Performance Comparison of Dithiophosphate Collectors for Copper Ore Flotation - SME Annual Meeting 2026

The flotation performance of Sodium O, O-diisobutyl Di thiophosphate (referred to as reagent A) was compared with Aerophine 3418A (referred to as reagent B) for floating a complex copper ore grab sample (Ore A). Preliminary test results indicated a cumulative copper concentrate grade of 10.19% with a recovery of 86.31%, which was achieved with reagent A from a feed consisting of 5.32% Cu. The grade and recovery achieved using reagent B are 9.11% and 87.85%, respectively. A comparative analysis based on the preliminary test results indicated that reagent A’s performance is better than that of reagent B at lower concentrate grades, specifically below 12% Cu. However, the flotation performance is better for reagent B at higher concentrate grades (>12% Cu). A more detailed study was conducted to optimize the grade-recovery performances achievable from both reagents on a complex low-grade copper ore sample (Ore B) from Western USA. Test results indicated a copper concentrate with a grade of 5.5% Cu and 78.59% recovery was obtained with reagent A compared to 4.31% Cu and 62.04% recovery with reagent B from a feed consisting of around 0.25% Cu.