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By Andrew Slifka, Pello Uranga, Douglas Glenn Stalheim

Structural steel final mechanical properties of strength and ductility are predominately generated by the final ferrite grain size/packet size and homogeneity of that ferrite grain size/packet size through the cross-sectional area. Forty to seventy percent of the strength components come from how fine the final cross-sectional ferrite grain size/packet size that can be produced.[1] All the ductility properties of structural steels for a given microstructure are predominately driven by how fine AND homogenous the final cross-sectional ferrite grain size/packet size can be refined.[2,3,4] One key ductility property of structural steels used in construction and energy transmission applications is fatigue. Both low and high cycle fatigue can be realized in these end applications, however, low cycle fatigue is typically the predominate mechanism. In construction applications the environment for fatigue is typically air, such as in wind towers or high-rise building construction. In energy applications, there is an interest in high pressure (5.5 – 21 MPa, 800-3000 psi) gaseous hydrogen as an alternative fuel source to fossil fuels. A project to study the effect of the cross-sectional grain size/homogeneity of a relatively pure polygonal ferrite microstructure on the fatigue performance in air and high-pressure gaseous hydrogen has been developed. This paper will discuss the project strategy, microstructure developed for the project and initial test results.

Oct 1, 2019

By José Aparecido Pereira

The customer asked for a 5” angle roll pass design. For this angle, in a normal pass design, a 160mm billet is required. For the production of this billet would be necessary a new 160mm mold for the Continuous Casting Machine, which produces 150mm billets, increasing the complexity of the melt shop. The rolling mill is designed to produce angles up to 4", technical information recommended the replacement of a gearbox because this process would generate torque up to 15% above nominal. An innovative roll pass design was done using 150mm billet using the Aparecido-W Method that cause a higher spread in the first three passes, thus reaching the desired leg length. As this method is not used in any other known rolling mill, a FES (Finite Element Simulation) and FEM (Finite Element Modeling) was done by a Research & Development center which demonstrated that the design was viable. From July, 2018, three tests were done being produced around 700 t of good quality products without difficulty of set up. The rolling mill team carried out this project at a very low cost and in record time of five months. The average torque of the motors was 36%, without overload for the equipment.

Oct 1, 2019

By Larissa Agrizzi Ronqueti

The effect of coiling temperature on selective oxidation behaviour of binary and ternary iron-based model alloys containing different contents of Si or Mn were investigated by SEM and SIMS. The experiments were carried out with a temperature ranging from 450 °C to 700 °C, under N2-5%H2 gas flow with a Dew Point of -3.3°C, for different durations. SEM images of binary iron-based model alloys revealed a decrease of grain boundary oxidation depth with increasing Silicon or Manganese content. At 530°C and 600°C SIMS results showed no Silicon diffusion toward surface, contrary to the results analyzed for Fe-x%Mn. Tests results and Wagner’s theory application (specific cases Fe-0.2%Si and Fe-0.5%Si) showed that grain boundary oxygen diffusion coefficient “DoGB” is almost 60 to 70 times faster than oxygen bulk diffusion coefficient. These results helped to broaden knowledge of single-element effects on grain boundary oxidation, in addition, will contribute of the future works in new steels with complex alloy compositions.

Aug 17, 2017

By Rodrigo Perito Cardoso

Low-temperature nitriding of stainless steels is applied to obtain wear resistant surfaces without losing its corrosion resistance. The treatment consists in introducing nitrogen into the steel surface avoiding chromium nitride precipitation. The corrosion resistance of martensitic stainless steels is expected to be improved if the treatment parameters are correctly selected. It can be related to ?Fe2-3N and a'N phase formation on the treated surface. In the present work the influence of the pretreatment and treatment temperature on corrosion resistance of plasma nitrided AISI 420 steel samples is studied. Annealed, as-quenched and 400ºC-tempered samples were nitrided at 300, 350, 400, 450 and 500°C, for 6 h at 600 V. The pressure was 3 Torr and the gas mixture was composed of 70%N2, 20%H2 and 10%Ar, at a gas flow rate of 3.34×106 Nm3s-1. Plasma was generated using a square-wave pulsed DC power supply and the sample temperature was controlled by the duty cycle. The modified layers were characterized by optical microscopy, X-ray diffraction and microhardness measurement. The corrosion resistance was studied by electrochemical characterization, by means of Open circuit potential and Anodic polarization curves. The maximum surface hardness was achieved at 400°C. This temperature seems to be near the limit temperature for low-temperature treatment aiming to improve or at least to keep unaltered the corrosion resistance in relation to that verified for non-treated steel samples. Results confirm that the pretreatment and treatment temperature significantly affects the corrosion resistance of the treated surface.

Aug 8, 2018

By Felipe Gianiselle

A liga de alumínio AA 7108 é uma liga endurecível por precipitação do sistema Al-Zn-Mg. Componentes da liga 7108 obtidos por extrusão têm sido crescentemente utilizados na fabricação de veículos de transporte terrestre. No presente trabalho foram estudadas as modificações microestruturais que ocorrem durante o tratamento térmico industrial de homogeneização, que precede a extrusão a quente desta liga. Foram utilizadas várias técnicas complementares de caracterização microestrutural, tais como microscopia óptica de luz polarizada, microscopia eletrônica de varredura eletrônica (MEV), espectroscopia de raios X por dispersão de energia (EDS), e medidas de dureza e de condutividade elétrica. Durante a homogeneização ocorreu dissolução parcial de compostos intermetálicos contendo Al, Fe, Zn, Mg e Si, enquanto as partículas de Al3(Zr,Ti) permaneceram inalteradas.

Oct 30, 2017

By Guilherme Corrêa Soares

The effects of temperature and strain rate on the mechanical behavior of a superelastic NiTi wire were investigated by uniaxial tensile testing. A universal testing machine with an attached heating chamber was used for the tensile tests. Temperature influence was studied through straining of samples until rupture at a fixed strain rate and temperatures of 25, 50, 75, 100, 125, 150, 175 and 200 °C. Strain rate effects were investigated by straining samples until rupture at room temperature and strain rates of 10-2, 5 x10-3 , 10-3, 5 x 10-4 and 10-4 s-1. The effects of temperature and strain rate on NiTi mechanical behavior were discussed in terms of critical stress to induce martensite and austenite yield strength, when applicable; upper plateau stress, transformation plateau length and ultimate plateau stress. It was found that increasing test temperature and strain rate shifted the stress-strain curve upwards, albeit temperature displayed a greater influence. Plateau length increased with temperature, but no significant changes were detected as a result of different strain rates.

Aug 17, 2017

By Shian Jia

Ultrasonic Stirring Technology (UST) is used in this study to manufacture Al-based nano-composites. Ultrasonic cavitation plays an important role in refining the microstructure, dispersing the nanoparticles and breaking up clusters of nanoparticles. In this paper, 6061/A356 alloys and Al2O3/SiC nanoparticles are used as the matrix alloys and the reinforcements, respectively. The nanoparticles were inserted into the molten alloy and dispersed by ultrasonic cavitation and acoustic streaming. A previously developed multiphase Computational Fluid Dynamics (CFD) model was used to study the cavitation and the nanodispersion phenomena during ultrasonic processing of these alloys. A comparison between the mechanical properties of the as-cast 6061 and 356 alloys and nano-composites has been performed.

Aug 16, 2017

By Aline Miranda Pessoa Passagli

No projeto da usina da Vallourec & Sumitomo Tubos do Brasil (VSB), em Jeceaba – MG está contemplado um circuito de preparação de carga para atender dois altos-fornos de 350 m³ de volume útil. Realizaram-se algumas etapas de testes com carga que possibilitaram a verificação da capacidade real dos equipamentos e a eficiência de peneiramento das matérias-primas. Foram também realizados testes de simulação da amostragem e ensaios físicos das matérias-primas. Nesta contribuição técnica descrevem-se os testes realizados, avaliação dos mesmos e melhorias implantadas.

Aug 1, 2018

By Luciano Gadonski

O Laminador Reversível a Frio 4-Hi de uma cadeira da CSN-PR não foi projetado para reduzir 100% da Bobina Quente Decapada (BQD), ficando sempre o trecho de miolo e capa fora da espessura de especificação. O descarte deste material é realizado na entrada da Linha de Galvanização Contínua (LGC) da CSN-PR, sendo o processo de descarte feito de forma manual baseado em critérios visuais, acarretando em diferentes resultados por turno de operação, assim como o descarte desnecessário de material bom como sucata na maioria dos casos. Este trabalho aborda o estudo e desenvolvimento de um projeto conduzido através da metodologia do Lean Seis Sigma, automatizando a decisão do descarte e atingindo à máxima utilização do material dentro da especificação de espessura, diminuindo assim o trecho fora de bitola descartado como sucata na entrada da LGC, o que afetava diretamente o indicador de Rendimento Metálico da linha.

Aug 17, 2017

By Rafael Fernandes Reis, Leonardo José Silva de Oliveira, Rodrigo Seara Martins

Alterações na cristalização dos pós fluxantes durante o processo, devido variações de composição química pelas reações metalúrgicas na interface metal/escória ou pela incorporação de compostos exógenos, afetam o fluxo de calor no molde de lingotamento contínuo. Um dos compostos importantes é o ZrO2, proveniente do desgaste da válvula submersa. A proposta do trabalho foi investigar o efeito deste composto, utilizando simulação laboratorial, na cristalização do pó fluxante e no fluxo de calor do molde. Os resultados demonstraram que quando há o incremento do teor de ZrO2 o fluxo de calor na região do menisco também se eleva. Tal efeito é crítico para formação de defeitos, uma vez que a região do menisco é crucial para a solidificação inicial do aço.

Oct 1, 2019

By Jose Maria Rodriguez-Ibabe, Ronaldo Antonio Neves Marques Barbosa, Douglas Glenn Stalheim

Major costs in the production of both flat and long commodity grade structural steel products include alloy, labor and energy. Flat and long commodity grade structural steels such as ASTM A36, ASTM A527Gr50, S235, S275, S355 and other equivalent world societal standards represent over 500 million annual tons worldwide. These simple commodity grades consist of a minimum of three base common alloying elements, carbon, manganese, silicon and then can be supplemented with microalloying elements of either vanadium or niobium. Since 2016 raw material costs for two of the five alloying elements in these commodity grade structural steels, FeMn and FeV, have risen significantly and/or have become volatile making it difficult to maintain stability in profitability for these commodity grades. For steel plants producing hundreds of thousands and in some cases over a million tons annually of these common structural steel grades because of the significant alloy cost increase for Mn and V alloy additions has squeezed profitability of these grades. These grades typically represent the base loading for cost controls in most all steel plants and hence a significant cost increase or volatility in two of the five elements used for these grades having a negative effect on overall production costs. However, with a proper strategy for alloy designs working in conjunction with the mills existing processing capabilities to achieve the desired end metallurgy/mechanical properties, alloy costs and operational efficiencies can be realized.

Oct 1, 2019

By John Malcolm Gray

Interest in X-80 linepipe steels emerged in the early 1980’s and it was first used in 1985 by Ruhr Gas [1]. The early steels were extensions of conventional Nb-V or Nb-Mo microalloyed X-70 steels but other alloying concepts emerged based on Nb-Mo-B alloying (NKSTAF [2] and ULCB [3]). The latter had acicular ferrite/bainitic microstructures and carbon contents below 0.05 percent. In parallel renewed interest developed in ultra low carbon (0.02 percent) higher niobium steels which had first been studied in 1962 [4]. Such steels exhibited excellent notch toughness when processed with high finish rolling temperatures (>950°C) which made them suitable for processing on weak, older rolling mills. With time such steels, designated “High Temperature Processed”, or HTP steels, were further optimized and produced in modern, very strong rolling mills due to their superior economy compared with traditional vanadium and molybdenum containing steels. The chronology of the HTP development is presented in the present paper. Full scale demonstration heats of a 0.06 percent carbon 0.10 percent niobium steel were produced by Bofors Steel Plant in 1972 and were converted from slabs to plates by nine different steel mills [5-7]. Commercial application in API Grade X-70 first occurred in Canada in 1974 [8,9] but the concept was only used sporadically after that until 1998 when it was applied for the API Grade X-70 Sour Service Cantarell Project [10] in Mexico. Soon thereafter, the El Paso Cheyenne Plains Project used a 0.05%C 0.095%Nb 0.27%Cr variant of the HTP steel [10-12]. Nowadays the HTP concept is being utilized for construction of approximately 6000 km of 48” OD x 18.4 mm X-80 per year in China. The metallurgical principles and history of the development are presented in details in this paper.

Aug 7, 2018

By Keli Vanessa Salvador Damin

O tratamento de austenitização é de fundamental importância para a qualidade do aço Hadfield, já que é o tratamento que garantirá a total austenitização do material. Dentre as variáveis que devem ser controladas estão à temperatura de tratamento e velocidade de resfriamento. O presente trabalho aborda um estudo de caso sobre o controle da temperatura dentro do forno de tratamento térmico bem como o comportamento da temperatura da água na piscina durante o resfriamento do material.

Aug 16, 2017

By Klaydison Silva, Maurício Curi Segato, Elves Matiolo, Neymayer Pereira Lima

Flotation is the main concentration process, has been applied with sucess for the removal of quartz on the iron ore industry aiming high quality concentrates. limiting the top size close to 0,300mm and the removal of slimes are fundamental for the efficiency of reverse flotation of quartz. The high consumption of reagents, leading to insufficient particle coverage, and increased foam stability, leading to the difficulty of removal of quartz particles, are the main deleterious effects of the presence of slimes. Recent characterization studies, together with the development of new collector of linear chain, allowed the obtaining of concentrate with SiO2 contents close to 3% with 94% of metallurgical recovery, based on pilot tests carried out on a sample flotation column of the Quadrilátero Ferrífero.

Oct 3, 2019

By Matheus Sampaio Modesto de Paula

O presente trabalho mostra o desenvolvimento de um produto, até então não comercializado pela CSN/PR, criado para o aproveitamento da capacidade ociosa de seu laminador reversível a frio. Historicamente, a produção do laminador era direcionada exclusivamente para o abastecimento de uma linha de galvanização contínua, mas trabalhos bem sucedidos para o aumento da produtividade do laminador resultaram em capacidade excedente do equipamento. Diante desse cenário, a comercialização de bobinas Full Hard se tornou uma opção viável para a abertura de mercado e aumento de competitividade, frente a atual pressão imposta por produtos importados. Visitas aos potenciais clientes foram necessárias para o levantamento das características importantes a seus processos produtivos e adequação dos parâmetros utilizados no laminador reversível. Atualmente o produto está homologado e sendo fornecido a clientes externos, e espera-se o aumento da carteira, dependendo apenas da evolução do mercado.

Jul 30, 2018

By Márcia Maria da Silva Monteiro Pereira

Durante o lingotamento contínuo de aço, partículas de ZrO2 adicionadas na escória de molde facilitam a nucleação heterogênea de cristais devido à sua limitada solubilidade. A adição de ZrO2 promove a cristalização da fase cuspidina, o que auxilia na redução da transferência horizontal de calor no molde, amenizando desta forma o problema das trincas longitudinais. Outro benefício da adição de ZrO2 em pós fluxantes é reduzir a taxa de desgaste da válvula submersa (SEN) na interface metal/escória; a erosão da SEN é um problema sério. Através de testes de laboratório e de testes industriais concluiu-se que a adição de ZrO2 em pós fluxantes reduz a taxa de transferência de calor horizontal no molde durante o lingotamento contínuo de aço, considerando os dois tipos de pós fluxantes que foram analisados no presente trabalho. Além disso, observou-se que a adição de ZrO2 reduz a taxa de desgaste da válvula submersa na interface metal/escória.

Aug 16, 2017

By Priscilla Pessin Coppo

The prevention of dental enamel wear has particular relevance for preventive and restorative purposes in dentistry. The wear damage can increase due to salivary disorders and/or parafunction (bruxism); antagonists incisal surfaces become flat and coincident. This study aims to investigate the wear behavior and the related mechanisms in sliding pairs of conformal incisal enamel, with similar values of hardness and fracture toughness, with different applied normal loads and lubricated conditions. Bovine incisors, under pin on flat configuration, were tested in two lubrication condition (dry or with natural saliva) and two applied normal loads (8 and 16 N). The worn surfaces were investigated by 3D profilometry and SEM. The analysis of worn surfaces indicated mechanisms of brittle fracture, but with different severities. Under a normal load of 16 N and dry condition, wear is controlled by a brittle process: microcracking with flake-like wear particles, which results in high friction coefficient (> 0.85), wear rate and wear volume. On the other hand, under a normal load of 8 N and natural saliva, wear took place in the interprismatic region, with consequent exposure of prisms and fracture in localized regions. In this case, the friction coefficient was 16% lower and the wear volume was one order of magnitude lower. Under 8 N and natural saliva, the wear was greater than in the dry condition, probably due to tribochemical reactions.

Jul 31, 2018

By Daniel Mapa Clemente

Processing of tin slags in reduction furnaces was studied in order to optimize tin recovery and reduce recirculation rates of slags containing thorium and uranium oxides. A theoretical approach considering a mass balance of the process was developed and adjusted by experimental results in order to predict the final slag composition. A metallic phase (FeSnSi) was discovered trapped in the slag due to high apparent viscosity, raising the FeO and SnO2 contents of the slag sample. This FeSnSi alloy is rich in tin and its recovery would help to reduce the slags recirculation. High contents of ZrO2 were found in the slag, restricting it from reaching complete fluid phase. Through an analysis of the slag in the CaO-FeOx-SiO2 and ZrO2-CaO-SiO2 phase systems it can be concluded that final slags should be modeled aiming fluid phase at working conditions and additions should be planned in order to control ZrO2 levels.

Oct 30, 2017

By Diogo de Oliveira Costa, Eduardo de Amorim Braga de Oliveira, Alan José Santos De Almeida, Deilton de Oliveira Sousa, Luciano Machado de Oliveira

A Ternium Brasil, localizada no Rio de Janeiro, possui dois Altos Fornos. Ambos iniciaram operação em 2010, Alto Forno 01 em 13/07/2010 e Alto Forno 02 em 06/12/2010. A GAD é uma unidade de processo que tem a finalidade de receber, classificar, dosar o carvão bruto, realizar sua moagem e secagem para o processo de injeção de carvão pulverizado em Alto Forno à coke. O trabalho apresenta o processo de melhoria, os recursos de gestão aplicados, a perspectiva a curto e longo prazo e o resultado alcançado até o momento.

Oct 1, 2019

By Fernando de Oliveira Boechat

As maiores pressões e temperaturas atualmente empregadas a fim de aumentar a produtividade de fornos de DRI têm resultado em um subproduto indesejado: o aumento da geração de clusters. Estes clusters prejudicam o fluxo da carga e a permeabilidade do leito. A fim de limitar o tamanho destes aglomerados o forno MIDREX dispõe de três conjuntos de quebradores localizados em diferentes posições do forno após a redução da carga. A interação entre clusters e esses quebradores, entretanto, pode também prejudicar o fluxo da carga e aumentar a geração de finos. O trabalho utilizou o método dos elementos discretos (DEM) para avaliar as energias e forças resultantes da interação entre os clusters formados e os quebradores. A descrição dos clusters foi realizada usando o bonded-particle model, disponível no EDEM. Simulações mostraram que a presença de clusters altera as forças e velocidades no entorno dos quebradores que tenderiam a aumentar a geração de finos no reator.

Aug 16, 2017