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Jan 1, 1962

By E. P. Mathewson

(Butte Meeting, August, 1913.) IN a discussion -of a paper on " The Basic Process as Applied to Copper Smelting," by Percy C. Gilchrist, read before the Society of Chemical Industry, London, Jan. 5, 1S91,1 Prof. W. C. Roberts Austen asked Mr. Gilchrist whether he thought that the substitution of a basic lining for acid lining in the Marshes process would afford anything like the service which it had been shown to render in the metallurgy, of iron. Claude Vautin stated that he had experimented for over two years with basic linings for Bessemer converters for copper mattes at Cobar, but had given up the attempt on the score of cost. Mr. Gilchrist in his reply stated that he did not believe in applying any system of Bessemerizing to copper. About the time of the presentation of the paper mentioned, Herman Keller, Superintendent of the Parrott smelter, in Butte, was experimenting on a large scale with converters lined with magnesite brick. He gave up the idea on account of the cost of linings and because no particular advantage was observed. My belief is that his tuyeres and converters were -too small. A short time; afterward similar experiments were tried at the Great Falls plant of the Boston & Montana Co., said at the Old Works of the Anaconda Copper Mining Co. in Anaconda. These were abandoned on the score of cost and the lack of advantages. The same cause of failure, in my opinion, holds here. The Anaconda Copper Mining Co., however, adopted the magnesite brick lining for its tilting casting machines.

Jan 6, 1913

By Russell Dayton

THE metallurgical polarization microscope has been utilized in several researches in the last few years, thus attaining a fair degree of prominence, but little has been written in a manner suitable to a metallurgist concern-ing the theory of this instrument. In this investigation the theory was carefully studied, and the results are presented here in a detailed manner, yet as simply as possible. The theory is discussed with particular reference to the three chief functions of the instrument: (1) determination of anisotropy; (2) effect of strain; and (3) identification of inclusions. Each of these is investigated experimentally, with especial attention to the mechanism of producing any effect. Where possible, the discussion is supplemented by photomicrographs. The instrument used had numerous defects as a polarization microscope; these and their remedies are discussed. In the microscopic study of transparent mineral sections (chal-cography) the use of polarized light has aided tremendously in the identification of a mineral. The determination of strain in transparent substances (photoelasticity) by the use of polarized light has lately become a commercial process, used in testing finished glass articles. The success of the use of polarized light with opaque materials has not been so great. The magnitude of the effects obtained is much less than that of the corresponding effects with transparent materials, and the mechanical difficulties are much greater. Konigsberger,(1)? in 1909, was the first to apply polarized light to the microscopic study of

Jan 1, 1935

By Leon Eliel

TEN years ago a broad knowledge of aerial mapping, coupled with a smattering of geology, qualified one to speak on the subject of the appli-cation of aerial mapping to geology. Today, with aerial maps a common tool in the hands of expert geologists on every continent throughout the world, it would be nothing short of presumptuous for the author of this paper, who is not a geologist, to give any geological statements on his own authority. Relatively, today we are only purveyors of general geological gossip, with a definite case here and there by way of illustration. But we can present a story of the really marvellous strides that have been made in the evolution of aerial mapping, built around a skeleton of geological tidbits, from which some useful conclusions may be drawn. The average geologist goes about reading his aerial maps much as one would approach the problem of deciphering a cryptogram. To begin with, typical key expressions appear in recurring sequences and under certain conditions. If once the meaning of these isolated bits of infor-mation can be ascertained, the message begins to take meaning. In a similar fashion, the geologist works out his key from aerial maps of territory with which he has some familiarity. He learns that a certain type of thin, white line may mean a vein of quartz. He sees that a certain change in the photographic tone of vegetation on the ground reflects two kinds of soils on opposite sides of, a contact. He sees that a certain type of alignment of topographical features often means a fault. He learns that by the erosion pattern .he can frequently distinguish soft formations from harder ones. And so, bit by bit, he ties together the information of the picture with his experience on the ground until he develops a reasonably creditable capacity of interpretation. Through the complete gamut of surface conditions, ranging all the way from flat, arid, exposed desert terrain to dense jungle, or rugged mountains, the evidence from which the geologist must make his inter-pretation varies with bewildering profusion. The quality of photographs which are obtainable may range from perfect pictures in the desert to almost useless smudges in the steaming jungles. One thing he has learned with certainty-the airplane carrying its mapping camera is a superb reconnaissance tool, only awaiting his ingenuity in correlating the pictures with the ground to simplify most exploratory problems.

Jan 1, 1936

By S. Andrew Kulin, L. Kaufman

A general treatment of the broadening of X-ray double-crystal spectrometer rocking curves due to distributions of tilts and strains has been carried out. The results of this treatment have been applied to the case where dislocations in a crystal give rise to both tilts and strains. On this basis it is found that the rocking-curve halfwidth due to imperfections in the crystal, ßC , increases with increasing Bragg angle, 8. These considerations predict linear relationships between & and tan2 , and ßCand tan 8, for Gaussian and Cauchy distributions of dislocations, respectively. The zero intercept of the ßC us 8 curve, which is a measure of the degree of imperfection of the crystal, is found to depend directly on the distribution rather than the number of dislocations. In addition, the slope-intercept ratio for the ßc - ? curve has been calculated for both the Gaussian and Cauchy distributions. Experimental determination of the - 8 curves for a series of copper single crystals prepared by the Bridgeman and Czochralski methods yields results in agreement with the calculated slope-intercept ratio for a Cauchy distribution of dislocations. CERTAIN X-ray techniques have been used to study the perfection of single crystals. Gay, Hirsch, and Kelly have considered the spreading of spots into arcs on Debye-Sherrer rings due to imperfections. The Double-Crystal Spectrometer has also been applied to this problem.2 The characteristics of Double-Crystal Spectrometer Rocking Curves have been described in the literature by various workers.2-4 By assuming a random spacing of dislocations which give rise to a Gaussian distribution of misorientations relative to some mean orientation in a crystal Gay, et al.,1 arrive at the conclu- sion that the most probable misorientation is given by where h is the spacing between dislocations, and 8 and are the relative misorientations of neighboring regions. If ßC is the halfwidth of the rocking curve (the width at one-half the peak intensity) due to dislocations in the crystal then5

Jan 1, 1960

By E. H. Mohr

At the McGill concentrator of the Nevada Consolidated Copper Co., all flotation operations have been carried out in Forrester cells since November, 1926. In respect to cost of operation, the new cell has proved to be superior to the Callow, which it supplanted, and its incorporation in the flow sheet has resulted in a marked improvement in the metallurgy. Before citing the advantages of the new machine over the old, it should be explained that the Forrester has not only replaced the Callow, but it has made possible the elimination of a number of tables as well. When Callow cells were in use, table concentration preceded flotation. The ball mill pulp was elevated, by means of air lifts, to roughing Wilfley tables situated two floors directly above the flotation floor. On an intermediate floor were additional tables which cleaned the concentrate from those above. The finished table concentrate constituted approximately 60 per cent. of the total mill production, and contained about 40 per cent, of the recovered copper. The table tailings were returned to the classifiers, the overflow from which went to the flotation cells and the oversize to the ball mills. As soon as the Forrester cells were installed, this tabling operation was discontinued. The ball mill pulp now discharges into the classifiers direct, without the intermediate tabling. It was impracticable to ernploy the present flow sheet when Callow cells were in use, for the reason that unless the great,er part of the heavy mineral was first removed, it accumulated on the mats and adversely affected the flotation operation. By tabling ahead of flotation, it was practicable to maintain the concentrator at 10 to 20 per cent. greater capacity (depending up on the pyrite contnt of the ore) than was possible by flotation alone. This was due to the necessity for finer grinding in the latter case. Even though the table conecntrates contained only 6 to 8 per cent'. copper content, the low smelting costs made it advantageous to operate at high mill capacity, at the cost of low grade of product. Standard Section equipment With the old flow sheet, a standard section consisted of four ball mills and classifiers, one air. lift, 20 roughing tables, 10 cleaner tables, 12 primary

Jan 1, 1928

By Alden B. Greninger, Victor G. Mooradian

Microscopic examinations of quenched (beta) 60:40 copper-zinc and quenched (beta) 74:26 copper-tin alloys have frequently disclosed long, thin parallel bands or markings within the polyhedral beta grains. Apparently, it has been accepted that these markings are mechanical twin bands, although there is no published account of experimental data that might tend to substantiate this belief for the copper-zinc system, and only meager evidence has been submitted for the copper-tin system. Johnsonl0 commented upon the markings he observed after deforming a quenched brass of 55.6 per cent copper and 44.4 per cent zinc. Clark's papers4 on the heat-treatment of Muntz metal contain many photomicrographs of markings in beta brass; these she referred to as Neumann bands (inasmuch as repolishing and re-etching failed to remove them) and stated that markings present in Muntz metal as quenched were the result of shock imparted during the polishing operation. Van Wert18 first suggested that these parallel markings in quenched beta brass (60:40) might be alpha precipitated along certain crystallographic planes of the matrix lattice. He showed that upon reheating the specimens to temperatures below 800" C., obvious precipitation of alpha within the large beta grains first occurred at the markings. In a discussion of this paper, Phillips stated (pp. 505-507) that in his opinion the markings observed by Van Wert were mechanical twins resulting from contraction strains produced during the quenching operation. In a study of segregate structures in beta copper-tin, Smith17 observed that in the quenched beta phase (containing 74.92 per cent Cu) parallel . bands or markings very similar to those in metastable beta brass could be

Jan 1, 1938

By Alden B. Greninger, Victor G. Mooradian

Microscopic examinations of quenched (beta) 60:40 copper-zinc and quenched (beta) 74:26 copper-tin alloys have frequently disclosed long, thin parallel bands or markings within the polyhedral beta grains. Apparently, it has been accepted that these markings are mechanical twin bands, although there is no published account of experimental data that might tend to substantiate this belief for the copper-zinc system, and only meager evidence has been submitted for the copper-tin system. Johnsonl0 commented upon the markings he observed after deforming a quenched brass of 55.6 per cent copper and 44.4 per cent zinc. Clark's papers4 on the heat-treatment of Muntz metal contain many photomicrographs of markings in beta brass; these she referred to as Neumann bands (inasmuch as repolishing and re-etching failed to remove them) and stated that markings present in Muntz metal as quenched were the result of shock imparted during the polishing operation. Van Wert18 first suggested that these parallel markings in quenched beta brass (60:40) might be alpha precipitated along certain crystallographic planes of the matrix lattice. He showed that upon reheating the specimens to temperatures below 800" C., obvious precipitation of alpha within the large beta grains first occurred at the markings. In a discussion of this paper, Phillips stated (pp. 505-507) that in his opinion the markings observed by Van Wert were mechanical twins resulting from contraction strains produced during the quenching operation. In a study of segregate structures in beta copper-tin, Smith17 observed that in the quenched beta phase (containing 74.92 per cent Cu) parallel . bands or markings very similar to those in metastable beta brass could be

Jan 1, 1938

By Kenneth K. Humphreys

INTRODUCTION What is automation? Why automate? Webster's New Collegiate Dictionary defines automation as "the automatically controlled operation of an apparatus, process or system by mechanical or electronic devices that take the place of human organs of observation, effort, and decision." This definition gives an implied answer to the second question, )"Why automate?" Automation, automatic control devices and process control equipment receive their justification in supplementing or replacing manpower, which results in decreased operating costs. In the past, processes were operated with a minimum of instruments for the purpose of merely guiding the operators. Processes were manually controlled by the operator on the basis of simple temperature, pressure, flow and level indications on a panel. Today the tendency is to design a new plant to operate in a fully automatic manner according to a preset pro- gram utilizing a minimum of manpower. In addition to this direct cost reduction savings in manual labor, increased equipment capacity results from uniformity of flow and uniform control of process variables. This control eliminates or minimizes surges and permits equipment to be operated at or near its ultimate capacity and, for a given material through- put, permits the use of smaller process equipment. Automatic control, therefore, be it in the field of coal processing or in any industrial field, is simply a problem of economics. Control equipment is justified in terms of its contribution toward increasing productivity, increasing profit margins or producing a new and saleable product at a profit. Instruments and control devices can be divided into two general groups: (1) units which measure, and (2) units which both measure and control a process variable. In coal processing, the first class of instruments, those which measure only, include analytical devices such as automatic ash, moisture and sulfur measuring units and the simple pressure, temperature, flow and level indicating devices mentioned previously. The second group of instruments, those which both measure and control, include a wide variety of units such as continuous weighing devices on conveyor belts and photoelectric cells which gauge the position of railroad cars on the track and insure that the cars are in the proper location for loading (see Chapter 15). The latter types of units as used in the coal industry differ from those used in other industries in one significant point. In coal processing these instruments need not be as highly sophisticated and accurate as in other industries; hence their cost is proportionately lower than in other industries. Because of the economic fact that coal sells for only a fraction of a cent per pound compared to dollars per pound for many chemical products, and

Jan 1, 1968

By Y. G. Shiau, J. E. Burke

Several attempts have been made to account for the fact that grains in a fully recrystallized metal will coarsen on annealmg. Two fundamentally different hypotheses have been advanced, with several variations of each. One school considers that the cause of grain growth is the surface energy of the grain boundary. The theory of Jeffriesl that grain size and grain size contrast control growth is an example. The second school considers the primary cause to be a difference in the lattice energy on either side of the grain boundary. The more perfect grains are considered to grow at the expense of their less perfect neighbors, with a decrease in free energy, and a consequent increase in the stability of the system. Burgers2 presents the case for the strain or lattice imperfection theory of grain growth quite completely. The latter theory is attractive, since there is no doubt that differences in lattice energy or lattice perfection can cause grain boundary migration. A recrystallization nucleus grows for this reason as was beautifully demonstrated by van Arkel and Ploos van Amstel.³ Although it is generally stated that grain growth does not precede recrystallization, several workers4-5 have shown that small strains may induce a single crystal in an aggregate to grow, or at least may cause some grain boundary migration. The origin and nature of the imperfections that are considered to be responsible for normal grain growth have never been clearly described, but it is generally agreed that they are a consequence of the difficulty of atomic reorientation in the solid state, and that they do not seriously differ from the type of imperfection that can be introduced by mechanical deformation. An object of the present work was to determine whether the introduction of mechanical deformation would cause grain growth in a specimen which would not otherwise show it under the conditions used. It was also planned to determine the effect of such deformation on the rate of growth in a specimen which would show growth in the unstrained condition. Recently Maddigan and Blank6 have indicated that slightly strained specimens of alpha brass can undergo considerable growth prior to recrystallization if annealed at low temperatures. French7 has reported that at deformations less than 17 pet it is very difficult to detect the beginning of recrystallization in the same material. It was therefore planned to broaden this work to include a complete study of the microscopic behavior of alpha brass under condition~ of temperature, time, grain size and deformation such that recrystallization would not occur or would occur to only a Small extent. Experimental Procedure The brass was prepared by melting cathode copper and commercially pure zinc

Jan 1, 1949

By J. E. Burke, Y. G. Shiau

Several attempts have been made to account for the fact that grains in a fully recrystallized metal will coarsen on annealmg. Two fundamentally different hypotheses have been advanced, with several variations of each. One school considers that the cause of grain growth is the surface energy of the grain boundary. The theory of Jeffriesl that grain size and grain size contrast control growth is an example. The second school considers the primary cause to be a difference in the lattice energy on either side of the grain boundary. The more perfect grains are considered to grow at the expense of their less perfect neighbors, with a decrease in free energy, and a consequent increase in the stability of the system. Burgers2 presents the case for the strain or lattice imperfection theory of grain growth quite completely. The latter theory is attractive, since there is no doubt that differences in lattice energy or lattice perfection can cause grain boundary migration. A recrystallization nucleus grows for this reason as was beautifully demonstrated by van Arkel and Ploos van Amstel.³ Although it is generally stated that grain growth does not precede recrystallization, several workers4-5 have shown that small strains may induce a single crystal in an aggregate to grow, or at least may cause some grain boundary migration. The origin and nature of the imperfections that are considered to be responsible for normal grain growth have never been clearly described, but it is generally agreed that they are a consequence of the difficulty of atomic reorientation in the solid state, and that they do not seriously differ from the type of imperfection that can be introduced by mechanical deformation. An object of the present work was to determine whether the introduction of mechanical deformation would cause grain growth in a specimen which would not otherwise show it under the conditions used. It was also planned to determine the effect of such deformation on the rate of growth in a specimen which would show growth in the unstrained condition. Recently Maddigan and Blank6 have indicated that slightly strained specimens of alpha brass can undergo considerable growth prior to recrystallization if annealed at low temperatures. French7 has reported that at deformations less than 17 pet it is very difficult to detect the beginning of recrystallization in the same material. It was therefore planned to broaden this work to include a complete study of the microscopic behavior of alpha brass under condition~ of temperature, time, grain size and deformation such that recrystallization would not occur or would occur to only a Small extent. Experimental Procedure The brass was prepared by melting cathode copper and commercially pure zinc

Jan 1, 1949

By F. Keller, J. D. Edwards

THE anodic treatment of aluminum presents problems of scientific as well as of commercial interest.1-3 Of particular interest is the fact that, during the anodic oxidation process, the oxide continues to form at the metal-oxide interface under any oxide previously formed. This has led to speculation as to the mechanism involved in the formation of the relatively thick oxide coatings that are used commercially for decorative or protective purposes. Furthermore, the ability of certain types of oxide coatings to adsorb dyes and other substances has stimulated research to determine the actual structure of these adsorptive coatings. It has been found that anodic oxide coatings on aluminum are composed essentially of aluminum oxide. They are formed by the action of oxygen ions penetrating to the metal surface during the electrolytic oxidation treatment. These coatings can be formed in a number of different electrolytes, as for example, those which contain sulphuric acid, chromic acid, oxalic acid, or boric acid. These are the commonest and most useful electrolytes employed commercially. Except for certain specific conditions of formation, the coatings in general have been found to be amorphous alumina, as far as can be determined by X-ray or electron-diffraction methods. Anodic oxidation processes can be arranged in three rather general classes if they are grouped in relation to the solvent action of the electrolyte on the coating.4 In the first class, the electrolyte has little or no solvent action on the coating that is formed. In general, coatings produced under such circumstances are nonporous and non- adsorptive. In the second class, the electrolyte exerts an appreciable solvent action on the coating. These coatings are porous and adsorptive. Finally, for the third class, the electrolyte tends to dissolve the coating about as rapidly as it is formed. This action produces electrolytic brightening or anodic polishing of the aluminum surface and at most leaves only a very thin film of oxide. The nonporous and nonadsorptive type of oxide film is represented by the coatings that are formed when solutions of boric acid are employed as the electrolyte. It is especially significant that these impervious films are formed in electrolytes that exert little or no solvent action on the coating. Where a boric acid electrolyte is used, the coating tends to form rapidly, with the result that the flow of current is soon reduced to substantially zero. This indicates that the growth of the coating has stopped. As a rule, the thickness of the coating is roughly proportional to the voltage employed for formation and the coatings of this type are exceedingly thin. In an electrolyte of this type, the coating has a high resistance when the aluminum is made anode; consequently, any current that may flow (leakage current) is very

Jan 1, 1944

By J. V. Emmons

It has long been known that the outside skin of tool steel frequently exhibits properties widely different from the interior of the mass.

Jan 1, 1915

By L. W. Saperstein, Y. J. Wang

The development of computer programs to solve complex ventilation networks has reached a point of refinement where these programs become a necessary tool of the ventilating engineer. Such a program is presented. This program has an increased efficiency over its predecessors; it also includes the important facility of fixed quantity branches. This is in addition to the earlier capabilities of free-splitting, internal or external fans, and natural ventilation pressures. The program is written in Fortran IV with double-precision arithmetic and is listed here. Sample problems with input and output are also given. The recent, and presumably continuing, official interest in mine safety is bound to result in more stringent control requirements for ventilation. Anticipating this requirement, the Dept. of Mining, The Pennsylvania State University, has developed a computer program for the solution of complex mine ventilation networks. It is the opinion of this department that the program has sufficient merit to warrant its use in normal industrial operating conditions. Although the undergraduate mining engineering students of this department are routinely trained to use the program, it was felt that this training did not present a fast enough means of dissemination; consequently, this paper was written. The conception of the program is not new;1; however, the present version incorporates features that changes it from a scientific endeavor to a useful operating tool. These features include those of earlier programs, such as free-splitting, external or internal fans, and natural ventilation processes plus the important ability of handling fixed quantity branches, and of increased efficiency giving reduced cost. The facility for fixed quantities will be discussed in more detail. The solution of any network depends upon satisfying Kirchchoff's laws. These state that the sum of flow at any junction is zero, and that the sum of the pressure drop in branches totals the pressure drop in the mesh constituted by those branches, that is that the pressure drop around any mesh is zero. The terminology is derived from Synge," and is, in fact, that used by Topologists. A branch is any airway of uniform characteristics; a junction is where two or more airways meet (the minimum number of two airways is useful for describing the point where a low resistance airway changes into a high resistance one due to some physical constriction); a mesh is a path, along some branches, that returns on to itself, but does not need to traverse the same branch twice in order to do so; and a tree describes all those branches in a network which, while connected through all the junctions, do not form any meshes. Obviously the branches-in-tree are open-ended and can be shown to be one less than the number of junction (J-1). The branches-out-of-tree, also called basic branches, are equal to the number of basic meshes and are M = N — J + 1, where M is the number of meshes and N is the number of branches. The major difference between this network and an electrical one is that the law attributed to Atkinson for pressure drop is utilized rather than Ohm's law. Atkinson stated that the pressure drop (potential) is equal to a resistance factor multiplied by the quantity squared. This is written H = RlQlQ where H is the head loss. Q? is written in this factored fashion so that H will always have the same sign as Q. A negative sign is used to indicate that flow in a branch is opposite to that of its containing mesh. A mesh takes the direction of its basic branch. Utilizing Atkinson's law in Kirchchoff's second law and bearing in mind that the first law must remain satisfied, the program will determine all quantities, or head losses as they are related, for the branches of the network. The program uses a Geuss-Seidel form of in-teration, starting from an arbitrary Q and using a correction factor of the type first suggested by Professor Hardy Cross' that will handle the nonlinear equation of Atkinson's law. A fuller description of the interative process is included in Wang and Hartman.' Iteration continues until the correction factor is less than or equal to a preset error (E) or until a maximum number of iterations (MAXIT) have been reached. Utilizing an E of 50 cfm, sample problems have had rapid solutions. Rapidity of solution is also ensured by the method of selecting meshes and basic branches. This is done by the computer, which chooses the highest resistance branches, fixed quantity branches, and those containing fans, as basic branches. Natural ventilation pressures are handled as fans of constant pressure and may be assigned to any branch. The computer will generate a fan characteristic by polynominal fitting if a few operating points from the desired fan are input. A fan may be placed in any branch of the network, except those with fixed quantities. The strength of the present program over its earlier versions is its ability to handle fixed quantity branches. This means that certain branches can have their quantity determined, or preset, by the ventilating engineer. Operating under this constraint, the program will analyze the network and output the pressure change necessary to achieve this desired quantity. A call for positive head loss would require an auxiliary fan; negative head loss would require a regulator. This represents a powerful tool for the ventilating engineer who must insure that certain quantities of air pass across the operating faces or through working stopes. McPherson6 suggested that a ventilation program would be useful for determining in advance which branches were receiving inadequate air, and that subsequent calculations would then indicate the necessary corrections. The present program makes these corrections. Thus the mine manager can know immediately the consequences of changes to his system;

Jan 1, 1971

By W. Gundaker, F. C. Schwerer

Natural chromium-bearing spinels (chromites), which are used as refractory materials in basic steelmaking, are the only commercially important chromium ore and are also encountered as difficult-to-separate contaminants in ore deposits of potential economic value. Techniques for characterization and separation of ore materials frequently are dependent on the magnetic properties of the constituent minerals. An experimental program was initiated to explore the effects of temperature and of simple mechanical and thermal treatments on the static magnetic properties of several ore-grade natural chromites. Studies of the temperature dependence of the magnetic properties showed that the natural chromites, which are dilute in the magnetic ions Fe and Cr, order magnetically only at cryogenic temperatures. However, mechanical treatment in the form of crushing produces a magnetic component that is ordered at room temperature and that is of sufficient strength to alter magnetic-separation characteristics. The additional magnetic component apparently is associated with surface structures which develop during crushing and disappear after heating to above about 500°C. Preliminary studies indicate that this surface structure enhances the susceptibility of the chromite grain surfaces to gas reactions at moderate temperatures.

Jan 1, 1976

By F. F. Aplan, D. W. Fuerstenau

This chapter presents modern concepts of the flotation of nonmetallic minerals. In particular, it is concerned with such minerals as metal oxides, silicates, sulfates, carbonates, and halides. It is not the purpose to duplicate the two excellent, recent treatises by Gaudin l and by Sutherland and ark,^ but rather to expand their correlations of data, particularly in view of recent, ex- citing new experiments which are shedding new light on the principles of non- metallic flotation. Outstanding success has been achieved over the past 50 years in separating one sulfide from another or from the gangue constituents using a minimal amount of reagents. In contrast to this, selective flotation in nonmetallic systems is often difficult in that one class of compounds alone, the carboxylic acids, may float nearly the entire array of nonmetallic minerals under the appropriate conditions. Moreover, while lime, cyanide, sodium sulfide, and copper sulfate constitute the principal modifiers used to obtain selectivity among the various sulfides, the nonmetallic mineral flotation engineer is con- fronted with a vast array of modifying reagents. In sulfide and native-metal flotation, a strong chemical adsorptive bond is generally formed between the mineral and sulfhydral collector. In fact, re- cent radio-tracer studies show that below monolayer coverage as much as 98% of added mercaptan is adsorbed on the surface of gold.? Contrasted to this, Bloecher's data indicate that for the quartz-amine system only about 60% of the collector is adsorbed.4 This greater residual concentration in the solution results from weaker forces of adsorption in the quartz-amine system. In the flotation of nonmetallic oxide minerals, collector adsorption results from rather weak physical forces, primarily electrostatic attraction and van der Waals attraction between hydrocarbon chains. In the flotation of salt-type minerals, carboxylic acids are adsorbed both by physical and chemical forces. It is a study of the effect of the electrical forces superimposed on the chemical adsorptive forces that contributes most toward understanding nonmetallic mineral flotation. The need for quantification of general rules for the flotation of nonmetallic minerals is so great that Taggart 5 with unmasked sarcasm suggested that after trying anionic and cationic collectors:

Jan 1, 1962

By P. CHARTERIS A.

THE following scanty notes on the Roumanian oil-region may serve as an introduction to more detailed future study and description. The Roumauian oil-belt, follows the outer edge of the sweep of the Carpathian Mountains, and may, in a broad sense, be regarded as a prolongation of the Galician belt. It is distributed over a tract of country from 300 to 400 miles in length, with a width of from 15 to 20 miles, and is believed to cover an area of at least 20,000 hectares (59,420 acres). The Government claims that 16,000 to 17,000 hectares of its land is petroliferous. The primary deposits of petroleum are considered to be in the Padeogene (Oligocene) and the Neogene (the salines of the Miocene) formations. Most of the other repositories, especially those of Muntenie, are only secondary, the petroleum there having been introduced by the orogeneric movements which raised the Carpathian Mountains. The oil-field has been divided by the Roumanian survey into two regions, the Flysch and the Sub-Carpathian, as is shown in the accompanying sketch-map, Fig. 1.(p. 518). So far as is yet, known, practically all the seepages and .productive pits and wells are situated oil anticlinals. Those which outcrop in the Flysch region. (called Paleogene anticlinals), as indicated in the sketch-map, Fig. 1, are : Solontz, Middle Oligocene; Moineshti, Moineshti and Tagu-Ocna-beds of the Eocene.

Jul 1, 1906

By Persifor Frazer

The subject of Egypt, to use the words of perhaps the second of modern writers on the subject [Deodat. de Dolomieu, in Observations sur la Physique, etc., January, 1793, vol. xlii., pp. 41+, 108+; Abbe Rozier, J. A. Mongez, and J. C. Delametherie, Paris], is one which strongly excites our interest, and everything relating to it demands our respect. "Thus," he continues, "the Greeks appeared to the Romans," ..." thus Egypt appeared to the Greeks, and thus all three appear to us." This writer, in the three parts of the memoire given above, speaks of Norden as the modern pioneer of Egypt, and does not seem to have made original observations himself; nevertheless he seems to have rendered the same service to his authority that Playfair not very long afterward rendered Hutton. The limitations of a paper will permit little else than citations, but these are so numerous that, unless much compressed, they would supply a chapter of moderate size. A great deal of the very interesting memoire of Dolomieu is taken up with Quixotic tilts

Jan 1, 1883

By Richard S. McCaffery, Clarence H. Lorig, Joseph F. Oesterle, Ira N. Goff, Oscar O. Fritsche

This paper is the report of an investigation to determine the relations between the viscosity, temperature and composition of that portion of the silica-alumina-lime-magnesia system(l) within which blast-furnace slags are found. The work reported in this paper was made possible by a grant of funds from Engineering Foundation. It is a part of a project, the determination of properties and structure of iron blast-furnace slags, upon which the laboratories of the University of Wisconsin have been at work for some years. Three papers have been published, which have marked the progress of the study of iron blast-furnace slags at Wisconsin. The first,(2) Desul-furizing Power of Iron Blast-furnace Slags, discussed the solubility of sulfur in slags that contained no magnesia and discussed the viscosity. The second, (3) The Constitution of Iron Blast-furnace Slags, developed the constitutions of slags in the four-component system, silica-alumina-lime-magnesia, and pointed out an explanation of slag structure. Composition of Iron Blast-furnace Slags,(l) which was the third paper, gave a method of calculating the percentages of the various compounds present in slags when the amount of oxide was given and also an interpretation of quaternary equilibrium. Illustrations were given of the mineral composition of blast-furnace slags and some applications of composition results were shown. Because of their relative ease of measurement, the viscosity-temperature relation for slags was selected as a factor which would be useful in correlating the physical properties of molten slags to furnace operation. With this in mind the viscosities of slags whose compositions are in that portion of the quaternary system, silica-alumina-lime-magnesia, in which blast-furnace slags occur, were thoroughly investigated.

Jan 1, 1932

For the US coal industry, 1978 was a nightmarish recurrence of 1977 as the United Mine Workers strike cut into production during the first three months of 1978, followed by the strike against the Norfolk and Western Railway during the summer and early autumn. Coking coal production was floored by the one-two punch of environmental constraints on US coke ovens and competition from low-cost, high-quality imports. At the same time, US ex orts of coal fell to their lowest level since 1962. And in the face of all of this, steam coal consumption was sluggish as utilities burned huge amounts of oil to conserve coal stockpiles during the UMW strike. This was followed by decreased electrical demands due to mild summer weather in many parts of the country and dramatically improved availability of hydroelectric power.

Jan 5, 1979