles is required for assays. Moreover, in some cases, the mass of individual particles is smaller than the minimum mass required for chemical assaying. Also, other quantification techniques such as automated mineralogy, eg Mineral Liberation Analysis (MLA), require extended measurement times to analyse statistically representative numbers of particles at these size ranges. This work investigates the use of 3D X-ray microtomography to fill this quantification gap at these size ranges (1 mm to 9 mm). In-house image processing algorithms are used to estimate the mineral/metal content in each particle. Particle grade distributions, as well as density distributions, are thus produced without a minimum mass requirement and with each scan providing information about tens to hundreds of particles at a time. Mineralogical data from MLA analysis, of finer size ranges, is used to inform X-ray microtomography, so a simpler 3D mineral map can be obtained using the image intensity. Chemical assay information of the scanned samples is used to validate and correct the mineral phase segmentation.

Aug 24, 2022

By R Frew, E Wong, G Ferguson

The Chang Jiang Tunnel and Bridge Project, when completed, will provide a fixed link between ShanghaiÆs rapidly developing Pudong District and Chong Ming Island, situated in the Yangtze River delta. The link includes 7.5 km of bored tunnel from the Pudong to the intermediate Changxing Island from where the link comprises viaduct and a cable stayed bridge. The bored section comprises twin 13.7 m internal diameter segmentally lined three-lane highway tunnels. At its deepest point the tunnel will be 55 m below the river. Cross passages will link the two bores for passenger evacuation. Tunnel boring commenced in October 2006 and is scheduled for completion in mid-2009. The paper describes the key features of the design and construction of the bored tunnel by two 14.53 m diameter slurry TBMs and eight cross passages using ground freezing techniques in alluvial sediments. A decision to include light rail below the road deck was taken after the completion of the detailed design. This posed a number of design challenges including passenger evacuation to the road deck, and the redesign of the low point sumps. The various options considered are discussed together with those adopted for construction.

Jan 1, 2008

By I Jabouri

There are many physical factors that can affect the self-heating rate of coal. The presence of seam gas has often been referred to as inhibiting coal self-heating due to the limited access of oxidation sites created by the presence of the gas adsorbed on the coal pores. Similarly, the presence of bed moisture in the coal also acts as an inhibitor of oxidation by blocking access of air into the pores. Gas drainage of a coal seam prior to mining removes both gas and moisture from the seam. Bulk coal self-heating tests in a two-metre column on both gassy, as-mined and gas-drained, dried high volatile bituminous coal show that removal of gas and moisture from the coal accelerates the rate of self-heating to thermal runaway from 8.5 days to 4.25 days, from a start temperature of 30¦C, with an airflow of 0.25 L/min. The corresponding gas evolution pattern for each of these situations is different. Therefore, it is necessary to take this change in coal condition into consideration when developing a spontaneous combustion management plan.

Jan 1, 2005